WO1995026645A1 - Edulcorant sous forme cristallisee - Google Patents

Edulcorant sous forme cristallisee Download PDF

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Publication number
WO1995026645A1
WO1995026645A1 PCT/EP1995/001166 EP9501166W WO9526645A1 WO 1995026645 A1 WO1995026645 A1 WO 1995026645A1 EP 9501166 W EP9501166 W EP 9501166W WO 9526645 A1 WO9526645 A1 WO 9526645A1
Authority
WO
WIPO (PCT)
Prior art keywords
water
crystalline
vessel
sweetener
mixture
Prior art date
Application number
PCT/EP1995/001166
Other languages
German (de)
English (en)
Inventor
Rudolf Weiner
Original Assignee
'worlée Sweet' E.H. Worlée & Co. Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 'worlée Sweet' E.H. Worlée & Co. Gmbh filed Critical 'worlée Sweet' E.H. Worlée & Co. Gmbh
Priority to AU22149/95A priority Critical patent/AU2214995A/en
Priority to EP95915167A priority patent/EP0763983A1/fr
Publication of WO1995026645A1 publication Critical patent/WO1995026645A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/343—Products for covering, coating, finishing, decorating
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/02—Apparatus specially adapted for manufacture or treatment of sweetmeats or confectionery; Accessories therefor
    • A23G3/0205—Manufacture or treatment of liquids, pastes, creams, granules, shred or powder
    • A23G3/0231—Transformation of a liquid, paste, cream, lump, powder, granule or shred into powder, granule or shred; Manufacture or treatment of powder
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/346—Finished or semi-finished products in the form of powders, paste or liquids
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30—Artificial sweetening agents
    • A23L27/31—Artificial sweetening agents containing amino acids, nucleotides, peptides or derivatives
    • A23L27/32—Artificial sweetening agents containing amino acids, nucleotides, peptides or derivatives containing dipeptides or derivatives
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30—Artificial sweetening agents
    • A23L27/33—Artificial sweetening agents containing sugars or derivatives
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30—Artificial sweetening agents
    • A23L27/33—Artificial sweetening agents containing sugars or derivatives
    • A23L27/34—Sugar alcohols
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G2200/00—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents
    • A23G2200/06—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF containing organic compounds, e.g. synthetic flavouring agents containing beet sugar or cane sugar if specifically mentioned or containing other carbohydrates, e.g. starches, gums, alcohol sugar, polysaccharides, dextrin or containing high or low amount of carbohydrate

Definitions

  • the invention relates to a sweet composition for use in the manufacture of sweetened foods and a process for their manufacture.
  • the invention relates to a sweet composition which is scatterable and crystalline.
  • Products such as baked goods, sweets, chocolate products, sweets, chewing gums or fillings thereof have long been sweetened with sugar substitutes or with a mixture of sugar and sugar substitutes in order to reduce calories or to be able to produce products suitable for diabetics.
  • sugar compositions and / or sweetening compositions containing artificial sweeteners has the disadvantage that they bring with them an unavoidable secondary taste which considerably affects the quality of the food.
  • the previously known scatterable sweet compositions generally have the further disadvantage that their appearance (white powder) and their processing properties or processing behavior differ considerably from sugar, the classic sweetener, e.g. in browning behavior, in solution behavior or in flow behavior.
  • REPLACEMENT BLA ⁇ (RULE 26)
  • the invention is therefore based on the object of providing a scatterable, free-flowing, crystalline sweet composition and a process for its preparation, the sweet composition being largely similar in its appearance, taste and processing properties to sugar, but being sugar-free, gentle on the teeth, preferably suitable for diabetics and reduced calories.
  • a crystalline sprinkling sweet composition which is characterized in that it contains a) 40 to 95% by weight of non-hygroscopic and non-crystallization-inhibiting sugar alcohol, b) 2.5 to 45% by weight of polydextrose and / or maltitol syrup (Mal ⁇ titanium content) and / or sorbitol, c) 0 to 10 wt .-% intense sweetener and d) 2.5 to 7.5 wt .-% water and optionally conventional auxiliaries.
  • the composition according to the invention has the advantages that it reduces calories, is gentle on the teeth and is particularly suitable for diabetics and a faster dissolution rate has a smoother melting behavior in the mouth, hardly causes crystal friction in the oral cavity, has a browning reaction comparable to sugar and has similar processing properties, offers the possibility of a finer or coarser grinding (depending on requirements) and a flow comparable to sugar
  • SPARE BLADE (RULE 26) has ability. As a rule, it is full-bodied and has no adverse aftertaste. In addition, it has a sensor system that can be described as slightly cooling, the sweetness being similar to that of sugar and flattening after consumption.
  • “Sugar” is primarily understood to mean sucrose, but also includes its breakdown products glucose and fructose and other saccharides such as lactose and the like. This does not include sugar alcohols which differ from the sugars (carbohydrates) which have aldehyde groups or which are present in acetal form and are therefore reducing.
  • sugar alcohols used herein accordingly designates carbohydrates in which the carbonyl function present in sugars is reduced to a hydroxylmethyl function, so that they are non-reducing polyhydroxy compounds.
  • the sprinkling sweet composition according to the invention can in particular be individually adjusted to a variety of possible uses and requirements. It can be used in all areas of application of sugar and sugar products, e.g. Confectionery, compromises also for pharmaceutical products, dairy products, dressings, sauces, carriers for dry seasoning as well as for roast and ready meals, as feed for the beverage industry or in baked goods as a full-fledged alternative for sugar. Products whose production is problematic when using conventional sugar substitutes because they often turn out to be too sweet are easily possible. For example, less sweet products can be made with a good taste, e.g. Foam confectionery. In the case of foam sugar confectionery, a minimum sweetness was previously prescribed due to the recipe, since it is necessary
  • REPLACEMENT BLA ⁇ ( «EGEL26) Contained sugar.
  • the sweet composition according to the invention has a basic sweetness, which, however, only makes up about half of that of the sugar. It therefore essentially represents a composition that can be regarded as a substitute for the "body / texture" or for the sweet mass, whereby its “sweetness” can be set individually, for example by, other than when sugar is used Intensive sweetener added.
  • the crystalline sprinkling sweet composition according to the invention preferably has a sugar alcohol content in the range from 50 to 95% by weight and in particular 70 to 95% by weight.
  • the content of polydextrose and / or maltitol syrup (maltitol content) and / or sorbitol is preferably 5 to 30% by weight and in particular 7 to 10% by weight, while the water content is preferably 3 to 7.5% by weight and in particular 3.5 to 7 wt .-% is.
  • the sweet composition also contains intensive sweetener, the content being in the range from 0 to 10% by weight, preferably in the range from 0 to 5% by weight and in particular 0.1 to 1% by weight.
  • intensive sweeteners are suitable as an intense sweetener, with aspartame (L-aspartyl-L-phenylalanine methyl ester), AceK (acesulfame-K, the potassium salt of 6-methyl-1,2,3-oxathiazin-4 (3H) -one- 2,2-dioxides) or a mixture containing aspartame and / or AceK and in particular aspartame is preferred.
  • the weight ratio of polydextrose and / or maltitol syrup (maltitol portion) and / or sorbitol to sugar alcohol is generally in the range from about 1: 1 to 1:38, preferably 1: 2 to 1:20, more preferably 1: 5 to 1: 15 and is particularly preferably 1:11.
  • Lactite and xylitol are particularly suitable as sugar alcohol, with lactite being preferred.
  • Lactitol is commercially available in several forms, for example as a white crystalline monohydrate form or in the form of the dihydrate.
  • Polydextrose is a polymer made by polycondensing glucose in the presence of sorbitol and citric acid.
  • Maltitol syrup contains maltitol as the main component, the maltitol content generally being between 55 and 80% by weight (see in each case "Manual sweetener: properties and application", pages 256 to 257 and 379 to 387, 1990 Behr's Verlag, Hamburg).
  • the crystalline sweet composition can also contain one or more other liquids or solvents. These preferably have a lower boiling point than water. This promotes drying of the composition during manufacture due to the lower evaporation point. This can make drying easier. In addition, faster crystallization is possible.
  • Liquids suitable for human consumption the boiling point of which is preferably not more than 85 ° C., are suitable for this purpose. These include alcohols and especially ethanol.
  • the amount of water present in the composition according to the invention can be replaced in part by one or more such liquids, but the proportion thereof, based on the amount of water, should not exceed 25%. The residual water content must in any case be so large that the solid components are completely dissolved during manufacture and the desired moisture content of the product can be set.
  • composition according to the invention can contain further auxiliaries, as are usually used in sweet compositions.
  • auxiliaries are cellulose ethers or agents for maintaining the flowability.
  • the total amount of such auxiliaries is a maximum of 5% by weight of the total composition.
  • the melting temperature of the sweet composition according to the invention is in the range from 67 to 75 ° C., which depends on the respective proportions of the individual components. In particular, it is in the range from 67 to 70 ° C. In comparison, the melting temperature (sintering range) of isomalt is over 145 ° C to 150 ° C.
  • the crystalline scattering sweet composition according to the invention is a product which consists of crystals of a homogeneous mixture.
  • it is not a physical mixture of crystals of the individual components which are present side by side, so that the constituents are separated mechanically, e.g. by seven, is not possible.
  • the process according to the invention for the production of the crystalline sprinkling sweet composition consists in that a) the sugar alcohol, the polydextrose and / or the maltitol syrup and / or the sorbitol and optionally the auxiliaries are mixed with the water, b) this mixture is stirred in a closed vessel Is heated to 75 to 95 ° C until everything has dissolved, c) a vacuum is applied and the mixture is slowly cooled to 40 to 65 ° C, in particular 40 to 60 ° C and preferably about 55 ° C, d) the vessel is aerated and seed crystals and, if necessary, intensive sweetener are added, e) after the vessel is closed again, stirring is continued rapidly, and f) the vessel is emptied.
  • the dry feedstocks can be mixed beforehand in the system, the water then being added.
  • the mixture is preferably stirred at a stirring speed of 1000 to 2000 rpm, in particular 1200 to 1500 rpm and preferably 1500 rpm, preferably heating to 80 to 95 ° C., in particular 85 to 90 ° C. and preferably about 85 ° C. becomes.
  • the required amount of water can be added in step a) or added in step b) together with / in the form of hot steam.
  • the use of hot steam has the advantage that the dissolving process is accelerated.
  • the water vapor also causes the contents of the vessel to heat up.
  • a double-jacket vessel can also be used for heating, the medium circulating therein supplying the heat.
  • a double jacket system with water as the coolant, which circulates in the closed circuit is suitably used.
  • the mixture is cooled to about 55 ° C. and stirred at about 200 to 500 rpm, in particular 300 to 400 rpm and preferably 300 rpm.
  • stage c By applying a vacuum that can range from almost atmospheric pressure to a high vacuum (eg water jet pump vacuum (2500 Pa) or oil pump vacuum (0.015 Pa)) ; in stage c) heat is also removed with the evaporated and removed water, which accelerates the cooling.
  • a high vacuum eg water jet pump vacuum (2500 Pa) or oil pump vacuum (0.015 Pa)
  • the vessel After cooling to 40 to 60 ° C., the vessel is opened and seed crystals (crystallization nuclei) are added to the contents.
  • the seed crystals preferably consist of the sugar alcohol used, the sweetener optionally used or a mixture of both.
  • the powders are suitably finely ground. Crystallization preferably begins only after vaccination.
  • the stirring speed is preferably 2000 to 4000 rpm, in particular 2500 to 3500 rpm and preferably 3000 rpm.
  • the stirring time is preferably up to 5 minutes, in particular up to 3 minutes, preferably up to 1 minute and can, for example, also be only 10 or 15 seconds.
  • the vessel is then opened and emptied as quickly as possible.
  • the emptying should definitely be finished as long as
  • REPLACEMENT BLADE (RULE 26) the crystallization of the mass has not yet been completed. As long as complete crystallization has not taken place, the mass is namely still moldable or pourable.
  • Any subsequent desired drying of the product can be carried out with the aid of temperature and / or air flow regulation, the moisture content being precisely controlled and adjusted to the desired value.
  • this grinding is preferably carried out at low temperatures such as about -20 ° C. and under nitrogen. After grinding, it is advisable to treat or store the product in such a way that no condensate forms on it due to the previous cold entry or this condensate is quickly removed.
  • Suitable devices are, for example, fluidized bed dryers.
  • composition according to the invention is given below.
  • the polydextrose, the lactitol and the water were filled into the production system (Stephan & Söhne, type HC 44 Pilot), which was then closed.
  • the mixture was then stirred at 1500 rpm and heated to 85 ° C. with hot steam. After the dissolution of the mixture constituents was complete, the speed was reduced to 300 rpm and the mixture was cooled to 55 ° C. by cooling using a double outer jacket with a vacuum applied.
  • the seed crystals were added and then stirred again at 3000 rpm for 15 seconds. The system was then emptied.
  • compositions of finished sprinkling sweet compositions according to the invention which were prepared analogously to the method given above, the respective product possibly being dried to the stated water content, are:

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Seasonings (AREA)

Abstract

L'invention concerne une composition édulcorante cristallisée à disséminer, contenant: a) entre 40 et 95 % en poids d'itol non hygroscopique, n'inhibant pas la cristallisation; b) entre 2,5 et 45 % en poids de polydextrose et/ou de syrop de maltitol (portion de maltitol) et/ou de sorbitol; c) entre 0 et 10 % en poids d'éculcorant intensif; et d) entre 2,5 et 7,5 % en poids d'eau, ainsi que, à titre facultatif, des substances auxiliaires classiques. L'invention a aussi pour objet un procédé de préparation d'une telle composition édulcorante cristallisée à disséminer, consistant: a) à mélanger avec de l'eau l'itol non hygroscopique qui n'inhibe pas la cristallisation, le polydextrose et/ou le syrop de maltitol et/ou le sorbitol et, éventuellement, les substances auxiliaires et l'édulcorant intensif; b) à porter ce mélange à une température entre 75 °C et 95 °C dans une cuve fermée tout en remuant jusqu'à ce que tout soit dissous; c) à faire le vide et à faire refroidir le mélange pour le ramener à une température entre 40 °C et 65 °C tout en remuant doucement; d) à aérer la cuve et à ajouter des germes d'inoculation et, éventuellement, l'édulcorant intensif; e), une fois la cuve refermée, à remuer à nouveau le mélange rapidement; puis f) à vider la cuve.
PCT/EP1995/001166 1994-03-30 1995-03-28 Edulcorant sous forme cristallisee WO1995026645A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU22149/95A AU2214995A (en) 1994-03-30 1995-03-28 Sweetener in crystal form
EP95915167A EP0763983A1 (fr) 1994-03-30 1995-03-28 Edulcorant sous forme cristallisee

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4411582.2 1994-03-30
DE4411582A DE4411582C2 (de) 1994-03-30 1994-03-30 Kristallsüße

Publications (1)

Publication Number Publication Date
WO1995026645A1 true WO1995026645A1 (fr) 1995-10-12

Family

ID=6514575

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1995/001166 WO1995026645A1 (fr) 1994-03-30 1995-03-28 Edulcorant sous forme cristallisee

Country Status (4)

Country Link
EP (1) EP0763983A1 (fr)
AU (1) AU2214995A (fr)
DE (1) DE4411582C2 (fr)
WO (1) WO1995026645A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0954982A1 (fr) * 1998-05-07 1999-11-10 Roquette FrÀ¨res Composition édulcorante et ses utilisations
KR100397408B1 (ko) * 2000-05-22 2003-09-13 주식회사 보락 감미제를 함유한 동시결정화 당알코올 및 그의 제조 방법
WO2005087020A1 (fr) * 2004-03-05 2005-09-22 Richmond Chemical Corporation Compositions edulcorantes puissantes a base de polyol
US11246835B2 (en) 2014-04-04 2022-02-15 Douxmatok Ltd Method for producing sweetener compositions and sweetener compositions

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1005201C2 (nl) * 1997-02-06 1998-08-07 Purac Biochem Bv Vloeibare, transparante samenstelling op basis van lactitol.
DE102007008056A1 (de) * 2007-02-15 2008-08-21 Mabea International Transport Expressservice Thelen Gmbh Verfahren zur Herstellung von Austauschzuckersirups
US9023414B2 (en) * 2011-12-08 2015-05-05 The Hershey Company Rapidly dissolving comestible solid

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990006317A1 (fr) * 1988-12-01 1990-06-14 Cultor Ltd. Monohydrate de lactitol cristallin, son procede de preparation et d'utilisation, et agent edulcorant
EP0377278A2 (fr) * 1988-11-14 1990-07-11 Xyrofin Oy Composition édulcorante diététique
WO1993012665A1 (fr) * 1991-12-20 1993-07-08 Wm. Wrigley Jr. Company Produits a base de chewing-gum comportant de la polydextrose
EP0575070A2 (fr) * 1992-06-17 1993-12-22 Jacobs Suchard Ag Produit et procédé pour la fabrication de cholocat au lait

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0376977A (ja) * 1989-08-17 1991-04-02 Mitsubishi Electric Corp 侵入監視システム
JPH06260450A (ja) * 1993-03-04 1994-09-16 Hitachi Ltd ドライエッチング装置
JPH071892A (ja) * 1993-06-21 1995-01-06 Dainippon Printing Co Ltd 転写シート及びその製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0377278A2 (fr) * 1988-11-14 1990-07-11 Xyrofin Oy Composition édulcorante diététique
WO1990006317A1 (fr) * 1988-12-01 1990-06-14 Cultor Ltd. Monohydrate de lactitol cristallin, son procede de preparation et d'utilisation, et agent edulcorant
WO1993012665A1 (fr) * 1991-12-20 1993-07-08 Wm. Wrigley Jr. Company Produits a base de chewing-gum comportant de la polydextrose
EP0575070A2 (fr) * 1992-06-17 1993-12-22 Jacobs Suchard Ag Produit et procédé pour la fabrication de cholocat au lait

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0954982A1 (fr) * 1998-05-07 1999-11-10 Roquette FrÀ¨res Composition édulcorante et ses utilisations
WO1999056562A1 (fr) * 1998-05-07 1999-11-11 Roquette Freres Composition edulcorante et ses utilisations
FR2778317A1 (fr) * 1998-05-07 1999-11-12 Roquette Freres Composition edulcorante et ses utilisations
KR100397408B1 (ko) * 2000-05-22 2003-09-13 주식회사 보락 감미제를 함유한 동시결정화 당알코올 및 그의 제조 방법
WO2005087020A1 (fr) * 2004-03-05 2005-09-22 Richmond Chemical Corporation Compositions edulcorantes puissantes a base de polyol
US11246835B2 (en) 2014-04-04 2022-02-15 Douxmatok Ltd Method for producing sweetener compositions and sweetener compositions
US11896714B2 (en) 2014-04-04 2024-02-13 Incredo Ltd Method for producing sweetener compositions and sweetener compositions

Also Published As

Publication number Publication date
DE4411582C2 (de) 1996-11-14
EP0763983A1 (fr) 1997-03-26
DE4411582A1 (de) 1995-10-05
AU2214995A (en) 1995-10-23

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