WO1988000179A3 - Procede de production d'aldehydes par hydroformylation - Google Patents

Procede de production d'aldehydes par hydroformylation Download PDF

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Publication number
WO1988000179A3
WO1988000179A3 PCT/GB1987/000408 GB8700408W WO8800179A3 WO 1988000179 A3 WO1988000179 A3 WO 1988000179A3 GB 8700408 W GB8700408 W GB 8700408W WO 8800179 A3 WO8800179 A3 WO 8800179A3
Authority
WO
WIPO (PCT)
Prior art keywords
pct
high boiling
hydroformylation
sec
aldehyde
Prior art date
Application number
PCT/GB1987/000408
Other languages
English (en)
Other versions
WO1988000179A2 (fr
Inventor
George Edwin Harrison
Alan James Dennis
Original Assignee
Davy Mckee London
George Edwin Harrison
Alan James Dennis
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27263082&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1988000179(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GB868616038A external-priority patent/GB8616038D0/en
Priority claimed from GB878705108A external-priority patent/GB8705108D0/en
Priority claimed from GB878706265A external-priority patent/GB8706265D0/en
Priority to JP62503454A priority Critical patent/JPH0832646B2/ja
Priority to KR1019880700224A priority patent/KR950012999B1/ko
Priority to DE8787903733T priority patent/DE3772574D1/de
Priority to AT87903733T priority patent/ATE66668T1/de
Priority to BR8707736A priority patent/BR8707736A/pt
Application filed by Davy Mckee London, George Edwin Harrison, Alan James Dennis filed Critical Davy Mckee London
Publication of WO1988000179A2 publication Critical patent/WO1988000179A2/fr
Publication of WO1988000179A3 publication Critical patent/WO1988000179A3/fr
Priority to DK085888A priority patent/DK85888A/da
Priority to NO880878A priority patent/NO169538C/no
Priority to SU884613118A priority patent/RU2005714C1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Procédé continu d'hydroformylation d'oléfines contenant généralement de 6 à 20 atomes de carbone, permettant de produire les aldéhydes correspondants. La formation de produits de condensation d'aldéhydes à point d'ébullition élevé est réduite au minimum par l'utilisation d'un solvant inerte présentant un point d'ébullition élevé situé, à la pression régnant dans la zone d'extraction du produit, à mi-chemin entre celui de l'aldéhyde produit pendant la réaction d'hydroformylation et présentant le point d'ébullition le plus élevé, et celui du ligand. La concentration de l'aldéhyde produit est également maintenue à un niveau égal ou inférieur à une valeur minimale prédéterminée. Il est ainsi possible de prolonger de manière significative la durée du cycle de production avant qu'il ne soit nécessaire d'arrêter l'installation, à cause de l'accumulation des condensats d'aldéhyde à point d'ébullition élevé.
PCT/GB1987/000408 1986-07-01 1987-06-12 Procede de production d'aldehydes par hydroformylation WO1988000179A2 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP62503454A JPH0832646B2 (ja) 1986-07-01 1987-06-12 ヒドロホルミル化によるアルデヒドの製造方法
KR1019880700224A KR950012999B1 (ko) 1986-07-01 1987-06-12 하이드로포르밀화에 의한 알데히드의 제조방법
DE8787903733T DE3772574D1 (de) 1986-07-01 1987-06-12 Verfahren zur herstellung von aldehyden durch hydroformylierung.
AT87903733T ATE66668T1 (de) 1986-07-01 1987-06-12 Verfahren zur herstellung von aldehyden durch hydroformylierung.
BR8707736A BR8707736A (pt) 1986-07-01 1987-06-12 Processo para a producao de aldeidos por hidroformilacao
DK085888A DK85888A (da) 1986-07-01 1988-02-19 Fremgangsmaade til fremstilling af aldehyder ved hydroformylering
NO880878A NO169538C (no) 1986-07-01 1988-02-29 Fremgangsmaate for fremstilling av aldehyder ved hydroformylering
SU884613118A RU2005714C1 (ru) 1986-07-01 1988-12-30 Способ непрерывного получения альдегидов c7-c17

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB8616038 1986-07-01
GB868616038A GB8616038D0 (en) 1986-07-01 1986-07-01 Process
GB878705108A GB8705108D0 (en) 1987-03-05 1987-03-05 Process
GB8705108 1987-03-05
GB878706265A GB8706265D0 (en) 1987-03-17 1987-03-17 Process
GB8706265 1987-03-17

Publications (2)

Publication Number Publication Date
WO1988000179A2 WO1988000179A2 (fr) 1988-01-14
WO1988000179A3 true WO1988000179A3 (fr) 1988-01-28

Family

ID=27263082

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1987/000408 WO1988000179A2 (fr) 1986-07-01 1987-06-12 Procede de production d'aldehydes par hydroformylation

Country Status (13)

Country Link
US (1) US5053551A (fr)
EP (1) EP0313559B1 (fr)
JP (1) JPH0832646B2 (fr)
KR (1) KR950012999B1 (fr)
AT (1) ATE66668T1 (fr)
AU (1) AU612580B2 (fr)
BR (1) BR8707736A (fr)
CA (1) CA1308118C (fr)
DE (1) DE3772574D1 (fr)
DK (1) DK85888A (fr)
ES (1) ES2007088A6 (fr)
MX (1) MX168892B (fr)
WO (1) WO1988000179A2 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0589463B1 (fr) * 1992-09-25 1997-08-20 Mitsubishi Chemical Corporation Méthode pour contrÔler une réaction d'hydroformylation
DE4300921C1 (de) * 1993-01-15 1994-04-14 Hoechst Ag Verfahren zur Lösungsmittel-Rückgewinnung sowie dafür geeignete Vorrichtung
JP3551509B2 (ja) * 1994-12-12 2004-08-11 三菱化学株式会社 アルデヒド類の製造方法
US6035743A (en) * 1998-03-18 2000-03-14 Schwinn Cycling & Fitness Inc. Multi-functional clipless pedal
TWI427094B (zh) * 2010-10-25 2014-02-21 Nanya Plastics Corp 一種提高丙二酚型氫化環氧樹脂產率的氫化方法
SG11201405863QA (en) 2012-04-12 2014-11-27 Basf Se Method for replenishing the catalyst in continuous hydroformylation
MX2015002936A (es) * 2012-09-07 2016-01-25 Hse Hitit Solar Enerji Anonim Sirketi Sistema de destilacion al vacio producido por una columna barometrica.
KR20140042402A (ko) * 2012-09-28 2014-04-07 주식회사 엘지화학 올레핀으로부터 알코올의 제조장치 및 제조방법
BR112018009017B1 (pt) * 2015-11-10 2021-01-26 Dow Technology Investments Llc processo para produção de aldeídos
CN109499081A (zh) * 2018-12-04 2019-03-22 江苏拓驰工程技术开发有限公司 一种带刮板加热功能的刮膜蒸发器
US20220176385A1 (en) * 2019-03-05 2022-06-09 Basf Se Mixture of octene hydroformylation by-product and diesel, kerosene or c8-c20 olefins as collectors
CN114521194B (zh) 2020-09-17 2024-03-29 株式会社Lg化学 醛的制备方法和醛的制备装置
CN114773172B (zh) * 2022-06-20 2022-10-18 中海油天津化工研究设计院有限公司 一种烯烃氢甲酰化制醛工艺优化方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1440413A (en) * 1973-09-21 1976-06-23 Mitsubishi Chem Ind Process for producing butyraldehydes
GB1458375A (en) * 1973-04-09 1976-12-15 Ici Ltd Hydroformylation
FR2459217A1 (fr) * 1979-06-18 1981-01-09 Celanese Corp Procede d'hydroformylation d'une olefine, ameliore par le choix du solvant de reaction et le controle des parametres d'extraction du produit
US4260828A (en) * 1980-04-16 1981-04-07 Union Carbide Corporation Hydroformylation process
EP0028378A1 (fr) * 1979-10-26 1981-05-13 Union Carbide Corporation Procédé d'hydroformylation utilisant un catalyseur au rhodium stable
WO1984003697A1 (fr) * 1983-03-16 1984-09-27 Exxon Research Engineering Co Hydroformylation a haute temperature
EP0096987B1 (fr) * 1982-06-11 1985-11-13 DAVY McKEE (LONDON) LIMITED Procédé d'hydroformylation

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3527809A (en) * 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4159999A (en) * 1974-11-22 1979-07-03 Celanese Corporation Hydroformylation of olefins
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4247486A (en) * 1977-03-11 1981-01-27 Union Carbide Corporation Cyclic hydroformylation process
FR2351077A1 (fr) * 1976-05-13 1977-12-09 Celanese Corp Procede perfectionne d'hydroformylation des olefines avec un catalyseur complexe au rhodium
US4282100A (en) * 1978-09-18 1981-08-04 The Sanko Steamship Co., Ltd. Apparatus for reforming fuel oil wherein ultrasonic waves are utilized
DE16286T1 (de) * 1979-03-21 1983-05-11 Davy Mckee (London) Ltd., London Hydroformylierungsverfahren.
EP0016285B2 (fr) * 1979-03-21 1986-03-05 DAVY McKEE (LONDON) LIMITED Procédé de préparation des valeraldéhydes par hydroformylation de butene-1
US4329511A (en) * 1979-06-18 1982-05-11 Celanese Corporation Hydroformylation process improved by choice of reaction solvent and control of product stripping parameters
JPS5645436A (en) * 1979-09-21 1981-04-25 Mitsubishi Chem Ind Ltd Hydroformylation of olefin
DE3114147A1 (de) * 1981-04-08 1982-10-28 Basf Ag, 6700 Ludwigshafen Verfahren zur gewinnung von aldehyden
DE3371067D1 (en) * 1982-06-11 1987-05-27 Davy Mckee London Hydroformylation process
ATE28183T1 (de) * 1982-06-11 1987-07-15 Davy Mckee London Hydroformylierungsverfahren.
DE3341035A1 (de) * 1983-11-12 1985-05-23 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4678857A (en) * 1986-03-31 1987-07-07 Texaco Inc. Process for separation of product resulting from hydroformylation
GB2192182B (en) * 1986-07-01 1990-05-23 Davy Mckee Process for the production of aldehydes

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1458375A (en) * 1973-04-09 1976-12-15 Ici Ltd Hydroformylation
GB1440413A (en) * 1973-09-21 1976-06-23 Mitsubishi Chem Ind Process for producing butyraldehydes
FR2459217A1 (fr) * 1979-06-18 1981-01-09 Celanese Corp Procede d'hydroformylation d'une olefine, ameliore par le choix du solvant de reaction et le controle des parametres d'extraction du produit
EP0028378A1 (fr) * 1979-10-26 1981-05-13 Union Carbide Corporation Procédé d'hydroformylation utilisant un catalyseur au rhodium stable
US4260828A (en) * 1980-04-16 1981-04-07 Union Carbide Corporation Hydroformylation process
EP0096987B1 (fr) * 1982-06-11 1985-11-13 DAVY McKEE (LONDON) LIMITED Procédé d'hydroformylation
WO1984003697A1 (fr) * 1983-03-16 1984-09-27 Exxon Research Engineering Co Hydroformylation a haute temperature

Also Published As

Publication number Publication date
JPH0832646B2 (ja) 1996-03-29
KR880701699A (ko) 1988-11-04
AU7482087A (en) 1988-01-29
KR950012999B1 (ko) 1995-10-24
JPH01503532A (ja) 1989-11-30
DE3772574D1 (de) 1991-10-02
AU612580B2 (en) 1991-07-18
CA1308118C (fr) 1992-09-29
ES2007088A6 (es) 1989-06-01
MX168892B (es) 1993-06-14
ATE66668T1 (de) 1991-09-15
BR8707736A (pt) 1989-10-31
DK85888D0 (da) 1988-02-19
EP0313559A1 (fr) 1989-05-03
US5053551A (en) 1991-10-01
DK85888A (da) 1988-02-19
WO1988000179A2 (fr) 1988-01-14
EP0313559B1 (fr) 1991-08-28

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