WO1987004921A1 - Composition de conditionnement des ongles a base de dissolvant - Google Patents

Composition de conditionnement des ongles a base de dissolvant Download PDF

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Publication number
WO1987004921A1
WO1987004921A1 PCT/US1987/000269 US8700269W WO8704921A1 WO 1987004921 A1 WO1987004921 A1 WO 1987004921A1 US 8700269 W US8700269 W US 8700269W WO 8704921 A1 WO8704921 A1 WO 8704921A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
wax
nail
weight
lower alkanol
Prior art date
Application number
PCT/US1987/000269
Other languages
English (en)
Inventor
Henry C. Jadow
Original Assignee
Krazy Glue Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krazy Glue Inc. filed Critical Krazy Glue Inc.
Publication of WO1987004921A1 publication Critical patent/WO1987004921A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/04—Nail coating removers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35—Ketones, e.g. benzophenone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/45—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic

Definitions

  • This invention relates to nail polish remover and conditioner and is particularly related to a composition which exhibits the dual properties of nail polish remover and nail conditioner. More particularly, the present invention is directed to such nail polish remover-nail conditioner compositions which are in gel form.
  • a representative nail polish remover composition contains acetone, ethyl alcohol, hydroxypropyl cellulose, paraffin wax and, optionally, fragrances and colorants.
  • the nail polish remover is applied to the nail surface by a cosmetic brush or the like to form a coating on the nail surface. After a few minutes, this coating is wiped off with a bleached cloth and the nails are washed clean.
  • the nail polish remover is carefully prepared, applied and removed, the nails may turn white and become cosmetically unappealling. This problem arises basically because present day nail polish remover compositions do not contain an effective nail conditioning ingredient.
  • SUBSTITUTE SHEET Accordingly, it is an object of the present invention to provide a novel composition which serves the dual function of removing the nail polish and conditioning the nail after the nail polish has been removed from the nail surface.
  • a combination nail polish remover-conditioner composition which, after applying to the nail surface and wiping it clean, imparts a smooth protective conditioning coating thereon and prevents discoloration and bleaching of the nail surface.
  • the composition basically comprises acetone, hydroxypropyl cellulose and a tallow polyamine, the latter serving as the nail conditioning ingredient of the composition. Suitable tallow polyamines are
  • compositions of this invention may contain a lower alkanol such as ethyl alcohol, a natural or synthetic wax, preferably a paraffin wax, a fragrance and a colorant.
  • these compositions are made in gel form to avoid the known problem of acetone toxicity.
  • the nail polish remover/nail conditioner compositions are prepared in gel form. This reduces the problem of toxicity, which is characteristic of the liquid acetone-based nail polish remover formulations, without adversely effecting the relative ease of application of the composition to the nail surface.
  • composition of this invention contains, as the essential ingredients, a solvent, e.g., acetone, a thickener, e.g., hydroxypropyl cellulose and a nail conditioning ingredient, e.g., certain tallow polyamines to be further described hereinafter in detail.
  • a solvent e.g., acetone
  • a thickener e.g., hydroxypropyl cellulose
  • a nail conditioning ingredient e.g., certain tallow polyamines to be further described hereinafter in detail.
  • the present composition may contain ethyl alcohol, a wax as well as fragrance and colorant (e.g., dye or pigment), if desired.
  • acetone is the solvent of choice in the practice of this invention
  • other solvents or mixed solvents may be used. These include, for example, mixtures of methylene with ethyl alcohol; 1,1,1- trichloroethane with ethyl alcohol; methyl alcohol with acetone; acetone with isopropanol; and butanol- ethyl alcohol-acetone mixture.
  • Acetone alone is generally preferred because of its low toxicity and because its odor is generally acceptable to most people.
  • the amount of acetone, or its equivalent solvent, in the novel compositions of the present invention may vary from about 30 to about 99 parts by weight, preferably from about 75 to about 94 parts by weight based on 100 parts by weight of the total composition.
  • all parts by weight are based on total weight of the composition unless otherwise specified.
  • a lower alkanol such as ethyl alcohol
  • ethyl alcohol in the nail polish remover-nail conditioner composition of this invention serves to increase the solubility of the hydroxypropyl cellulose in the composition.
  • ethyl alcohol in the composition inhibits the solubilizing action of acetone on the nail.
  • the amount of alkanol in the composition may vary from 0 to about 55 parts by weight, preferably from about 3 to about 10 parts by weight.
  • hydroxypropyl cellulose serves to repress evaporation of the acetone or the solvent and increases the viscosity of the resulting mixture.
  • Nail polish remover-nail conditioner compositions with increased viscosity exhibit improved adhesion to the nail while effectively dissolving the oily and greasy substances on the nail surface.
  • the preferred hydroxypropyl cellulose exhibits a viscosity of from about 6000 to about 10,000 cps when used as 2% aqueous solution at 20 C. It is available in powder form and is used whenever it is desired to impart high viscosity and uniformity to the resulting ge.. Lower viscosity types of hydroxypropyl cellulose are also available and may be used, but they are not as effective in imparting high viscosity or uniformity to the resulting gel. If desired, a mixture of the
  • hydroxypropyl cellulose In general, and depending on the specific hydroxypropyl cellulose which is used, its amount can vary from about 1 to about 10 parts by weight, preferably from about 2 to about 5 parts by weight. If the concentration of hydroxypropyl cellulose is too small; e.g., below about 1 part by weight, the viscosity of the resulting liquid composition will be too low. Consequently, the liquid composition will run off more quickly from the nail surface and acetone will evaporate more readily. On the other hand, if this concentration is too high; e.g., more than about 10 parts by weight, the resulting composition will be too viscous and thus difficult to apply, with less effective solubilizing action on the oil and grease on the nail surface.
  • thickeners which can be used in the practice of this invention include ethyl hydroxyethyl cellulose, hydroxypropyl methyl cellulose and the amine salts of polyacrylic acid graft polymer (e.g., Carbopol made by B.F. Goodrich Company) with a tallow amine. These thickeners may be used in lieu of, or preferably in admixture with, hydroxypropyl cellulose.
  • polyacrylic acid graft polymer e.g., Carbopol made by B.F. Goodrich Company
  • composition of this invention may include a wax, such as, paraffin wax, carnauba wax, shoe wax, beeswax, whale wax,
  • SHEET montain wax hydrogenated castor oil, polyethylene wax, and the like.
  • paraffin wax is preferred due to its ready availability and relative low cost.
  • the amount of wax in the composition may vary from about 0.1 to about 5 parts by weight, preferably from about 0.1 to about 3 parts by weight.
  • the wax used in the composition of this invention forms a film with the hydroxypropyl cellulose and thus serves to repress evaporation of the acetone solvent.
  • the composition of this invention include a nail conditioning ingredient, such as, for example, a tallow polyamine in order to exhibit the desired nail conditioning property.
  • a nail conditioning ingredient such as, for example, a tallow polyamine
  • the application of the composition for removal of the nail polish causes the nail to be discolored (turn white) from acetone.
  • an oily conditioner remains on the nail after the acetone has evaporated and hence the nail surface will be protected from discoloration or bleaching.
  • Suitable tallow polyamines which are effective as nail conditioning ingredients in the compositions of this invention are polyoxyethylene tallow amine and polyoxyethylene diamine having oxyethylene degree of polymerization of from about 5 to about 30, preferably from about 10 to about 20.
  • polyoxyethylene (POE)-15 tallow amine available from Protamein Chemicals, U.S.A. constitutes one of the
  • the numeral 15 indicates the degree of polymerization of the oxyethylene units. If the degree of polymerization of the oxyethylene units is too low, for example, it is 2 or 3, the resulting nail polish remover-conditioner composition will be too oily. On the other hand, if the degree of polymerization of the oxyethylene is too high, for example, it exceeds about 30, the resulting gel will be too viscous and hence more difficult to apply to the nail and is less effective.
  • POE tallow amines are nonionic surfactants exhibiting pseudoacationic characteristics with the ability of removing adhesive soil and imparting softness, smoothness and brightness to the nail surface. They are effective emulsifying agents as well as nail conditioners.
  • R is an alkyl group containing 1 to 4 carbon atoms and x + Y is an integer having a value of from about 5 to about 30, preferably from about 10 to about 20.
  • alkylamines which are readily available include palmamine, soybean amine, tallow amine and steric amine.
  • Another nail conditioning ingredient which can be used is polyoxyethylene polyamine which can be represented by the following general formula:
  • R is an alkyl group having 1 to 4 carbon atoms and x + y + z is an integer having a value of from about 5 to about 30, preferably from about 10 to about 30.
  • the amount of tallow polyamine, or other nail conditioning ingredients hereinbefore described may vary from about 1.5 to about 10 parts by weight, preferably from about 1 to about 5 parts by weight. The amount used must, in general, be sufficient to
  • SHEET 1 0.. prevent the nail surface from turning white without deceaseing the effectiveness of the nail polish remover.
  • Non-uniform gels show a mass of gel floating in a liquid, or uneveness (concave or convex) on the gel surface. Such gel mass changes in viscosity after a period of time and is therefore considered to be unstable.
  • T.T ⁇ T SHEET 12 amount of the oil conditioning ingredient is included in the composition (Sample B). When this quantity is increased to 8 parts by weight (Sample C) , no white residue or discoloration was observed on the nail. Moreover, the increased amount of the oil conditioning ingredient resulted in increased gel viscosity and inproved gel uniformity.
  • Paraffin wax 0 0.2 0 0
  • the polyacrylic graft copolymer was Carbopol available from B.F. Goodrich Company
  • Sample C was more adherent than samples A or B indicating that the polyacrylic graft copolymer reacts with tallow polyamine to form an amine salt, an adhesive, preventing the stripping function.
  • composition of this invention In forming the composition of this invention, and in order to obtain gel uniformity, it is preferable to add the various ingredients to acetone while the entire mixture is mixed by a high speed mixer. During the addition of hydroxypropyl cellulose powder to acetone, it is recommended that the temperature be kept as low as possible in order to prevent a sudden increase in viscosity of the mixture. Otherwise, the powder becomes entrapped in the gel and prevents the formation of a uniform mass of gel even by prolonged agitation.
  • tallow polyamine as the preferred nail conditioning ingredent
  • other oils may be used in lieu of, or in admixture with the tallow polyamine provided that such oils, when used in the proper concentrations, exhibit mutual solubility in the solvent (e.g., acetone) and the thickener (e.g., hydroxypropyl cellulose).
  • a small quantity of a mineral oil such as paraffin oil may be included in the composition.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

Une composition combinée de conditionnement des ongles et de dissolvant du vernis à ongles comprenant de l'acétone, de la cellulose d'hydroxypropyle et une polyamine de suif, p.ex. une amine de suif de polyoxyéthylène ou une diamine de suif de polyoxyéthylène confère des propriétés de conditionnement des ongles au dissolvant pour vernis à ongles. Eventuellement la composition peut comprendre un alcanol inférieur, une cire, du parfum et un colorant. La composition permet non seulement d'enlever le vernis à ongles mais sert également à protéger la surface des ongles contre la décoloration ou le blanchiment après avoir enlevé le dissolvant et forme un revêtement protecteur doux sur la surface des ongles.
PCT/US1987/000269 1986-02-13 1987-02-10 Composition de conditionnement des ongles a base de dissolvant WO1987004921A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US82953886A 1986-02-13 1986-02-13
US829,538 1986-02-13
US84546286A 1986-03-28 1986-03-28
US845,462 1986-03-28

Publications (1)

Publication Number Publication Date
WO1987004921A1 true WO1987004921A1 (fr) 1987-08-27

Family

ID=27125279

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1987/000269 WO1987004921A1 (fr) 1986-02-13 1987-02-10 Composition de conditionnement des ongles a base de dissolvant

Country Status (2)

Country Link
EP (1) EP0263128A1 (fr)
WO (1) WO1987004921A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5543085A (en) * 1995-03-24 1996-08-06 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Thickened nail polish remover
FR2868947A1 (fr) * 2004-04-20 2005-10-21 Durlin France Sa Dissolvant gel sans acetone
WO2015135021A1 (fr) * 2014-03-14 2015-09-17 Rochelle Rosemarie Mercado Dissolvant pour vernis à ongles

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3441645A (en) * 1964-05-28 1969-04-29 Robert W Mckissick Composition for treating nails
US4197212A (en) * 1973-07-03 1980-04-08 Anheuser-Busch, Incorporated Gelled nail polish remover and process of making the same
US4444933A (en) * 1982-12-02 1984-04-24 Borden, Inc. Adhesive cyanoacrylate compositions with reduced adhesion to skin

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3441645A (en) * 1964-05-28 1969-04-29 Robert W Mckissick Composition for treating nails
US4197212A (en) * 1973-07-03 1980-04-08 Anheuser-Busch, Incorporated Gelled nail polish remover and process of making the same
US4444933A (en) * 1982-12-02 1984-04-24 Borden, Inc. Adhesive cyanoacrylate compositions with reduced adhesion to skin

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5543085A (en) * 1995-03-24 1996-08-06 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Thickened nail polish remover
FR2868947A1 (fr) * 2004-04-20 2005-10-21 Durlin France Sa Dissolvant gel sans acetone
EP1591101A1 (fr) * 2004-04-20 2005-11-02 Durlin France Dissolvant gel sans acetone
WO2015135021A1 (fr) * 2014-03-14 2015-09-17 Rochelle Rosemarie Mercado Dissolvant pour vernis à ongles

Also Published As

Publication number Publication date
EP0263128A1 (fr) 1988-04-13

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