WO1994015015A1 - Complex fiber string and method of manufacturing the same - Google Patents
Complex fiber string and method of manufacturing the same Download PDFInfo
- Publication number
- WO1994015015A1 WO1994015015A1 PCT/JP1993/001894 JP9301894W WO9415015A1 WO 1994015015 A1 WO1994015015 A1 WO 1994015015A1 JP 9301894 W JP9301894 W JP 9301894W WO 9415015 A1 WO9415015 A1 WO 9415015A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fiber
- thermosetting resin
- bundled
- fiber core
- semi
- Prior art date
Links
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C5/00—Reinforcing elements, e.g. for concrete; Auxiliary elements therefor
- E04C5/08—Members specially adapted to be used in prestressed constructions
- E04C5/12—Anchoring devices
- E04C5/125—Anchoring devices the tensile members are profiled to ensure the anchorage, e.g. when provided with screw-thread, bulges, corrugations
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/38—Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/40—Yarns in which fibres are united by adhesives; Impregnated yarns or threads
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/02—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics
- D07B1/025—Ropes built-up from fibrous or filamentary material, e.g. of vegetable origin, of animal origin, regenerated cellulose, plastics comprising high modulus, or high tenacity, polymer filaments or fibres, e.g. liquid-crystal polymers
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/16—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics
- D07B1/165—Ropes or cables with an enveloping sheathing or inlays of rubber or plastics characterised by a plastic or rubber inlay
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C5/00—Reinforcing elements, e.g. for concrete; Auxiliary elements therefor
- E04C5/07—Reinforcing elements of material other than metal, e.g. of glass, of plastics, or not exclusively made of metal
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C5/00—Reinforcing elements, e.g. for concrete; Auxiliary elements therefor
- E04C5/08—Members specially adapted to be used in prestressed constructions
- E04C5/085—Tensile members made of fiber reinforced plastics
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C5/00—Reinforcing elements, e.g. for concrete; Auxiliary elements therefor
- E04C5/08—Members specially adapted to be used in prestressed constructions
- E04C5/12—Anchoring devices
- E04C5/127—The tensile members being made of fiber reinforced plastics
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/20—Organic high polymers
- D07B2205/2046—Polyamides, e.g. nylons
- D07B2205/205—Aramides
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/30—Inorganic materials
- D07B2205/3007—Carbon
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2207/00—Rope or cable making machines
- D07B2207/40—Machine components
- D07B2207/404—Heat treating devices; Corresponding methods
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
Definitions
- the present invention relates to a fibrous composite filament used as a tension member for a PC (prestressed concrete) structure in civil engineering and construction, a power cable or a communication cable, and contains a thermosetting resin. It is formed by twisting a plurality of fiber cores.
- the base material is a steel fired wire, it is heavy and magnetic, and if the coating of the synthetic resin is damaged, the stranded steel wire will corrode, possibly impairing the mechanical properties.
- a fiber composite filament described in Japanese Patent Publication No. B2-18B79 is known as one having a high tensile strength.
- a fiber core is impregnated with a thermosetting resin, the periphery is covered with a dry powder agent, the outer periphery is covered with a fiber braid, and this is heated to cure the thermosetting resin. .
- the dry powder is used to prevent the thermosetting resin impregnated in the fiber core from leaking.However, the dry powder is evenly spread and the amount of the dry powder is controlled. Required, making production management difficult. If leakage of the thermosetting resin cannot be prevented, the leaked thermosetting resin will bond the fiber cores together and stop the mutual movement during later fitting, resulting in a decrease in mechanical strength and flexibility. Further, the presence of the powder desiccant does not have a favorable effect on the integral fixing of the thermosetting resin of the fiber core and the covering yarn.
- thermosetting resin of the fiber core when the thermosetting resin of the fiber core is hardened, almost no plasticity is exhibited, so that twisting becomes difficult, and There was a problem that if this were done, the resulting striatum would be broken when it was cut. Disclosure of the invention
- the present inventors first use high-tensile materials such as carbon fibers, glass fibers, and aramide fibers without using heavy, low-corrosion-resistant steel combustion wires as a base material.
- high-tensile materials such as carbon fibers, glass fibers, and aramide fibers without using heavy, low-corrosion-resistant steel combustion wires as a base material.
- the tendon was composed of a low elongation fiber system.
- the first characteristic of the fiber composite filament of the present invention is that a plurality of fiber cores containing a thermosetting resin and rubbing fiber yarns bundled on the outer periphery in one direction without gaps are twisted. Is what you do.
- the fiber core impregnated with the thermosetting resin is heated to make the thermosetting resin semi-cured, and the bundled fiber yarns are unidirectionally wound around the fiber core. It is preferable to wrap the fiber cores without any gaps, twist a plurality of the obtained fiber cores, and heat the semi-cured thermosetting resin to produce the core.
- the fiber yarn In order to prevent the thermosetting resin from leaking by rubbing the fiber yarn bundled around the fiber core without leaving a semi-cured thermosetting resin to prevent leakage of the thermosetting resin, the fiber yarn must be thickened or wrapped. It is necessary to control the manufacturing conditions strictly, for example, by controlling the winding force in the appropriate range. If the fiber yarn is too thick, the diameter increases and the tensile strength per cross-sectional area decreases.
- Another feature of the present invention is that a composite is obtained by twisting a plurality of fiber cores, each of which has been subjected to secondary rubbing in the opposite direction with fiber yarns further bundled, in the opposite direction with the primary wrapped outer periphery in one direction. To provide a striatum.
- the fiber core impregnated with the thermosetting resin is heated to make the thermosetting resin semi-cured, and the bundled fiber yarns are wrapped around the fiber core in one direction. Primary rubbing, and secondary wrapping of the same fiber yarn in the opposite direction without any gaps.Two or more obtained fiber cores are twisted and heated to form semi-cured thermosetting. It is preferable to manufacture by curing a conductive resin. In either method, a thermosetting resin is applied to the inside of the bundled fiber yarn to be rubbed, or the semi-cured state of the fiber core is adjusted so that the thermosetting resin penetrates the bundled fiber yarn to be rubbed. As a result, the integral fixation of the fiber core and the rubbed fiber yarn can be improved.
- the thermosetting resin impregnated in the fiber core is not semi-cured in place of dusting the powder desiccant in order to prevent the thermosetting resin from leaking, and the thermosetting resin is collected around the fiber core by convergence.
- the fiber yarn is rubbed in one direction without gaps. It is difficult to prevent leakage if the thermosetting resin is in a liquid state, and it is not preferable to add a powder desiccant. Therefore, it is processed in a semi-cured state with high viscosity. And wrapping it over with a fiber thread without gaps can surely prevent leakage.
- a bundled fiber yarn is further wound around the outer periphery of the wrapping in the opposite direction, and a biaxial rubbing can be used to manufacture a striated body with a fiber core having no twist. That is, when the wrapping with the fiber yarn is performed only in one direction, the fiber core is rotated by the wrapping and the twist is easily generated because the thermosetting resin is not yet cured. Such torsion hinders the uniform elongation of each fiber constituting the fiber core in the longitudinal direction, and is a factor of deteriorating the mechanical properties of the striatum. However, by applying rubbing without any gap in the direction opposite to the one direction as in the present invention, the fiber core can be rotated in the reverse direction to cancel the twist.
- thermosetting resin is contained, and a plurality of fiber cores, each of which is rubbed without any gaps, around the outer periphery of the bundle, are twisted together.
- adhesion to fixing body is large.
- the adhesive force is small, when the end of the striated body is fixed by the wedge and the wedge receiver, the end of the striated body is easily slipped between the wedge and the striated body, and in some cases, slippage occurs. Even when the mortar or resin is filled into the cylinder into which the end of the striatum is inserted and solidified and fixed, the striated body is easily slipped between the mortar or resin and the striated body. However, it is difficult to fix with a practically short fixing section length. Furthermore, when the fiber core constituting the stranded wire alone is viewed, the primary rubbing and the secondary rubbing are not performed. Sliding tends to occur between the rubbings or between the fiber core and the slipping may also occur between them.
- Yet another important feature of the present invention is that in order to dramatically increase the adhesion, one of the primary wrapping and the secondary wrapping is mottled, that is, the lapping surface is provided with irregularities on the rubbing surface. It was formed.
- FIG. 1 is a process chart of the manufacturing method in Example 1, wherein (A) shows the former stage and (B) shows the latter stage.
- FIG. 2 is a perspective view showing a state where the outer periphery of the fiber core is rubbed in one direction by a bundled fiber yarn without any gap.
- FIGS. 3A and 3B are process diagrams of the manufacturing method in Example 2, wherein FIG. 3A shows the former stage and FIG. 3B shows the latter stage.
- FIG. 4 is a perspective view showing a state in which (A) rubs the outer periphery of the fiber core in two directions with the bundled fiber yarns without any gaps, and (B) shows the outer periphery of the fiber core in one direction with the bundled fiber yarns.
- FIG. 9 is a perspective view showing a state in which primary lapping is performed without any gap and secondary rubbing is performed at intervals so as to scatter in the opposite direction.
- Fig. 5 shows the pull-out resistance of the striated body of the present invention to the fixing body by the tensile tester (Appendix).
- FIG. 4 is an explanatory diagram of a method for measuring (adhesion). BEST MODE FOR CARRYING OUT THE INVENTION
- FIG. 1 is a process diagram of Example 1.
- a plurality of high-tension, low-elongation aramid fibers fed from each supply reel 1 are bundled to form a fiber core A.
- the fiber core A is led to the thermosetting resin tank 2 and impregnated with a thermosetting resin (for example, unsaturated polyester or epoxy).
- a die 3 or a metal mold
- excess resin is dropped and introduced into the heater 4.
- the thermosetting resin is semi-cured.
- thermosetting resin is introduced into the wrapping machine 5, and the outer periphery of the fiber core A is bundled with the bundled fiber yarn 10. Wraps without gaps in one direction.
- the fiber yarn 10 may be coated with a thermosetting resin on the inside of the winding to promote the integration of the fiber core.
- FIG. 2 shows a state in which the fiber core A is rubbed with the fiber yarn 10 without any gap. Then, the obtained fiber core A is taken up by the take-up reel 6.
- the fiber core A is unwound from a take-up reel 6 and is introduced into a twisting machine 7 to be twisted.
- the burned wire was heated by the heater 8 to cure the semi-cured thermosetting resin, and wound up by the take-up reel 9 to produce a composite filament.
- thermosetting resin when the thermosetting resin is semi-cured, the outer periphery is wrapped without gaps, thereby preventing leakage of the resin without using a powder desiccant. Can be prevented from adhering to each other. In addition, defects in appearance such as protrusions caused by resin leakage can be solved.
- FIG. 3 is a process chart showing the manufacturing method of Example 2.
- a plurality of high-tension, low-elongation polyamide fibers drawn from each supply reel are bundled. Construct fiber core A.
- the fiber core A is led to the thermosetting resin tank 2 and impregnated with a thermosetting resin (for example, unsaturated polyester or epoxy).
- a thermosetting resin for example, unsaturated polyester or epoxy.
- the resin is formed into a predetermined outer diameter by passing through a die 3 (or a die), and excess resin is dropped and introduced into the heater 4.
- the thermosetting resin is semi-cured by heating at 90 ° C.
- FIG. 4 (A) shows a state where the fiber core A is wrapped with the fiber yarn 10 without any gap. Then, the obtained fiber core A is taken up by the take-up reel 6.
- the fiber core A is unwound from a take-up reel 6 and introduced into a twisting machine 7 for twisting. Then, the insulated wire was heated by the heater 8 to cure the thermosetting resin in a semi-cured state, and wound up by the take-up reel 9 to produce a composite wire.
- thermosetting resin when the thermosetting resin is semi-cured, the outer periphery is wrapped without gaps, thereby preventing leakage of the resin and preventing adhesion of the fiber cores at the time of twisting, which has occurred conventionally.
- twisting of the fiber core can be prevented by bidirectional wrapping.
- the fiber core carbon fiber, glass fiber, etc. can be used in addition to the amide fiber.
- the fiber yarn to be wrapped aramide fiber, vinylon, polyester or the like can be used, but as the tension member for the PC structure, aramide fiber is preferable in order to increase alkali resistance.
- the primary rubbing by the lapping machine 5A is rubbed without gaps in one direction, and the secondary rubbing by the rubbing machine 5B is performed with an interval in the opposite direction, and is applied to the surface.
- Form mottled irregularities Fig. 4 (B) shows this state, where the bundled fiber yarn 10A formed by the primary wrapping is wound without any gap inside, and the bundled fiber yarn 10B formed by the secondary wrapping is spaced in the opposite direction on the outer circumference. Is placed around and mottled.
- This mottled winding is performed by changing one or more of the number, shape, pitch, and wrapping tension of the fiber yarns to be bundled, as compared to the case of the primary rubbing honey winding.
- the thermosetting resin penetrates into the bundled fiber yarns to promote the integral fixation with the fiber core.
- Example 2 After rubbing in both directions, it is also possible to wrap in mottle by tertiary rubbing. In this case, the diameter increases.
- a plurality of fiber cores having irregularities formed on the surface in this manner were burned in the same manner as in Examples 1 and 2, and then heated to form irregularities on the target outer surface, and to adhere to the fixing portion.
- a fiber composite striatum with a high value was obtained.
- the height difference in the unevenness was 0.5 mm in the example, it is considered that it is preferably about 0.3 to 0.8 mm.
- Fig. 5 shows the tensile tester used for the test.
- the tester is designed to fix both ends of the test material 13 with a cylindrical fixing jig 12 filled with mortar 11 and pull it. The evaluation is made at the maximum tensile load at that time.
- 14 is a crosshead
- 15 is a plate
- 1B is a rubber stopper.
- test materials used were, for comparison, the Example 1 material with one-way wrapping as described above without gaps and the Example 2 material with two-way wrapping without gaps as described above.
- test material was fixed on a tensile tester under the following conditions, a load was applied, and the tensile load of the test material was measured.
- Fixing jig size inner diameter 0 3 O mm, length 500 mm Filler: mortar, curing for 5 days
- the test results are shown below. It was confirmed that all of the examples had higher tensile loads than the comparative examples. This indicates that the example material is suitable as a tension member for a PC structure, a power / communication cable capturing member.
- thermosetting resin when the thermosetting resin is semi-cured surely prevents leakage of the resin, and the twisted groove can be kept loose by curing after twisting. .
- twisting of the fiber core can also be prevented, and this tendency seems to be further promoted.
- the length of the fixing jig 12 was shortened, and the load at which the test material 13 was pulled out of the mortar 11 was measured and defined as the allowable tension load.
- the test material used was the Example 3-1 material in which the secondary rubbing was mottled, and the Example 3-2 material in which the primary rubbing was mottled.
- the thermosetting resin impregnated into the fiber core was used for comparison.
- the state of the fixing unit is shown below.
- Fixing jig size inner diameter ⁇ 30 mm, length 200 mm Filler: mortar, curing for 5 days
- the results are as follows, using the index when the allowable tensile load of the comparative material is 100. Is shown.
- Example 3 2 materials 1 4 0
- the fiber composite filament according to the present invention reliably prevents leakage of the thermosetting resin impregnated in the fiber core, and prevents the fiber cores from adhering to each other in the subsequent assembling step.
- a composite filament having excellent mechanical properties can be obtained.
- the fiber core can be prevented from being twisted, and a striated body having more excellent mechanical properties can be obtained.
- the one with the mottled one has a feature that the adhesive force at the fixing portion is high.
- the fiber composite filament according to the present invention has a tensile strength comparable to that of a PC steel material, and also has features such as high corrosion resistance, non-magnetism and light weight that are not available in the material. Therefore, it can be expected to be used for a wide range of applications, such as marine structures and PC structures for linear motors, whose demand is expected to increase gradually.
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- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Ropes Or Cables (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP94903071A EP0633348A4 (en) | 1992-12-28 | 1993-12-27 | COMPLEX FIBER CABLE AND METHOD FOR PRODUCING THE SAME. |
NO943156A NO943156L (no) | 1992-12-28 | 1994-08-26 | Kompositt-fibertau samt fremgangsmåte for dets fremstilling |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP36131892 | 1992-12-28 | ||
JP4/361318 | 1992-12-28 | ||
JP5/39557 | 1993-02-02 | ||
JP3955793 | 1993-02-02 | ||
JP5270077A JPH07102491A (ja) | 1993-10-01 | 1993-10-01 | 繊維複合線状体及びその製造方法 |
JP5/270077 | 1993-10-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994015015A1 true WO1994015015A1 (en) | 1994-07-07 |
Family
ID=27290177
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1993/001894 WO1994015015A1 (en) | 1992-12-28 | 1993-12-27 | Complex fiber string and method of manufacturing the same |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0633348A4 (ja) |
CA (1) | CA2126980A1 (ja) |
NO (1) | NO943156L (ja) |
WO (1) | WO1994015015A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109577559A (zh) * | 2019-01-09 | 2019-04-05 | 浙江新纳复合材料有限公司 | 一种玄武岩复合材料筋材 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9700796D0 (en) * | 1997-01-16 | 1997-03-05 | Camplas Technology | Improvements relating to reinforcing bars |
ES2156498B1 (es) * | 1998-09-07 | 2002-01-16 | Solteulat S L | Procedimiento para la elaboracion de tejido textil. |
FI125355B (fi) * | 2007-04-19 | 2015-09-15 | Kone Corp | Nostolaitteen köysi ja menetelmä nostolaitteen köyden valmistamiseksi |
CN102345238A (zh) * | 2010-07-27 | 2012-02-08 | 江苏恒神碳纤维复合材料工程研究中心有限公司 | 一种纤维加强芯材湿法生产装置 |
CN102345236A (zh) * | 2010-07-27 | 2012-02-08 | 江苏恒神碳纤维复合材料工程研究中心有限公司 | 一种多芯绞合型纤维加强芯材湿法生产工艺 |
KR20180132937A (ko) * | 2010-10-21 | 2018-12-12 | 리포스테크 엘티디. | 보강 바 및 그의 제조방법 |
CN103306150B (zh) * | 2013-06-07 | 2016-01-20 | 南京诺尔泰复合材料设备制造有限公司 | 梯形截面的高强度复合材料绞线及其一步法制备方法 |
BE1021747B1 (nl) * | 2013-07-05 | 2016-01-15 | Building A Future Foundation | Kabel en werkwijze om een dergelijke kabel te vervaardigen |
CN106812254A (zh) * | 2015-12-01 | 2017-06-09 | 衡阳市新德力预应力有限公司 | 一种预应力锚具及其生产方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49119554U (ja) * | 1973-02-21 | 1974-10-14 | ||
JPS53134953A (en) * | 1977-04-22 | 1978-11-25 | Uotsu Seikoushiyo Kk | Rope |
JPS5526070U (ja) * | 1978-08-11 | 1980-02-20 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1045576A (en) * | 1962-07-03 | 1966-10-12 | Dunlop Rubber Co | Cords |
JPS6128092A (ja) * | 1984-07-11 | 1986-02-07 | 東京製綱繊維ロ−プ株式会社 | 複合線条体およびその製造方法 |
JPH0686718B2 (ja) * | 1988-10-31 | 1994-11-02 | 東京製綱株式会社 | 複合撚合型線条体の製造方法 |
-
1993
- 1993-12-27 EP EP94903071A patent/EP0633348A4/en not_active Withdrawn
- 1993-12-27 CA CA 2126980 patent/CA2126980A1/en not_active Abandoned
- 1993-12-27 WO PCT/JP1993/001894 patent/WO1994015015A1/ja not_active Application Discontinuation
-
1994
- 1994-08-26 NO NO943156A patent/NO943156L/no unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49119554U (ja) * | 1973-02-21 | 1974-10-14 | ||
JPS53134953A (en) * | 1977-04-22 | 1978-11-25 | Uotsu Seikoushiyo Kk | Rope |
JPS5526070U (ja) * | 1978-08-11 | 1980-02-20 |
Non-Patent Citations (1)
Title |
---|
See also references of EP0633348A4 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109577559A (zh) * | 2019-01-09 | 2019-04-05 | 浙江新纳复合材料有限公司 | 一种玄武岩复合材料筋材 |
Also Published As
Publication number | Publication date |
---|---|
NO943156D0 (no) | 1994-08-26 |
NO943156L (no) | 1994-08-26 |
EP0633348A1 (en) | 1995-01-11 |
EP0633348A4 (en) | 1995-03-29 |
CA2126980A1 (en) | 1994-07-07 |
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