WO1995009049B1 - Catalyseur d'hydrotraitement et ses utilisations - Google Patents
Catalyseur d'hydrotraitement et ses utilisationsInfo
- Publication number
- WO1995009049B1 WO1995009049B1 PCT/US1994/011095 US9411095W WO9509049B1 WO 1995009049 B1 WO1995009049 B1 WO 1995009049B1 US 9411095 W US9411095 W US 9411095W WO 9509049 B1 WO9509049 B1 WO 9509049B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- component
- refractory oxide
- region
- molybdenum
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract 21
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract 14
- 229910052759 nickel Inorganic materials 0.000 claims abstract 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract 6
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract 6
- 239000011733 molybdenum Substances 0.000 claims abstract 6
- 239000011148 porous material Substances 0.000 claims abstract 6
- 229910003301 NiO Inorganic materials 0.000 claims abstract 3
- 238000001237 Raman spectrum Methods 0.000 claims abstract 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 3
- 229910052698 phosphorus Inorganic materials 0.000 claims 3
- 239000011574 phosphorus Substances 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 1
- 229910052753 mercury Inorganic materials 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract 5
- 239000002184 metal Substances 0.000 abstract 5
- 230000003197 catalytic Effects 0.000 abstract 2
- 229910015621 MoO Inorganic materials 0.000 abstract 1
- 238000001069 Raman spectroscopy Methods 0.000 abstract 1
- 230000001747 exhibiting Effects 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
Abstract
Catalyseur contenant une couche supérieure de promoteur de catalyse disposée sur un support réfractaire poreux contenant un composant sous-jacent d'un métal du groupe VIII. Ledit catalyseur se prépare par incorporation séquentielle dudit métal puis dudit promoteur qui est généralement un métal du groupe VIB avec le support réfractaire poreux. Les composants de nickel sous-jacents se caractérisent par leur spectre de Raman unique présentant des bandes de Raman dans la région allant d'env. 240 cm-1 à env. 250 cm-1 et dans la région allant d'env. 595 cm-1 à env. 595 cm-1. Le catalyseur présente un rapport MoO¿3?/NiO en poids inférieur à 6/1 et plus de 4 % en poids de NiO. Le catalyseur se prépare en produisant d'abord un mélange particulaire calciné contenant un groupe de composés de métaux du groupe VIII et un oxyde réfractaire, auquel on ajoute un promoteur tel qu'un composé de métaux du groupe VIB, puis en recalcinant la composition ainsi obtenue. Les promoteurs préférés sont des composés de molybdène et de phosphore et la composition préférée consiste en oxydes de Ni-P-Mo sur l'alumine. Le catalyseur sert plus particulièrement à l'hydrodénitrogénation et à l'hydrodésulfurisation simultanées du gazole surtout lorsque le support d'oxyde réfractaire présente une distribution étroite de la taille de ses pores.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK94929966T DK0721373T3 (da) | 1993-09-30 | 1994-09-29 | Hydrogenbehandlingskatalysator samt dens anvendelse |
JP51047095A JP3821483B2 (ja) | 1993-09-30 | 1994-09-29 | 水素化処理用の触媒とその利用法 |
DE69423106T DE69423106T2 (de) | 1993-09-30 | 1994-09-29 | Wasserstoffbehandlungskatalysator und seine verwendung |
EP94929966A EP0721373B1 (fr) | 1993-09-30 | 1994-09-29 | Catalyseur d'hydrotraitement et ses utilisations |
AU79242/94A AU676393B2 (en) | 1993-09-30 | 1994-09-29 | Hydroprocessing catalyst, its use, and method of preparation |
AT94929966T ATE189860T1 (de) | 1993-09-30 | 1994-09-29 | Wasserstoffbehandlungskatalysator und seine verwendung |
NO961265A NO961265L (no) | 1993-09-30 | 1996-03-28 | Katalysator for anvendelse ved hydroprosessering |
FI961429A FI961429A (fi) | 1993-09-30 | 1996-03-29 | Vetykäsittelykatalyytti ja sen käyttö |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/130,109 US5389595A (en) | 1993-09-30 | 1993-09-30 | Hydroprocessing catalyst, its use, and method of preparation |
US08/130,109 | 1993-09-30 | ||
US08/313,723 US5686375A (en) | 1993-09-30 | 1994-09-27 | Hydroprocessing catalyst and its use |
US08/313,723 | 1994-09-27 |
Publications (3)
Publication Number | Publication Date |
---|---|
WO1995009049A2 WO1995009049A2 (fr) | 1995-04-06 |
WO1995009049A3 WO1995009049A3 (fr) | 1995-06-08 |
WO1995009049B1 true WO1995009049B1 (fr) | 1995-08-03 |
Family
ID=26828181
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1994/011095 WO1995009049A2 (fr) | 1993-09-30 | 1994-09-29 | Catalyseur d'hydrotraitement et ses utilisations |
Country Status (6)
Country | Link |
---|---|
US (1) | US5906731A (fr) |
JP (1) | JP3821483B2 (fr) |
CN (1) | CN1074687C (fr) |
CA (1) | CA2170625A1 (fr) |
NO (1) | NO961265L (fr) |
WO (1) | WO1995009049A2 (fr) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7291257B2 (en) * | 1997-06-24 | 2007-11-06 | Process Dynamics, Inc. | Two phase hydroprocessing |
JP4174079B2 (ja) * | 1997-06-24 | 2008-10-29 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 2相水素化処理 |
US7569136B2 (en) | 1997-06-24 | 2009-08-04 | Ackerson Michael D | Control system method and apparatus for two phase hydroprocessing |
JP2000000470A (ja) * | 1998-06-15 | 2000-01-07 | Idemitsu Kosan Co Ltd | 水素化処理触媒及び重質油の水素化処理方法 |
CA2320485C (fr) * | 1998-12-08 | 2005-02-08 | Japan Energy Corporation | Catalyseur d'hydrodesulfuration et son procede de preparation |
ATE296163T1 (de) * | 1999-04-08 | 2005-06-15 | Albemarle Netherlands Bv | Verfahren zur sulfidierung eines organischen stickstoff und carbonyl enthaltenden hydrobehandlungskatalysators |
US6841512B1 (en) * | 1999-04-12 | 2005-01-11 | Ovonic Battery Company, Inc. | Finely divided metal catalyst and method for making same |
CN1093434C (zh) * | 1999-09-17 | 2002-10-30 | 厦门大学 | 细菌还原法制备负载型金催化剂 |
JP4638610B2 (ja) * | 2001-01-05 | 2011-02-23 | 日本ケッチェン株式会社 | 水素化処理用触媒並びに水素化処理方法 |
US6759364B2 (en) * | 2001-12-17 | 2004-07-06 | Shell Oil Company | Arsenic removal catalyst and method for making same |
WO2004020090A1 (fr) | 2002-08-30 | 2004-03-11 | Japan Energy Corporation | Procede de production d'un catalyseur d'hydrodesulfurisation |
TW200513320A (en) * | 2003-06-16 | 2005-04-16 | Shell Int Research | A process and catalyst for the selective hydrogenation of diolefins contained in an olefin containing stream and for the removal of arsenic therefrom and a method of making such catalyst |
US8070937B2 (en) * | 2003-12-19 | 2011-12-06 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
US7745369B2 (en) * | 2003-12-19 | 2010-06-29 | Shell Oil Company | Method and catalyst for producing a crude product with minimal hydrogen uptake |
US20070000808A1 (en) * | 2003-12-19 | 2007-01-04 | Bhan Opinder K | Method and catalyst for producing a crude product having selected properties |
EP1702682A4 (fr) * | 2004-01-09 | 2009-06-10 | Nippon Oil Corp | Catalyseur d'hydrogenation et de desulfuration pour hydrocarbure de petrole et procede d'hydrogenation et de desulfuration utilisant ce catalyseur |
JP4249632B2 (ja) * | 2004-01-09 | 2009-04-02 | 新日本石油株式会社 | 石油系炭化水素の水素化脱硫触媒および水素化脱硫方法 |
JP2006035052A (ja) * | 2004-07-23 | 2006-02-09 | Nippon Oil Corp | 石油系炭化水素の水素化脱硫触媒および水素化脱硫方法 |
JP2008545812A (ja) * | 2005-04-26 | 2008-12-18 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | オレフィン含有炭化水素原料の選択的水添脱硫のための方法 |
MXPA05012893A (es) * | 2005-11-29 | 2007-11-23 | Mexicano Inst Petrol | Catalizador para la hidrodesulfuracion de residuos y crudos pesados. |
GB201000045D0 (en) * | 2010-01-04 | 2010-02-17 | Johnson Matthey Plc | Catalyst and method of catalyst manufacture |
WO2011140175A1 (fr) | 2010-05-07 | 2011-11-10 | Mannkind Corporation | Détermination d'un pourcentage de solides en suspension par spectrométrie raman |
WO2012100068A2 (fr) | 2011-01-19 | 2012-07-26 | Process Dynamics, Inc. | Procédé d'hydrotraitement de matières premières non-pétrole |
US20130105357A1 (en) * | 2011-10-27 | 2013-05-02 | Shell Oil Company | Self-activating hydroprocessing catalyst and process for treating heavy hydrocarbon feedstocks |
WO2016007686A1 (fr) * | 2014-07-11 | 2016-01-14 | Shell Oil Company | Catalyseur d'hydrotraitement pour le traitement d'une charge d'hydrocarbures ayant une concentration d'arsenic et un procédé de fabrication et d'utilisation de ce catalyseur |
WO2016195973A1 (fr) * | 2015-05-29 | 2016-12-08 | Advanced Refining Technologies Llc | Catalyseur d'hydrotraitement à haute sélectivité hdn |
CN105772004A (zh) * | 2016-03-24 | 2016-07-20 | 山东成泰化工有限公司 | 一种苯加氢催化剂及其制备方法 |
US10023813B2 (en) | 2016-06-23 | 2018-07-17 | King Fahd University Of Petroleum And Minerals | Process for selective deep hydrodesulfurization of a hydrocarbon feedstock using an unsupported nanocatalyst made by laser pyrolysis |
US9919293B1 (en) * | 2017-07-17 | 2018-03-20 | Kuwait Institute For Scientific Research | Catalyst for mild-hydrocracking of residual oil |
FR3075072B1 (fr) * | 2017-12-14 | 2021-11-26 | Ifp Energies Now | Catalyseur d'hydrodesulfuration selective des essences de fcc |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2983691A (en) * | 1957-02-04 | 1961-05-09 | Union Oil Co | Preparation of supported metal molybdate catalysts |
US3285860A (en) * | 1963-12-09 | 1966-11-15 | Union Oil Co | Method of preparing nickel-molyb-denum-alumina catalysts |
US3770618A (en) * | 1967-06-26 | 1973-11-06 | Exxon Research Engineering Co | Hydrodesulfurization of residua |
US3617528A (en) * | 1969-10-16 | 1971-11-02 | Universal Oil Prod Co | Hydrotreating process and catalyst |
US3751380A (en) * | 1971-12-06 | 1973-08-07 | Universal Oil Prod Co | Method of preparing a catalyst |
US3853788A (en) * | 1973-02-06 | 1974-12-10 | American Cyanamid Co | Process for hydrotreating catalyst and product thereby |
US4013547A (en) * | 1976-01-22 | 1977-03-22 | Union Oil Company Of California | Desulfurization of residual petroleum oils with a catalyst calcined at higher temperatures |
GB2055599B (en) * | 1979-07-31 | 1983-04-07 | Coal Industry Patents Ltd | Alumina-supported hydrotreatment catalysts |
US4434048A (en) * | 1980-11-21 | 1984-02-28 | The Lummus Company | Hydrotreating catalyst and use thereof |
US4317746A (en) * | 1980-11-28 | 1982-03-02 | Union Oil Company Of California | Hydrotreating catalysts |
NL8201696A (nl) * | 1982-04-23 | 1983-11-16 | Unilever Nv | Werkwijze ter bereiding van methaneringskatalysatoren. |
US4818743A (en) * | 1983-04-07 | 1989-04-04 | Union Oil Company Of California | Desulfurization catalyst and the catalyst prepared by a method |
US4579649A (en) * | 1983-12-19 | 1986-04-01 | Intevep, S.A. | Process for demetallization of heavy crudes using a catalyst having high metal retention capacity and good stability |
US4520128A (en) * | 1983-12-19 | 1985-05-28 | Intevep, S.A. | Catalyst having high metal retention capacity and good stability for use in the demetallization of heavy crudes and method of preparation of same |
US4738944A (en) * | 1986-12-05 | 1988-04-19 | Union Oil Company Of California | Ni-P-Mo catalyst and hydroprocessing use thereof |
US4846961A (en) * | 1986-12-05 | 1989-07-11 | Union Oil Company Of California | Hydroprocessing catalyst with a Ni-P-Mo |
US4729980A (en) * | 1987-04-27 | 1988-03-08 | Intevep, S.A. | Catalyst for the simultaneous hydrodemetallization and hydroconversion of heavy hydrocarbon feedstocks and process for preparing the catalyst |
US4969990A (en) * | 1988-06-29 | 1990-11-13 | Union Oil Company Of California | Hydroprocessing with a catalyst having a narrow pore size distribution |
US5290429A (en) * | 1990-05-25 | 1994-03-01 | Union Oil Company Of California | Catalytic aromatic saturation in the presence of halide |
US5135902A (en) * | 1990-05-25 | 1992-08-04 | Union Oil Company Of California | Nickel-tungsten-phosphorus catalyst |
US5403806A (en) * | 1993-10-22 | 1995-04-04 | Union Oil Company Of California | Phosphorous-containing hydroprocessing catalyst and method of preparation |
-
1994
- 1994-09-29 WO PCT/US1994/011095 patent/WO1995009049A2/fr active IP Right Grant
- 1994-09-29 CN CN94193604A patent/CN1074687C/zh not_active Expired - Lifetime
- 1994-09-29 JP JP51047095A patent/JP3821483B2/ja not_active Expired - Lifetime
- 1994-09-29 CA CA002170625A patent/CA2170625A1/fr not_active Abandoned
-
1996
- 1996-03-28 NO NO961265A patent/NO961265L/no not_active Application Discontinuation
-
1997
- 1997-07-28 US US08/901,354 patent/US5906731A/en not_active Expired - Lifetime
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO1995009049B1 (fr) | Catalyseur d'hydrotraitement et ses utilisations | |
WO1995009049A3 (fr) | Catalyseur d'hydrotraitement et ses utilisations | |
CA2228889C (fr) | Procede d'hydroconversion au moyen d'un catalyseur a repartition de dimensions de pores specifique, sans ajout de silice | |
US4255282A (en) | Hydrotreating catalyst and process for its preparation | |
US5545602A (en) | Catalyst with specified pore size distribution | |
US5399259A (en) | Hydroconversion process employing catalyst with specified pore size distribution | |
AU676393B2 (en) | Hydroprocessing catalyst, its use, and method of preparation | |
KR100209814B1 (ko) | 수소화처리 촉매조성물, 그 제조방법 및 용도 | |
US5616530A (en) | Hydroconversion process employing catalyst with specified pore size distribution | |
US5928499A (en) | Hydroconversion process employing catalyst with specified pore size distribution, median pore diameter by surface area, and pore mode by volume | |
EP0201762B2 (fr) | Catalyseurs pour l'hydroconversion d'huiles lourdes | |
GB2156847A (en) | Demetallization of heavy crudes | |
CA2470393A1 (fr) | Catalyseur d'extraction d'arsenic et procede de fabrication de ce catalyseur | |
EP0876442B1 (fr) | PROCEDE D'HYDROCONVERSION UTILISANT UN CATALYSEUR NiMoP CHARGE DE PHOSPHORE AVEC UNE REPARATITION SPECIFIEE DE LA TAILLE DES PORES | |
CA2358695A1 (fr) | Methode hydraulique d'affinage mettant en oeuvre des catalyseurs en vrac des groupes viii et vib | |
KR960010073A (ko) | 수소처리촉매, 그의 용도 및 그의 제조방법 | |
EP1567617B1 (fr) | Hydrotraitement d'hydrocarbones au moyen d'un melange de catalyseurs | |
CA2143166A1 (fr) | Catalyseur pour conversion d'hydrocarbures lourds, produisant moins de composes insolubles dans le toluene | |
JP2008093493A (ja) | 脱メタル触媒及びそれを用いた重質油の水素化処理方法 | |
EP0686687A1 (fr) | Hydrocraquage doux de charges d'hydrocarbonées lourdes avec des catalyseurs silice-alumine | |
EP1567262B1 (fr) | Procede d'hydrotraitement de charge lourde reposant sur l'utilisation d'un melange de catalyseurs | |
JP2000313890A (ja) | 炭化水素供給原料のウルトラディープhdsを行うための方法 | |
EP0590894B1 (fr) | Procédé d'hydroconversion | |
US4832829A (en) | Catalyst for the simultaneous hydrodemetallization and hydroconversion of heavy hydrocarbon feedstocks | |
US3425934A (en) | Catalytic refining with hydrogen |