WO1990009277A1 - Panneau composite thermo-isolant - Google Patents
Panneau composite thermo-isolant Download PDFInfo
- Publication number
- WO1990009277A1 WO1990009277A1 PCT/JP1990/000161 JP9000161W WO9009277A1 WO 1990009277 A1 WO1990009277 A1 WO 1990009277A1 JP 9000161 W JP9000161 W JP 9000161W WO 9009277 A1 WO9009277 A1 WO 9009277A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat
- composite panel
- insulating composite
- panel according
- thickness
- Prior art date
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 44
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000010439 graphite Substances 0.000 claims abstract description 22
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims description 47
- 239000004033 plastic Substances 0.000 claims description 17
- 229920003023 plastic Polymers 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 13
- 229920001228 polyisocyanate Polymers 0.000 claims description 6
- 239000005056 polyisocyanate Substances 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 5
- 239000011888 foil Substances 0.000 claims description 5
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910000838 Al alloy Inorganic materials 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 210000000689 upper leg Anatomy 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 2
- 239000010440 gypsum Substances 0.000 claims description 2
- 229910052602 gypsum Inorganic materials 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229920001807 Urea-formaldehyde Polymers 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 239000002984 plastic foam Substances 0.000 abstract description 5
- 238000004079 fireproofing Methods 0.000 abstract 1
- 239000000123 paper Substances 0.000 description 10
- 239000006260 foam Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000002265 prevention Effects 0.000 description 7
- 238000009413 insulation Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- -1 phosphoric acid compound Chemical class 0.000 description 5
- 229920000582 polyisocyanurate Polymers 0.000 description 5
- 239000011495 polyisocyanurate Substances 0.000 description 5
- 229920005862 polyol Polymers 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000011162 core material Substances 0.000 description 4
- 239000004088 foaming agent Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
- 229920005906 polyester polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 241000282376 Panthera tigris Species 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- YDVNLQGCLLPHAH-UHFFFAOYSA-N dichloromethane;hydrate Chemical class O.ClCCl YDVNLQGCLLPHAH-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- WDPYDDUVWLUIDM-UHFFFAOYSA-N ethyl carbamate;phenol Chemical compound CCOC(N)=O.OC1=CC=CC=C1 WDPYDDUVWLUIDM-UHFFFAOYSA-N 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- RLEFZEWKMQQZOA-UHFFFAOYSA-M potassium;octanoate Chemical compound [K+].CCCCCCCC([O-])=O RLEFZEWKMQQZOA-UHFFFAOYSA-M 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/26—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
- E04C2/284—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
- E04C2/296—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and non-metallic or unspecified sheet-material
Definitions
- the present invention relates to a heat-insulating composite panel, and particularly to a heat-insulating composite panel having excellent fire resistance and fire resistance.
- Insulated composite panels are siding panels made of various surface materials and rigid plastic forms, and have shown remarkable growth in recent years as building materials because of their excellent heat insulation, light weight, and workability. ing.
- a method of imparting fire protection to such a heat-insulating composite panel As a method of imparting fire protection to such a heat-insulating composite panel, a method of making the rigid plastic form itself flame-retardant has been studied, and various proposals have been made. For example, a method of adding an organic or inorganic compound such as a phosphoric acid compound, a halogen compound, aluminum hydroxide and borax, or a pearl, or a method of adding a polyol as one of the raw materials to a sintering polyol. It is known to use as a halogen polyol or a polyester polyol (Japanese Patent Publication No. 57-42086). Also known are methods of using nitrogen-containing compounds such as melamine, urea, and isocyanuric acid, nitrogen-containing polyols such as aminopolyol, and aromatic polyester polyols. .
- An object of the present invention is to solve the above-mentioned conventional problems and to provide a heat insulating composite panel excellent in fire resistance and fire resistance.
- the heat-insulating composite panel of the present invention is a heat-insulating composite panel having a heat-insulating layer of a hard plastic form between a front material and a back material, wherein the heat-insulating composite panel has Characterized in that heat-expandable graphite is interposed therebetween.
- a polynuclear foam is suitable as the rigid plastic form.
- Examples of the surface material used in the present invention include metal materials such as a colored zinc-iron plate and a colored aluminum alloy plate, and those having a plate thickness of 0.27 to 0.5 are preferably used.
- ceramic materials such as calcium carbonate, gypsum board, and extruded cement board can be used. In this case, the thickness of the board is preferably 6 to: L5 thigh.
- metal foil such as aluminum foil or iron foil having a thickness of 0.03 to 0.15, or aluminum Paper paper, aluminum foil-aluminum hydroxide dipped paper, aluminum foil-calcium carbonate dipped paper, etc. with a thickness of 0.01 to 0.05 .
- Hard plastic forms that serve as a heat insulating layer to be filled between the front and back materials include polyurethane, polyisocyanurate, and phenol urethane. Hard plastics such as phenol, phenol, and urea can be used. Of these, polyisocyanurate is particularly preferred.
- the polysocyanate form is a polysocyanate with a polyhydroxy compound, a trimerization catalyst, a foaming agent and a foam stabilizer ⁇ in the presence of NC0 Z0H equivalent ratio 2. It is manufactured by reacting at 0 or more.
- a poly-sodium format is a modified poly-sodium format, which is a poly-sodium or poly-method.
- the catalyst may be an alkali metal salt such as potassium acetate or potassium octylate, or a tertiary amine such as triethylamine or trisdimethylamine phenol.
- a silicone-based surfactant for example, SH-193 (manufactured by Resilicon Co., Ltd.) and L-5420 (manufactured by Nippon Unicar) are used.
- foaming agent all foaming agents used for producing urethane form and isocyanurate foam can be used. Specifically, fluorinated compounds, methylene chloride Water and acid amides may be mentioned as those which generate a gas by the reaction and the reaction, and a foam-based blowing agent is preferable. In the present invention, such a rigid plastic form may be subjected to a conventionally known flame retarding treatment.
- the raw graphite used in the production of the heat-expandable graphite used in the present invention there is no particular limitation on the raw graphite used in the production of the heat-expandable graphite used in the present invention and on the production method.
- the heat-expandable graphite is in the range of about 20-100 mesh, for example, in a mixture of 98% by weight concentrated sulfuric acid and 60% by weight aqueous hydrogen peroxide. It can be produced by contacting the crushed graphite at 45'C or less for 10 to 30 minutes, washing with water and drying.
- such a heat-expandable graphite may be interposed only between the surface material and the hard plastic form, or may be interposed only between the back material and the hard plastic foam. Further, it may be interposed between both the front surface material and the rigid plastic foam and between the back surface material and the rigid plastic form.
- heat-expandable graphite is applied to the back surface of the surface material and Z or the back material (the hard plastic form side).
- the amount of the heat-expandable graphite to be applied is too small, the effect of improving the fire protection and fire resistance according to the present invention cannot be sufficiently obtained, and if it is too large, the heat insulating property is reduced.
- the amount of the heat-expandable graphite applied is It is preferable that the content is 5 to 100% by weight based on the raw material forming the hard plastic form.
- thermoly expandable graphite is applied to the back surface of the surface material continuously fed.
- a liquid polyisocyanurate material to be a core heat insulating layer is mixed and discharged onto the application surface.
- the aluminum craft laminate paper of the back material was protruded onto the raw material of polyisocyanate, and sandwiched between the front material and the back material. Heat and press to foam. If the sandwich structure obtained is a continuous band, the continuous portion is cut into predetermined lengths to produce a product.
- the heat-expandable graphite does not expand at room temperature and at the time of foam molding of a rigid plastic form such as polyisocyanurate form, but when heated to 3701 or more, it expands to form a fire-resistant cut-off Si. Improves the fire protection and fire resistance of the insulated composite panel.
- '' In particular, according to the heat insulation composite panel using the polyisocyanate foam as the heat insulation layer, a remarkably excellent heat insulation composite panel is provided.
- a foam molded product obtained by reacting a polyisocyanate with a polyhydroxy compound in the presence of a trimerizing catalyst, a surfactant, and a foaming agent at an NC00H equivalent ratio of 2.0 or more.
- the fire prevention test method for the manufactured insulated composite panel is as follows.
- Table 1 shows the fire prevention test results of the obtained heat insulating composite panels. Examples 2 and 3
- a heat insulating composite panel was manufactured in the same manner as in Example 1 except that the amount of the heat-expandable graphite applied was set to the amount shown in Table 1, and a fire protection test was conducted. The results are shown in Table 1.
- a heat insulating composite panel was manufactured in the same manner as in Example 2 except that the thickness of the core material was changed to 25 mm, and a fire prevention test was performed. Table 1 shows the results.
- heat-insulating composite panels were manufactured in the same manner as in Examples 1, 4, and 9, respectively, and fire prevention tests were performed.
- the results are shown in Table 1. According to Table 1, heat-expandable graphite is interposed between the surface material or back surface material and the hard plastic form, so that the heat-expandable graphite becomes a barrier when heated and expanded during a fire prevention test. It is clear that the fire resistance and fire resistance of the composite panel are improved.
- Cutout thickness (recite) 0.35 0.35 0.27 0.35 0.27 0.27 ⁇ 7 ⁇ Krafta, Krafta »Micrafta ft Micraft Aluminumcraft A, Kraft surface Paper paper materials
- Form 7 Form, Form 7 Form, Form 7 Form, Form A Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form Form
- Test pass / fail ⁇ pass / fail As described in detail above, according to the heat-insulating composite panel of the present invention, the fireproof and fire-resistant properties that can sufficiently satisfy the criteria for quasi-noncombustible materials in the flame retardancy test for building materials UIS-A-1321) are remarkable. An excellent insulating composite panel is provided.
- the heat-insulating composite panel of the present invention can be used as an excellent building member.
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Physics & Mathematics (AREA)
- Acoustics & Sound (AREA)
- Electromagnetism (AREA)
- Building Environments (AREA)
- Laminated Bodies (AREA)
Abstract
Panneau composite thermo-isolant comportant une couche thermo-isolante composée d'une mousse en plastique rigide placée entre un élément de surface et un élément de support. Le panneau se caractérise en ce que du graphite thermo-expansible est pris en sandwich entre l'élément de surface et/ou l'élément de support et la mousse en plastique rigide. Ce panneau est réfractaire et présente d'excellentes caractéristiques d'ignifugeage.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019900702084A KR910700566A (ko) | 1989-01-23 | 1990-01-16 | 고속 프리스케일러 |
KR1019900702237A KR910700142A (ko) | 1989-02-10 | 1990-02-09 | 단열 복합 판넬 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1032163A JPH02209229A (ja) | 1989-02-10 | 1989-02-10 | 断熱複合パネル |
JP01/32163 | 1989-02-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1990009277A1 true WO1990009277A1 (fr) | 1990-08-23 |
Family
ID=12351273
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1990/000161 WO1990009277A1 (fr) | 1989-01-23 | 1990-02-09 | Panneau composite thermo-isolant |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPH02209229A (fr) |
AU (1) | AU5039890A (fr) |
WO (1) | WO1990009277A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2248030A (en) * | 1990-07-06 | 1992-03-25 | Sanwa Kako Co | Non-flammable open-cell cross-linked polyolefin foam |
EP0694372A1 (fr) * | 1994-07-29 | 1996-01-31 | Ucar Carbon Technology Corporation | Elément de structure ignifugé comprenant des plaques avec des fibres orientées |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL1026339C2 (nl) * | 2004-06-04 | 2005-12-06 | Opstalan B V | Samengesteld plaatvormig isolatiemateriaal, werkwijze ter vervaardiging daarvan alsmede een wand-, gevel- en dakconstructie. |
JP5912265B2 (ja) * | 2011-03-01 | 2016-04-27 | 旭化成建材株式会社 | 断熱性積層体 |
CA2858603C (fr) * | 2011-10-25 | 2016-11-22 | B/E Aerospace, Inc. | Panneau composite thermique |
CN109517330A (zh) * | 2018-11-22 | 2019-03-26 | 山东莱芜润达新材料有限公司 | 一种酚醛泡沫树脂用固化剂的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5163518A (fr) * | 1974-10-08 | 1976-06-02 | Ici Ltd | |
JPS59145853A (ja) * | 1983-02-03 | 1984-08-21 | 株式会社アイジー技術研究所 | 防火パネル |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2577064B2 (ja) * | 1988-08-30 | 1997-01-29 | 株式会社アイジー技術研究所 | 防火パネル |
-
1989
- 1989-02-10 JP JP1032163A patent/JPH02209229A/ja active Pending
-
1990
- 1990-02-09 WO PCT/JP1990/000161 patent/WO1990009277A1/fr unknown
- 1990-02-09 AU AU50398/90A patent/AU5039890A/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5163518A (fr) * | 1974-10-08 | 1976-06-02 | Ici Ltd | |
JPS59145853A (ja) * | 1983-02-03 | 1984-08-21 | 株式会社アイジー技術研究所 | 防火パネル |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2248030A (en) * | 1990-07-06 | 1992-03-25 | Sanwa Kako Co | Non-flammable open-cell cross-linked polyolefin foam |
GB2248030B (en) * | 1990-07-06 | 1994-05-25 | Sanwa Kako Co | Non-flammable open-cell cross-linked polyolefin foam and method for production thereof |
EP0694372A1 (fr) * | 1994-07-29 | 1996-01-31 | Ucar Carbon Technology Corporation | Elément de structure ignifugé comprenant des plaques avec des fibres orientées |
Also Published As
Publication number | Publication date |
---|---|
AU5039890A (en) | 1990-09-05 |
JPH02209229A (ja) | 1990-08-20 |
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