WO1985000181A1 - Improvements in and relating to combustion - Google Patents

Improvements in and relating to combustion Download PDF

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Publication number
WO1985000181A1
WO1985000181A1 PCT/GB1984/000222 GB8400222W WO8500181A1 WO 1985000181 A1 WO1985000181 A1 WO 1985000181A1 GB 8400222 W GB8400222 W GB 8400222W WO 8500181 A1 WO8500181 A1 WO 8500181A1
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WO
WIPO (PCT)
Prior art keywords
combustion
iron oxide
combustion process
boiler
scale
Prior art date
Application number
PCT/GB1984/000222
Other languages
French (fr)
Inventor
Leonard Rhys Hardy
Richard Geoffrey Ayre
Original Assignee
Leonard Rhys Hardy
Richard Geoffrey Ayre
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Leonard Rhys Hardy, Richard Geoffrey Ayre filed Critical Leonard Rhys Hardy
Publication of WO1985000181A1 publication Critical patent/WO1985000181A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation

Definitions

  • the present invention relates to the reduction of undesirable combustion by-products in boilers, incinerators and similar plant.
  • organic compounds containing metals such as lead, cobalt, manganese, copper, nickel and chromium chromium can under certain conditions function as soot destroyers or combustion aids and it has been proposed to add these metals to fuels to provide for more complete combustion of the fuel to CO 2 and H 2 O.
  • soot destroyers or combustion aids it has been proposed to add these metals to fuels to provide for more complete combustion of the fuel to CO 2 and H 2 O.
  • the relatively large amounts of these metals which must be added to the fuel to give a significant improvement causes the fuel to become so unstable that the catalytic properties of these metals cannot be used. This effect can be offset by adding stabilisers or antioxidents to the fuel but again, large amounts are required which renders this economically impractical and gives rise to further disadvantageous secondry effects.
  • the present invention provides a combustion process comprising passing combustion air over an ignited fossil fuel in a combustion chamber and prior to or during combustion introducing into the combustion chamber finely divided iron oxide which acts during combustion to reduce the amount of solid combustion byproducts deposited in flue passes and chimneys of the combustion chamber during the combustion process.
  • the substance is introduced during the combustion process, although it may also be introduced prior to combustion in the fueld.
  • a preferred substance is sesquioxide of iron (Fe 2 O 3 ).
  • the present invention stems from the unexpected discovery that the addition into the combustion zone of finely divided iron oxide particles alone or mixed with an inert material in small quantities significantly reduces the formation and deposition of scale, smut and other solid combustion by-products and also acts to reduce existing scale. This results in the maintenance of heat transfer rates for very much longer periods and improved plant performance than in the absence of the substance with consequent saving in fuel consumption and maintenance costs.
  • Finely divided iron is introduced into the combustion chamber in any suitable manner, conveniently in the form of ferric oxide (Fe 2 O 3 ) or in some other form which converts to ferric oxide under the conditions in the combustion chamber.
  • the substance is preferably blown into or over the combustion zone repeatedly over short periods of time at intervals as desired, as a fine powder during combustion either in the combustion air or separately.
  • the quantity of ferric oxide required to achieve the desired effect is very small, depending on the quality and type of the fuel.
  • the substance may alternatively or additionally be added to the fuel itself and although the substance is described as being added during combustion it will be appreciated that quantities can be added prior to combustion.
  • the substance may also be added continuously if desired and can be in the form of a powder, a suspension in a substantially inactive or combustible liquid, or in the form of small pellets.
  • the dosage rate of the substance is a minimum of 0.1134 Kg (0.25 lbs) to 0.4536 Kg (1 lb) per tonne of coal consumed, or the therm equivalent of oil, gas and other fossil fuels, a preferred range being 0.1134Kg to 0-4536 0.4536 Kg (11b).
  • the quantities of substance injected into the combustion chamber can be more easily controlled by first mixing the substance intimately with a neutral powder. This also aids dispersion of the substance throughout the chamber.
  • a diluent powder composed, for example, of bentonite, synthetically organically modified bentonite, dolomite or calcined dolomite or other finely divided diluent powder which is inactive i.e. does not adversely affect the process of the present invention may be used.
  • Smut content is also reduced in the boiler flue deposits resulting in a generally free-flowing powder which is easily removed and contains fewer oil and other carbon compounds. Acid smut emission due to entrainment of smut in the flue gases is considerably reduced. The overall effect, therefore, is a cleaner combustion chamber, flue passes and chimneys resulting in the maintenance of the boiler at higher efficiency and performance for long periods with consequently lowered fuel costs, a significant reduction in the cost of maintenance and cleaning and reduction in smut emission due to entrainment.
  • oxide means one or more of the following: a suboxide, oxide of known valency, super-oxide, peroxide, hydroxide, hydrated oxide or carbonate.
  • a mixture of iron oxide (Fe 2 O 3 ) as 30% by weight in an inactive finely divided naturally occurring clay powder was injected into the combustion chamber of a Colifax Hot Water boiler in the proportion of 0.227 Kg (0.5 lbs) weight of the mixture to each tonne of coal consumed.
  • the powder was injected every 3 hours for the requisite period to achieve the above dose rate.
  • the boiler had not been cleaned prior to the use of the powder and contained adherent scale.
  • the boiler efficiency as measured by flue gas analysis and temperature method improved from 65% to 71% over a period of 6 days and was associated with the removal of substantially all the adherent scale.
  • the reduction in the carbonacous content of the boiler flue passes was some 50% as measured in before and after conditions.
  • Example 1 A mixture of iron oxide (Fe 2 O 3 ) as 25% by weight in an inactive powder was injected as for Example 1 into the combustion chambers of three Centrax coal-fired boilers over a period of 6 months. The boilers became free from adherent scale within the first 3 to 4 weeks and the flue
  • Example 4 A 40% mixture of iron oxide (Fe 2 O 3 ) mixed with a neutral clay based powder was injected into the combustion chamber of a Thermax oil fired (3500 sees.) boiler at the rate of 0.1134 Kg (0.25 lbs.) per 300 galls. of oil consumed. Although new, prior to the injection of the iron oxide mix the boiler was subject to heavy deposition of hard scale on the flue side of the boiler tubes which was difficult to remove and meant that the boiler had to be shut down monthly for cleaning.
  • Thermax oil fired 3500 sees.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Air-Conditioning For Vehicles (AREA)
  • Glass Compositions (AREA)
  • Combustion Of Fluid Fuel (AREA)
  • Incineration Of Waste (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)
  • Rear-View Mirror Devices That Are Mounted On The Exterior Of The Vehicle (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

During operation of a fossil fuel boiler the combustion process results in the deposition in the boiler flues and heat transfer pipes of scale, smut and soot and other solid products which have a serious effect on boiler efficiency. Regular cleaning therefore has to be undertaken in order to maintain a reasonable standard of boiler efficiency and this is both expensive and time consuming. The present invention introduces controlled amounts of ferric oxide (Fe2 O3) the effect of which is to inhibit the deposition of further solid combustion products such as scale, soot and smut and also to alter the character of existing scale, reducing its adhesion and causing the scale to fall away. The effect is to improve boiler efficiency and reduce maintenance costs.

Description

Title: Improvements in and relating to combustion
The present invention relates to the reduction of undesirable combustion by-products in boilers, incinerators and similar plant.
A major problem associated with the combustion of fossil fuels in, for example,boilers is the considerable amount of adherent scale, soot and smut deposits which build up in the boiler combustion chambers, flue systems and chimneys. The effect of these deposits in the boiler tubes is to reduce boiler heat transfer rates dramatically, resulting in considerable increases in fuel consumption. Regular cleaning by vigorous mechanical means to remove these deposits is therefore necessary to maintain a reasonable level of boiler efficiency, which causes damage to the tubes and is both time consuming and expensive. Also, this often requires the use of a "back-up" boiler while the main boiler is shut down for cleaning. Additionally, smut deposits within the flue passes become entrained in the flue gases during load fluctuations causing smut emission and deposition in the immediate locality.
The above-mentioned problems are well known in the art and many attempts have been made to overcome them. For example, organic compounds containing metals such as lead, cobalt, manganese, copper, nickel and chromium chromium can under certain conditions function as soot destroyers or combustion aids and it has been proposed to add these metals to fuels to provide for more complete combustion of the fuel to CO2 and H2O. However, the relatively large amounts of these metals which must be added to the fuel to give a significant improvement causes the fuel to become so unstable that the catalytic properties of these metals cannot be used. This effect can be offset by adding stabilisers or antioxidents to the fuel but again, large amounts are required which renders this economically impractical and gives rise to further disadvantageous secondry effects.
It has also been proposed to add lead or cobalt soaps to fuel to reduce soot but again considerable problems are caused by the resulting unwanted byproducts.
It has also been suggested that a mixture of compounds of manganese or copper and lead, cobalt, nickel, zinc, chromium, antimony, tin or vanadium in specified proportions can prove effective in improving the burning properties of fuel without serious side effects and that the improvement is not obtained when using a compound of only one of the metals. Accordingly the present invention provides a combustion process comprising passing combustion air over an ignited fossil fuel in a combustion chamber and prior to or during combustion introducing into the combustion chamber finely divided iron oxide which acts during combustion to reduce the amount of solid combustion byproducts deposited in flue passes and chimneys of the combustion chamber during the combustion process.
Preferably the substance is introduced during the combustion process, although it may also be introduced prior to combustion in the fueld.
A preferred substance is sesquioxide of iron (Fe2 O3).
The present invention stems from the unexpected discovery that the addition into the combustion zone of finely divided iron oxide particles alone or mixed with an inert material in small quantities significantly reduces the formation and deposition of scale, smut and other solid combustion by-products and also acts to reduce existing scale. This results in the maintenance of heat transfer rates for very much longer periods and improved plant performance than in the absence of the substance with consequent saving in fuel consumption and maintenance costs. Finely divided iron is introduced into the combustion chamber in any suitable manner, conveniently in the form of ferric oxide (Fe2 O3) or in some other form which converts to ferric oxide under the conditions in the combustion chamber. The substance is preferably blown into or over the combustion zone repeatedly over short periods of time at intervals as desired, as a fine powder during combustion either in the combustion air or separately. The quantity of ferric oxide required to achieve the desired effect is very small, depending on the quality and type of the fuel. The substance may alternatively or additionally be added to the fuel itself and although the substance is described as being added during combustion it will be appreciated that quantities can be added prior to combustion. The substance may also be added continuously if desired and can be in the form of a powder, a suspension in a substantially inactive or combustible liquid, or in the form of small pellets.
The dosage rate of the substance is a minimum of 0.1134 Kg (0.25 lbs) to 0.4536 Kg (1 lb) per tonne of coal consumed, or the therm equivalent of oil, gas and other fossil fuels, a preferred range being 0.1134Kg to 0-4536 0.4536 Kg (11b).
The quantities of substance injected into the combustion chamber, because they are so small, can be more easily controlled by first mixing the substance intimately with a neutral powder. This also aids dispersion of the substance throughout the chamber. A diluent powder composed, for example, of bentonite, synthetically organically modified bentonite, dolomite or calcined dolomite or other finely divided diluent powder which is inactive i.e. does not adversely affect the process of the present invention may be used.
In the combustion chamber itself, during combustion the ferric oxide causes an alteration in the character of existing scale deposits within the chamber, flue passes and chimney, the deposits becoming friable and easily removed. The property of the scale which causes it to adhere strongly to the boiler heat transfer surfaces, ducts and chimneys is reduced as a result of which the scale becomes detached from these areas and falls away, allowing for a greater rate of heat transfer and therefore increased boiler efficienty and performance. In addition, since this avoids the need for abrasive cleaning methods the life of the boiler tubes is improved. Further scale formation is reduced and the soot and carbonaceous content of deposits in the tubes and flues is reduced enabling easier removal. Smut content is also reduced in the boiler flue deposits resulting in a generally free-flowing powder which is easily removed and contains fewer oil and other carbon compounds. Acid smut emission due to entrainment of smut in the flue gases is considerably reduced. The overall effect, therefore, is a cleaner combustion chamber, flue passes and chimneys resulting in the maintenance of the boiler at higher efficiency and performance for long periods with consequently lowered fuel costs, a significant reduction in the cost of maintenance and cleaning and reduction in smut emission due to entrainment.
The term "oxide" as used herein means one or more of the following: a suboxide, oxide of known valency, super-oxide, peroxide, hydroxide, hydrated oxide or carbonate.
The following examples are typical of the results achieved by the process of the present invention in some 30 installations involving Thompson, Cochran, Danks,
Hartley & Sugden, Centrax, Robey, Vekos and Trianco boilers of various capacities for industrial and domestic use.
Example 1
A mixture of iron oxide (Fe2 O3) as 30% by weight in an inactive finely divided naturally occurring clay powder was injected into the combustion chamber of a Colifax Hot Water boiler in the proportion of 0.227 Kg (0.5 lbs) weight of the mixture to each tonne of coal consumed. The powder was injected every 3 hours for the requisite period to achieve the above dose rate. The boiler had not been cleaned prior to the use of the powder and contained adherent scale.
The boiler efficiency as measured by flue gas analysis and temperature method improved from 65% to 71% over a period of 6 days and was associated with the removal of substantially all the adherent scale.
The reduction in the carbonacous content of the boiler flue passes was some 50% as measured in before and after conditions.
Example 2
A mixture of iron oxide (Fe2O3) as 25% by weight in an inactive powder was injected as for Example 1 into the combustion chambers of three Centrax coal-fired boilers over a period of 6 months. The boilers became free from adherent scale within the first 3 to 4 weeks and the flue
deposits become substantially free from soot and greasy smut which made them extremely free flowing and easily removed.
Heavy falls of hard sooty scale occurred in the breach ducts and stack which, once removed, left the passes in an almost new condition.
Fuel savings of 11% overall were recorded after allowing for seasonal differences in ambient conditions. Example 3
A 1 00% mixture of iron oxide (Fe2 O3 ) was used by injection or added to the coal in a number of smaller coal-fired domestic boilers over a period of some 6 months. All boilers , although initially heavily contaminated with scale and soot deposits soon became substantially free of depos its with very little cleaning being necessary ( and then only with a brush) once the main detached scale debris was removed.
Example 4 A 40% mixture of iron oxide (Fe2 O3) mixed with a neutral clay based powder was injected into the combustion chamber of a Thermax oil fired (3500 sees.) boiler at the rate of 0.1134 Kg (0.25 lbs.) per 300 galls. of oil consumed. Although new, prior to the injection of the iron oxide mix the boiler was subject to heavy deposition of hard scale on the flue side of the boiler tubes which was difficult to remove and meant that the boiler had to be shut down monthly for cleaning.
The injection of the iron oxide mixture removed the hard scale and prevented further formations. As a result the boiler was operated for a period of 4 months without any deterioration in performance or shut down for cleaning being necessary. An accurate evaluation of the fuel savings achieved by the use of iron oxide (Fe2 O3) is difficult to establish because of the many variables involved and the well known difficulties encountered in monitoring boiler performance accurately even with the most sophisticated instrumentation. It will be appreciated, however, that it is self evident that a boiler which is free from adherent scale, soot and smutty products will give a substantially better performance than one which is not free of such deposits and the boiler condition will be obvious on inspection and sophisticated instrumentation would not be required to establish this.

Claims

CLAIMS :
1. A combustion process comprising passing combustion air over an ignited fossil fuel in a combustion chamber and prior to or during combustion introducing into the combustion chamber finely divided iron oxide which acts during combustion to reduce the amount of solid combustion by-products deposited in flue passes and chimneys of the combustion chamber during the combustion process.
2. A combustion process as claimed in claim 1 wherein said iron oxide is ferric oxide (Fe2 O3).
3. A combustion process as claimed in claim 1 or 2 wherein said iron oxide is introduced during the combustion process.
4. A combustion process as claimed in any of claims 1 to
3 wherein said iron oxide is introduced into the combustion chamber as a powder.
5. A combustion process as claimed in any of claims 1 to
4 wherein prior to the introduction of said iron oxide into the combustion chamber the iron oxide is mixed substantially uniformly with a substantially inert material.
6. A combustion process as claimed in claim 5 wherein said iron oxide is a finely divided powder and is uniformly mixed with a diluent powder selected from at least one of the following: bentonite, synthetically organically modified bentonite, dolomite, calcined dolomite.
7. A combustion process as claimed in any of claims 1 to
6 wherein said iron oxide is mixed with a combustible liquid to inhibit coagulation.
8. A combustion process as claimed in any of claims 1 to
7 wherein said iron oxide is introduced into the combustion chamber over the fuel combustion area.
9. A combustion process as claimed in any of claims 1 to
8 wherein said iron oxide is introduced into the combustion chamber for a preselected time period at preset intervals of time.
10. A combustion process as claimed in claim 1 and substantially as hereinbefore described.
PCT/GB1984/000222 1983-06-22 1984-06-22 Improvements in and relating to combustion WO1985000181A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB838316937A GB8316937D0 (en) 1983-06-22 1983-06-22 Combustion processes
GB8316937 1983-06-22

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WO1985000181A1 true WO1985000181A1 (en) 1985-01-17

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EP (1) EP0130065B1 (en)
JP (1) JPS60501669A (en)
AT (1) ATE38852T1 (en)
AU (1) AU3741785A (en)
DE (1) DE3475320D1 (en)
GB (2) GB8316937D0 (en)
WO (1) WO1985000181A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0986034A2 (en) * 1998-09-09 2000-03-15 Honda Giken Kogyo Kabushiki Kaisha Battrey charging apparatus and battery returning apparatus

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3432365A1 (en) * 1984-09-03 1986-03-13 Deutsche Bp Ag, 2000 Hamburg COAL-BASED FUEL
JPS6348392A (en) * 1986-08-15 1988-03-01 Toa Netsuken Kk Method of controlling clinker ash of coal exhaust gas dust
CN101955818B (en) * 2010-10-15 2013-01-02 鞠立梅 Coke-removing and soot-cleaning combustion improver for boiler

Citations (4)

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Publication number Priority date Publication date Assignee Title
GB1335462A (en) * 1972-01-12 1973-10-31 Vp Chemicals Ltd Method of cleaning and or maintaining the cleanliness of heating surfaces in a fuel-fired heating appliance
DE2361091A1 (en) * 1973-08-28 1975-03-27 Geb Baykam Mueyesser Goerguen Additives for producing smokeless coal-dust briquettes - comprising iron cpds., plastics, or minerals and asphalt
US4191115A (en) * 1978-06-23 1980-03-04 The United States Of America As Represented By The United States Department Of Energy Carbonaceous fuel combustion with improved desulfurization
FR2510237A1 (en) * 1981-07-22 1983-01-28 Steinmueller Gmbh L & C PROCESS FOR INCORPORATING AN ADDITIVE TO A REACTION GAS CURRENT

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GB490064A (en) * 1936-02-18 1938-08-09 Jean Benjamin Toustou Process for improving solid carbonaceous fuels
GB469241A (en) * 1936-04-29 1937-07-21 Katalik Ltd Catalytic composition for improving the combustion of solid fuels
CH281765A (en) * 1950-03-28 1952-03-31 Tech Studien Ag Process for reducing damage to heat-resistant metal parts at high temperatures by combustion products.
GB743472A (en) * 1951-03-01 1956-01-18 Power Jets Res & Dev Ltd Improvements in or relating to fuel oils and the combustion of fuel oils
GB858942A (en) * 1957-02-04 1961-01-18 Nat Cylinder Gas Co Method of inhibiting slag formation in boilers and inhibitor materials for use therein
GB858096A (en) * 1957-09-27 1961-01-04 Amber Chemical Company Ltd Improvements relating to the reduction of the corrosive attack of gases of combustion on metal
GB1189356A (en) * 1967-07-13 1970-04-22 Apollo Chem Improvements in or relating to Fuel Compositions
GB1164856A (en) * 1967-09-19 1969-09-24 Apollo Chem Improvements in or relating to Fuel Compositions
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GB1435090A (en) * 1972-11-09 1976-05-12 Gen Electric Briquettes for coal gasification

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1335462A (en) * 1972-01-12 1973-10-31 Vp Chemicals Ltd Method of cleaning and or maintaining the cleanliness of heating surfaces in a fuel-fired heating appliance
DE2361091A1 (en) * 1973-08-28 1975-03-27 Geb Baykam Mueyesser Goerguen Additives for producing smokeless coal-dust briquettes - comprising iron cpds., plastics, or minerals and asphalt
US4191115A (en) * 1978-06-23 1980-03-04 The United States Of America As Represented By The United States Department Of Energy Carbonaceous fuel combustion with improved desulfurization
FR2510237A1 (en) * 1981-07-22 1983-01-28 Steinmueller Gmbh L & C PROCESS FOR INCORPORATING AN ADDITIVE TO A REACTION GAS CURRENT

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0986034A2 (en) * 1998-09-09 2000-03-15 Honda Giken Kogyo Kabushiki Kaisha Battrey charging apparatus and battery returning apparatus
EP0986034B1 (en) * 1998-09-09 2005-10-12 Honda Giken Kogyo Kabushiki Kaisha Battery charging apparatus and battery returning apparatus

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Publication number Publication date
GB8416184D0 (en) 1984-08-01
GB2142342B (en) 1988-01-27
AU3741785A (en) 1985-01-25
EP0130065B1 (en) 1988-11-23
GB8316937D0 (en) 1983-07-27
GB2142342A (en) 1985-01-16
JPS60501669A (en) 1985-10-03
DE3475320D1 (en) 1988-12-29
ATE38852T1 (en) 1988-12-15
EP0130065A1 (en) 1985-01-02

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