WO1991018055A1 - Melanges de resines de polyphenylene a fonctionnalisation carboxy et de copolymeres de methacrylate d'ethylene-glycidyle - Google Patents

Melanges de resines de polyphenylene a fonctionnalisation carboxy et de copolymeres de methacrylate d'ethylene-glycidyle Download PDF

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Publication number
WO1991018055A1
WO1991018055A1 PCT/US1991/003394 US9103394W WO9118055A1 WO 1991018055 A1 WO1991018055 A1 WO 1991018055A1 US 9103394 W US9103394 W US 9103394W WO 9118055 A1 WO9118055 A1 WO 9118055A1
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WO
WIPO (PCT)
Prior art keywords
composition
olefin
carboxylic acid
polyphenylene sulfide
weight
Prior art date
Application number
PCT/US1991/003394
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English (en)
Inventor
Choon Yol Han
Original Assignee
General Electric Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Company filed Critical General Electric Company
Priority to JP51043391A priority Critical patent/JPH0639566B2/ja
Publication of WO1991018055A1 publication Critical patent/WO1991018055A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Definitions

  • the present invention relates to polyphenylene sulfide/olefin copolymer blends, and more particularly relates to blends of carboxy functionalized polyphenylene sulfide with olefin copolymer.
  • Blends of polyphenylene sulfide resin with an olefin copolymer containing (i) an ⁇ -olefin such as ethylene and (ii) an ester of ⁇ , ⁇ -unsaturated carboxylic acid such as glycidyl methacrylate are set forth in European Patent Application 0228268 which teaches treating the polyphenylene sulfide with acid treatments and water treatments to improve the polyphenylene sulfide resins affinity with the olefin copolymer. While blends of polyphenylene sulfide resin and olefin copolymers can exhibit acceptable levels of various properties for certain applications, it is often desirable to enhance levels of particular properties of the blends.
  • one object of the present invention involves providing polyphenylene sulfide/olefin copolymer blends exhibiting improved physical properties.
  • the present invention involves blends of carboxy-functionalized polyphenylene sulfide and olefin copolymers.
  • the blends exhibit improved physical properties such as unnotched Izod impact strengths and percent tensile elongation.
  • the blends of the present invention contain respective amounts of (a) an carboxy functional polyphenylene sulfide and (b) an olefin copolymer containing 60% to 99.5% by weight of an ⁇ -olefin and 0.5% to 40% by weight of a glycidyl ester of an , -unsaturated carboxylic acid.
  • the blends exhibit improved levels of unnotched Izod impact strength.
  • the polyphenylene sulfide polymer can be linear, branched or lightly crosslin ed.
  • Suitable polyphenylene sulfide polymers can be produced, for example, by the methods of Edmonds, et. al., in U.S. Patent No. 3,354,129 and Campbell in U.S. Patent No. 3,919,177. If desired, such polymers can be subjected to mild, partial curing or light crosslinking, as in the method of Rohlfing, U.S. Patent No. 3,717,620, prior to being used in the compositions of this invention.
  • the polymers will generally have crystalline melting points ranging from about 200'C to about 480 g C.
  • a presently preferred polyphenylene sulfide polymer has a crystalline melting point ranging from about 250 ⁇ C to 300"C.
  • Preferred polyphenylene sulfide polymers have an inherent viscosity in 1-chloronaphthalene at 206 ⁇ C and a polymer concentration of 0.4 g/100 ml solution ranging from about 0.1 to 0.6.
  • the polyphenylene sulfide (hereinafter referred to as PPS) used in the present invention is a polymer comprising at least 70 molar %, preferably at least 90 molar %, of recurring units of the structural formula: (I)
  • PPS polymers include generally those having a relatively low molecular weight prepared by, for example, a process disclosed in the specification of U.S. Patent No. 3,354,129 and essentially linear polymers having a relatively high molecular weight prepared by, for example, a process disclosed in the specification of U.S. Patent No. 3,919,177.
  • the degree of polymerization of the polymers prepared by the process of U.S. Patent No. 3,354,129 can be further increased by heating the same in an oxygen atmosphere or in the presence of a crosslinking agent such as a peroxide after the polymerization.
  • a crosslinking agent such as a peroxide after the polymerization.
  • an essentially linear polymer having a relatively high molecular weight prepared by the process of said U.S. Patent No. 3,919,177 is preferably used.
  • melt viscosity of PPS used in the present invention is not particularly limited so far as the moldings can be obtained, a melt viscosity of at least 100 poise is preferred from the viewpoint of the toughness of PPS per se and that of 10,000 poise or less is preferred from the viewpoint of the moldability.
  • polyphenylene sulfide contain carboxylic acid group. It may be provided in a number of ways.
  • the polyphenylene sulfide is prepared by the reaction of an alkali metal sulfide with a mixture of dichloroaromatic compounds and/or monochloroaromatic compounds (used as chain termination agents), including at least one such compound which contains the required carboxylic acid group.
  • a second method, disclosed and claimed in copending application Serial No. 07/373,080 filing. is the reaction of a carboxy free polyphenylene sulfide with a disulfide containing carboxylic acid group such as 4,4'-bis(4-carboxy-phthali ⁇ ridophenyl) disulfide (chemical structure is shown below). Said reaction typically occurs at temperatures in the range of about 225°C to 375 ⁇ C in the melt.
  • the disulfide is most preferably of the formula:
  • the carboxy functionality is preferably incorporated in the PPS by employing an carboxy disulfide in the reactants.
  • the carboxy disulfide may be of the formula:
  • R 1 is selected from monovalent hydrocarbon radicals and monovalent hydrogen radicals.
  • R may be methyl.
  • R 1 is hydrogen.
  • R 2 is a group containing a carboxylic acid and is preferably selected from the group consisting of -C00H and -R 3 -C00H wherein R 3 is a divalent radical selected from the group consisting of C j to C 2 Q alkylene radicals, Cg to C 2Q cycloalkylene radicals, Cg to C 24 arylene radicals, C 7 to C 24 alkylarylene radicals and C 7 to C 24 arylalkylene radicals and divalent phthali idyl radicals.
  • polyphenylene sulfides can be "cured" by heating in contact with an oxygen-containing gas (usually air) at temperatures above about 200 ⁇ C, resulting in a substantial decrease in melt flow and, apparently, a concomitant increase in molecular weight. While the exact nature of the curing reaction is not known, it appears to involve branching and/or chain extension, which probably occurs thermally or by oxidation of some type.
  • the polyphenylene sulfides employed in the method of this invention are preferably cured before blending with the ethylene-glycidyl methacrylate copolymers. Typical curing conditions are in the solid or liquid state at temperatures in the range of about 250 ⁇ C to 350 ⁇ C, for time periods of about 2-10 hours.
  • carboxy functional PPS should preferably have a carboxylic acid level of at least 5 carboxylic acid milliequivalents per kilogram of PPS, more preferably from 10 to 200 - 7 - carboxylic acid m ll equivalents per kilogram PPS, and most preferably from 20 to 100 carboxylic acid milliequivalents per kilogram PPS.
  • the olefinic copolymers (B) used in the present invention are copolymers of an ⁇ -olefin with a glycidyl ester of an ⁇ , ⁇ -unsaturated acid.
  • -olefin as used herein means ethylene, propylene, butene-1, etc. Among them, ethylene is preferred.
  • the amount of ⁇ -olefin in the olefin copolymer is 60% to 99.5% by weight, preferably 70% to 97% by weight based on the total weight of ⁇ -olefin and glycidyl esters of , ⁇ -unsaturated acids.
  • the glycidyl esters of the ⁇ , @ -unsaturated acids are compounds of the general formula:
  • CH 2 C - C - 0 - CH 2 - CH - CH 2
  • R represents a hydrogen atom or a lower alkyl group.
  • Examples of the glycidyl esters of ⁇ , ⁇ -unsaturated acids include glycidyl acrylate, methacrylate and ethacrylate. Among them, glycidyl methacrylate is preferred.
  • the amount of the glycidyl ester of the ⁇ , ⁇ -unsaturated acid in the olefinic copolymer is 0.5% to 40% by weight, preferably 3% to 30% by weight based on the total weight of ⁇ -olefin and glydicyl esters of ⁇ , ⁇ -unsaturated acids. When this amount is less than 0.5% by weight, no intended effects can be obtained and, on the contrary, when it exceeds 40% by weight, gelation can occur during melt-blending with PPS which can damage the extrusion stability. moldability and mechanical properties of the product.
  • the olefinic copolymer may further be copolymerized with 40% by weight or less of another copolymerizable unsaturated monomer such as vinyl ether, vinyl acetate, vinyl propionate, methyl acrylate, methyl methacrylate, acrylonitrile or styrene.
  • another copolymerizable unsaturated monomer such as vinyl ether, vinyl acetate, vinyl propionate, methyl acrylate, methyl methacrylate, acrylonitrile or styrene.
  • the preferred olefin copolymer is a 90/10 weight ratio ethylene/glycidyl methacrylate copolymer.
  • a suitable copolymer is sold under the trade name Bondfast E ® by Sumitomo Chemical.
  • Fibrous and/or granular reinforcing agent can be incorporated in an amount of 50 parts by weight or less for 100 parts by weight of the total weight of PPS and the olefinic copolymer, if necessary, in the present invention.
  • the strength, rigidity, heat resistance and dimensional stability of the product can be improved by incorporating 10 to 50 parts by weight of the reinforcing agent.
  • the fibrous reinforcing agents include inorganic and carbonaceous fibers such as glass fibers, shirasu glass fibers, alumina fibers, silicon carbide fibers, ceramic fibers, asbestos fibers, gypsum fibers and metal fibers.
  • the granular reinforcing agents include silicates such as wollastonite, sericite, kaolin, mica, clay, bentonite, asbestos, talc, alumina silicate; metal oxides such as alumina and oxides of silicon, magnesium, zirconium and titanium; carbonates such as calcium and magnesium carbonates and dolomite; sulfates such as calcium and barium sulfates; as well as glass beads, boron nitride, silicon carbide, sialon and silica. These granules may be hollow. These reinforcing agents may be used either alone or in the form of a mixture of two or more of them. If necessary, they can be pretreated with a silane or titanium coupling agent.
  • the preferred fibers are glass fibers and, if employed, are preferably at a level of from 5% to 30% by weight based on the total weight of the composition.
  • the carboxy functional polyphenyl sulfide resin is preferably present in the composition at a level of from 50% to 99.5% by weight based on the total weight of the composition, more preferably from 70% to 96% by weight thereof, and most preferably about 94% to 96% by weight thereof; the olefin copolymer is preferably present at a level of from 0.5% to 50% by weight of the composition, more preferably from 4% to 30% by weight thereof, and most preferably about 4% to 6% by weight thereof.
  • the composition may contain reinforcing fibers such as glass fibers at a level of from 1% to about 50% by weight of the composition, or may be free of reinforcing fibers.
  • Example B is a blend of the PPS of Example A with an olefin copolymer.
  • Example 2 is a blend of the carboxy functional PPS of Example 1 with an olefin copolymer.
  • the blends of PPS and olefin copolymer were extruded on a twin-screw extruder at temperatures from 250°C to 350°C. The extrudates were quenched in water, pelletized, dried and molded into test specimens which were then tested.
  • Heat distortion temperatures were measured in ⁇ F under a load of 264 psi pursuant to ASTM D648; Unnotched Izod Impact strengths (UNI) were measured in ft-lb pursuant to ASTM D256; Notched Izod Impact Strengths (NI) were measured in ft-lb pursuant to ASTM D256; Tensile elongation (TE) was measured as % elongation pursuant to ASTM D638; Tensile Strength was measured in KPSI pursuant to ASTM D638; Flexural Strength was measured in Kpsi pursuant to ASTM D790; and Flexural modulus was measured in Kpsi pursuant to ASTM D790.
  • PPS COMPARATIVE EXAMPLE A The PPS of the comparative example A was made by reacting respective amounts of disodium sulfide and para dichlorophenyl in N-methyl-2-pyrrolidone (NMP) solvent
  • the olefin copolymer employed in the following examples was a 90/10 w and glycidyl methacrylate.
  • the compositions of examples B and 2 are free of gl fillers and fibers.
  • Example B uses the PPS of example A.
  • Example 2 uses t of example 1.
  • Example 2 3 of 5 of the test bars of example 2 did not break during Unnotched Izod testing thereof. Also note that the tensile elongation of example 2 was greater than the tensile elongation of example B.
  • the carboxylic acid functional PPS of Example 1 when blended with the olefin copolymer, generally provided superior tensile elongation and unnotched Izod impact strength to blends of the PPS of comparative Example A with the olefin copolymer.
  • the PPS of Example 1 is similar to the PPS of Comparative Example A except for the high degree of carboxy functionality of the PPS of Example 1.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Une composition de polyphénylènesulfure contient une résine de polyphénylènesulfure à fonctionnalisation carboxy ainsi qu'un copolymère oléfinique. La composition présente des niveaux améliorés de propriétés physiques. Les compositions sont utiles dans la fabrication d'articles moulés.
PCT/US1991/003394 1990-05-15 1991-05-15 Melanges de resines de polyphenylene a fonctionnalisation carboxy et de copolymeres de methacrylate d'ethylene-glycidyle WO1991018055A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP51043391A JPH0639566B2 (ja) 1990-05-15 1991-05-15 カルボキシ官能化ポリフエニレン樹脂と、エチレン―グリシジルメタクリレート共重体とのブレンド

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US52378390A 1990-05-15 1990-05-15
US523,783 1990-05-15

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WO1991018055A1 true WO1991018055A1 (fr) 1991-11-28

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0560046A1 (fr) * 1992-03-10 1993-09-15 General Electric Company Mélange polymérique contenant du polysulfure d'arylène, un élastomère et un sel métallique
US20150141550A1 (en) * 2012-06-11 2015-05-21 Sk Chemicals Co.,Ltd. Polyarylene sulfide resin composition and a preparation method thereof
US9182056B2 (en) 2012-04-13 2015-11-10 Ticona Llc Pipe section having polyarylene sulfide composition barrier layer
US9494262B2 (en) 2012-04-13 2016-11-15 Ticona Llc Automotive fuel lines including a polyarylene sulfide
US9493646B2 (en) 2012-04-13 2016-11-15 Ticona Llc Blow molded thermoplastic composition
US9718225B2 (en) 2013-08-27 2017-08-01 Ticona Llc Heat resistant toughened thermoplastic composition for injection molding
US9757892B2 (en) 2013-08-27 2017-09-12 Ticona Llc Thermoplastic composition with low hydrocarbon uptake
US9758674B2 (en) 2012-04-13 2017-09-12 Ticona Llc Polyarylene sulfide for oil and gas flowlines
US9765219B2 (en) 2012-04-13 2017-09-19 Ticona Llc Polyarylene sulfide components for heavy duty trucks

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4961921B2 (ja) * 2006-09-14 2012-06-27 東ソー株式会社 ポリアリーレンスルフィド組成物
JP5970793B2 (ja) * 2011-11-30 2016-08-17 Dic株式会社 樹脂組成物、その製造方法、成形品およびその製造方法
KR102224074B1 (ko) * 2013-09-27 2021-03-08 도레이 카부시키가이샤 폴리아릴렌 설파이드 수지 조성물

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0228268B1 (fr) * 1985-12-27 1990-05-23 Toray Industries, Inc. Composition de poly(sulfure de phénylène) et procédé pour sa préparation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0228268B1 (fr) * 1985-12-27 1990-05-23 Toray Industries, Inc. Composition de poly(sulfure de phénylène) et procédé pour sa préparation

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Patent Abstracts of Japan, vol. 12, no. 301 (C-521)[3148], 16 August 1988, & JP-A-63 75059 (TORAY IND. INC.) 5 April 1988 *
Patent Abstracts of Japan, vol. 7, no. 277 (C-199)[1422], 9 December 1983, & JP-A-58 154 757 (TORAY K.K.) 14 September 1983 *
WPIL, File Supplier, AN = 86-071993, Derwent Publications Ltd, (London, GB), & JP-A-61 021 156 (DAINIPPON INK) 29 January 1986 *

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0560046A1 (fr) * 1992-03-10 1993-09-15 General Electric Company Mélange polymérique contenant du polysulfure d'arylène, un élastomère et un sel métallique
WO1993018091A1 (fr) * 1992-03-10 1993-09-16 General Electric Company Melange de polymeres comprenant un sulfure de polyarylene, un elastomere et un sel metallique
US5681893A (en) * 1992-03-10 1997-10-28 General Electric Company Polymer mixture comprising polyarylene sulphide elastomeric polymer and metal salt
US9765219B2 (en) 2012-04-13 2017-09-19 Ticona Llc Polyarylene sulfide components for heavy duty trucks
US10359129B2 (en) 2012-04-13 2019-07-23 Ticona Llc Automotive fuel lines including a polyarylene sulfide
US9494262B2 (en) 2012-04-13 2016-11-15 Ticona Llc Automotive fuel lines including a polyarylene sulfide
US9493646B2 (en) 2012-04-13 2016-11-15 Ticona Llc Blow molded thermoplastic composition
US9494260B2 (en) 2012-04-13 2016-11-15 Ticona Llc Dynamically vulcanized polyarylene sulfide composition
US10563062B2 (en) 2012-04-13 2020-02-18 Avx Corporation Polyarylene sulfide for oil and gas flowlines
US10501626B2 (en) 2012-04-13 2019-12-10 Ticona Llc Dynamically vulcanized polyarylene sulfide composition
US10358556B2 (en) 2012-04-13 2019-07-23 Ticona Llc Blow molded thermoplastic composition
US9758674B2 (en) 2012-04-13 2017-09-12 Ticona Llc Polyarylene sulfide for oil and gas flowlines
US9182056B2 (en) 2012-04-13 2015-11-10 Ticona Llc Pipe section having polyarylene sulfide composition barrier layer
US20150141550A1 (en) * 2012-06-11 2015-05-21 Sk Chemicals Co.,Ltd. Polyarylene sulfide resin composition and a preparation method thereof
US9650515B2 (en) * 2012-06-11 2017-05-16 Sk Chemicals Co., Ltd. Polyarylene sulfide resin composition and a preparation method thereof
US9757892B2 (en) 2013-08-27 2017-09-12 Ticona Llc Thermoplastic composition with low hydrocarbon uptake
US9718225B2 (en) 2013-08-27 2017-08-01 Ticona Llc Heat resistant toughened thermoplastic composition for injection molding

Also Published As

Publication number Publication date
JPH0639566B2 (ja) 1994-05-25
EP0482186A1 (fr) 1992-04-29
JPH05502055A (ja) 1993-04-15

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