WO1997033946A2 - Feuille adhesive de calage et structure de calage - Google Patents

Feuille adhesive de calage et structure de calage Download PDF

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Publication number
WO1997033946A2
WO1997033946A2 PCT/US1997/003822 US9703822W WO9733946A2 WO 1997033946 A2 WO1997033946 A2 WO 1997033946A2 US 9703822 W US9703822 W US 9703822W WO 9733946 A2 WO9733946 A2 WO 9733946A2
Authority
WO
WIPO (PCT)
Prior art keywords
cushioning
adhesive
adhesive sheet
adherend
convex part
Prior art date
Application number
PCT/US1997/003822
Other languages
English (en)
Other versions
WO1997033946A3 (fr
Inventor
Michiru Hata
Original Assignee
Minnesota Mining And Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining And Manufacturing Company filed Critical Minnesota Mining And Manufacturing Company
Priority to AU22053/97A priority Critical patent/AU2205397A/en
Publication of WO1997033946A2 publication Critical patent/WO1997033946A2/fr
Publication of WO1997033946A3 publication Critical patent/WO1997033946A3/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/003—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor characterised by the choice of material
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/10—Adhesives in the form of films or foils without carriers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0097—Glues or adhesives, e.g. hot melts or thermofusible adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037—Other properties
    • B29K2995/0091—Damping, energy absorption
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00—Presence of (meth)acrylic polymer

Definitions

  • the present invention relates to an adhesive sheet. More particularly, the present invention relates to a cushioning adhesive sheet.
  • Adhesive sheets having an adhesive layer with a (regular) concave-convex pattern are disclosed in several references.
  • the height of the convex part (102) is comparatively small, for example, about 3 to 50 ⁇ m.
  • no airtight space is formed between the adherend and adhesive layer at the state where it is adhered on the adherend.
  • this adhesive tape it is suggested that good positionability can be obtained by adjusting the distance between convex parts (203) to 0.1 to 0.5 mm, because an adhesive surface (204) of the concave part present between convex parts does not contact the adherend. Similar to the above adhesive sheet, however, it is intended that the convex part (203) flows and becomes flat after the completion of positioning. Accordingly, it is impossible to form an airtight space between the adherend and the adhesive layer and impossible to maintain the airtight space while using at the state where the adhesive tape is adhered on the adherend.
  • Japanese Laid-Open Utility Model Publication No. 170848 there is suggested to provide a concave-convex pattern having a regular shape such as a network pattern for the purpose of increasing the adhesive area onto a non-flat adherend surface such as wall paper, etc.
  • a concave-convex pattern having a regular shape such as a network pattern
  • an adhesive tape comprising an substrate and an adhesive layer having a concave- convex pattern with a regular shape and an arrangement of 1 mm or less in pitch on the surface, the adhesive layer being provided on the substrate.
  • This concave- convex pattern has an extremely fine structure consisting of a convex part having a height of 20 ⁇ m or less and an concave part having a depth which is 10 to 90% of the height of the convex part.
  • the adhesive consists of a n-butyl acrylate-acrylic acid copolymer and a polyisocyanate compound, the amount of the isocyanate compound being 1 g based on 100 g of the copolymer. Since a concave-convex pattern of the adhesive layer of this adhesive tape is hardly deformed even after it was adhered on the adherend, the pattern can be visually recognized as literature, figure, symbol, etc. through the substrate. However, regarding such a concave-convex pattern, an extremely small airtight space can be formed, which results in no cushioning ability.
  • an article comprising an adhesive layer having a microstructured surface which can form a space having a volume of about 1 x 10 "3 mm 3 between the article and the adherend.
  • This adhesive layer is formed by UV polymerizing a monomer mixture comprising 90 parts of isooctyl acrylate, 10 parts of acrylic acid, and a comparatively small amount of a crosslinking agent (0.1 parts of 1,6-hexanediol diacrylate).
  • a tape comprising an adhesive layer having the same microstructured surface as that described above.
  • sheet materials made of a polymer material in which a plurality (i.e. many) airtight spaces having a comparatively large volume and concave-convex patterns are provided on almost the entire surface.
  • the sheet materials can absorb, subside or release an external action such as impact, vibration (including sound), heat, etc.
  • These materials are applied as cushioning materials (including cushioning materials and shock-absorbing materials), vibration-deadening materials (vibration-damping materials), soundproofing materials (sound-absorbing materials, sound insulating materials) or warming materials (insulating materials).
  • cushioning materials including cushioning materials and shock-absorbing materials
  • vibration-deadening materials vibration-deadening materials
  • soundproofing materials sound-absorbing materials, sound insulating materials
  • warming materials insulating materials.
  • they can have any one of these functions or two or more functions.
  • a insulating sheet for applying to glass comprising an insulating layer consisting of a cushioning material which encloses a plurality of independent partitions and a self- adhesive plastic film layer provided on at least one surface thereof.
  • the insulating layer is provided by laminating a first concave-convex film and a second flat film, and the closed partition in the sheet corresponds to the concave part.
  • the sheet is applied on an object such as an window through a self-adhesive film.
  • a soundproofing sheet of Japanese Laid-Open Patent Publication No. 3- 43241 teaches that energy passing through it is subsided and soundproofing performance is improved by laminating the first plate material superior in soundproofing properties having a concave-convex pattern on the whole surface thereof and the second plate material having excellent soundproofing properties, and by forming a hollow part between both materials.
  • a plurality of independent projecting chambers are formed close to each other on an embossed film and the other flat film is laminated/adhered so as to close an opening part of this projecting chamber, and a plurality of independent hollow chambers, each of which has a volume of about 14 to 7,000 mm 3 , is formed on the whole surface, thereby exhibiting an excellent insulating effect.
  • a solid-patterned decorative sheet of which the solid pattern can be visually recognized which is applied on glass through an adhesive.
  • This decorative sheet has a surface part comprising a pressed part at which the sheet completely adheres to the underlaid colored sheet and a figure thereon can be seen clearly and a non-pressed part at which the sheet does not adhere and a space is present, and a flat back surface part on which the pressed part is pressed, thereby, it has a sealed space in the sheet so that the concave-convex pattern is not easily broken by an external pressure.
  • the soundproofing insulator of Japanese Laid-Open Patent Publication No. 3-213334 is obtained by laminating glass wool as a porous material, a film of which one surface is applied a polyethylene resin (EV APG) added an ethylene vinyl acetate copolymer as a thermoplastic synthetic film, and a skin material of a soft polyurethane foam.
  • EV APG polyethylene resin
  • the insulator is easily processed into a complicated concave- convex shaped product, such as dashpanel, and is superior in cushioning properties.
  • a concave-convex synthetic resin sheet is laminated/adhered on the back surface of a foamed polyurethane resin sheet having a high extent of foaming to form a cushioning material, which is adhered appropriately on a floor base plate through a nonwoven fabric to improve a soundproofing effect.
  • This floor covering material is deposited on use so that the convex part is brought into contact with the adherend floor surface.
  • the cushioning sheet of Japanese Laid-Open Utility Model Publication No. 4-79105 has a plurality of projections for adhering to a backing, and a plurality of projections for supporting the sheet itself on an object.
  • an adhesive surface of the projection for adhering the backing is flat and, therefore, it can be adhered strongly on the backing.
  • the flat surface and a tip part of the projection for supporting the sheet are deposited so that they are not present in the same region, when they are viewed from a section in the thickness direction of the cushioning sheet. Therefore, the impact force applied to the backing is not transmitted linearly to the object.
  • the projection for supporting is not adhered on the surface of the object and is used so that no airtight space is formed between the object and the sheet.
  • the action (e.g. sound absorption, insulation, etc.) of these materials such as insulator are mainly derived from the constitution material and/or shape of the projection, and are not obtained by using an airtight space.
  • a vibration-deadening layer provided in the magnetic optical disc of Japanese Laid-Open Utility Model Publication No. 4-126369 consists of an adhesive layer having a thickness of at least about 25.4 ⁇ m, said adhesive layer being made of an UV crosslinked isooctyl acrylate-acrylic acid copolymer, and a polyester film having a thickness of at least about 102 ⁇ m.
  • This vibration-deadening layer inhibits vibration of the disc of at a frequency of at least 850 Hz.
  • the adhesive material and vibration-deadening layers are composed of an adhesive polymer material and have self-adhesiveness, but they are not for forming an airtight space between them and the applied adherend.
  • Several references disclose articles capable of forming an airtight space between themselves and the adherend.
  • Japanese Laid-Open Utility Model Publication No. 462520 there is disclosed an information recording optical medium obtained by laminating two recording mediums to each other with a double surface adhesive film.
  • the cushioning effect of the adhesive due to a concave-convex pattern which is provided on at least one adhesive layer of the double surface adhesive film can eliminate the deformation due to the warpage of the medium, effectively, even if a thermal action is applied externally.
  • the thickness of the adhesive layer is preferably about 10 to 50 ⁇ m and the volume of the airtight space to be formed by the adhesive layer is comparatively small, which results in low cushioning ability.
  • the air-enclosed cushioning material of Japanese Laid Open Utility Model Publication No. 5-70933 as shown in Fig. 7, consists of an adhesive film (302) and a non-adhesive film (307), both films being laminated to each other, and a second flat synthetic resin film (304) is laminated on a first synthetic resin film (301) having a plurality of concave parts at the adhesive film side through an adhesive film (305) so as to cover an opening part of a concave part (303), thereby forming an independent air chamber (306).
  • the cushioning material can be easily assembled at the site on use without heating for laminating synthetic resin films, and is not bulky at the time of preserving and transporting.
  • This adhesive film is made by mixing an adhesive with a thermoplastic resin such as polyacryls, etc.
  • a non-adhesive film (307) corresponding to the concave- convex pattern of the adhesive film (e.g. crosslinking of adhesive film, its modulus).
  • the 70933 discloses a cushioning material which can form an airtight space having a comparatively large size between it and an applied adherend (in this case, the second - 7 - flat synthetic resin film (304) corresponds to it).
  • an applied adherend in this case, the second - 7 - flat synthetic resin film (304) corresponds to it.
  • a non-adhesive film processed to follow the shape of the space is required in order to stably maintain the airtight space.
  • An object of the present invention is to provide a cushioning adhesive sheet which forms an airtight space of comparatively large volume on an adherend on the place by laminating it, and maintains the airtight space stably with time so that the cushioning ability does not deteriorated with time. More particularly, the present invention provides a cushioning adhesive sheet, comprising:
  • a convex part comprising a crosslinked adhesive polymer and having an adhesive surface which is provided on at least one major surface of the base part so as to enclose a plurality of concave parts having a geometric shape; wherein a volume of the concave part is 0.8 to 600 mm 3 , a modulus G of the convex part measured according to a dynamic viscoelasticity measuring method at a frequency of 1 rad/second under shear mode at 25°C is within a range of 5 x 10 5 to 4 x 10 6 dynes/cm 2 , and a decrease of logio G within a range of 25 to 125°C is less than 1.0.
  • a cushioning structure having an airtight space consisting of an adherend surface and an inner surface of the concave part is provided by adhering the above cushioning adhesive sheet on a surface of the adherend.
  • Fig. 1(a) is a perspective view illustrating one embodiment of the cushioning adhesive sheet of the present invention
  • Fig. 1(b) is a sectional view taken in the line IT of Fig. 1(a).
  • Fig. 2(a) and Fig. 2(b) are sectional views illustrating one embodiment of the cushioning structure of the present invention, respectively.
  • Fig. 3(a) is a sectional view illustrating one embodiment of the cushioning structure of the present invention
  • Fig. 3(b) is a penetrative top view of Fig. 3(a).
  • Fig. 4(a) and Fig. 4(b) are schematic sectional views illustrating the process for producing the cushioning adhesive sheet of the present invention.
  • Fig. 5 is a perspective view illustrating one embodiment of a conventional adhesive sheet.
  • Fig. 6 is a sectional view illustrating one embodiment of a conventional adhesive sheet.
  • Fig. 7 is a sectional view illustrating one embodiment of a conventional cushioning sheet.
  • Base part (10) may be composed of the same material as that of the convex part (11) containing a crosslinked adhesive polymer and formed integrally with the convex part (11).
  • the base part ( 10) may also be composed of a material which is different from that of the convex part (11), i.e. material (e.g. plastic film, metal foil, etc.) capable of fixing the convex part (11) containing the crosslinked adhesive polymer, and the base part serves as a substrate of the convex part (11).
  • the thickness of the base part (10) is generally 0.05 to 3 mm, preferably 0.1 to 1 mm, more preferably 0.2 to 0.7 mm.
  • the thickness of the base part is less than 0.05 mm, the maintaining performance of the airtight space (41) is likely to be deteriorated.
  • the cushioning adhesive sheet becomes bulky, which results in deterioration of handling and appearance after application.
  • the cushioning adhesive sheet of the present invention is superior in cushioning ability even if it is comparatively thin, because the airtight space (41 ) has high airtightness and the convex part (1 1) has a predetermined modulus.
  • a non- adhesive flexible substrate (6) can be laminated on the plane major surface (5) on which the convex part is not provided.
  • the convex part (11) can take any shape unless the performance for maintaining the airtight space (41) is deteriorated.
  • the sectional shape thereof may be generally square, rectangular and trapezoidal, and a wall-like shape enclosing the concave part (4).
  • the shape has an adhesive surface (12) with a sufficient area and is superior in processability.
  • the sectional shape of the convex part (1 1) is preferably rectangular having a width of 0.1 to 5 mm, particularly 0.5 to 3 mm. Otherwise, the convex part (1 1) is a trapezoid having an upside of 0.1 to 5 mm, particularly 0.2 to 3 mm, and a base of 0.2 to 10 mm, particularly 0.5 to 7 mm.
  • the convex part (11) can be provided on an end edge of the base part (10) to form an airtight space on the whole surface when applying on an adherend. Otherwise, the convex part is not formed on an end edge of the base part (10) to remain a handgrip which makes it easy to peel off.
  • the modulus G of the convex part (1 1) when measured at a frequency of 1 rad/second under shear mode according to a dynamic viscoelasticity measuring method is 5 x 10 5 to 4 x 10 6 dynes/cm 2 at 25°C, preferably 6 x 10 5 to 2 x 10 6 dynes/cm 2 , more preferably 6.1 x 10 5 to 1.5 x 10 6 dynes/cm 2 .
  • a decrease of logioG within a range of 25 to 125°C is less than 1.0, preferably less than 0.5, more preferably less than 0.4.
  • the convex part (1 1) plastically flows with time after the cushioning adhesive sheet was adhered on the adherend surface (31), thereby it becomes impossible to form the airtight space (41).
  • the modulus G exceeds 4 x 10 6 dynes/cm 2 , adhesiveness of the convex part ( 1 1 ) is deteriorated, and airtightness at the interface between the cushioning adhesive sheet (1) and adherend surface (31) is not obtained.
  • the modulus G of the convex part (11) at 25 °C is preferably within a range of 6 x 10 5 to 2 x 10 6 dynes/cm 2 . When it is not within this range, the remarkable improvement of the cushioning performance can not be expected.
  • the concave part (4) forms a space enclosed by the surface of the base part and side of the convex part.
  • Each concave part has a volume within a range of 0.8 to 600 mm 3 , preferably 0.9 to 150 mm 3 , more preferably 1.0 to 10 mm 3 .
  • the volume of the concave part is smaller than 1 mm 3 , the cushioning ability of the cushioning adhesive sheet is deteriorated.
  • the concave part (4) plastically flows with time and, at the same time, the cushioning action is also deteriorated.
  • the concave part (4) is uniformly arranged on the almost all of the surface of the major surface (2) of the base part (10). Thereby, the airtight space- maintaining performance of the concave part (4) is enhanced.
  • the concave part (4) can be regularly arranged, for example, in a lattice pattern or a cross pattern
  • the number of concave parts (4) per unit area is generally 1 to 50/cm , preferably 2 to 25/cm .
  • the cushioning ability is likely to be deteriorated.
  • it exceeds 25/cm 2 the cushioning ability is likely to be deteriorated because the volume of the concave part (4) becomes small.
  • the depth of the concave part (4) that is, the height of the convex part (1 1) is generally 0.5 to 10 mm, preferably 0.7 to 2 mm. When this depth is smaller than 0.5 mm, no effective cushioning action is likely to be obtained. On the other hand, when it exceeds 10 mm, the airtight space-maintaining performance is likely to be deteriorated.
  • the concave part (4) can take various shapes. Examples thereof include geometric solids such as cylinder, prism, pyramid, cone, truncated cone, near-sphere, near-ellipsoid, etc.
  • the concave part (4) can also take a composite shape of one or more sorts selected from the group consisting of these shapes.
  • a groups of spaces consisting of a plurality of concave parts (4) is visually recognized as a sort of a solid pattern by an observer. Accordingly, the above space groups can take any form such as geometric arrangement pattern, literature, numeral, figure, indication of symbol, etc. so as to impart a design unless the effect of the present invention is deteriorated.
  • the convex part (1 1) comprising the crosslinked adhesive polymer adheres firmly on the adherend surface (31 ) and seals air of a predetermined volume in the interior and maintains the airtight space (41). Air in the interior of the airtight space (41) may leak from an adhesive interface between (i) the convex part (11) and adherend surface (31), or may leak through (ii) the convex part (11).
  • the crosslinked adhesive polymer is superior in adhesiveness, and improves the shape retention of the convex part (1 1) and barrier properties (impervious properties) of air, i.e. improves airtightness.
  • the storage modulus controlled within a predetermined range and its decrease proportion imparts a suitable cohesive force to the convex part (1 1) and enhances the barrier properties thereof.
  • the crosslinked adhesive polymer is a crosslinked acrylic polymer formed by polymerizing a monomer component substantially comprising alkyl (meth)acrylates, ethylenically unsaturated acids and a crosslinking agent monomer having two or more (meth)acryl groups in the molecule.
  • the crosslinked acrylic polymer is particularly superior in airtightness. Such an airtightness is particularly enhanced when the amount of the above crosslinking agent monomer is within a range of 0.5 to 5% by weight, based on the total amount of the monomer component.
  • a particularly preferred amount of the crosslinking agent monomer is within a range of 0.7 to 2% by weight.
  • isooctyl acrylate is preferred. Because isooctyl acrylate imparts adhesiveness to the adhesive surface (12) of the convex part (1 1), effectively, and it makes easy the applying operation of the cushioning adhesive sheet.
  • alkyl (meth)acrylate there can be used one or more sorts selected from alkyl acrylates or methacrylates, of which alkyl includes methyl, ethyl, isopropyl, butyl, isobutyl, isooctyl, 2-methylbutyl, 2-ethylhexyl, lauryl, stearyl, cyclohexyl, isobornyl, 2-hydroxyethyl, 2-hydroxypropyl, 3-chloro-2-hydroxypropyl, hydroxyethyoxy ethyl, methoxyethyl, ethoxyethyl, dimethylaminoethyl, diethylaminoethyl and glycidyl.
  • alkyl includes methyl, ethyl, isopropyl, butyl, isobutyl, isooctyl, 2-methylbutyl, 2-ethylhexyl, lauryl, stearyl,
  • (meth)acrylic acid is preferred.
  • (meth)acrylic acid effectively enhances the cohesive force of the adhesive polymer, and improves the shape retention of the convex part (1 1), thereby airtightness of the airtight space is enhanced, effectively.
  • the other ethylenically unsaturated acid there can be used one or more sorts selected from ⁇ -hydroxyethyl carboxylic acid, itaconic acid, maleic acid and fumaric acid.
  • the formulation proportion of the alkyl (meth)acrylate (A) to ethylenically unsaturated acid (E) is selected so that the modulus of the convex part (11) becomes a value within a predetermined range, preferably within a range of 80:20 to 99: 1
  • crosslinking agent monomer having two or more
  • 1 ,6-hexanediol diacrylate is preferred.
  • the 1,6- hexanediol diacrylate effectively enhances crosslink density of the adhesive polymer and improves adhesiveness, air barrier properties and shape retention with good balance.
  • the crosslinked adhesive polymer can be obtained by polymerizing a monomer component containing the above components as the starting material by using heat or radiation (e.g. ultraviolet ray, electron beam, etc.).
  • the monomer component is polymerized or crosslinked while contacting with a mold having a predetermined geometric structure to form a cushioning adhesive sheet (1).
  • a preliminary component which contains a monomer component but does not contain a crosslinking agent monomer is partially polymerized, previously, and a mixture of the viscosity-adjusted partially polymerized syrup and the crosslinking agent monomer can be polymerized and crosslinked while contacting with a mold.
  • the viscosity of the syrup is generally 100 to 100,000 cps.
  • polyisoprene a natural rubber
  • styren- butadiene rubber butyl rubber, nitrile rubber, silicone rubber, neoprene, polyisobutylene
  • polyvinyl ethers such as polyvinyl butyl ether, polyurethane, polyvinyl acetate, ethylene-vinyl acetate copolymer, poly-alpha-olefin and the like may be used as the adhesive polymer.
  • the adhesive polymer may be used alone or in combination thereof.
  • the adhesive sheet which is comprised of the adhesive polymer and the unreacted crosslinking agent is prepared and adhered to the adherend, thereafter the crosslinking reaction is conducted.
  • a curable resin may be employed together with the adhesive polymer unless it does not fail the technical effects of the present invention.
  • a thermoplastic resin which is non-tacky at ambient temperature may be employed together with the adhesive polymer unless it does not fail the technical effects of the present invention. If the convex part is composed of the adhesive polymer and the thermoplastic resin, and do not have sufficient adhesiveness, the convex part may be heated and tackified in order to adhere the adherend.
  • the peel strength measured at 25°C when the cushioning adhesive sheet (1) is peeled off from the adherend surface (31 ) is preferably within a range of 20 to 2,500 g/25 mm, particularly within a range of 350 to 2,000 g/25 mm.
  • the peel strength is less than 20 g/25 mm, airtightness of the space (41) is likely to be deteriorated with time when it is applied on the vertical surface of the adherend.
  • it exceeds 2,500 g/25 mm it becomes difficult to peel off the cushioning adhesive sheet (1) immediately after applying. It also becomes difficult to position for applying, which results in deterioration of operating properties.
  • it is advantageous that the cushioning adhesive sheet which was once used can be used again by applying on another adherend.
  • the cushioning material comprising an adhesive surface (12) having re-peelablity, which can be used repeatedly, is useful in view of resources saving. From such a point of view, particularly preferred peel strength is 50 to 1 ,000 g/25 mm.
  • the present cushioning adhesive sheet has a base part and a plurality of convex parts provided on the major surface of the base part so as to enclose a plurality of concave parts, said convex parts containing a crosslinked adhesive polymer, and a polymer of the adhesive polymer of the convex part being crosslinked and the convex part having a predetermined modulus.
  • the concave part is designed so that the airtight space consisting of the concave part and adherend surface having a predetermined volume at the part where it is adhered.
  • the fact exhibits a cushioning action, that is, it releases an impact force applied from the plane major surface of the base part on which no convex part is provided, before the impact transfers to the adherend.
  • the cushioning adhesive sheet (1) of the present invention is used as follows.
  • the cushioning adhesive sheet (1) is disposed so that the adhesive surface (12) of the convex part (1 1) contacts with the adherend surface (31), and the cushioning adhesive sheet is softly pressed with hands, press roller, etc. from the side of the plane major surface (5) of the base part (10) on which no convex part is provided to adhere the adhesive surface (12) on the adherend surface (31).
  • the convex part (1 1) contains an adhesive polymer and, therefore, it can adhere on the adherend surface of the cushioning adhesive sheet (1) by the same light press operation as that of a normal pressure-sensitive adhesive sheet.
  • the adhered cushioning adhesive sheet (1) forms a plurality of independent airtight spaces (41) which is enclosed between the concave part (4) and adherend surface (31 ).
  • the modulus (measured value G) of the convex part (1 1) at 25°C is not less than 5 x 10 5 dynes/cm 2 , that the decrease of log ⁇ 0 G within a range of 25 to 125°C is less than 1.0 and that the airtight space (41) is retained so as not to be broken by a constant pneumatic pressure, cooperate and maintain the shape and volume of the airtight space (41).
  • the procedure for pressing can be carried out under the pressure by which the airtight space (41) is not broken, e.g. 10 kPa or less, by the procedure.
  • the cushioning adhesive sheet (1) may have a flexible substrate (6) fixed on the plane major surface (5) of the base part (10) on which no convex part is provided.
  • the form in which the cushioning adhesive sheet (1) is adhered on the adherend surface (31 ) is useful as a cushioning structure which releases an impact force applied from the side of the plane major surface (5) of the base part (10) on which no convex part is provided before the impact force transfers to the adherend
  • the present invention provides an utilization form of the self- adhesive cushioning material in which the cushioning adhesive sheet (1) is used for adhering on the adherend surface (31 ).
  • the flexible substrate (6) is useful to make the handling of the cushioning adhesive sheet (1) easy when the cushioning adhesive sheet (1) has a comparatively high flexibility and the plane major surface (5) on which no convex part is provided has adhesiveness.
  • the flexible substrate (6) there can be used a polyester film, a polyvinyl chloride (and the polymer thereof) film, a polycarbonate film, a polyamide film, a polyolefin (and the copolymer thereof) film, an acrylic copolymer film etc.
  • the thickness of the flexible substrate (6) is generally within a range of 10 to 200 ⁇ m.
  • an adhesion promoting treatment such as corona treatment, primer treatment, etc. can be carried out at the interface between the plane major surface (5) of the base part (10) on which the convex part is not provided and flexible substrate (6).
  • two cushioning adhesive sheets can be laminated to each other to form a cushioning material having a multi-layer structure.
  • it has an airtight chamber (44) in the interior of the cushioning material, in addition to the airtight space (41).
  • a provided wall (13) enclosing the airtight chamber (44) is preferably adhered on the base part (10) of the lower cushioning adhesive sheet at the position which generally corresponds to the center of the airtight space (41 ), in order to enhance the cushioning effect.
  • a material having smooth and flat surface having no void, which can form an effective airtight space at the time of applying this adhesive sheet may be employed.
  • the material include glass, ceramic (china), plastic, metal, etc.
  • the cushioning adhesive sheet of the present invention is useful for a packing material for preventing the adherend from breaking during transferring, or the surface protective material for preventing the adherend surface from damaging, as the embodiment utilizing the excellent cushioning ability thereof. It is particularly suitable for protective applications such as window, top plate of desk, lens, dish, cup, vase, etc. Because the cushioning adhesive sheet of the present invention is superior in adhesiveness to glass and china, and the airtight space is easily formed and maintained thereon.
  • the cushioning adhesive sheet of the present invention may be used even when the peel strength from the adherend is very small (i.e. 180 degree peel strength is near zero), provided it has the retaining force of within a predetermined range. For example, when a plurality of glass plates are stacked and packed, a failure due to the contact between glass plates can be prevented by interposing the cushioning adhesive sheet between two glass plates. A high peel strength is not also necessarily when it is used as the surface protective material of the top plate of the glass plate disposed horizontally.
  • the retaining force in this case is measured as follows. Firstly, a cushioning adhesive sheet (1) having a size of 25 mm x 50 mm is placed on the surface of a green plate glass deposited vertically in the atmosphere (temperature: 25°C, humidity: 60 %RH) to adhere the whole adhesive surface (12) thereon. The time required for peeling off at any position of the adhesive surface ( 12) by the weight of itself is measured.
  • the retaining force of the cushioning adhesive sheet of the present invention is preferably not less than 10 minutes, particularly not less than 600 minutes.
  • the cushioning adhesive sheet (1) is produced as follows.
  • a preliminary component comprising a monomer component containing isooctyl acrylate and acrylic acid in a predetermined proportion, and a photoinitiator component is charged in a stirring device, and is subjected to ultraviolet polymerization with stirring.
  • a partial polymerization is carried out so that the viscosity becomes a value within a range of 100 to 100,000 cps to prepare a partially polymerized syrup.
  • a predetermined amount of a crosslinking agent monomer, 1 ,6-hexanediol diacrylate, and an additional photoinitiator are added, and the resultant is mixed uniformly to prepare a precursor composition of the cushioning adhesive sheet.
  • the interior of the stirring device is generally purged with an inert gas such as nitrogen gas, etc. at the time of photopolymerization.
  • Such a polymerization reaction generally does not include a heating step.
  • a mold having a predetermined geometric structure for molding a cushioning adhesive sheet is prepared as follows.
  • a positive mold (80) having a predetermined geometric structure of a comparatively hard plastic is prepared.
  • the plastic there can be used acrylics, polycarbonates, etc.
  • a detachable resin is brought into contact with this positive mold and those obtained by curing the detachable resin at normal temperature are detached from the positive mold (80) to form a negative mold (81).
  • the positive mold include "Acrisunday plate (trade name)” manufactured by Acrisunday Co., Ltd.
  • the peelable resin include templating silicone SE9555 manufactured by Toray Dow Corning Co., Ltd.
  • a precursor composition (82) of the above cushioning adhesive sheet is brought into contact with the negative mold (81) and the composition (82) is covered with a transparent film.
  • the negative mold (81) and film (83) are disposed at a predetermined distance so that the part (822) which will become a base part of the cushioning adhesive sheet and the part (821) which will become a convex part are formed, when the composition (82) is polymerized and crosslinked (i.e. curing reaction).
  • ultraviolet ray is irradiated on the film (83) to complete the curing reaction and, after the negative mold (81) and film (83) are removed, a cushioning adhesive sheet of a cured article of the composition (82) is obtained.
  • the transparent film (83) is used for the purpose of barring oxygen and making flat the plane major surface (5) of the base part (10) on which the convex part is not provided. Such a transparent film (83) can also be used as the flexible substrate (6) fixed on the base part (10), as described above.
  • a flexible plastic film such as polyester (PET) is generally used.
  • PET polyester
  • the following method is used in order to determine the thickness of the base part.
  • an excess amount of the precursor composition (82) is poured into the negative mold (81), the film (83) is covered thereon to form a precursor- containing laminate (8). Then, the laminate (8) is passed through a gap of a knife coater having the gap fixed in a predetermined distance, and the excess precursor composition (82) is discharged from the edge part to adjust the thickness and flatness of the part (822) which will become the base part.
  • the wavelength of ultraviolet ray is generally 300 to 400 nm, and the irradiation intensity is within a range of 100 to 1,000 J/cm 2 .
  • the above positive mold can also be formed by carving a glass plate having a sufficient thickness using a sanding method.
  • the negative mold there can be used a metal mold of which molding surface is treated with fluorine resin (e.g. TeflonTM).
  • the cushioning adhesive sheet (1) may contain various additives which are used in a normal pressure-sensitive adhesive unless the effect of the present invention is deteriorated.
  • the additive include tackifiers, plasticizers, ultraviolet absorbers, antioxidants, polymerization initiators (e.g. those to be added at the production of adhesive polymer, such as photoinitiators, etc.), colorants, fillers, etc. These additives are included in the base part which is integrated with the convex part and/or the concave part, together with the adhesive polymer.
  • the cushioning adhesive sheet of the present invention forms an airtight space between the sheet and adherend, and maintains the airtight space even after applying. Therefore, it can also be utilized for forming a material selected from the group consisting of a vibration-deadening material, a soundproofing material and an insulating material, and an adhered composite material having a plurality of the functions.
  • the airtight space forms a decorative solid pattern
  • it can also be utilized for forming a material of a decorative sheet.
  • the convex part (11) may be coated with a flexible film, and the adhesive surface (12) may be adhered to the film, thereby, the airtight space may be enclosed as a cellular chamber from the beginning.
  • the adhesive interface between the convex part of the cushioning adhesive sheet and flexible film is sealed, the convex part is crosslinked and has a suitable cohesive force (storage modulus controlled within a predetermined range and its decrease proportion), thereby, leaking of the air from the cellular chamber is prevented. Accordingly, the cellular chamber-enclosing sheet formed from the cushioning adhesive sheet of the present invention can maintain the effect for a long period of time.
  • the cushioning adhesive sheet of the present invention may be employed as a packing material.
  • a body to be packed is a thin rectangular body such as a case of floppy disks
  • the body may be sandwiched between two sheets of the adhesive sheet having a size larger than the major surface of the body, and an adhesive surface of the adhesive sheet was adhered to the surface.
  • a blank part of the adhesive sheet, which was protruded around an edge of the body should not be adhered to a side surface of the body, but the upper blank part and the lower blank part should be adhered to each other to pack the body.
  • the packing procedure is convenient, because additional adhesive means is not required for packing.
  • An adhesive surface of the blank part may be deformed, thereby, adhesiveness of the blank part may be controlled.
  • a pulp materials such as a paper may be provided on a plane surface of the adhesive sheet of the present invention as the support.
  • the modulus G of the convex part (1 1) is a storage modulus measured under the above described conditions, using a dynamic analyzer "Model No.: RDA II" manufactured by Rheometrix Co. Further, a sample holder used for the measurement was a parallel plate having a diameter of 7.9 mm.
  • a change (decrease) in logioG is a value calculated from a fluctuation based on G at 25°C, which was read from a viscoelastic spectrum obtained within a rage of 25 to 125°C.
  • the sheet was applied to an adherend (a glass slide), and if an airtight space corresponding to the concave part of the cushioning adhesive sheet was not formed, the sheet was evaluated as "NG”, and if an airtight space was formed, the sheet was evaluated as "OK".
  • the concave part (4) has a shape lacking in one bottom surface (or side surface) of geometric solids such as truncated pyramid, rectangular parallelopipedon, etc., it can be calculated from its geometric size.
  • the cushioning adhesive sheet was applied on one surface of a breakable test piece (glass slide) so as to cover almost all of the surface, and the resultant was employed as a sample. At this time, the applying pressure should be constant. In order to make the pressure constant, a press roller (2 kg) was used and the roller was once moved back and forth on the cushioning adhesive sheet placed on the test piece.
  • the slide glass was a "MICRO SLIDE GLASS (trade name), No. 1" manufactured by Matustomi Glass Industries Co. Ltd. and had a size of 76 mm in length x 26 mm in width x 1 mm in thickness.
  • the sample made as described above was placed on a iron plate through a paper towel "FUJI PAPI (trade name)" manufactured by Taiyo Shigyo Co., Ltd., so that a surface of the sample, on which the cushioning adhesive sheet was applied, look upward, and an iron ball having a predetermined weight was dropped from a predetermined height.
  • a test was started from the height of 30 cm using an iron ball having a diameter of 15 mm and a weight of 30 g.
  • a falling ball impact test was carried out according to the same manner as that described above except for changing the height to 40 cm. Thereafter, the height was increased by 10 cm until the test piece was broken and the height which was 10 cm smaller than the height where the breakage arose was taken as an evaluated value (cm) (test conditions: temperature; 25°C, humidity; 60%).
  • a partially polymerized syrup was prepared by UV polymerizing a preliminary component comprising a monomer component of 90 parts by weight of isooctyl acrylate and 10 parts by weight of acrylic acid and 0.1 parts by weight of azobisisobutyronitrile (AIBN) as the photoinitiator.
  • AIBN azobisisobutyronitrile
  • 1 part by weight of 1 ,6-hexanediol diacrylate as the crosslinking agent monomer and 0.2 parts by weight of AIBN as the additional photoinitiator were added and the result was uniformly mixed to prepare a precursor composition of a cushioning adhesive sheet.
  • a cushioning adhesive sheet was prepared by ultraviolet curing according to the method shown in Fig. 4, using "Acrisunday plate (trade name), Model No.
  • a PET film “Lumilar 50T (thickness, 50 ⁇ m)” manufactured by Toray Co., Ltd. was used and, it was fixed to the base part after forming the cushioning adhesive sheet and utilized as the flexible substrate.
  • the shape of the concave part of the cushioning adhesive sheet was a truncated pyramid (width of adhesive surface side is wide) and its volume was 6 mm .
  • the width and length of the adhesive surface side of the convex part were 1 mm and 3 mm, respectively, and the thickness of the base part was 0.5 mm.
  • the concave part was arranged in the proportion of 9/cm 2 (interior of horizontal surface, lattice pattern). Modulus, decrease of logioG within a range of 25 to 125°C, shape imparting properties, shape retention, cushioning ability and peel strength of the resulting cushioning adhesive sheet were evaluated. The results are shown in Table 1.
  • Example 1 According to the same manner as that described in Example 1 except for changing the amount of 1 ,6-hexanediol diacrylate as the crosslinking agent monomer as shown in Table 1 , a cushioning adhesive sheet was obtained and evaluated. The results are shown in Tables 1 and 2. In Examples 5 and 6, the 180 degree peel strength was nearly zero, but the sheet had enough tack to maintain the airtight space. Accordingly, the cushioning adhesive sheet did not shift from the position where the glass slide was adhered even if the sample was transported after applying.
  • the retaining force of the sheets of Examples 5 and 6 was measured by the above-described method. As a result, they were 10 minutes and 12 hours, respectively. Further, the retaining force of the sheets of Examples 1 and 4 showed not less than 48 hours (measurement was stopped within 48 hours).
  • Example 2 According to the same manner as that described in Example 1 except for using as the positive mold those obtained by carving a glass having a thickness of about 5 mm according to a sanding method and forming a concave-convex pattern so that the concave part of the cushioning adhesive sheet made from the mold becomes a rectangle having a predetermined size, a cushioning adhesive sheet was obtained and evaluated.
  • the results are shown in Tables 2 and 3.
  • the size of the space of the concave part of the respective Examples is as follows.
  • Example 7 The top surface (bottom surface) is a square having a side of 1 mm and the height is 1 mm.
  • Example 8 The top surface (bottom surface) is a square having a side of 2 mm and the height is 1 mm.
  • Example 9 The top surface (bottom surface) is a square having a side of 3 mm and the height is 1 mm.
  • Example 10 The top surface (bottom surface) is a square having a side of 5 mm and the height is 1 mm.
  • Example 1 1 The top surface (bottom surface) is a square having a side of 10 mm and the height is 0.8 mm.
  • Example 12 The top surface (bottom surface) is a square having a side of 10 mm and the height is 1.5 mm.
  • the width of the convex part was 1 mm and the thickness of the base part was 0.2 mm.
  • a cushioning adhesive sheet (containing no flexible substrate) having a concave part of which top surface (bottom surface) is a square having a side of 3 mm (height: 0.5 mm) and a base part having a thickness of 0.5 mm and that obtained by fixing a PET film (flexible substrate) to the base part of the same cushioning adhesive sheet were separately prepared and they were laminated to each other by a self adhesive force to obtain a composite cushioning adhesive sheet. According to the same manner as that described in Example 1, the composite was evaluated. The results are shown in Table 3. Comparative Example 3
  • Example 2 According to the same manner as that described in Example 1 except for molding into a flat sheet (no concave-convex part) having a thickness of 1.2 mm, an adhesive sheet was obtained and evaluated.
  • the cushioning ability was 30 cm, and the 180 degree peel strength was 1 150 g/25 mm.
  • SOLF has a structure comprising a plurality of prism projections in which a plurality of trigonal prisms having an isosceles triangle (height: about 0.18 mm, base: about 0.36 mm) as the bottom surface are horizontally disposed in parallel with each other.
  • the space of the concave part between adjacent prisms is composed of the same trigonal prism as that described above. Accordingly, the cushioning adhesive sheet can form only a space having an opening on the bottom surface side of the trigonal prism (no airtightness).
  • the cushioning ability was 30 cm, and the 180 degree peel strength was 50 g/25 mm.
  • the cushioning adhesive sheet of Example 1 was formed so that it has an area of 8 cm x 10 cm.
  • the sheet was applied on the above PET film "Lumilar 50T" manufactured by Toray Co., Ltd. so that the convex part side faced to the PET film to prepare a cellular chamber enclosing sheet.
  • This sheet was placed on a flat laboratory-table and allowed to stand under the condition of an environmental temperature of 25°C and a relative humidity of 60% RH for 7 days at the state where a static load (4 kg/8 cm x 10 cm) is applied thereon to evaluate the maintaining performance of the cellular chamber to the static load.
  • the sheet was evaluated according to the same manner as the above shape retention. As a result, the cellular chamber was scarcely deformed.
  • Air bag (trade name), Model No. #37” manufactured by Kawakami Sangyo Co., Ltd as a control sample
  • This air bag is molded from a non-adhesive thermoplastic film (considered to be a polyolefm film) and is a cushion sheet enclosing many cellular chambers, each of which has a height of about 3 mm and a volume of about 230 mm .
  • this air bag was evaluated according to the same manner as that described above. As a result, it was 40 cm. When four air bags were stacked and was disposed on the glass slide, the evaluation value of 80 cm was obtained
  • a cushioning adhesive sheet was prepared as the same manner as described in Example 9, except that the flexible support (a PET film) was not provided and a volume of the concave part is controlled as shown in Table 4.
  • the vibration- deadening ability of the cushioning adhesive sheet was evaluated by using a vibration analyzer manufactured by Hewlett-Packard Co. "3562A Dynamic Signal Analyzer", as follows. An adhesive surface of the convex part of the adhesive sheet was adhered on the whole surface of the first metal sheet (an aluminum sheet) having a size of 25 mm (width) x 100 mm (length) x 2 mm (thickness) to form airtight spaces.
  • a detector manufactured by PCB (PIZETRONICS) Co., "Acceleration Pick Up” was set on about center of a surface of the first metal sheet. Substantially the same metal sheet was then adhered on the another main surface of the adhesive sheet to prepare the sample.
  • a surface of the second metal sheet was pounded once by using a metal bar having a diameter of 3.5 mm and a decaying constant (h) is calculated by analyzing a vibration detected on the first metal sheet. The measurement was carried out three times and average thereof was adopted as an evaluation for vibration-deadening ability.
  • Xi represents the first amplitude
  • X 2 represents the second amplitude.
  • a sheet of acrylic adhesive sheet as described in Comparative Example 5 has good vibration-deadening ability (For example, see Japanese Laid-Open Utility Model Publication No. 4-126369). But cushioning adhesive sheets of Examples 15— to 17 exhibit the decaying constant grater than Comparative Example 5. According to the present invention, there is provided a cushioning adhesive sheet which can maintain a plurality of independent airtight spaces having a comparatively large volume, stably, with time even after the completion of application. By applying such a cushioning adhesive sheet on an adherend, there can be formed an adhesive structure which is superior in effect of releasing an impact force transmitted to the adherend.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)

Abstract

On décrit une feuille adhésive de calage dont la faculté de calage n'est pas sujette à se détériorer avec le temps, qui s'obtient par application sur une surface adhésive d'un espace étanche à l'air et possédant un volume relativement important, et qui maintient cet espace stable avec le temps. Cette feuille comprend: (i) une partie base, et (ii) une partie convexe, laquelle se compose d'un polymère adhésif réticulé, présente une surface adhésive et est placée sur au moins une surface principale de la base, de manière à enfermer une pluralité de parties concaves possédant une forme géométrique. Cette feuille est caractérisée en ce qu'un volume de la partie concave est compris entre 0,8 et 600 mm3, en ce qu'un module G de la partie convexe mesuré selon un procédé de mesure de viscoélasticité dynamique, à une fréquence d'1 rad/seconde, sous cisaillement à 25 °C, est de l'ordre de 5 x 105 à 4 x 106 dynes/cm2, et en ce qu'une diminution de log¿10?G se situant dans la plage de 25 à 125 °C est inférieure à 1,0.
PCT/US1997/003822 1996-03-13 1997-03-12 Feuille adhesive de calage et structure de calage WO1997033946A2 (fr)

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AU22053/97A AU2205397A (en) 1996-03-13 1997-03-12 Cushioning adhesive sheet and cushioning structure

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JP8056023A JPH09241589A (ja) 1996-03-13 1996-03-13 衝撃緩和性粘着シート及び衝撃緩和構造体
JP8/56023 1996-03-13

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WO1999024519A1 (fr) * 1997-11-10 1999-05-20 Minnesota Mining And Manufacturing Company Feuille adhesive pour structure de verre a vitres
EP1270694A1 (fr) * 2000-01-13 2003-01-02 Nitto Denko Corporation Feuille adhesive poreuse, plaquette a semi-conducteurs munie de la feuille adhesive poreuse, et procede de fabrication associe
WO2003031529A1 (fr) * 2001-10-09 2003-04-17 3M Innovative Properties Company Stratifies presentant des couches structurees
EP2154218A3 (fr) * 2008-08-09 2014-03-12 Tesa Se Film alvéolaire autocollant comme protection pour laques fraîches dans des montages de véhicules et procédé de fabrication
US8846197B2 (en) 2006-08-03 2014-09-30 Nitto Denko Corporation Impact-absorbing pressure-sensitive adhesive sheet and method of producing the same
WO2014197375A1 (fr) 2013-06-06 2014-12-11 3M Innovative Properties Company Procédé pour préparer des articles adhésifs structurés
US10106707B2 (en) 2013-06-06 2018-10-23 3M Innovative Properties Company Method for preparing structured adhesive articles
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US10316226B2 (en) 2013-06-06 2019-06-11 3M Innovative Properties Company Method for preparing structured laminating adhesive articles
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CN110650414A (zh) * 2018-06-27 2020-01-03 三星显示有限公司 面板底部构件及包括面板底部构件的显示装置
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US6736854B2 (en) * 2002-05-10 2004-05-18 C. R. Bard, Inc. Prosthetic repair fabric with erosion resistant edge
JP4515014B2 (ja) * 2002-08-19 2010-07-28 大日本印刷株式会社 粘着シート
JP5743285B2 (ja) * 2012-12-18 2015-07-01 日東電工株式会社 衝撃吸収粘着剤シートおよびその製造方法
PT2970589T (pt) * 2013-03-13 2017-10-23 3M Innovative Properties Co Politioéteres curáveis por radiação com ligação baseada em alcino
JP6216586B2 (ja) * 2013-09-18 2017-10-18 中興化成工業株式会社 凸部が設けられたシート
JP5963286B2 (ja) * 2015-04-06 2016-08-03 日東電工株式会社 衝撃吸収粘着剤シートおよびその製造方法
KR101957767B1 (ko) * 2018-04-05 2019-07-04 유니웹스 주식회사 다중 버전 백업 기능을 갖는 사설 클라우드 장치

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WO1999024519A1 (fr) * 1997-11-10 1999-05-20 Minnesota Mining And Manufacturing Company Feuille adhesive pour structure de verre a vitres
EP1270694A1 (fr) * 2000-01-13 2003-01-02 Nitto Denko Corporation Feuille adhesive poreuse, plaquette a semi-conducteurs munie de la feuille adhesive poreuse, et procede de fabrication associe
EP1270694A4 (fr) * 2000-01-13 2004-11-10 Nitto Denko Corp Feuille adhesive poreuse, plaquette a semi-conducteurs munie de la feuille adhesive poreuse, et procede de fabrication associe
US6890617B1 (en) 2000-01-13 2005-05-10 Nitto Denko Corporation Porous adhesive sheet, semiconductor wafer with porous adhesive sheet, and method of manufacture thereof
US7056406B2 (en) 2000-01-13 2006-06-06 Nitto Denko Corporation Porous adhesive sheet, semiconductor wafer with porous adhesive sheet and method of manufacture thereof
WO2003031529A1 (fr) * 2001-10-09 2003-04-17 3M Innovative Properties Company Stratifies presentant des couches structurees
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KR100901348B1 (ko) 2001-10-09 2009-06-05 쓰리엠 이노베이티브 프로퍼티즈 컴파니 구조화된 층을 가진 라미네이트
US8323773B2 (en) 2001-10-09 2012-12-04 3M Innovative Properties Company Laminates with structured layers
US9657198B2 (en) 2006-08-03 2017-05-23 Nitto Denko Corporation Impact-absorbing pressure-sensitive adhesive sheet and method of producing the same
US8846197B2 (en) 2006-08-03 2014-09-30 Nitto Denko Corporation Impact-absorbing pressure-sensitive adhesive sheet and method of producing the same
EP2154218A3 (fr) * 2008-08-09 2014-03-12 Tesa Se Film alvéolaire autocollant comme protection pour laques fraîches dans des montages de véhicules et procédé de fabrication
US10316226B2 (en) 2013-06-06 2019-06-11 3M Innovative Properties Company Method for preparing structured laminating adhesive articles
US10106707B2 (en) 2013-06-06 2018-10-23 3M Innovative Properties Company Method for preparing structured adhesive articles
US10308004B2 (en) 2013-06-06 2019-06-04 3M Innovative Properties Company Method for preparing structured adhesive articles
WO2014197375A1 (fr) 2013-06-06 2014-12-11 3M Innovative Properties Company Procédé pour préparer des articles adhésifs structurés
US10723919B2 (en) 2013-06-06 2020-07-28 3M Innovative Properties Company Method for preparing structured adhesive articles
US10185058B2 (en) 2013-07-01 2019-01-22 3M Innovative Properties Company Protection film suitable for illuminated display devices
US11591497B2 (en) 2017-12-14 2023-02-28 Avery Dennison Corporation Pressure sensitive adhesive with broad damping temperature range
WO2019234684A1 (fr) 2018-06-07 2019-12-12 3M Innovative Properties Company Doublures détachables microstructurées pour transfert sélectif d'encre sur un film
US11572492B2 (en) 2018-06-07 2023-02-07 3M Innovative Properties Company Microstructured release liners for selective transfer of ink to film
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US11262862B2 (en) 2018-06-27 2022-03-01 Samsung Display Co., Ltd. Panel bottom member and display device including ihe same
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Publication number Publication date
JPH09241589A (ja) 1997-09-16
WO1997033946A3 (fr) 1997-11-06
AU2205397A (en) 1997-10-01

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