WO1989000181A1 - Composition resineuse de sulfure de polyarilene - Google Patents

Composition resineuse de sulfure de polyarilene Download PDF

Info

Publication number
WO1989000181A1
WO1989000181A1 PCT/JP1987/000447 JP8700447W WO8900181A1 WO 1989000181 A1 WO1989000181 A1 WO 1989000181A1 JP 8700447 W JP8700447 W JP 8700447W WO 8900181 A1 WO8900181 A1 WO 8900181A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
polyarylene sulfide
ethylene
resin composition
present
Prior art date
Application number
PCT/JP1987/000447
Other languages
English (en)
Japanese (ja)
Inventor
Masakazu Inoue
Kuniaki Asai
Yasuro Suzuki
Original Assignee
Sumitomo Chemical Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Company, Limited filed Critical Sumitomo Chemical Company, Limited
Publication of WO1989000181A1 publication Critical patent/WO1989000181A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene

Definitions

  • the present invention relates to a modified polyarylene sulfide tttt composition having a high balance.
  • Rewarding technology POLYF * Polyurethane salid y represented by urelen salf guide, etc. «The belly is excellent in heat resistance, dynamism, cafeteria, etc. In recent years, it has been attracting attention as a near-ring plastic, especially in the field of electric appliances and motor vehicle parts.
  • the present invention # is based on the above-mentioned conditions, and is characterized by the addition of sugar *, polyphenylene sulfite, ethylene, a By blending a polyethylene copolymer consisting of benzylalkyl pentyl and anhydrous maleic fiber, the poly-lens sulfide tree ar
  • the present invention has been found that a parent product having excellent characteristics can be obtained while maintaining the above characteristics. It is an object of the present invention to provide a composition having improved properties such as heat resistance and durability of a poly (phenylene sulfide) balance w without deteriorating its properties. You. That is, the present invention relates to the following:
  • the poly-lens salfide used in the present invention is represented by the general formula ⁇ Ar— It is a polymer represented by 2: In ⁇ ——for example, ,
  • PPS polygonal universal guide represented by the general 3 ⁇ 4- ⁇ -s ⁇ .), which is a U.S. Slipstick ⁇ -series. It is commonly marketed by Am Corporation under the trademark Ryton.
  • the production method is described in U.S. Pat. No. 8,8 ⁇ 4,129 #Migration and its corresponding Japanese Patent Publication No. 51-38S8, and is disclosed in US Pat.
  • a solvent of 1650 to 250 in a don solvent, and under a pressurized condition
  • the unitary component of the ethylene copolymer is ethylene, a, jS—unsweetened urea, a polyester, and an anhydrous male. Is it made of Inn Yabu? ), 50 to 90 weight% of ethylene, or 60 to 8 ⁇ -fold i3 ⁇ 4, a, / 3 — 5 to 49 weight of unsaturated carbon H alkyl ester ⁇ , Preferably between 7 and 4 6 All good beauty anhydrous Ma Tray down. »Is 0, ⁇ ⁇ 1 OS amount, rather than the favored Ru 1 to 8 double S» Der 0
  • ⁇ , 3 —No! 3 ⁇ 43 ⁇ 43 karmon mongolian arresting styling is an unconventional bonbon with 8 to 8 cubic meters of search, for example, acryl, methacrylic number, etc.
  • esters include, but are not limited to, acrylic acid, methyl acid, acrylic acid ester, acrylic acid 11- probe, and acrylic acid.
  • the amount of these ethylene copolymers to be S3 mixed was determined by comparing the amount of JPP S 70-99 with respect to the combination of FfS and ethylene copolymers, Copolymer 80 to 1 S amount is appropriate! ), Is 99
  • the weight of the ethylene copolymer is less than 1% by weight, the effect of refreshing the target vulnerability is insufficient.
  • the PJPS exceeds 70% by weight and the ethylene copolymer exceeds 80% by weight, the heat resistance and the durability, which are the characteristics of fPS, are significantly reduced. I don't like it.
  • the compounding agent a of the composition ⁇ of the present invention is not particularly determined ⁇ . 1 »PS and styrene copolymers are separately supplied to the port.» »It is possible to supply to the combined machine. Also, these raw materials are mortar, hensyl * in advance. It is also possible to use a mixer, a VOLMIR, a lip blender, etc., to preliminarily match before supplying to the smelting machine.
  • an antioxidant and a heat stabilizer, an ultraviolet absorber, a clarifier, a bell dye, a dye, a coloring agent such as a pigment, etc. to the extent that the object of the present invention is not included.
  • One or more ordinary additives such as a flame retardant, a flame retardant aid, an antistatic agent, and an antioxidant, can be added.
  • thermogenic fleas eg., polyethylene, polypropylene, polyamide, polycarbonate, polysulfone, Politi Chilsa Le phon, modified volume Re off ⁇ les emission O key support wells', etc.
  • thermosetting plum butter e.g. full Roh Lumpur «I fat, Bo key sheet trees JW, etc.
  • fillers such as glass fibers, carbon fibers, pon fibers, soybean fiber fibers, asbestos fibers, metal fibers, etc. It is also possible to combine fillers such as glass, glassite, glass beads, aruna, and charcoal charcoal.
  • glass fibers or carbon fibers have remarkable effects of improving the durability and heat resistance by their pitting, and provide a useful composition.
  • the fiber has a diameter of 5 to 15 and a length of 3 to 8 * » and is composed of hundreds to thousands of single fibers.
  • -Use a mouth bing made of long fibers or even fibers, and distribute them evenly in the final boat so that the average fiber diameter is in the range of 0.1 ⁇ to 0.
  • Is preferred 0 BEST MODE FOR SOLOTING THE INVENTION 3
  • the present invention will be described with reference to examples, but these are merely examples, and the present invention is not limited thereto. Not ⁇
  • Table 1 shows the styrene copolymers consisting of ⁇ -4) and 6% of diethylene, acrylyl ethylene 30. ⁇ and anhydrous malein 2. ⁇ 3 ⁇ 4.
  • the composition shown in the table below is combined with a twin-screw extruder (Ikegu Iron Works PC ⁇ —
  • the strand was cut with water »and pelletized.
  • the obtained pellets were injection-molded (Sumitomo Heavy Industries' Nestor 47/28 injection molding machine, cylinder SL degree 8100, gold S degree 1800> Test piece, bending test piece, thermal deformation degree
  • the obtained pellets were injection molded (Sumitomo Heavy Industries, Ltd. 47/28 injection molding machine, 'No Linda *', temperature: 320 2; gold: 2B ⁇ , 180 °).
  • the test pieces were as follows: ASTM D-256, D-790, and D-648. Therefore, it was inserted.
  • the male and female glass fibers used in the shojo 4-5 were combined at the ratios shown in Table 2 and processed in the same manner as in Examples 4-5, and the physical properties were measured. Table 2
  • the polyarylene sulfide of the present invention is also combined with an ethylene copolymer base comprising ethylene, ⁇ , ⁇ -unsaturated carboxylic acid alkyl ester and maleic anhydride in addition to the polyarylene sulfide IS.
  • the ⁇ 3 ⁇ 4 is a genuinely improved one without reducing the maturity and rigidity. Therefore, the arrowhead structure of the present invention is used as an automotive electronics for products such as electric and electronic products, automotive products, and OA roof gap products, even if it is required to be thinner and smaller.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Cette invention se rapporte à une composition de résine comprenant: (A) 70 à 99 % en poids de sulfure de polyarylène et (B) 30 à 1 % en poids d'un copolymère d'éthylène se composant de 50 à 90 % en poids d'éthylene, de 5 à 49 % en poids d'un ester d'alkyle d'un acide carboxylique insaturé alpha, beta, et de 0,5 à 10 % en poids d'anhydride maléique. La composition de résine de la présente invention présente une fragilité sensiblement réduite alors qu'elle conserve la résistance à la chaleur et la caractéristique de rigidité d'une résine de sulfure de polyarylène elle-même, et est utile à titre de plastiques à usage industriel pour des applications telles que dans des composants électriques ou électroniques, dans des pièces d'automobiles, et dans des pièces pour appareils de bureautique, pour lesquels on cherche à atteindre une diminution de l'épaisseur et des dimensions.
PCT/JP1987/000447 1985-12-26 1987-06-30 Composition resineuse de sulfure de polyarilene WO1989000181A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29458485A JPS62151460A (ja) 1985-12-26 1985-12-26 ポリアリ−レンサルフアイド樹脂組成物

Publications (1)

Publication Number Publication Date
WO1989000181A1 true WO1989000181A1 (fr) 1989-01-12

Family

ID=17809668

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1987/000447 WO1989000181A1 (fr) 1985-12-26 1987-06-30 Composition resineuse de sulfure de polyarilene

Country Status (2)

Country Link
JP (1) JPS62151460A (fr)
WO (1) WO1989000181A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5191020A (en) * 1989-07-05 1993-03-02 Asahi Kasei Kogyo Kabushiki Kaisha Polyphenylene sulfide resin composition
GB2348152A (en) * 1997-12-08 2000-09-27 Baby Think It Over Inc Infant simulator

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0653848B2 (ja) * 1986-01-23 1994-07-20 東レ株式会社 ポリフエニレンスルフイド組成物
JPH0826221B2 (ja) * 1987-09-14 1996-03-13 呉羽化学工業株式会社 ポリアリーレンチオエーテル組成物及びその成形物
US5219920A (en) * 1988-11-04 1993-06-15 Mitsubishi Rayon Co., Ltd. Polyarylene sulfide resin composition
US5270375A (en) * 1988-11-04 1993-12-14 Mitsubishi Rayon Co., Ltd. Polyarylene sulfide resin
US5087666A (en) * 1990-07-10 1992-02-11 Phillips Petroleum Company Modified poly(arylene sulfide) composition with improved impact strength and reduced shrinkage
JP4307908B2 (ja) 2003-06-05 2009-08-05 ポリプラスチックス株式会社 ポリアリーレンサルファイド樹脂組成物および塗装成形品
JP5029476B2 (ja) * 2008-04-15 2012-09-19 東ソー株式会社 ポリアリーレンスルフィド組成物
JP6048019B2 (ja) * 2012-09-12 2016-12-21 東レ株式会社 ポリフェニレンスルフィド樹脂組成物成形品、その製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56136847A (en) * 1980-03-31 1981-10-26 Dainippon Ink & Chem Inc Polyarylenesulfide composition
JPS58154757A (ja) * 1982-03-10 1983-09-14 Toray Ind Inc ポリアリ−レンスルフイド樹脂組成物
JPS60229949A (ja) * 1984-04-16 1985-11-15 東レ株式会社 強化ポリアリ―レンサルファイド成形用組成物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56136847A (en) * 1980-03-31 1981-10-26 Dainippon Ink & Chem Inc Polyarylenesulfide composition
JPS58154757A (ja) * 1982-03-10 1983-09-14 Toray Ind Inc ポリアリ−レンスルフイド樹脂組成物
JPS60229949A (ja) * 1984-04-16 1985-11-15 東レ株式会社 強化ポリアリ―レンサルファイド成形用組成物

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5191020A (en) * 1989-07-05 1993-03-02 Asahi Kasei Kogyo Kabushiki Kaisha Polyphenylene sulfide resin composition
GB2348152A (en) * 1997-12-08 2000-09-27 Baby Think It Over Inc Infant simulator
GB2348152B (en) * 1997-12-08 2002-09-25 Baby Think It Over Inc Infant simulator

Also Published As

Publication number Publication date
JPS62151460A (ja) 1987-07-06
JPH0518352B2 (fr) 1993-03-11

Similar Documents

Publication Publication Date Title
CN102443256B (zh) 一种高耐热pc/asa合金材料及其制备方法
CN101693778B (zh) 一种pvc/abs共混物及其管材
CN101508817B (zh) 一种高光abs合金及其制备方法
US10287434B2 (en) Polymer resin composition having excellent chemical resistance
EP1932885B1 (fr) Composition de résine thermoplastique résistant au feu et aux rayures
CN104086969A (zh) 一种透明的耐刮擦pc/pmma合金材料及其制备方法
WO1989000181A1 (fr) Composition resineuse de sulfure de polyarilene
CN102372915A (zh) 一种高冲击高流动pc/asa合金材料及其制备方法
JP6565652B2 (ja) （メタ）アクリル系共重合体、樹脂組成物及びその成形体
CN103183935B (zh) 高韧性pbt/pc合金及其制备方法
CN101787190B (zh) 一种阻燃环保高强度pc-as复合材料及其制备方法
CN105385065A (zh) 一种聚氯乙烯/聚氨酯合金线缆料及其制备方法
CN101220194A (zh) 一种环保阻燃abs体系母料的制备方法
CN102108181A (zh) 一种热塑性合金及其制备方法
CN105348724A (zh) 一种高光高硬度抗刮伤改性pc/abs合金料及其制备方法
JP3235856B2 (ja) 成形用樹脂組成物
EP3042931A1 (fr) Composition de résine de polymère et produit moulé associé
KR102217754B1 (ko) 고분자 수지 조성물
CN101077922B (zh) 一种abs/pc改性合金
JPS5941355A (ja) 熱可塑性樹脂組成物
KR950001641B1 (ko) 열가소성 수지 조성물
CN111484721A (zh) 一种耐低温冲击pc/abs复合材料及其制备方法
CN105038062A (zh) 一种高流动性增韧聚甲基丙烯酸甲酯及其制备方法
CN113728054A (zh) 热塑性树脂的耐碱溶液性改善方法
CN101096441A (zh) Abs/pc改性合金

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU BR US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE FR GB IT NL SE