WO1989011147A1 - Procedes et elements optiques ternaires - Google Patents

Procedes et elements optiques ternaires Download PDF

Info

Publication number
WO1989011147A1
WO1989011147A1 PCT/US1989/001831 US8901831W WO8911147A1 WO 1989011147 A1 WO1989011147 A1 WO 1989011147A1 US 8901831 W US8901831 W US 8901831W WO 8911147 A1 WO8911147 A1 WO 8911147A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
optical recording
thickness
deformations
recording
Prior art date
Application number
PCT/US1989/001831
Other languages
English (en)
Inventor
James Charles Fleming
Michael Eric Meichle
James Fitzpatrick
Original Assignee
Eastman Kodak Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Company filed Critical Eastman Kodak Company
Publication of WO1989011147A1 publication Critical patent/WO1989011147A1/fr

Links

Classifications

    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/2407—Tracks or pits; Shape, structure or physical properties thereof
    • G11B7/24085—Pits
    • G11B7/24088—Pits for storing more than two values, i.e. multi-valued recording for data or prepits
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/004—Recording, reproducing or erasing methods; Read, write or erase circuits therefor
    • G11B7/0045—Recording
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/2407—Tracks or pits; Shape, structure or physical properties thereof
    • G11B7/24085—Pits

Definitions

  • the present invention relates to optical recording elements having at least ternary informa ⁇ tion recorded thereon and to methods for recording using the elements.
  • optical resolution is determined by the wave- length of the writing radiation, typically a laser, and the numerical aperture of the objective lens.
  • the numerical aperture of the lenses currently used in optical heads is near to the maximum which still preserves both an adequate working distance and a reasonable lens mass.
  • the semiconductor lasers cur ⁇ rently used in optical recording have the shortest wavelength which satisfies the requirements of suf ⁇ ficient power and access time.
  • an optical recording element comprising a reflective support having there— on a deformable optical recording layer having a thickness corresponding to about the half—wave thick ⁇ ness with respect to the reading wavelength, said layer having information recorded therein in the form of: a) deformations which are of a depth so as to leave remaining about a quarter-wave thickness of the layer with respect to the reading wavelength and, interspersed with said deformations, b) deformations which are at least substantially through to the reflective support.
  • a method for recording using the described element is provided.
  • the present invention is to be contrasted with the invention described in the KOKAI mentioned above.
  • the unrecorded layer has a very low reflectance.
  • the information is recorded in the form of deformations of at least two types , each having a reflectance above the unrecorded layer.
  • the unrecorded layer has a reflectance that is intermediate between one type of deformation and the other type.
  • the information appears in the layer as interspersed "positive" deformations, i.e. those having a reflectance lower than the unrecorded material and "negative" deformations, i.e. those having a reflec ⁇ tance that is higher than the unrecorded layer.
  • Figure 1 is a plot of the reflectance vs. thickness for a typical material that is used in deformation recording.
  • Figure 2 is a plot of the signal vs. time for an element according to the prior art and accord- ing to the invention.
  • the present invention will be described in detail with reference to ternary recording. It will be understood however, that deformations with reflec ⁇ tivities other than just the reflectivities corres- ponding to the optical quarter-wave thickness can also be recorded, as is illustrated in the KOKAI mentioned above.
  • the invention is adaptable to any form of multi-level information storage and retrieval.
  • the principle of the present invention is best understood by referring to Figure 1. There is illustrated a typical reflectance vs. thickness curve for a material that is used in deformation record ⁇ ings .
  • the wavelength that is used to make the curve is the wavelength that is used to read the informa ⁇ tion on the element.
  • Point A corresponds to the uncoated substrate having a high reflectance.
  • the reflectance decreases up to thickness 31 corresponding to the quarter-wave thickness of the material with respect to the reading wavelength. This is also referred to in the art as the "anti-reflection con ⁇ dition".
  • the reflectance increases achieving a maxima at point £ where the layer approximates the half-wave thick ⁇ ness .
  • the optical recording layer is coated at a thickness that corresponds to about the half— ave thickness with respect to the reading radiation.
  • power levels are chosen so that some of the deformations leave about a quarter-wave thickness corresponding to decreased reflectance points £, and some of the deformations are at least substantially through to the support corresponding to point A.
  • the variation of reflectance with thickness is very well known in the art and has been applied to advantage in binary recording on optical elements .
  • the present ternary recording is not disclosed.
  • the exact reflectance vs. thickness curve is determined by the material that is used for the recording layer and the wavelength that is used to measure the reflectance. It will there ⁇ fore be understood, that when selecting a thickness either for the unrecorded layer or the thickness that is about the quarter—wave thickness, the wavelength of the recording and reading wavelength must be con ⁇ sidered.
  • the thickness of the unrecorded layer is "about” the half—wave thickness and some of the deformations are such so as to leave “about” the quarter-wave thickness. It is contem ⁇ plated that the layer may be coated at a thickness that is different from the exact peak corresponding to the half—wave thickness and that the remaining thickness for the quarter— ave deformations may not be exactly the quarter—wave thickness. These parameters can be adjusted so as to optimize the element as necessary.
  • the difference between the reflectance of the unrecorded layer and the negative deformations is such that the signal to noise ratio (SNR) for that portion of the recording is more than is needed while the difference between the unrecorded layer and the positive deformations might be less than is needed for optimum SNR.
  • SNR signal to noise ratio
  • optical recording elements that can be used in the preparation of the recorded elements of the invention are conventional except for requiring a certain thickness for the optical recording ' layer .
  • they comprise a reflective support and a radiation sensitive optical recording layer.
  • the preferred optical recording elements comprise, in the following order, an aluminum support, a smoothing layer, a metal reflective layer and an optical recording layer.
  • the element can also include an overcoat layer as is known in the art, for example, U.S. Patent 4,527,173.
  • the aluminum support is coated with the smoothing layer formulation prior to the coating of the reflective layer and the recording layer.
  • the preferred smoothing layer compositions are described in U. S. Patents 4,446,223 and 4,619,890 cited above.
  • polymerization of the fluid produces a smooth surface on the support.
  • the thus formed smoothing layer is made reflective by vacuum metallization of the smooth surface.
  • Useful metals for this purpose include gold and aluminum.
  • Useful recording layers are coated by any of a wide variety of methods. Most conveniently, the dye and binder are coated from a common solvent or, alterna ⁇ tively, from a mixture of miscible solvents.
  • the dye-binder composition is coated by spray coating, air knife coating, whirl coating or by any other suitable method.
  • Useful dyes and binders are dis ⁇ closed in U.S. Patent 4,380,769 and U.S. Patent 4,499,165. These patents also describe in detail methods for making the recording layer.
  • Other useful recording layers include metallic or alloy layers.
  • the currently preferred optical recording layer is a dye—binder layer described in U. S. Patent 4,499,165.
  • That patent describes an optical record ⁇ ing layer comprising a binder mixture and a dye, which layer is characterized in that the binder mix ⁇ ture (a) is amorphous at high dye to binder ratios, (b) exhibits a single thermal transition with no phase separation after annealing, (c) is solid at about 20° C, and (d) comprises at least two different compounds each having at least two linking components joining one multivalent organic nucleus with at least two organic nuclei wherein at least one of the multi ⁇ valent organic nucleus and the organic nuclei is a multicyclic aromatic nucleus .
  • Another preferred dye—binder composition comprises an amorphous layer of a binder and a oxo— indolizine or oxoihdoliziniu dye as described in United States Patent 4,446,223 issued May 1, 1984. - The preparation of these dyes is described in United States Patent 4,577,024 issued March 18, 1986.
  • the dye in the preferred dye—binder optical recording layer is not critical. Innumerable dyes are available and well—known.
  • a preferred group of dyes which are especially compatible with the pre- ferred binder mixtures are metal complexes of bis-[cis-l,2-bis-(alkyl, hydrogen, aryl or hetero- cyclic)ethylene-l,2—dithiene] . They are commonly referred to as metal dithiene complexes. Mixtures of these dyes can also be used.
  • information is encoded in the form of interspersed deformations in the recording layer.
  • the preferred method is to modulate the incident power of the recording radiation. This can be accomplished by changing the power level of the incident radiation or by varying the duty cycle of a laser modulated at high frequency. Either of these methods can be used to vary the energy delivered to the recording layer on a deformation by deformation basis .
  • Algorithms for encoding the written infor ⁇ mation and for reading the encoded information are within the skill of those in the art.
  • Ternary recording has been * shown for magnetic materials and analogous methods for writing and reading information are adaptable to the present invention. Reference is made to Dixon, French and Wolf, J. 1987 Intermag. Conf.
  • relative motion must be provided between the optical recording element and the source of the recording radiation.
  • the ele ⁇ ment is moved relative to a fixed source of radiation as in a typical optical disk system.
  • the alterna ⁇ tive where the optical recording element is held stationary and the radiation source is moved, is also within the scope of the invention.
  • An optical recording element was prepared in the form of an optical disk.
  • a diamond turned 5 1/4" diameter aluminum substrate was coated with a smooth ⁇ ing layer composition similar to that described in example 1 of U.S. Patent 4,619,890 described above.
  • the smoothing layer was the same except that the solvent was butyl propionate and the "monomer 1" of the example was changed to an 80:20 mixture of 1,2,4—benzenetricarboxylic acid, tris 2—((l-oxo-2- propenyl)oxy)ethyl) ester and 2—propenoic acid—2— (benzoyloxy) ethyl ester.
  • This smoothing layer com- position was cured as described in the patent.
  • the smoothing layer was then coated with a reflecting layer of 200 nm of gold.
  • the disk was then coated with a solution of a dye and a binder in the ratio of 4:6 by weight and 2% solids.
  • the solvent for the coating composition was a mixture consisting of 20% trichloropropane and 80% bromobenzene.
  • the binder was a mixture as described in United States Patent 4,169,890 and was similar to "No. 11" in Col 21 and 22 of that patent.
  • the mixture was a nonpolymeric, amorphous glass mix ⁇ ture which was the reaction product of 1,1,3—tri— methyl—5—amino-3(p-aminophenyl) indan with 1-naph— thoyl chloride (50.00 mole%) ; p-bromobenzoyl chloride (16.67 mole7 0 ); and p-methoxybenzoyl chloride (33.33 mole%) . ?
  • the dye in the dye-binder mixture was the dye described in United States Patent 4,577,024 (men ⁇ tioned above) at Col 45, the second structure in that column.
  • the chemical name of the dye is: 2,3-di(2,4,6,-trimethylphenyl)-7-[2-(l,2- dimethyl-1,2,3,4-tetrahydro-6-quinolinyl) —1—ethenyl]-l—oxo-lE—indolizinium trifluoro— methanesulfonate.
  • the disk was coated such that the thickness of the dye—binder optical recording layer was 213 nm. This corresponds to a thickness which is near the half-wave thickness for this layer at a reading wavelength of 780nm. (Half-wave thickness is about 235nm. )
  • test tracks were recorded on the ' optical recording layer using a diode laser operating at a wavelength of 830nm.
  • the recorded tracks were read back using a similar diode laser operating at 780nm.
  • the test tracks were recorded using a variety of laser power levels and the carrier to noise ratio (CNR) was measured for each power level.
  • the velocity of the recording layer at point of recording was 9.4 meters per second.
  • the playback amplitude showed waveforms corresponding to high reflectivity- arks .
  • the playback amplitude showed waveforms corresponding to low reflectivity.
  • Examination of the resulting tracks indicated that the deformations in the recording layer made using the 10 mW recording power were of a higher reflectivity than the unrecorded areas of the layer while the deformations in the recording layer made using the 5 mW recording power were of a lower reflectivity than the unrecorded layer .
  • the CNR at both 5 and 10 mW was at least 55 dB (with a 30 KHz resolution bandwidth) . This CNR performance is sufficient for practical data recording at conventional data rates.
  • the reflectivity of the high reflectivity deformations approached the reflectivity of the uncoated substrate indicating that the deformations were substantially through to the support.
  • the reflectivity of the low reflectivity deformations corresponded to about the reflectivity of the quarter—wave thickness.
  • the laser recording power was alternated between the high power and the low power.
  • both the high reflectivity high power deformations and the interspersed low power, low reflectivity deformations could be distinguished even when a high power deformation was adjacent to a low power deformation.

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  • Optical Record Carriers And Manufacture Thereof (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

La présente invention concerne des éléments d'enregistrement optique ayant des informations multi-niveaux, au moins ternaires, enregistrées sur ces éléments, ainsi que des procédés d'enregistrement utilisant les éléments. Un élément d'enregistrement optique comprend un support réfléchissant sur lequel est appliquée une couche déformable d'enregistrement optique dont l'épaisseur correspond environ à l'épaisseur d'une demi-onde, par rapport à la longueur d'onde de lecture, ladite couche portant des informations enregistrées sous la forme de: a) des déformations dont la profondeur laisse environ une épaisseur d'un quart d'onde de la couche par rapport à la longueur d'onde de lecture et, dispersées entre lesdites déformations, b) des déformations qui traversent et vont jusqu'au support réfléchissant.
PCT/US1989/001831 1988-05-11 1989-05-01 Procedes et elements optiques ternaires WO1989011147A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US19245388A 1988-05-11 1988-05-11
US192,453 1988-05-11

Publications (1)

Publication Number Publication Date
WO1989011147A1 true WO1989011147A1 (fr) 1989-11-16

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PCT/US1989/001831 WO1989011147A1 (fr) 1988-05-11 1989-05-01 Procedes et elements optiques ternaires

Country Status (3)

Country Link
EP (1) EP0372051A1 (fr)
JP (1) JPH02504196A (fr)
WO (1) WO1989011147A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0575176A1 (fr) * 1992-06-18 1993-12-22 Canon Kabushiki Kaisha Milieu d'enregistrement optique, méthode d'enregistrement d'information et méthode de reproduction d'information
WO2001027917A1 (fr) * 1999-10-14 2001-04-19 Tdk Corporation Support d'enregistrement optique, procede d'enregistrement optique, procede de reproduction de support optique enregistre
WO2003019542A1 (fr) * 2001-08-24 2003-03-06 Koninklijke Philips Electronics N.V. Procede d'enregistrement de supports d'enregistrement optique

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7012870B2 (en) 2001-03-30 2006-03-14 Tdk Corporation Optical recording method, optical recording medium and optical irradiating time controlling device
US6754166B2 (en) 2001-03-30 2004-06-22 Tdk Corporation Optical recording medium and optical recording method
US6699557B2 (en) 2001-03-30 2004-03-02 Tdk Corporation Optical recording medium and optical recording method
US7082088B2 (en) 2001-03-30 2006-07-25 Tdk Corporation Optical recording medium and optical recording method by irradiation

Citations (8)

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US4455632A (en) * 1980-04-25 1984-06-19 U.S. Philips Corporation Apparatus for optically reading a record carrier with two types of information areas
JPS59207444A (ja) * 1983-05-12 1984-11-24 Nippon Telegr & Teleph Corp <Ntt> レ−ザカ−ド
JPS60209948A (ja) * 1984-04-03 1985-10-22 Nec Corp 情報記録原盤の製造方法
JPS60209939A (ja) * 1984-04-02 1985-10-22 Nec Corp 情報記録原盤の製造方法
JPS6174148A (ja) * 1984-09-20 1986-04-16 Nec Corp 光記録媒体
JPS6194249A (ja) * 1984-10-16 1986-05-13 Nec Corp 光記録媒体
JPS6199953A (ja) * 1984-10-19 1986-05-19 Nec Corp 光記録媒体
JPS61129748A (ja) * 1984-11-27 1986-06-17 Canon Inc 光情報記録媒体

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4455632A (en) * 1980-04-25 1984-06-19 U.S. Philips Corporation Apparatus for optically reading a record carrier with two types of information areas
JPS59207444A (ja) * 1983-05-12 1984-11-24 Nippon Telegr & Teleph Corp <Ntt> レ−ザカ−ド
JPS60209939A (ja) * 1984-04-02 1985-10-22 Nec Corp 情報記録原盤の製造方法
JPS60209948A (ja) * 1984-04-03 1985-10-22 Nec Corp 情報記録原盤の製造方法
JPS6174148A (ja) * 1984-09-20 1986-04-16 Nec Corp 光記録媒体
JPS6194249A (ja) * 1984-10-16 1986-05-13 Nec Corp 光記録媒体
JPS6199953A (ja) * 1984-10-19 1986-05-19 Nec Corp 光記録媒体
JPS61129748A (ja) * 1984-11-27 1986-06-17 Canon Inc 光情報記録媒体

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Title
PATENT ABSTRACTS OF JAPAN vol. 10, no. 243 (P-489)(2299) 21 August 1986, & JP-A-61 074148 (NEC CORPORATION) 16 April 1986, see the whole document *
PATENT ABSTRACTS OF JAPAN vol. 10, no. 271 (P-497)(2327) 16 September 1986, & JP-A-61 094249 (NEC CORPORATION) 13 May 1986, see the whole document (cited in the application) *
PATENT ABSTRACTS OF JAPAN vol. 10, no. 278 (P-499)(2334) 20 September 1986, & JP-A-61 099953 (NEC CORPORATION) 19 May 1986, see the whole document *
PATENT ABSTRACTS OF JAPAN vol. 10, no. 322 (P-511)(2378) 31 October 1986, & JP-A-61 129748 (CANON INC.) 17 June 1986, see the whole document *
PATENT ABSTRACTS OF JAPAN vol. 10, no. 72 (P-438)(2129) 22 March 1986, & JP-A-60 209939 (NIPPON DENKI K.K.) 22 October 1985, see the whole document *
PATENT ABSTRACTS OF JAPAN vol. 10, no. 72 (P-438)(2129) 22 March 1986, & JP-A-60 209948 (NIPPON DENKI K.K.) 22 October 1985, see the whole document *
PATENT ABSTRACTS OF JAPAN vol. 9, no. 76 (P-346)(1799) 05 April 1985, & JP-A-59 207444 (NIPPON DENSHIN DENWA KOSHA) 24 November 1984, see the whole document *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0575176A1 (fr) * 1992-06-18 1993-12-22 Canon Kabushiki Kaisha Milieu d'enregistrement optique, méthode d'enregistrement d'information et méthode de reproduction d'information
US5428599A (en) * 1992-06-18 1995-06-27 Canon Kabushiki Kaisha Optical recording medium, information recording method and information reproducing method
WO2001027917A1 (fr) * 1999-10-14 2001-04-19 Tdk Corporation Support d'enregistrement optique, procede d'enregistrement optique, procede de reproduction de support optique enregistre
WO2003019542A1 (fr) * 2001-08-24 2003-03-06 Koninklijke Philips Electronics N.V. Procede d'enregistrement de supports d'enregistrement optique

Also Published As

Publication number Publication date
JPH02504196A (ja) 1990-11-29
EP0372051A1 (fr) 1990-06-13

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