WO1994015940A1 - Procede de production d'oligomeres olefiniques - Google Patents

Procede de production d'oligomeres olefiniques Download PDF

Info

Publication number
WO1994015940A1
WO1994015940A1 PCT/JP1994/000033 JP9400033W WO9415940A1 WO 1994015940 A1 WO1994015940 A1 WO 1994015940A1 JP 9400033 W JP9400033 W JP 9400033W WO 9415940 A1 WO9415940 A1 WO 9415940A1
Authority
WO
WIPO (PCT)
Prior art keywords
compound
chromium
producing
oligomer
aluminum
Prior art date
Application number
PCT/JP1994/000033
Other languages
English (en)
Japanese (ja)
Inventor
Haruhito Satou
Harumi Nakashima
Original Assignee
Idemitsu Kosan Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co., Ltd. filed Critical Idemitsu Kosan Co., Ltd.
Publication of WO1994015940A1 publication Critical patent/WO1994015940A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic System
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé permettant de produire un complexe de chrome réduit par réduction d'au moins un composé sélectionné parmi des composés de chrome (III) et de chrome (IV), possédant chacun un anion oxygène comme ligand, avec un agent de réduction et en présence d'un donneur d'électrons, en un composé de chrome (II); un procédé permettant de produire un catalyseur constitué d'un complexe de chrome réduit, par mélange d'un donneur d'électrons, d'au moins un composé choisi parmi des composés de chrome (III), de chrome (IV), de chrome (V) et de chrome (VI), possédant chacun un anion oxygène comme ligand, d'un agent réducteur, et d'un composé aluminiumoxy; et un procédé permettant de produire un oligomère oléfinique par réaction d'une oléfine en présence dudit catalyseur constitué d'un complexe de chrome réduit. Ce procédé permet de produire, de façon sélective et avec efficacité, de l'héxène-1 et de l'octène-1 utiles comme comonomères d'un polyéthylène basse densité linéaire.
PCT/JP1994/000033 1993-01-13 1994-01-13 Procede de production d'oligomeres olefiniques WO1994015940A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP370293 1993-01-13
JP5/3702 1993-01-13

Publications (1)

Publication Number Publication Date
WO1994015940A1 true WO1994015940A1 (fr) 1994-07-21

Family

ID=11564707

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1994/000033 WO1994015940A1 (fr) 1993-01-13 1994-01-13 Procede de production d'oligomeres olefiniques

Country Status (1)

Country Link
WO (1) WO1994015940A1 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5750816A (en) * 1995-03-02 1998-05-12 Mitsubishi Chemical Corporation Process for the preparation of α-olefin oligomers
DE19930213A1 (de) * 1999-06-30 2001-04-05 Studiengesellschaft Kohle Mbh Donor-Ligand-Substituierte Cyclopentadienyl-Chrom-Verbindungen als Katalysatoren für die Oligomerisation von Alkenen
US7820581B2 (en) 2004-02-20 2010-10-26 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
US7910670B2 (en) 2005-08-19 2011-03-22 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7994376B2 (en) 2004-02-19 2011-08-09 Chevron Phillips Chemical Company Lp Olefin oligomerization
US20120108768A1 (en) * 2007-12-20 2012-05-03 Chevron Phillips Chemical Company Lp Continuous Catalyst Activator
US8329608B2 (en) 2004-02-20 2012-12-11 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
JP2015182078A (ja) * 2014-03-25 2015-10-22 イエフペ エネルジ ヌヴェルＩｆｐ Ｅｎｅｒｇｉｅｓ Ｎｏｕｖｅｌｌｅｓ 新規な触媒組成物およびエチレンの１−ヘキセンへのオリゴマー化方法
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
CN116063595A (zh) * 2021-10-29 2023-05-05 中国石油化工股份有限公司 乙烯聚合催化剂、由此得到的聚乙烯树脂及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62265237A (ja) * 1986-03-14 1987-11-18 ユニオン・カ−バイド・コ−ポレ−シヨン 三量体化方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62265237A (ja) * 1986-03-14 1987-11-18 ユニオン・カ−バイド・コ−ポレ−シヨン 三量体化方法

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5750816A (en) * 1995-03-02 1998-05-12 Mitsubishi Chemical Corporation Process for the preparation of α-olefin oligomers
DE19930213A1 (de) * 1999-06-30 2001-04-05 Studiengesellschaft Kohle Mbh Donor-Ligand-Substituierte Cyclopentadienyl-Chrom-Verbindungen als Katalysatoren für die Oligomerisation von Alkenen
US7994376B2 (en) 2004-02-19 2011-08-09 Chevron Phillips Chemical Company Lp Olefin oligomerization
US7820581B2 (en) 2004-02-20 2010-10-26 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US8993822B2 (en) 2004-02-20 2015-03-31 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US8329608B2 (en) 2004-02-20 2012-12-11 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7910670B2 (en) 2005-08-19 2011-03-22 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US8349264B2 (en) * 2007-12-20 2013-01-08 Chevron Phillips Chemical Company Lp Continuous catalyst activator
US20130109818A1 (en) * 2007-12-20 2013-05-02 Chevron Phillips Chemical Company Lp Continuous Catalyst Activator
US8790579B2 (en) 2007-12-20 2014-07-29 Chevron Phillips Chemical Company Lp Continuous catalyst activator
US20120108768A1 (en) * 2007-12-20 2012-05-03 Chevron Phillips Chemical Company Lp Continuous Catalyst Activator
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
JP2015182078A (ja) * 2014-03-25 2015-10-22 イエフペ エネルジ ヌヴェルＩｆｐ Ｅｎｅｒｇｉｅｓ Ｎｏｕｖｅｌｌｅｓ 新規な触媒組成物およびエチレンの１−ヘキセンへのオリゴマー化方法
CN116063595A (zh) * 2021-10-29 2023-05-05 中国石油化工股份有限公司 乙烯聚合催化剂、由此得到的聚乙烯树脂及其制备方法

Similar Documents

Publication Publication Date Title
JP3217500B2 (ja) エチレンの低重合
AU748033B2 (en) Manufacture of alpha-olefins
CA2770520C (fr) Systeme catalytique et procedes de (co-)trimerisation d'olefines et de (co-)polarisation d'oligomeres olefiniques
US6740715B2 (en) Manufacture of alpha-olefins
JPH06239920A (ja) 触媒系の製造法及びオレフィンを三量体化、オリゴマー化及び／又は重合する方法
JP2004536154A (ja) 線状アルファオレフィンへのエチレンオリゴマー化のための配位子およびその触媒系
TWI615380B (zh) 用於使乙烯寡聚合以製造１－己烯及／或１－辛烯之觸媒組成物及方法
JPS5825361B2 (ja) アルフア−オレフインの重合方法
WO1997033924A1 (fr) PROCEDE DE PRODUCTION D'OLIGOMERS D'α-OLEFINES
WO2004037415A2 (fr) Systemes de catalyseurs destines a l'oligomerisation d'ethylenes en olefines alpha lineaires
WO2009085411A1 (fr) Procédés de dimérisation ou d'isomérisation des oléfines
US6555723B2 (en) Continuous manufacturing process for alpha-olefins
WO2002079276A2 (fr) Catalyseurs supportes de polymerisation d'olefines
WO1994015940A1 (fr) Procede de production d'oligomeres olefiniques
JP2018503509A (ja) オレフィンオリゴマー化反応用触媒システムおよびこれを用いたオレフィンオリゴマー化方法
JPH0195110A (ja) オレフイン重合用触媒
JP2003527403A (ja) オレフィンの重合
CN110753695B (zh) 杂原子配体、包含其的低聚催化剂及低聚物的制备方法
WO2012048646A1 (fr) Nouveau catalyser au chrome et son utilisation en catalyse d'oligomérisation et de polymérisation d'alcènes
US20080306226A1 (en) Polymerization Catalyst System Based on Monooxime Ligands
JP2003513165A (ja) オレフィン重合用の活性をもった二配座または三配座不均一担持触媒
JPH06329562A (ja) オレフィンオリゴマーの製造方法
JP3324163B2 (ja) α−オレフィンの低重合方法
JPH07215896A (ja) α−オレフィンオリゴマーの製造方法
KR20170036233A (ko) 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): CA JP US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA