WO1997025458A1 - Verfahren und vorrichtung zur herstellung von schmelzgesponnenen monofilen - Google Patents
Verfahren und vorrichtung zur herstellung von schmelzgesponnenen monofilen Download PDFInfo
- Publication number
- WO1997025458A1 WO1997025458A1 PCT/EP1996/005810 EP9605810W WO9725458A1 WO 1997025458 A1 WO1997025458 A1 WO 1997025458A1 EP 9605810 W EP9605810 W EP 9605810W WO 9725458 A1 WO9725458 A1 WO 9725458A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- spinning
- spinning shaft
- thread
- shaft
- cooling
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
- D01D5/0885—Cooling filaments, threads or the like, leaving the spinnerettes by means of a liquid
Definitions
- the invention relates to a continuous process and an apparatus for
- the polymer melt is spun from a spinning head in air, blown to the side in a spinning shaft with a defined air velocity profile and then cooled in a liquid bath
- thermoplastic monofilaments (with a diameter greater than 60 ⁇ m) can be spun, for example in water, with an outlet speed of the finished monofilaments of a maximum of 600 m / min
- German published patent application DE 41 29 521 AI describes a device for the rapid spinning of multifilament threads at a winding speed of at least 2000 m / min
- both direct spinning drawing processes are limited to the production of thin monofilament diameters (ie with a thread diameter ⁇ 57 ⁇ m) due to the unfavorable heat dissipation due to air cooling and the poor internal heat conduction in the thread
- German patent application with the file number P 43 36 097 1 describes a continuous high-speed production process for the production of melt-spun monofilament threads with a diameter of 60 ⁇ m to 500 ⁇ m.
- the polymer threads formed are laterally underneath the spinning head over a distance of 1 to 10 cm blown with tempered air from blowing nozzles to stabilize the smooth running of the threads. After the air cooling, the polymer threads are cooled in a liquid bath
- the monofilaments show a loss of strength and a large spread with regard to their knot strength
- REPLACEMENT BLA ⁇ (RULE 26) An additional air blowing between the spinning head and the spinning bath by means of blowing nozzles over an air distance of 1 to 10 cm (according to DE 43 36 097) leads to satisfactory textile properties with rapidly spun thin monofilaments (with a diameter of ⁇ 200 ⁇ m).
- the use of the air cooling section described is not sufficient for thicker monofilaments.
- the method is extremely susceptible to air movement in the area of the thread formation, as a result of which the running safety of the system is impaired.
- the invention has for its object to improve the spinning process for monofilaments described so that the spinning security and the textile properties of the monofilaments obtained, in particular their knot strength, are increased.
- the object is achieved according to the invention by a continuous process for the production of monofilament threads with a diameter of 60 ⁇ m to 2000 ⁇ m from thread-forming thermoplastic polymers by melt spinning the melted polymer from a spinning head in air, blowing on the side with cooling gas in a spinning shaft, cooling the threads formed in one
- Liquid bath removal of the adhering liquid, optionally preparation, stretching of the threads in one or more stages, fixing and winding up the threads at an outlet speed of the fixed threads of 100 to 4000 m / min, characterized in that the cooling gas has a temperature of 0 to 50 ° C and that the cooling gas falling over the direction of the thread
- Speed profile measured perpendicular to the direction of the threads, shows that the coolant has a temperature of -10 to 150 ° C.
- the thread-forming polymer is melt-spun in particular from a basically known melt spinning head in air, in a spinning shaft with a defined air velocity profile with tempered air (a temperature of
- 0 ° C to 50 ° C preferably from one side from blowing nozzles or, in the case of round spinning nozzles, annularly blown from the side from ring nozzles and then cooled in a liquid bath at a temperature of 5 ° C. to 50 ° C.
- the air speed across the monofilaments is just below the spinneret (for example at a distance of 0.5 to 6 cm from the nozzle) from 0.1 to 10 m / sec, in particular from 0.1 to 2 m / sec sec, and falls to a lower but above all in the further course of the spinning shaft seen the longitudinal section surface of the spinning shaft extremely uniform Beerge ⁇ speed of 0.001 m / sec to 1 m / sec, in particular 0.01 to 0.2 m / sec
- the cooling gas flows from nozzles, which are arranged in a ring around the filaments in the spinning shaft, into the spinning shaft, and the cooling gas is sucked out together with the outgassings from the spun thread beneath the blowing nozzle
- the nozzles are arranged on one side in the spinning shaft and the cooling gas, together with the outgassing, is drawn off from the spun threads relative to the blow nozzles
- the spinning shaft can have a length of 2 to 200 cm.
- the spinning shaft preferably has a length of 8 to 60 cm
- the air speed in the spinning shaft is transverse to the monofilaments at a distance of 0.5 to 6 cm from the
- Spinning nozzle 0.05 to 10 m / sec, in particular 0.1 to 2 m / sec.
- the air speed in the spinning shaft is from 0.001 m / sec to 1 m / sec, preferably of 0.01 to 0.2 m / sec
- the monofilaments are preferably blown in the spinning shaft with tempered air at a temperature of 0 to 50 ° C., in particular 10 to 30 ° C.
- the air blown into the spinning shaft, together with the outgassings from the spun threads is sucked off uniformly over the entire spinning shaft relative to the air inlet.
- a pressure difference to the ambient pressure becomes high from 10 to
- the temperature of the cooling bath is preferably 5 to 50 ° C
- the outlet speed of the threads is preferably 1000 to 3500 m / min.
- the monofilaments obtainable from the process have in particular a diameter of 100 to 400 ⁇ m, preferably 180 to 250 ⁇ m.
- Polyamide, polyethylene terephthalate, polybutylene terephthalate, polypropylene and polyethylene are particularly suitable as thread-forming polymer.
- the preferred polymer is polyamide, in particular polyamide-6, polyamide-6.6, polyamide-6.10, polyamide-6.12, polyamide 11, polyamide 12, a mixture of the polyamides mentioned or a copolyamide of the polyamides mentioned.
- a copolyamide consisting of polyamide-6 and polyamide-6.6, a copolyamide made of polyamide-6 and polyamide-12 and a copolyamide consisting of polyamide-6 and polyamide-1 1 are particularly preferred.
- Another preferred mixed polyamide consists of polyamide-6, polyamide -6.6 and either polyamide-1 1 or polyamide-12.
- the spinning shaft closes on its underside with the liquid surface of the cooling liquid of the spinning bath.
- the monofilaments After leaving the liquid bath, the monofilaments are usually freed of adhering cooling liquid and aftertreated by optionally preparing, stretching and fixing. The monofilaments are then wound up.
- the monofilaments produced according to the new so-called dry / wet melt spinning process are characterized by a smoother surface and a higher working capacity (defined as a product of the tenacity and maximum tensile strength).
- the described spinning method according to the invention is necessary at a higher production speed of 600 to 3000 m / min in order to achieve that of the
- the melt spinning process according to the invention is preferably used for the production of fishing wires, in particular for high-strength transparent fishing wires and for the production of technical monofilaments, in particular at a higher production speed (> 600 m / min) or an increased number of die holes
- Another object of the invention is a device for carrying out the inventive method consisting of a melt spinning head with spinneret, a spinning shaft with a blowing unit and suction unit, a liquid bath with thread deflection and flow breakers, scrapers and an adhesive liquid suction, optionally a preparation point , one or more stretching units, in particular for hot stretching, a fixing zone and winding points.
- the device is characterized in that the spinning shaft surrounds or in particular encloses the space between the spinning head and the liquid surface of the cooling liquid bath in a gas-tight manner
- gas nozzles for blowing the monofilaments in the spinning shaft are provided on one side of the shaft, which are optionally provided with flow comparators in the area of the monofilaments
- the first blowing nozzle in the spinning shaft below the spinning nozzle is a flat nozzle with an adjustable nozzle gap. All the air nozzles in the spinning shaft can preferably be regulated separately, so that the air streams can be adjusted in accordance with the required air flow profile
- a variant of the device has a ring nozzle with flow comparators for comparing the gas velocity profile in front of the nozzle for blowing on the monofilaments in the spinning shaft The spun thread can be sucked off.
- a device is preferred in which the suction is arranged in the spinning shaft opposite the air inlet nozzles The invention is explained in more detail below with reference to FIGS. 1 to 3 without restricting the invention in detail
- Figure 1 is a schematic view of the front part of the spinning device according to the invention
- FIG. 1 An enlarged view of the spinneret and cooling bath from one
- Figure 3 is a schematic view of the entire spinning device with
- the polymer melt is fed via a line to the melt spinning head 17 with the spinneret 1 (see FIG. 1).
- the spinning shaft 2 has an air-blowing unit 3 and suction unit 4, which are used for feeding and discharging the
- the suction unit 4 has a suction channel 22 which extends in a ring around the spinning shaft 2 and which causes the spatially uniform escape of the spinning gas.
- the slot nozzle 19 there is an annular nozzle 20 and as a blowing unit 3 there are annular nozzles with flow equalizers.
- the thread sheet 23 of the monofilaments is pre-cooled in the spinning shaft 2 in both variants by blowing with air.
- the thread sheet 23 is then further cooled and solidified in a liquid bath 5.
- a thread deflection 6 causes the gentle change in direction of the running direction of the thread sheet 23 by means of a plurality of deflecting rods.
- flow breakers 16 calm the cooling bath liquid at high production speed in order to avoid turbulence in the cooling bath liquid due to the liquid carried by the monofilaments and to prevent the still soft monofilaments from beating (see FIG. 1).
- liquid wipers 7 are attached behind the outlet of the monofilaments 23 from the cooling bath liquid and in front of the pair of traction rollers 8, which, like a further adhesive liquid suction device 9, remove the entrained cooling bath liquid from remove the monofilament 23.
- the spinning device also has a preparation site 10 and subsequent suction 11 for excess preparation, a hot stretching zone 13, a fixing zone 14 and winding machines 15 for winding the monofilaments. The running speed of the
- the spinning shaft 2 of the spinning device is designed in both device variants in such a way that the spinning shaft 2 gas-tightly encloses the space between the spinning head 17 and the liquid surface 18 of the cooling liquid bath 5 in which the monofilaments are formed.
- a device in the variant according to FIG. 1 was used for the following test examples.
- the spinning shaft 2 had not been used to enclose the space between the spinning head 17 and the liquid surface 18 in a gas-tight manner.
- One or three standing on top of each other were used for blowing
- Nozzles 19 and 3a, 3b used.
- the width of the nozzles covered the width of the thread sheet.
- the nozzle 19 was a slot nozzle with the height indicated in each of the examples.
- the nozzles 3a and 3b were nozzles equipped with a more uniform flow, the height of which covered the remaining height below the spinning nozzle.
- Monofilaments with a diameter of 0.40 mm were produced from a commercially available copolyamide with the designation Ultramid C 35 (manufacturer: BASF AG, Ludwigshafen) under the standard conditions described above.
- the distance between the exit of the melt from the spinning nozzle opening and the surface of the cooling medium (water) was 60 mm.
- a slot nozzle 19 with a slot height of 25 mm was installed in this zone, with the aid of which the monofilaments between the nozzle outlet and the inlet into the cooling medium were blown with air in a defined manner.
- the linear and knot strength measured on the monofilaments obtained is as indicated in Table 1
- Monofilaments with a diameter of 0.20 mm were produced from a commercially available polyamide of type Durethan B 31 (manufacturer BAYER AG, Leverkusen) under the standard conditions described.
- the distance between the melt exit from the spinneret opening and the surface of the cooling medium was ( Water) 280 mm
- Monofilaments of different diameters were produced from a commercially available copolyamide with the designation Ultramid C 35 (manufacturer BASF AG, Ludwigshafen) under the standard conditions described.
- the distance between the exit of the melt from the spinneret opening and the surface of the cooling medium (water ) 60 mm
- a protective nozzle 19 with a slot height of 25 mm was installed, with the aid of which the monofilaments between the nozzle outlet and the entry into the cooling medium were blown with air in a defined manner.
- the installation of blowing nozzles was dispensed with The
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9524811A JP2000503076A (ja) | 1996-01-03 | 1996-12-23 | 溶融紡糸されたモノフイラメントを製造する方法及び装置 |
EP96944640A EP0871805A1 (de) | 1996-01-03 | 1996-12-23 | Verfahren und vorrichtung zur herstellung von schmelzgesponnenen monofilen |
US09/101,044 US6036895A (en) | 1996-01-03 | 1996-12-23 | Process and device for the formation of monofilaments produced by melt-spinning |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19600090A DE19600090A1 (de) | 1996-01-03 | 1996-01-03 | Verfahren und Vorrichtung zur Herstellung von schmelzgesponnenen Monofilen |
DE19600090.4 | 1996-01-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997025458A1 true WO1997025458A1 (de) | 1997-07-17 |
Family
ID=7782106
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1996/005810 WO1997025458A1 (de) | 1996-01-03 | 1996-12-23 | Verfahren und vorrichtung zur herstellung von schmelzgesponnenen monofilen |
Country Status (5)
Country | Link |
---|---|
US (1) | US6036895A (de) |
EP (1) | EP0871805A1 (de) |
JP (1) | JP2000503076A (de) |
DE (1) | DE19600090A1 (de) |
WO (1) | WO1997025458A1 (de) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1221499A1 (de) * | 2001-01-05 | 2002-07-10 | Acordis Industrial Fibers bv | Verfahren zum Spinnstrecken von schmelzgesponnenen Garnen |
DE10200406A1 (de) * | 2002-01-08 | 2003-07-24 | Zimmer Ag | Spinnvorrichtung und -verfahren mit turbulenter Kühlbeblasung |
DE10204381A1 (de) * | 2002-01-28 | 2003-08-07 | Zimmer Ag | Ergonomische Spinnanlage |
DE10213007A1 (de) * | 2002-03-22 | 2003-10-09 | Zimmer Ag | Verfahren und Vorrichtung zur Regelung des Raumklimas bei einem Spinnprozess |
DE10223268B4 (de) * | 2002-05-24 | 2006-06-01 | Zimmer Ag | Benetzungseinrichtung und Spinnanlage mit Benetzungseinrichtung |
DE10314878A1 (de) * | 2003-04-01 | 2004-10-28 | Zimmer Ag | Verfahren und Vorrichtung zur Herstellung nachverstreckter Cellulose-Spinnfäden |
DE102004024028B4 (de) * | 2004-05-13 | 2010-04-08 | Lenzing Ag | Lyocell-Verfahren und -Vorrichtung mit Presswasserrückführung |
DE102004024029A1 (de) * | 2004-05-13 | 2005-12-08 | Zimmer Ag | Lyocell-Verfahren und -Vorrichtung mit Steuerung des Metallionen-Gehalts |
DE102004024030A1 (de) | 2004-05-13 | 2005-12-08 | Zimmer Ag | Lyocell-Verfahren mit polymerisationsgradabhängiger Einstellung der Verarbeitungsdauer |
US20060033231A1 (en) * | 2004-08-10 | 2006-02-16 | Reuter Rene F | Monofilament reinforced rubber component and method of producing |
US8303288B2 (en) * | 2008-12-24 | 2012-11-06 | Taiwan Textile Research Institute | Machine for manufacturing nonwoven fabric |
JP5140609B2 (ja) * | 2009-01-19 | 2013-02-06 | クレハ合繊株式会社 | 熱可塑性樹脂モノフィラメントおよびその製造方法 |
DE102009021117A1 (de) * | 2009-05-13 | 2010-11-18 | Oerlikon Textile Gmbh & Co. Kg | Verfahren und Vorrichtung zum Schmelzspinnen und Abkühlen einer Vielzahl von Monofilamenten |
DE102010017841A1 (de) | 2009-05-20 | 2010-11-25 | Oerlikon Textile Gmbh & Co. Kg | Vorrichtung zum Extrudieren und Abkühlen einer Folie oder einer Vielzahl von Monofilamenten |
WO2011006092A2 (en) * | 2009-07-10 | 2011-01-13 | North Carolina State University | Highly oriented and crystalline thermoplastic filaments and method of making same |
US9334585B2 (en) * | 2011-06-15 | 2016-05-10 | Truetzschler Nonwovens Gmbh | Spinning bath vat |
EP2565304A1 (de) | 2011-09-02 | 2013-03-06 | Aurotec GmbH | Extrusionsverfahren und -vorrichtung |
JP7021328B2 (ja) * | 2020-11-10 | 2022-02-16 | コルドサ・テクニク・テクスティル・アノニム・シルケティ | モノフィラメント糸製造のための方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0251799A2 (de) * | 1986-07-03 | 1988-01-07 | Toray Industries, Inc. | Verfahren und Vorrichtung zur Herstellung von synthetischen thermoplastischen Garnen |
US5362430A (en) * | 1993-07-16 | 1994-11-08 | E. I. Du Pont De Nemours And Company | Aqueous-quench spinning of polyamides |
DE4336097A1 (de) * | 1993-10-22 | 1995-04-27 | Bayer Ag | Kontinuierliches Verfahren zum Schmelzspinnen von monofilen Fäden |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1991011547A1 (de) * | 1990-02-05 | 1991-08-08 | Rhone-Poulenc Viscosuisse Sa | Verfahren und vorrichtung zum schnellspinnen von monofilamenten und damit hergestellte monofilamente |
DE4129521A1 (de) * | 1991-09-06 | 1993-03-11 | Akzo Nv | Vorrichtung zum schnellspinnen von multifilen faeden und deren verwendung |
-
1996
- 1996-01-03 DE DE19600090A patent/DE19600090A1/de not_active Withdrawn
- 1996-12-23 EP EP96944640A patent/EP0871805A1/de not_active Ceased
- 1996-12-23 WO PCT/EP1996/005810 patent/WO1997025458A1/de not_active Application Discontinuation
- 1996-12-23 US US09/101,044 patent/US6036895A/en not_active Expired - Fee Related
- 1996-12-23 JP JP9524811A patent/JP2000503076A/ja active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0251799A2 (de) * | 1986-07-03 | 1988-01-07 | Toray Industries, Inc. | Verfahren und Vorrichtung zur Herstellung von synthetischen thermoplastischen Garnen |
US5362430A (en) * | 1993-07-16 | 1994-11-08 | E. I. Du Pont De Nemours And Company | Aqueous-quench spinning of polyamides |
DE4336097A1 (de) * | 1993-10-22 | 1995-04-27 | Bayer Ag | Kontinuierliches Verfahren zum Schmelzspinnen von monofilen Fäden |
Also Published As
Publication number | Publication date |
---|---|
US6036895A (en) | 2000-03-14 |
EP0871805A1 (de) | 1998-10-21 |
JP2000503076A (ja) | 2000-03-14 |
DE19600090A1 (de) | 1997-07-10 |
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