Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/83—Mixtures of non-ionic with anionic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
  • C11D1/146—Sulfuric acid esters
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
  • C11D17/065—High-density particulate detergent compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/0005—Other compounding ingredients characterised by their effect
  • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/02—Inorganic compounds ; Elemental compounds
  • C11D3/12—Water-insoluble compounds
  • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
  • C11D3/1246—Silicates, e.g. diatomaceous earth
  • C11D3/128—Aluminium silicates, e.g. zeolites
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/37—Polymers
  • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
  • C11D3/3776—Heterocyclic compounds, e.g. lactam
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/38—Products with no well-defined composition, e.g. natural products
  • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
  • C11D3/38609—Protease or amylase in solid compositions only
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/39—Organic or inorganic per-compounds
  • C11D3/3942—Inorganic per-compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/29—Sulfates of polyoxyalkylene ethers
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/66—Non-ionic compounds
  • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

• the present invention relates to detergent compositions containing percarbonate bleach, and amylase enzyme at narrowly defined ratios, to provide synergistic stain removal performance, in particular on specific stains such as starch- based stains, and blood stains.
• the inorganic perhydrate bleach most widely used in laundry detergent compositions is sodium perborate in the form of either the onohydrate or tetrahydrate.
• concerns about the impact of boron salts on the environment have led to an increasing interest in other perhydrate salts, of which sodium percarbonate is the most readily available.
• Detergent compositions containing sodium percarbonate are known in the art.
• Sodium percarbonate is an attractive perhydrate for use in detergent compositions because it dissolves readily in water, is weight efficient and, after giving up its available oxygen, provides a useful source of carbonate ions for detergency purposes. - .
• enzymes including amylase in percarbonate-based compositions is known from e.g. JP 57028197; PCT/US93/06302 and PCT/US93/06877.
• particulate stains such as peat clay, mud, fertilizing soil, high organic content clay.
• laundry detergent compositions including laundry additives and automatic dishwashing compositions are encompassed by the term "detergent compositions" herein.
• Methods of treatment of textile are also encompassed.
• the laundry detergent or automatic dishwashing compositions herein typically contain from 1. to 40., preferably from 3% to 30% by weight, most preferably from 5% to 25% by weight of an alkali metal percarbonate bleach (when expresssed on an AvOx basis of 13.5%) in the form of particles having a mean size from 25- ⁇ . c 900 micrometers, preferably 500 to 700 micrometers .
• Laundry adc tives typically contain from 20 to 80 of said percarbonate particles.
• the alkali metal percarbonate bleach is usually in the form of the sodium salt.
• Sodium percarbonate is an addition compound having a formula corresponding to 2Na2C ⁇ 3 3H2O2 •
• the percarbonate bleach can be coated with e.g. a further mixed salt of an alkali metal sulphate and carbonate.
• Such coatings together with coating processes have previously been described in GB-1, 66, 799, granted to Interox on 9th March 1977.
• the weight ratio of the mixed salt coating material to percarbonate lies in the range from 1:2000 to 1:4, more preferably from 1:99 to 1:9, and most preferably from 1:49 to 1:19.
• the mixed salt is of sodium sulphate and sodium carbonate which has the general formula Na2S0 .n.Na2C03 wherein n is from 0.1 to 3, preferably n is from 0.3 to 1.0 and most preferably n is from 0.2 to 0.5.
• Suitable coating materials are sodium silicate, of S ⁇ 2:Na2 ⁇ ratio from 1.6:1 to 2.8:1, and magnesium silicate.
• carbonate/sulphate coated percarbonate bleach may include a low level of a heavy metal sequestrant such as EDTA, 1-hydroxyethyl ⁇ dene 1, 1-d ⁇ phosphon ⁇ c acid (HEDP) or an aminophosphonate, that is incorporated during the manufacturing process.
• a heavy metal sequestrant such as EDTA, 1-hydroxyethyl ⁇ dene 1, 1-d ⁇ phosphon ⁇ c acid (HEDP) or an aminophosphonate
• Preferred heavy metal sequestrants for incorporation as described herein above include the organic phosphonates and ammo alkylene poly (alkylene phosphonates) such as the alkali metal ethane 1-hydroxy diphosphonates, the nitrilo trimethylene phsphonates, the ethylene diamme tetra methylene phosphonates and the diethylene triamme penta methylene phosphonates . Amvlasi;
• compositions herein further comprise as an essential ingredient an amylase enzyme (expressed on an activity of about 60KNU/g) m a weight ratio with percarbonate expressed on an activity basis of 13.5% AvOx) of 1:2 to 300:1, preferably 1:2 to 200:1.
• an amylase enzyme expressed on an activity of about 60KNU/g
• m a weight ratio with percarbonate expressed on an activity basis of 13.5% AvOx
• An even more preferred ratio is 1:2 to 60:1 while the most preferred ratio is 20:1 to 40:1.
• Preferred amylases include, for example, &-amylases obtained from a special strain of B. licheniforms, described in more detail in GB-1,296,839 (Novo Nordisk) .
• Preferred commercially available amylases include for example, Rapidase, sold by International Bio-Synthetics Inc. and Terma yl, sold by Novo Nordisk A/S.
• the detergent compositions herein also contain a protease enzyme
• AvOx 13.5% AvOx of from 5:1 to 1:60, preferably 2:1 to 1:10.
• Preferred commercially available protease enzymes include those sold under the trade names Alcalase and Savmase by Novo Nordisk A/S (Denmark) and Maxatase by International Bio- Synthetics, Inc. (The Netherlands) .
• the laundry detergent compositions herein also comprise a surface-active agent and a builder.
• Surface active agent :
• the detergent compositions of the present invention usually contain one or more anionic surfactants as described below.
• Alkyl sulfate surfactants hereof are water soluble salts or acids of the formula ROSO3M wherein R preferably is a C]_o -c 24 hydrocarbyl, preferably an alkyl or hydroxyalkyl having a C20 alkyl component, more preferably a C]_2" c 18 alkyl or hydroxyalkyl, and M is H or a cation, e.g., an alkali metal cation (e.g., sodium, potassium, lithium), or ammonium or substituted ammonium (e.g., methyl-, dimethyl-, and trimethyl ammonium cations and quaternary ammonium cations, such as tetramethyl-ammonium and dimethyl piperdinium cations and quarternary ammonium cations derived from alkylamines such as ethylamine, diethylamine, triethylamine, and mixtures thereof, and the like) .
• alkyl chains
• Alkyl alkoxylated sulfate surfactants hereof are water soluble salts or acids of the formula R0(A) m S03M wherein R is an unsubstituted C10-C24 alkyl or hydroxyalkyl group having a c 10 ⁇ c 24 alkyl component, preferably a ]_2 -c 20 alkyl or hydroxyalkyl, more preferably C]_2-C_g alkyl or hydroxyalkyl, A is an ethoxy or propoxy unit, m is greater than zero, typically between about 0.5 and about 6, more preferably between about 0.5 and about 3, and M is H or a cation which can be, for example, a metal cation (e.g., sodium, potassium, lithium, calcium, magnesium, etc.), ammonium or substituted- ammonium cation.
• R is an unsubstituted C10-C24 alkyl or hydroxyalkyl group having a c 10 ⁇ c 24 alkyl
• Alkyl ethoxylated sulfates as well as alkyl prcpoxyla-te ⁇ Sulfates are contemplated nere .
• suest tateo ammonurn cations include methyl-, dimethyl-, trireth_v-i-ar.mon_.ur. and quaternary arnmonium cations, such as tetramethyl-ammonium, dimethyl piperdinium and cations derived from alkanolamines such as ethylamme, diethylam e, triethylam e, mixtures thereof, and the like.
• Exemplary surfactants are C * -_2 ⁇ C_ .
• anionic surfactants useful for detersive purposes can also be included in the laundry detergent compositions of the present invention. These can include salts (including, for example, sodium, potassium, ammonium, and substituted ammonium salts such as mono-, di- and tnethanolamme salts) of soap, C9-C20 linear alkylbenzenesulphonates, C-8 _c 22 primary or secondary alkanesulphonates, c 8 -c 24 olefmsulphonates, sulphonated polycarboxylic acids prepared by sulphonation of the pyrolyzed product of alkaline earth metal citrates, e.g., as described in British patent specification No.
• salts including, for example, sodium, potassium, ammonium, and substituted ammonium salts such as mono-, di- and tnethanolamme salts
• C9-C20 linear alkylbenzenesulphonates C-8 _c 22 primary or secondary alkanesulphonates
• alkylpolyglycolethersulfates (containing up to 10 moles of ehtylene oxide) ; alkyl ester sulfonates such as C]_4_i6 methyl ester sulfonates; acyl glycerol sulfonates, fatty oleyl glycerol sulfates, alkyl phenol ethylene oxide ether sulfates, paraffin sulfonates, alkyl phosphates, lsethionates such as the acyl lsethionates, N-acyl taurates, alkyl succinamates and sulfosuccmates, monoesters of sulfosucc ate (especially saturated and unsaturated ]_2 ⁇ 8 monoesters) diesters of sulfosuccmate (especially saturated and unsaturated g-C]_4 diesters) , acyl sarcosm
• Res acids and hydrogenated resin acids are also suitable, such as rosin, hydrogenated rosin, and resm acids and hydrogenated resm acids present m or derived from tall oil. Further examples are given in "Surface Active Agents and Detergents" (Vol. I and II by Schwartz, Perry and Berch) . A variety of such surfactants are also generally disclosed in U.S. Patent 3,929,678, issued December 30, 1975 to Laughlm, et al. at Column 23, line 58 through Column 29, line 23 (herein incorporated by reference) .
• Preferred surfactants for use m the compositions herein are the alkyl sulfates, alkyl alkoxylated sulfates, and mixtures thereof.
• the laundry detergent compositions of the present invention typically comprise from about 1 % to about 40 %, preferably from about 3 % to about 20 % by weight of such anionic surfactants.
• the present laundry detergent compositions preferably also comprise a nonionic surfactant.
• nonionic surfactant While any nonionic surfactant may be normally employed in the present invention, two families of nonionics have been found to be particularly useful. These are nonionic surfactants based on alkoxylated (especially ethoxylated) alcohols, and those nonionic surfactants based on amidation products of fatty acid esters and N-alkyl polyhydroxy amme. The amidation products of the esters and the amines are generally referred to herein as polyhydroxy fatty acid amides. Particularly useful in the present invention are mixtures comprising two or more nonionic surfactants wherein at least one nonionic surfactant is selected from each of the groups of alkoxylated alcohols and the polyhydroxy fatty acid amides.
• Suitable non cn c surfactants include compounds produced by the condensation of alkylene oxide groups (hydrophilic in nature) with an organic hydrophobic compound, which may be aliphatic or alkyl aromatic in nature.
• the length of the polyoxyalkylene group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water- soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
• nonionic surfactants such as the polyethylene oxide condensates of alkyl phenols, e.g., the condensation products of alkyl phenols having an alkyl group containing from about 6 to 16 carbon atoms, in either a straight chain or branched chain configuration, with from about 4 to 25 moles of ethylene oxide per mole of alkyl phenol.
• Preferred nonionics are the water-soluble condensation products of aliphatic alcohols containing from 8 to 22 carbon atoms, in either straight chain or branched configuration, with an average of up to 25 moles of ethylene oxide per more of alcohol.
• Particularly preferred are the condensation products of alcohols having an alkyl group containing from about 9 to 15 carbon atoms with from about 2 to 10 moles of ethylene oxide per mole of alcohol; and condensation products of propylene glycol with ethylene oxide.
• the nonionic surfactant system herein can also include a polyhydroxy fatty acid amide component.
• Polyhydroxy fatty acid amides may be produced by reacting a fatty acid ester and an N-alkyl polyhydroxy amine .
• the preferred amine for use in the present invention is N-(R1)- CH2 (CH20H) -CH2-OH and the preferred ester is a C12-C20 fatty acid metfwl . ester .
• Most preferred is the reaction product of N-methyi glucamme witn C12-C20 fatty acid retny_. ester.
• Nonionic surfactant systems and granular detergents made from such systems have been described m WO 92 6160, published on 16th April, 1992.
• This application describes (example 15) a granular detergent composition prepared by fine dispersion mixing in an Eirich RV02 mixer which comprises N-methyl glucamide (10%), nonionic surfactant (10%) .
• the laundry detergent compositions of the present invention may also contain cationic, ampholytic, zwitterionic, and semi- polar surfactants, as well as nonionic surfactants other than those alrea ⁇ y described herein, including the semi-polar nonionic amine oxides described below.
• Cationic detersive surfactants suitable for use in the laundry detergent compositions of the present invention are those having one long-chain hydrocarbyl group.
• cationic surfactants include the ammonium surfactants such as alkyldimethylammonium halogenides, and those surfactants having the formula :
• each R 4 is selected from the group consisting of C1-C4 alkyl, C1-C4 hydroxyalkyl, benzyl ring structures formed by joining the two R 4 groups,
• R6 is any hexose or hexose polymer having a molecular weight less than about 1000, and hydrogen when y is not 0;
• R * * *** is the same as R 4 or is an alkyl chain wherein the total number of carbon atoms of R 2 plus R * *- *1 is not more than about 18; each y is from 0 to about 10 and the sum of the y values is from 0 to about 15; and
• X is any compatible anion.
• the laundry detergent compositions of the present invention typically comprise from 0 % to about 25 %, preferably form about 3 - to about 15 by weight of such cationic surfactants.
• Ampholytic surfactants are also suitable for use in the laundry detergent compositions of the present invention. These surfactants can be broadly described as aliphatic derivatives of secondary or tertiary amines, or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical can be straight- or branched chain.
• One of the aliphatic substituents contains at least 8 carbon atoms, typically from about 8 to about 18 carbon atoms, and at least one contains an anionic water-solubilizing group e.g.
• the laundry detergent compositions of the present invention typically comprise form 0 % to about 15 %, preferably from about 1 % to about 10 % by weight of such ampholytic surfactants.
• Zwitterionic surfactants are also suitable for use in laundry detergent compositions. These surfactants can be broadly described as derivatives of secondary and tertiary, amines, derivates of heterocyclic secondary and tertiary amines, or derivatives of quaternary ammonium, quarternary phosphoniu or tertiary sulfoniu compounds. See U.S. Patent No. 3,929,678 to Laughlin et al . , issued December 30, 1975 at columns 19, line 38 through column 22, line 48 (herein incorporated by reference) for examples of zwitterionic surfactants .
• the laundry detergent compositions of the present invention typically comprise form 0 % to about 15 %, preferably from about 1 % to about 10 % by weight of such zwitterionic surfactants.
• Semi-polar nonionic surfactants are a special category of nonionic surfactants which include water-soluble amine oxides containing one alkyl moiety of from about 10 to about 18 carbon atoms, and 2 mcieties selected frcir the group consisting af alkyl groups ana nyarocyal yl groups containing form about 1 to about 3 carbon atoms; water-soluble phosphine oxides containing one alkyl moiety of form about 10 to about 18 carbon atoms and 2 moieties selected form the group consisting of alkyl groups and hydroxyalkyl groups containing from about 1 to about 3 carbon atoms.
• Semi-polar nonionic detergent surfactants include the amine oxide surfactants having the formula :
• compositions herein preferably contain a builder, most preferably non-phosphate detergent builders. These can include, but are not restricted to alkali metal carbonates, bicarbonates, silicates, aluminosilicates, carboxylates and mixtures of any of the foregoing.
• the builder system is present in an amount of from 25% to 80% by weight of the composition, more preferably from 30% to 60% by weight.
• Suitable silicates are those having an S1O2 '• Na2 ⁇ ratio in the range from 1.6 to 3.4, the so-called amorphous silicates of Si ⁇ 2 : Na2 ⁇ ratios from 2.0 to 2.8 being preferred.
• M is sodium or hydrogen
• x is a number from 1.9 to 4
• y is a number from 0 to 20.
• Crystalline layered sodium silicates of this type are disclosed in EP-A-0164514 and methods for their preparation are disclosed in DE-A-3417649 and DE-A-3742043.
• x in the—general formula above has a value of 2,3 or 4 and is preferably 2. More preferably M is sodium and y is 0 and a preferred example of this formula comprise the form of a2Si2 ⁇ 5- These materials are available from Hoechst AG FRG as respectively NaSKS-5, NaSKS-7, NaSKS-11 and NaSKS-6. The most preferred material is -Na2Si2 ⁇ 5, NaSKS-6.
• Crystalline layered silicates are incorporated either as dry mixed solids, or as solid components of agglomerates with other components.
• preferred sodium alummosilicate zeolites have the unit cell formula
• Amorphous hydrated alummosilicate materials useful herein have the empirical formula
• M is sodium, potassium, ammonium or substituted ammonium
• z ' is from about 0.5 to about 2 and y is 1, said material having a magnesium ion exchange capacity of at least about 50 milligram equivalents of CaC03 hardness per gram of anhydrous alummosilicate.
• Hydrated sodium Zeolite A with a particle size of from about 1 to 10 microns is preferred.
• the alummosilicate ion exchange builder materials herein are in hydrated form and contain from about 10% to about 28% of water by weight if crystalline, and potentially even higher amounts of water if amorphous. Highly preferred crystalline alummosilicate ion exchange materials contain from about 18% to about 22% water in their crystal matrix.
• the crystalline alummosilicate ion exchange materials are further characterized by a particle size diameter of from about 0.1 micron to about 10 microns. Amorphous materials are often smaller, -e.g., down tc less tnan aoout ⁇ .Ol micron.
• Preferred ion excnange -ater_als have a particie size diameter of from about 0.2 micrcn tc about 4 microns.
• the term "particle size diameter" herein represents the average particle size diameter by weight of a given ion exchange material as determined by conventional analytical techniques such as, for example, microscopic determination utilizing a scanning electron microscope .
• Alummosilicate ion exchange materials useful in the practice of this invention are commercially available.
• the alummosilicates useful in this invention can be crystalline or amorphous in structure and can be naturally occurring alummosilicates or synthetically derived.
• a method for producing alummosilicate ion exchange materials is discussed in U.S. Pat. No. 3,985,669, Kru mel et al., issued Oct. 12, 1976, incorporated herein by reference.
• Preferred synthetic crystalline alummosilicate ion exchange materials useful herein are available under the designations Zeolite A, Zeolite X, P and MAP, the latter species being described in EPA 384070.
• the crystalline alummosilicate ion exchange material is a Zeolite A having the formula
• x is from about 20 to about 30, especially about 27 and has a particle size generally less than about 5 microns.
• Suitable carboxylate builders containing one carboxy group include lactic acid, glycollic acid and ether derivatives thereof as disclosed in Belgian Patent Nos. 831,368, 821,369 and 821,370.
• Polycarboxylates containing two carboxy groups include the water-soluble salts of succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic acid, diglycollic acid, tartaric acid, tartronic acid and fumaric acid, as well as the ether carboxylates described in German Offenlegenschrift 2,446,686 and 2,446,687 and U.S. Patent No. 3,935,25-3- and the sulfmyl carboxylates described Belgian Patent No. 640,623.
• Polycarooxylates containing three carboxy groups include, in particular, water-soluble citrates, acomtrates and citraconates as well as succinate derivatives such as the carboxymethyloxysuccinates described in British Patent No. 1,379,241, lactoxysuccinates described in Netherlands Application 7205873, and the oxypolycarboxylate materials such as 2-oxa-l, 1, 3-propane tricarboxylates described in British Patent No. 1,387,447.
• Polycarboxylates containing four carboxy groups include oxydisuccinates disclosed in British Patent No. 1,261,829,1, and the 1,2,2-ethane tetracarboxylates , 1, 1, 3, 3-propane tetracarboxylates and 1, 1, 2, 3-propane tetracarboxylates.
• Polycarboxylates containing sulfo substituents include the sulfosuccinate derivatives disclosed in British Patent Nos. 1,398,421 and 1,398,422 and in US Patent No. 3,936,448, and the sulfonated pyrolysed citrates described in British Patent No. 1,082,179, while polycarboxylates containing phosphone substituents are disclosed in British Patent No. 1,439,000.
• Alicyclic and heterocyclic polycarboxylates include cyclopentane-cis, cis, cis-tetracarboxylates, cyclopentadienide pentacarboxylates, 2, 3, 4, 5-tetrahydrofuran - cis, cis, cis- tetracarboxylates, 2, 5-tetrahydrofuran -cis- dicarboxylates, 2, 2, 5, 5, -tetrahydrofuran - tetracarboxylates, 1,2,3,4,5,6- hexane hexacarboxylates and carbxoymethyl derivatives of polyhydric alcohols such as sorbitol, mannitol and xylitol.
• Aromatic polycarboxylates include mellitic acid, pyromellitic acid and the phtalic acid derivates disclosed in British Patent No. 1,425, 343.
• the preferred polycarboxylates are hydroxycarboxylates containing up to three carboxy groups per molecule, more particularly citrates.
• the parent acids of the monomeric or oligomeric polycarboxylate chelating agents or mixtures thereof with their salts are a so—conteirpiate ⁇ as components cf D_ ⁇ der systems useful in the present invention .
• compositions are preferably m a compact form, having a bulk density of at least 650 g/1, but can also be in a conventional form, with densities in a range of from 200 g/1 to 700 g/1.
• Automatic dishwashing compositions typically contain, in addition to the percarbonate and silica of the inventions, a builder, such as described above, and a source of alkalinity, such as silicate or carbonate, those ingredients amounting to up to 70% of the formulation.
• a builder such as described above
• a source of alkalinity such as silicate or carbonate
• optional ingredients include polymers and enzymes.
• Laundry Additive Compositions typically contain in addition to the percarbonate and silica of the invention, a builder and a source of alkalinity.
• ingredients which are known for use in detergent compositions may also be used as optional ingredients the various embodiments of the present invention, such as bleach activators, other bleaching agents, polymers, other enzymes, suds suppressing agents, as well as dyes, fillers, optical b ⁇ ghteners, pH adjusting agents, non builder alkalinity sources, enzyme stability agents, hydrotopes, perfumes.
• the present compositions especially the laundry detergent compositions/additives, preferably contain from 1. to 20. by weight of the composition, preferably from 2 to 15 by weight, -mos.t preferably f: .m to 10 V weight oi peroxyacid bleach activator.
• Peroxyacid bleach activators as additional bleaching components in accordance with the invention can be selected from a wide range of class and are preferably those containing one or more N-or O-acyl groups.
• Suitable classes include anhydrides, esters, amides, and acylated derivatives of imidazoles and oximes, and examples of useful materials within these classes are disclosed in GB-A- 1586789.
• the most preferred classes are esters such as are disclosed in GB-A-836 988, 864,798, 1 147 871 and 2 143 231 and amides such as are disclosed in GB-A-855 735 and 1 246 338.
• Particularly preferred bleach activator compounds as additional bleaching components in accordance with the invention are the N-,N,N'N' tetra acetylated compounds of the formula
• x can be 0 or an integer between 1 and 6,
• TAMD tetra acetyl methylene diamine
• TAED tetra acetyl ethylene diamine
• TAHD Tetraacetyl hexylene diamine
• R! is an aryl or alkaryl group with from about 1 to about 14 carbon atoms
• R 2 is an alkylene, arylene, and alkarylene group containing from about 1 to about 14 carbon atoms
• R * ** * ' is H or an alkyl, aryl, or alkaryl group containing 1 to 10 carbon atoms and L can be essentially any leaving group.
• R! preferably contains from about 6 to 12 carbon atoms.
• R 2 preferably contains from about 4 to 8 carbon atoms.
• R- * - may be straight chain or branched alkyl, substituted aryl or alkylaryl containing branching, substitution, or both and may be sourced from either synthetic sources or natural sources including for example, tallow fat.
• R Analogous structural variations are permissible for R .
• the substitution can include alkyl, aryl, halogen, nitrogen, sulphur and other typical substituent groups or organic compounds.
• R- ** - * is preferably H or methyl.
• R! and R * - *** should not contain more than 18 carbon atoms total.
• Amide substituted bleach activator compounds of this type are described in EP-A-0170386.
• Another class of bleach activators to use in combination with percarbonate comprises Cg, Cg, and/or C]_o (6- octanamidocaproyl) oxybenzenesulfonate, 2-phenyl- (4H) 3, 1 benzoxazin-4-one, benzoyllactam preferably benzoylcaprolactam and nonanoyl lactam preferably nonanoyl caprolactam.
• compositions herein may also contain another bleaching system such as perborate and activator, or a preformed organic peracid or perimidic acid, such as N,N phthaloylaminoperoxy caproic acid, 2-carboxy- phtaloylaminoperoxy caproic acid, N,N phthaloylaminoperoxy valeric —acid, Nonyl amide of peroxy adipic acid, 1,12 diperoxydodecanedoic acid, Peroxybenzoic acid and ring substituted peroxybenzoic acid, Monoperoxyphtalic acid
• another bleaching system such as perborate and activator, or a preformed organic peracid or perimidic acid, such as N,N phthaloylaminoperoxy caproic acid, 2-carboxy- phtaloylaminoperoxy caproic acid, N,N phthaloylaminoperoxy valeric —acid, Nonyl amide of peroxy adipic acid, 1,
• organic polymers some of which also may function as builders to improve detergency. Included among such polymers may be mentioned sodium carboxy-lower alkyl celluloses, sodium lower alkyl celluloses and sodium hydroxy-lower alkyl celluloses, such as sodium carboxymethyl cellulose, sodium methyl cellulose and sodium hydroxypropyl cellulose, polyvinyl alcohols (which often also include some polyvinyl acetate) , polyacrylamides, polyacrylates and various copolymers, such as those of maleic and acrylic acids. Molecular weights for such polymers vary widely but most are within the range of 2,000 to 100,000. Also very useful are terpolymers of maleic/acrylic acid and vinyl alcohol having a molecular weight ranging from 3.000 to 70.000.
• Polymeric polycarboxylate builders are set forth in U.S.- Patent 3,308,067, Diehl, issued March 7, 1967. Such materials include the water-soluble salts of homo-and copolymers of aliphatic carboxylic acids such as maleic acid, itaconic acid, mesaconic acid, fumaric acid, aconitic acid, citraconic acid and methylenemalonic acid.
• Other useful polymers include species known as soil release polymers, such as described in EPA 185 427 and EPA 311 342.
• Still other polymers suitable for use herein include dye transfer inhibition polymers such as polyvinylpyrrolidone, polyvinylpyrridine, N-oxide, N-vinylpyrrolidone, N-imidazole, polyvinyloxozolidone or polyvinylimidazole.
• dye transfer inhibition polymers such as polyvinylpyrrolidone, polyvinylpyrridine, N-oxide, N-vinylpyrrolidone, N-imidazole, polyvinyloxozolidone or polyvinylimidazole.
• Enzymatic materials otner than amylases and proteases can oe incorporated into the detergent compositions herein. Suitable are lipases, cellulases and mixtures thereof.
• a suitable lipase enzyme is manufactured and sold by Novo Nordisk A/S (Denmark) under the trade name L ⁇ polase R and mentioned along with other suitable lipases in EP-A-0258068 (Novo Nordisk A/S) .
• Suitable cellulases are described in e.g. WO-92/13057 (Novo) .
• Starch-based stains include chocolate stains, as well as typical kitchen stains such as mayonnaise, mustard, ice-cream, dairy products.
• Such stains are very difficult to remove at low temperature, and the present invention provides for a method of treating textiles at all temperatures, including at low temperature, wherein a detergent composition according to the above description is used.
• the invention also encompasses a similar method for treating fabrics to remove blood stains and fabrics stained with stains rich in blood.
• particulate stains is meant for instance peat clay, mud, high organic content clay mainly found m socks, sportswear and the like.
• Mucin — cr mucin-protem based stains include female secretions and handkerchief stains (bronchial mucus) .
• Such stains are very difficult to remove at low temperature, and the present invention provides for a method of treating textiles at all temperatures, including at low temperature, wherein a detergent composition according to the above description is used.
• the method for treating fabrics is typically a laundry machine washing operation, and can be conducted by any method well known in the art; a particularly preferred method includes the use of a reusable dispensing device, in which the detergent composition is put before the washing cycle, and which is placed in the drum of the washing machine together with the clothes to be washed, before starting the washing machine.
• composition II
• Zeolite A 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0
• Example 1 blood based stain removal
• Example 2 stain removal from chocolate ice cream
• Example 3 blood based stain removal
• Example 5 particulate stain removal Conditions as mentioned under Example 4
• Example _L chocolate ice cream stain removal

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• 1994
  • 1994-12-15 CA CA002176697A patent/CA2176697C/en not_active Expired - Lifetime
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  • 1994-12-15 CN CN94194598A patent/CN1138346A/zh active Pending
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• 2000
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