WO1980002143A1 - Process for preparing gel-like composition of acetylene high polymer,and process for fabrication thereof - Google Patents
Process for preparing gel-like composition of acetylene high polymer,and process for fabrication thereof Download PDFInfo
- Publication number
- WO1980002143A1 WO1980002143A1 PCT/JP1980/000053 JP8000053W WO8002143A1 WO 1980002143 A1 WO1980002143 A1 WO 1980002143A1 JP 8000053 W JP8000053 W JP 8000053W WO 8002143 A1 WO8002143 A1 WO 8002143A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acetylene
- high polymer
- gel
- polymerization
- solvent
- Prior art date
Links
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 title claims abstract description 207
- 229920000642 polymer Polymers 0.000 title claims abstract description 121
- 238000000034 method Methods 0.000 title claims abstract description 67
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 title claims abstract description 14
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 title claims abstract 25
- 230000008569 process Effects 0.000 title abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 33
- 238000000465 moulding Methods 0.000 claims abstract description 28
- 238000006116 polymerization reaction Methods 0.000 claims description 110
- 239000003054 catalyst Substances 0.000 claims description 92
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 84
- 239000002904 solvent Substances 0.000 claims description 48
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 42
- -1 vanadin Chemical compound 0.000 claims description 28
- 150000002736 metal compounds Chemical class 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 17
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 150000003623 transition metal compounds Chemical class 0.000 claims description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 238000007710 freezing Methods 0.000 claims description 10
- 230000008014 freezing Effects 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 9
- 229910052719 titanium Inorganic materials 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 229910052723 transition metal Inorganic materials 0.000 claims description 8
- 150000003624 transition metals Chemical group 0.000 claims description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 238000001465 metallisation Methods 0.000 claims description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 6
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 5
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 150000002902 organometallic compounds Chemical class 0.000 claims description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 5
- LKUDPHPHKOZXCD-UHFFFAOYSA-N 1,3,5-trimethoxybenzene Chemical compound COC1=CC(OC)=CC(OC)=C1 LKUDPHPHKOZXCD-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 230000007704 transition Effects 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 150000008282 halocarbons Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 3
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 claims description 2
- 229940100630 metacresol Drugs 0.000 claims description 2
- 239000013081 microcrystal Substances 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims 2
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 101150101561 TOM70 gene Proteins 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 125000006267 biphenyl group Chemical group 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 101150115693 ompA gene Proteins 0.000 claims 1
- 101150090944 otomp gene Proteins 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 239000011135 tin Substances 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 239000004065 semiconductor Substances 0.000 abstract description 21
- 125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 181
- 239000000499 gel Substances 0.000 description 64
- 239000000243 solution Substances 0.000 description 58
- 239000007789 gas Substances 0.000 description 50
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 30
- 229910001873 dinitrogen Inorganic materials 0.000 description 20
- 239000011521 glass Substances 0.000 description 17
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 16
- 238000003756 stirring Methods 0.000 description 14
- 238000007796 conventional method Methods 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- KKEBXNMGHUCPEZ-UHFFFAOYSA-N 4-phenyl-1-(2-sulfanylethyl)imidazolidin-2-one Chemical compound N1C(=O)N(CCS)CC1C1=CC=CC=C1 KKEBXNMGHUCPEZ-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 8
- 239000012456 homogeneous solution Substances 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 239000011630 iodine Substances 0.000 description 6
- 238000003672 processing method Methods 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 125000005843 halogen group Chemical group 0.000 description 5
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000004108 freeze drying Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 3
- YBGKQGSCGDNZIB-UHFFFAOYSA-N arsenic pentafluoride Chemical compound F[As](F)(F)(F)F YBGKQGSCGDNZIB-UHFFFAOYSA-N 0.000 description 3
- ILAHWRKJUDSMFH-UHFFFAOYSA-N boron tribromide Chemical compound BrB(Br)Br ILAHWRKJUDSMFH-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- OBCUTHMOOONNBS-UHFFFAOYSA-N phosphorus pentafluoride Chemical compound FP(F)(F)(F)F OBCUTHMOOONNBS-UHFFFAOYSA-N 0.000 description 3
- 210000004894 snout Anatomy 0.000 description 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 3
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
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- JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 2
- 150000007824 aliphatic compounds Chemical class 0.000 description 2
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- VBVBHWZYQGJZLR-UHFFFAOYSA-I antimony pentafluoride Chemical compound F[Sb](F)(F)(F)F VBVBHWZYQGJZLR-UHFFFAOYSA-I 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- CBEQRNSPHCCXSH-UHFFFAOYSA-N iodine monobromide Chemical compound IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 description 2
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- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 2
- AQRLNPVMDITEJU-UHFFFAOYSA-N triethylsilane Chemical compound CC[SiH](CC)CC AQRLNPVMDITEJU-UHFFFAOYSA-N 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 229910021630 Antimony pentafluoride Inorganic materials 0.000 description 1
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- LHUOGFMPTOSXSL-UHFFFAOYSA-N C(CCC)[Fe](CCCC)(CCCC)CCCC Chemical compound C(CCC)[Fe](CCCC)(CCCC)CCCC LHUOGFMPTOSXSL-UHFFFAOYSA-N 0.000 description 1
- RNEVEVNPPDRJTB-UHFFFAOYSA-N C[AlH]O[Al](C)C.Cl Chemical compound C[AlH]O[Al](C)C.Cl RNEVEVNPPDRJTB-UHFFFAOYSA-N 0.000 description 1
- ZKLPARSLTMPFCP-UHFFFAOYSA-N Cetirizine Chemical compound C1CN(CCOCC(=O)O)CCN1C(C=1C=CC(Cl)=CC=1)C1=CC=CC=C1 ZKLPARSLTMPFCP-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DSYAUIUTWNAGPN-UHFFFAOYSA-N F.F.S Chemical compound F.F.S DSYAUIUTWNAGPN-UHFFFAOYSA-N 0.000 description 1
- 240000009029 Gluta renghas Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010062717 Increased upper airway secretion Diseases 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical group OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 206010036790 Productive cough Diseases 0.000 description 1
- 241000124033 Salix Species 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- ADSXDBCZNVXTRD-UHFFFAOYSA-N [Mg]C1=CC=CC=C1 Chemical compound [Mg]C1=CC=CC=C1 ADSXDBCZNVXTRD-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical group CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- MXTOFRMIIQQSOE-UHFFFAOYSA-N butane;titanium(4+) Chemical compound [Ti+4].CCC[CH2-].CCC[CH2-].CCC[CH2-].CCC[CH2-] MXTOFRMIIQQSOE-UHFFFAOYSA-N 0.000 description 1
- VNQWVDUPMVNWEY-UHFFFAOYSA-M calcium;benzene;iodide Chemical compound [Ca+2].[I-].C1=CC=[C-]C=C1 VNQWVDUPMVNWEY-UHFFFAOYSA-M 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 229960001803 cetirizine Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KWTSZCJMWHGPOS-UHFFFAOYSA-M chloro(trimethyl)stannane Chemical compound C[Sn](C)(C)Cl KWTSZCJMWHGPOS-UHFFFAOYSA-M 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- CTHHBLWYPDKYFP-UHFFFAOYSA-N ctk3i9005 Chemical compound FS(=O)(=O)OOS(F)(=O)=O CTHHBLWYPDKYFP-UHFFFAOYSA-N 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- INVPQTFQRFNBFL-UHFFFAOYSA-N dibutyl(chloro)borane Chemical compound CCCCB(Cl)CCCC INVPQTFQRFNBFL-UHFFFAOYSA-N 0.000 description 1
- PKKGKUDPKRTKLJ-UHFFFAOYSA-L dichloro(dimethyl)stannane Chemical compound C[Sn](C)(Cl)Cl PKKGKUDPKRTKLJ-UHFFFAOYSA-L 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- YDRVUMXQCDEMDQ-UHFFFAOYSA-N diethyl(ethylalumanyloxy)alumane Chemical compound CC[AlH]O[Al](CC)CC YDRVUMXQCDEMDQ-UHFFFAOYSA-N 0.000 description 1
- GMNSEICSYCVTHZ-UHFFFAOYSA-N dimethylalumanyloxy(dimethyl)alumane Chemical compound C[Al](C)O[Al](C)C GMNSEICSYCVTHZ-UHFFFAOYSA-N 0.000 description 1
- AXAZMDOAUQTMOW-UHFFFAOYSA-N dimethylzinc Chemical compound C[Zn]C AXAZMDOAUQTMOW-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- QNDQILQPPKQROV-UHFFFAOYSA-N dizinc Chemical compound [Zn]=[Zn] QNDQILQPPKQROV-UHFFFAOYSA-N 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- XGZNHFPFJRZBBT-UHFFFAOYSA-N ethanol;titanium Chemical compound [Ti].CCO.CCO.CCO.CCO XGZNHFPFJRZBBT-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 1
- KTSWBLUMAWETAK-UHFFFAOYSA-N heptane octane Chemical compound CCCCCCC.CCCCCCCC.CCCCCCC KTSWBLUMAWETAK-UHFFFAOYSA-N 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
- RYEXTBOQKFUPOE-UHFFFAOYSA-M magnesium;propane;chloride Chemical compound [Mg+2].[Cl-].CC[CH2-] RYEXTBOQKFUPOE-UHFFFAOYSA-M 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- ZEIWWVGGEOHESL-UHFFFAOYSA-N methanol;titanium Chemical compound [Ti].OC.OC.OC.OC ZEIWWVGGEOHESL-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- KQJBQMSCFSJABN-UHFFFAOYSA-N octadecan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-] KQJBQMSCFSJABN-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- GGROONUBGIWGGS-UHFFFAOYSA-N oxygen(2-);zirconium(4+);hydrate Chemical compound O.[O-2].[O-2].[Zr+4] GGROONUBGIWGGS-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 208000026435 phlegm Diseases 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- UHZYTMXLRWXGPK-UHFFFAOYSA-N phosphorus pentachloride Chemical compound ClP(Cl)(Cl)(Cl)Cl UHZYTMXLRWXGPK-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 208000024794 sputum Diseases 0.000 description 1
- 210000003802 sputum Anatomy 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- RPBNQQGUJBCUGO-UHFFFAOYSA-N sulfanylidenechromium Chemical compound [S].[Cr] RPBNQQGUJBCUGO-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- RWWNQEOPUOCKGR-UHFFFAOYSA-N tetraethyltin Chemical compound CC[Sn](CC)(CC)CC RWWNQEOPUOCKGR-UHFFFAOYSA-N 0.000 description 1
- VXKWYPOMXBVZSJ-UHFFFAOYSA-N tetramethyltin Chemical compound C[Sn](C)(C)C VXKWYPOMXBVZSJ-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229940030010 trimethoxybenzene Drugs 0.000 description 1
- WXRGABKACDFXMG-UHFFFAOYSA-N trimethylborane Chemical compound CB(C)C WXRGABKACDFXMG-UHFFFAOYSA-N 0.000 description 1
- UKHQRARQNZOXRL-UHFFFAOYSA-N trimethyltin Chemical compound C[SnH](C)C UKHQRARQNZOXRL-UHFFFAOYSA-N 0.000 description 1
- NVSDADJBGGUCLP-UHFFFAOYSA-N trisulfur Chemical compound S=S=S NVSDADJBGGUCLP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/003—Thick film resistors
- H01C7/005—Polymer thick films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F38/00—Homopolymers and copolymers of compounds having one or more carbon-to-carbon triple bonds
- C08F38/02—Acetylene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/124—Intrinsically conductive polymers
- H01B1/125—Intrinsically conductive polymers comprising aliphatic main chains, e.g. polyactylenes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/141—Organic polymers or oligomers comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE
- H10K85/143—Polyacetylene; Derivatives thereof
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Definitions
- the present invention relates to a method for producing a high-polymerized acetylene "gel composition of a book”! Or a porous acetylene high polymer, and a molding method. ⁇ Useful as a semiconductor.
- Acetylene is polymerized using a so-called Ziegler's Natta catalyst, which is composed of a transition metal compound and an organic compound.
- Ziegler's Natta catalyst which is composed of a transition metal compound and an organic compound.
- the acetylene high polymer obtained in this way does not melt even when heated with a sword, and is easily degraded under heat, so it is molded by a molding method such as a normal thermoplastic resin. I can't.
- no solution for dissolving the acetylene high-weight support has yet been found, and therefore, those who produce practically molded acetylene high polymers; S is limited to the following two methods .
- _OMPI Polymerization is carried out on the surface coated with acetylene to form a film-like or fibrous acetylene polymer (Japanese Patent Publication No. 48-32581).
- the transition metal compound " ⁇ " be used in an amount of more than 0.1 mol per 1 of the polymerization solvent.
- a gel-like acetylene high polymer is also known to be obtained by polymerization using a special catalyst and hexane as a solvent.
- the present inventors have found that in the above method (a), it is possible to obtain a solid molded article having mechanical strength.
- the present invention provides (1) acetylene as (A) IVa, Ya,
- Transition metal compounds containing at least one transition metal from ⁇ and V group transition metals and at least one of the [!], II 6, £ ⁇ and IV ⁇ group metals of the (5) table of contents In the polymerization using a metal compound containing a kind of metal, such as metal compound, a polymerization solvent containing 0.01 to 0.1 molno is included in the metal compound.
- a forming sword characterized by producing a gel consisting of acetylene high-gravity ⁇ having a fibril structure and a polymerization solvent consisting of i9 and a polymerization solvent by performing polymerization in a gel.
- the present invention also provides (2) a sword having a fibril structure in which a gel-like snout of an acetylene high polymer having a fibril structure having a solvent having a freezing point of ⁇ 50 to 50 C is freeze-dried.
- the method of producing highly porous polyacetylene highly polymerized books is easy.
- the present invention provides (3) an acetylene high polymer having a fibril structure 5 to
- the gel sleeve obtained from (1) should be used as the gel sleeve formed from the high-polymerized 1 * -styrene having a fibril structure used in (2) and (3) of the present invention and the organic solvent. Needless to say, a gel other than the acetylene high polymer having a fibrinole structure and an organic solvent can be used except for (1).
- Uniform gel-like shape that can be achieved by Manpo (1) of the present invention.
- the shape can be made to have any shape and thickness by pressure molding as described in (3) above. It is extremely useful because the mechanical strength of the resulting molded article is extremely high.
- the homogeneous gel-like polymerization catalyst (1) of the present invention is different from the special catalyst used in (c) above; Since the catalyst can be used, the cost of the catalyst can be significantly reduced; Furthermore, in the method (1) of the invention, a uniform gel can be formed, and since a powdery rose-like substance is not formed, a molded article formed by pressure molding is uniform and its mechanical change is sufficiently large.
- the acetylene high-gravity porous material having a fibril structure which can be obtained by the method (2), can be of any desired bulk density depending on the polymerization conditions, and has excellent forming power.
- Method or calendar processing method it is possible to easily make ⁇ or shape _ which can be easily formed into an arbitrary shape and an arbitrary thickness.
- the porous acetylene high polymer is industrially very useful because it has a fibril structure and the resulting molded article has large mechanical changes.
- the gel-like material referred to in the present invention is a gel-like material which is in a state of being swelled with a solvent in which fibrils of acetylene high polymer are entangled with each other. Is essentially different. BEST MODE FOR CARRYING OUT THE INVENTION
- the transfer metal compound having at least one type of transition metal among the group IVa, Va, VIa, and VI transition metals used as the polymerization catalyst in the present invention is, specifically, titanium. emissions, vanadium, chromium, iron, cobalt, at the most a halogen atom or carbon atoms of the metal of the motor tungsten and motor Ribuden 2 0 ⁇ solid of completion alkyl group, an alkenyl group, Ariru (dr Z) group, Ryo aralkyl group A compound having a carboxylic acid residue, a phenoxide group, a carboxylic residue, a cyclopentagenenyl group, an acetylacetate residue, a carbon atom (carbonyl group), and a pyrididine; Complexes such as triphenylcarbine and dipyridyl are electron donating compounds.
- transition metal compounds compounds of titanium, vanadin, iron, chromium, and cobalt are preferable, and compounds of titanium are particularly preferable.
- transition formula metallization represented by the general formulas (I) to (! [] Can be used.
- transition metal compounds include, but are not limited to, tetramethoxytitanium, tetraethoxytitanium, tetraw-propoxytitanium, tetrabutylpropoxytitanium, tetraw-butoxytitanium, Tetrisobutoxytitanium, Tetraoctadecyloxytitanium, Tetrafuenoxytitanium, Trisacetyl acetate Totitanium squirrel Ryo cetyl Ryo Setona Toku Russia-time, door squirrel ⁇ cetirizine Norre acetate Tonato cobalt, titanium O carboxymethyl Ryo cetyl Ryose Tonato, is vanadium O carboxymethyl Ryo Sechiruase Tonato like there ⁇ 0
- the organometallic compound used in the present invention is a metal compound having at least one metal among the metals belonging to groups 11a, Ib, I ⁇ and IV of the periodic table.
- M is a metal belonging to the group I1A, fl, or IV with a period of ⁇ , or at most 20 alkyl groups or alkenyl having at most 20 carbon atoms.
- J which may be single or heterogeneous, at least one of which is a hydrogen atom or the valence group, and n is the highest valence number of the metal or less. Is a number)
- metal ties used in the present invention typical ones are magnesium, calcium, and sub! &, Boron, Aluminum, Carbide, Silicon and Tin Metallic Compounds + + Of course] 3, especially Magnesium, Zinc, Aluminum and Tin: Metallization is preferred, and Aluminum-based compounds are preferred.
- the existing compounds are: triethyl aluminum, tri-impregnated aluminum, tri-hexyl, aluminum, jetinole, norm, etc.
- the amount of anti-reaction between the aluminum and the water is lower than the ratio of the petroleum to the aluminum oxide and the triethyl aluminum and the water. The ratio is 1: 0.5 (molar ratio).
- Can be Other finished aluminum compounds include aluminum
- the killing formula used in the present invention as the organometallic compound is as follows.
- K z and ⁇ 3 may be j- or different, and are a halogen atom or an alkyl group or an alkoxy group having at most 10 carbon atoms.
- 5 is a halogen atom or an alkyl or alkoxy group having at most 10 carbon atoms or a general formula.
- One of the aluminum siloxane siloxes used in the present invention is trimethyldimethyl-siloxalene, tri Methynorethetinole-siloxalen, tri-methyltinol-n-propynole-siloxalen, trimethinole-diisobutyl-siloxalen, trimethyltinol-siloxalen, trichloride methylinol-siloxalen, dimethinoletinol -Siloxalene, trimethoxydimethinole-Siloxalen ⁇ Trietinoresimetinole-Siloxalene, Trimethinoresinethoxy-Siloxalen, Trimethyldimethoxy-Siloxalen and Trimethoxyd
- an organic metal compound is used.
- i 1 , R 2 and i may be single or different, Z element or an alkyl group having at most 10! Carbon atoms, and R 4 is often a halogen atom or carbon atom. (Although these are also 10 alkyl groups.)
- typical ones are getyl aluminum dimethyl imide, and getyl aluminum dimethyl imide. ⁇ , ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w w
- the kill formula of the dialxane compound used as a gold halide is represented by the following formula.
- dialumoxane compounds used in the present ⁇ a include tetramethyldialumoxane, tetramethyldilumoxane, rumolexan, tetraisobutinoresin-noremoxane, -dimethyl-3, 3 Jetyldilumoxane, tetraisobutyldilumoxane, 1,1-dimethyl-3,3-diimptyldialumoxane, tetradecyldialmoxane, trimethyldialumoxane chloride and triethyldialumoxane can give.
- t ⁇ of the organometallic compounds other than the organic aluminum compound and the tenth compound include getyl magnesium, chloridylethyl magnesium, hydridylmethylmagnesium chloride, and the like.
- a ⁇ l yl Magnesium: normal propyl magnesium chloride, tertiary-butylmagnesium lip, odor 1 phenyl magnesium, dipheninole
- examples of the compound used in the present invention include double salts of the above-mentioned organic compounds (for example, lithium aluminum tetrahydride and calcium tetraethyl).
- these organometallic compounds may be used alone or in combination of two or more.
- the ratio of the metal compound to the transition metal of the metal compound is in the range of 1 to 100% by mole, preferably 1 to 50, particularly preferably 1 to 2 5
- the transition metal compound and the metallization can be used in combination with the third component, if necessary, to control the polymer yield, polymerization rate, and the like.
- the third component includes an impurity compound such as alcohol, peroxide, and calcium.
- OMPI Bonn ⁇ anhydride, acid chloride, 'ester, ketone, etc. can be mentioned as examples.
- Other compounds containing nitrogen, compounds containing sulfur, compounds containing halogen, molecular iodine, etc. Lewis or the like can also be used.
- any organic solvent can be used as long as it is inert to the catalyst and is liquid for polymerization.
- the concentrated fatigue of the ⁇ -gold compound in the catalyst system depends on the catalyst used and the polymerization conditions. 0.001 to 0.1 mole, preferably 0.001 to 0.1 mole, more preferably 0.01 to 0.1 mole of car Eg with respect to 1 It is necessary to carry out the polymerization of the polymer. If the amount of the transition metal exceeds 0.1 mol per 1 ⁇ of the polymerization solution, it is difficult to process the resulting gel.
- the contact solution may be uniform or non-uniform, but from the viewpoint of easy removal of the catalyst, the contact solution and the solution are preferably uniform.
- the polymerization temperature is not particularly limited, but is usually preferably from 100 to 300 ° C, and from the viewpoint of easy handling, it is particularly preferably from 180 to 200 ° C.
- the degree of contact between the transition metal compound and the metal compound and the aging conditions of the catalyst system cannot be specified unconditionally because they are determined by the amount and weight of the catalyst component used. In the 0 ⁇ 100C car ⁇ range] ?, if necessary, it is possible to ripen the acetylene before starting, and the ⁇ is usually 1 20 ⁇ : L0C car ⁇ 3 ⁇ 41 It is.
- Transition metal compound ⁇ Of course, the sword for the direct dissolution of metallic compounds and acetylene gas ⁇ )
- the trace is not particularly limited, but for example,
- the polymerization can be performed in a state where the polymerization solution is kept still, or in a state where the polymerization solution is mechanically stirred.
- the polymerization temperature g the catalyst system: ⁇
- the catalyst system it is possible to control the steric structure of the high-molecular-weight polymer, it is generally possible to produce a flexible poly (ethylene glycol) polymer having a low cis content and a high cis-content when the polymerization temperature is low.
- a high content acetylene high polymer is produced.
- the pressure of the acetylene gas in the polymerization is not particularly limited, but practically, it is preferable to perform the pressure at 10 atm or less.
- the polymerization can be performed by a method of supplying acetylene gas to the surface of the polymerization solution, or by a method of directly introducing acetylene gas into the polymerization solution.
- a method for removing ⁇ ⁇ ⁇ ⁇ from the acetylene high polymerization I-gel obtained by the polymerization the usual removal method, for example, washing with a solvent that dissolves the catalyst i3 ⁇ 4 # is used, In particular, it can be used without removing the catalyst.
- the uniform gel of the acetylene-highly polymerized book thus obtained can be easily formed into a uniform molded article having a large mechanical strength having an arbitrary shape and a desired thickness by performing a sword pressure molding.
- the high-acetylene polymer thus obtained has a fibril structure.
- the acetylene high polymer having a fibrous structure having a fibrous structure referred to in the present invention is a crystalline form of disordered microcrystalline having a diameter of 200 to 60 OA. It is a high polymer, and it is a linear acetylene high polymer consisting of cis or trans conjugated double bonds. .
- the freezing point is 15 .
- ⁇ ⁇ * and a 1 volume: f are gelled in the form of “ ⁇ ”, those produced by any method can be used again.
- Specific examples of the production method include the method of the present invention.
- the acetylene high polymer may have any cis-transition ratio, and the solvent in the gel-like material may be any one. However, at least during freeze-drying, the freezing point must be from ⁇ close to the chamber.
- bearing medium refers to a carrier medium of * E having a freezing point of 1 to 50 ° C., preferably —31: to 20 ° C. Any solvent having a freezing point outside the above range can be used, but it is industrially disadvantageous because the equipment for freeze-drying is expensive.
- the amount of the above-mentioned solvent in the gel is from 1 to 100 parts by weight per 1 part by weight of the acetylene high polymer. It is difficult to obtain a high porous acetylene high polymer. Freeze-drying may be performed by a method commonly used in the art, for example, sublimation of the lysate frozen in a vacuum device *. The temperature for freezing and drying depends on the solvent used, but is usually in the range of 150 to 50 ° C.
- the acetylene high polymer in the ⁇ gel state can be arbitrarily adjusted by adjusting the polymerization conditions. ⁇ Since the bulk density of the porous acetylene high polymer can be adjusted ⁇ 0.1? No! ⁇ 0 0 0 0 1? It can be adjusted to the range of no.
- the porous acetylene high polymer obtained by the production method of the present invention may be used as it is, or may be molded! It may be used as a product.
- the gel of the present invention comprising 5 to 95% by weight of a heavy-weight acetylene body having a fibril structure and 95 to 5% by weight of inactive 'raw-dissolved' is subjected to pressure 1. Pressurizing at more than 0 ° C ⁇
- a special method of molding acetylene high polymer; the gel-like material used in the past consists of fibril resin, which is composed of acetylene high gravity ⁇ : As long as it is a gel, it can be made by any method! You can use it.
- a specific example is the Manpo method of the present invention, but is not necessarily limited to this.
- OMPI IPO Absent OMPI IPO Absent.
- the cis-trans of acetylene high-gravity ⁇ can use any 3 ⁇ 4.
- Solvents used in the present invention are particularly marketable, but typical solvents include aliphatic or aromatic hydrocarbons, halogenated hydrocarbons, ethers, carboxylic esters, and the like. ⁇ No 7J items, ketones, etc. can be opened.
- Typical examples are benzene, toluene, gicillen, etilbenzen methinolefeninole, ethinolef enoinole, terinolef enoinole, and tertiary dipheninole.
- a polar solvent such as an aliphatic or aromatic alcohol, carboxylic acid, etc. May be directly lysed.
- the amount of the acetylene resin used in the gel form used in the present invention is 5 to 95% by weight.o If the acetylene high direct bond in the gel form is less than 5 fold, the wall thickness is uniform. Is it difficult to manufacture molded products? If the weight of the acetylene in the gel is more than 95 M, it is difficult to form a molded article of any shape by pressure molding.
- ⁇ of the pressure-molded ⁇ is not more than 100 C, preferably not more than 80 C, and if it exceeds 100 t :, the acetylene high polymer becomes unsuitable due to deterioration of the acetylene high polymer. is there.
- Pressure molding at a low pressure is preferred because the acetylene-rich s coalescence tends to deteriorate, but molding at 150 ° C. or less is not practical.
- the pressure of the molding 'if is more than 1 ⁇ , preferably 5 Z c ⁇
- a molded article having a sufficiently large ⁇ ] ⁇ J strength ⁇ can be obtained.
- the residual-dissolved ⁇ can be used as it is in practical use-it is acceptable. It may be easily removed, but it may be removed by a method such as vacuum drying.
- a molded product having a high mechanical strength and a predetermined shape and thickness can be easily obtained.
- the electrical resistance of the molded article of the acetylene high polymer obtained in this manner is extremely low, and shows various characteristics peculiar to semiconductors.
- the air conductivity can be increased from 10 to 10 3 ⁇ - 1 'cm. - it can be freely controlled to Rukoto over a wide range of 1.
- electron-accepting compounds are iodine, iodine, bromine iodide, arsenic pentafluoride, antimony pentafluoride, silicon tetrafluoride, phosphorus pentafluoride, phosphorus pentafluoride, Lumichloride, Lumibromide, Peroxydisulfuryl difluoride, Sulfur ⁇ , Shixiao ⁇ , Full-sulfur ⁇ sulfur ⁇ , Triflusulfur-lumetansulfon, Black sulfur ⁇ , Boron trichloride, Trisulfur Boron bromide, zirconium trioxide, oxygen dioxide, etc. can be opened.
- Representative examples of the electron donating compound include sodium, potassium, and cesium.
- Toluene 200 which was ovalized according to the usual method as heavy and dissolved, was added to the glassy reaction of 1, which was completely straightened with nitrogen gas, and tetrabutyl iron was used as a catalyst. 7.34 millimoles were sequentially charged in the chamber ⁇ to prepare a catalyst solution, and the catalyst solution was a homogeneous solution. The reactor was cooled at night with nitrogen and the nitrogen gas in the yarn was evacuated with a vacuum pump.
- the gel-like acetylene polymer that has been severely moistened in toluene is a homogenous substance in which cut-off microcrystals (fibrils) having a diameter of 200 to 500 A are entangled with the non-woven fibers lj. Rose-shaped polymer is generated and
- This film was a P-type semiconductor with an “air conduction” (DC fi terminal method) of 2 and 5.3 ⁇ 10 ⁇ — 1 'cm _ 1 .
- the S vessel was cooled with liquid oxygen, and the nitrogen gas in the system was evacuated with a vacuum pump.
- the reactor was then turned into the chamber ⁇ , and the magnetic stirrer was used to remove the solvent ⁇ volume 3 ⁇ 4 : 1) Atmospheric pressure of acetylene gas was blown in.7) 10 minutes after the polymerization reaction was started, the system ⁇ : became an agar-like gel-like material. ⁇ 3 ⁇ 4 ⁇ ⁇ The whole system was black-brown agar-like.
- the unreacted acetylene gas was gradually removed, and the mixture was washed four times with ⁇ combined ⁇ 200 of 1: 1 (volume, ratio) of methanol and toluene. .
- the resulting gel-like " ⁇ is a real Jg i7 [j 1 and a uniform 3 ⁇ 4 gel-like material] 3. There was a film.
- OMPI Tris-acetyl-cetonato iron 5.0 millimol and triisoptyl-luminium 1 were used instead of tritium-butoxytitanium and triethyl-luminum used in Example 1. . 5 0 except for using the Mi Rimoru is carried Kiyoshi 1 exactly I hundred] like the preparation preliminary acetylene catalytic polymerization 3 ⁇ 4 line 3 ⁇ 4 Ii example 1 and I Tsukasa like 3 ⁇ 4 -. gel 3 ⁇ 4 ⁇ T ⁇ o
- a glass reaction vessel (1) completely replaced with nitrogen gas, toluene (200) purified according to a conventional method as a polymerization solvent, tetrabutoxytitanium (0.01 mmol) and triethylamine (0.1 mol) as catalysts were used.
- the reaction solution was charged at room temperature to prepare a catalyst solution.
- the catalyst solution was 1 volume in average.
- the reactor was cooled with sputum humor and the humid gas in the system was evacuated with a vacuum pump.
- This powdery acetylene high polymer was washed four times with purified toluene 200 times, washed and dried in vacuo to obtain a powdery acetylene high polymer.
- This powdery acetylene high polymer was sandwiched between ⁇ and ⁇ -plates, and pressed at room temperature under a pressure of 100 0 / C ⁇ . It was not in film form.
- Glass 1 completely replaced with nitrogen gas ⁇ Into a container, 200 ⁇ m of toluene, purified by a conventional method, as a polymerization solvent, and 40 ⁇ mol of tetrabutoxytitanium and 80 ⁇ mol of triethylaluminum as catalysts. A catalyst solution was prepared by sequentially charging. The catalyst; volume was a homogeneous solution.
- Example 1 and I After Example 1 and I, and then pressure-molded as in Example 1, a uniform film was not obtained.
- Example 1 While carrying out the polymerization of acetylene,
- the film was removed in the same manner as in Example 1. Then, the film-like gel was pressed and pressed at a pressure of 1 ton between the foamed ⁇ -plates to increase the metallic luster. A film of acetylene high polymer with high mechanical strength was found.
- OMPI Remove the rengas and repeat the system four times with a 200 elliptical curve while keeping the intensity at 1 78 C! ) Return washing. Dissolved after cooling; dark brown at night, catalyst completely removed.
- the gel-like acetylene polymer swelled in toluene is a gel-like material in which fibrils with a diameter of 300 to 500 A are irregularly intertwined! ), No powdery or bulky polymer was formed.
- the gel-like phlegm plate was press-molded at room temperature at 100 K ° C. When pressed, it had a reddish-brown metallic luster and large mechanical strength.
- the film was r r.
- the Fi Lum electrical conductivity 9. (a DC four-terminal method) 2 0 C 4 X 1 0 one 7 n - 1 - cm - 1 of? ) Type semiconductor.
- Example 8 In Example 7, except that ⁇ -heptane was used in place of toluene used as the polymerization solvent, the procedure was completely the same as in Example 7, except that ⁇ -heptane was used.
- the polymerization of acetylene was carried out according to the method of Mr. I. -The obtained gel was press-molded by the same method as that of ⁇ !
- the acetylene was dissolved by a mild amount in 5. Then, a catalyst solution was prepared by adding 1.50 millimoles of triisobutyl chloride. The catalyst solution was a homogeneous solution.
- the ⁇ of the 5-5 units was brought to room temperature, and purified acetylene gas at a pressure of 1 atm was injected. 10 minutes after the start of the polymerization reaction, the entire system 1 * is a gel-like agar
- Example 7 In the same manner as in Example 7, the catalyst was adjusted in the same manner as in Example 7: ⁇ and acetylene, and the actual gel was similar to W ⁇ 7.
- Example 9 In place of the tetrabutoxytitanium and trisobutinolealuminum used in Example 9, the amount of tris-butyltinacetone was reduced to 0.5 mmol and triseptylaluminum. Except that millimol was used, the medium was cleaved and acetylene was polymerized in the same manner as in Example 9 to obtain a gel-like material similar to that in Example 9.
- Toluene which was ovalized according to a conventional method, was charged into a glass reaction vessel (1), which was completely exchanged with nitrogen gas, according to a conventional method, and cooled to —78 C. After removing the elemental sulfur gas in the system with, the acetylene gas is blown in at 1 atm to dissolve the acetylene by the saturated amount, and then the catalyst is tetrabutyloxytitanium 0.01 mimol and triethyl. preparing a catalyst solution Ruminiu ⁇ 0.1 to 1 Mi Rimoru sequentially one 7 8 C ⁇ 3 ⁇ 4 Nde
- OMPI WIPO did.
- the catalyst solution was homogeneous.
- the reactor was cooled with liquid nitrogen and the nitrogen gas in the system was evacuated with a vacuum bomb.
- This powdery acetylene high-coagulated product was washed four times with purified water: ⁇ toluene 200, and then dried to obtain a powdery acetylene high polymer.
- the weight of acetylene was completely determined in the same manner as in Example 7. As a result, some of the acetylene-rich polymer was gel-like, but most of the acetylene-rich polymer was a solid ⁇ polymer and had a phase difference of il.
- the 30-lens polymer was composed of irregularly intertwined fibrils having a diameter of 300 to 400 A.
- the gel scissors to click ⁇ plated was FUERO plate, room temperature, 1 0 0 K? Bruno ⁇ pressure of a flexible bracelet molded at a metallic luster reddish brown acetylene high polymer with a film of is ⁇ 7to the Fi Lum electrical conductivity (direct current four-terminal method) 2 0 C in 6 5 X 1 0- 7 ⁇ , -. 1 ' was cm one first P-type semiconductor.
- the centrifuge is cooled with liquid oxygen and the gas in the system is evacuated using a vacuum pump.Tto Next, the temperature of the reactor is increased to room temperature, and the catalyst solution is removed with a magnetic stirrer. While stirring, acetylene gas of 1 atm pressure was blown. 1 0 minutes the whole system after from the start of the polymerization reaction was continued Polymerization while maintaining a 1 atm pressure of agar-like gel in summer 2 4 between acetylene gas continued stirring. The whole system was black-brown agar-like. After the polymerization reaction,
- Example 1 5 The obtained gel is in the form of a gel, which is the same as that of “ ⁇ ” 13]. When molded in the same manner as in Example 13, a flexible film was obtained.
- Example 1 5 When molded in the same manner as in Example 13, a flexible film was obtained.
- Example 13 trisacetinolease toner totitanium 5.0 mi and triethylamine Using 27.0 millimoles and using tetrahydrofuran instead of n-heptane, the procedure of Example 1 was repeated except that the catalyst was adjusted and polymerization of acetylene was carried out in the same manner as in Example 13. 3 and ⁇ A gel was obtained.
- Tris-acetyl cetonato iron 5.0 mmol and triisobutyl luminium 25.0 mmol were used.
- a catalyst was prepared and polymerization of acetylene was carried out in exactly the same manner as in Example 13 except for the above, to obtain Example 13 and a gel.
- Example 2 In place of the contact titanium and triisobutyl luminium used in Example 1, the tris-cetyl-settler medium was added. Use 0.5 mmol and triisobutyl mini-2.5 mol and use instead of Jettlether. A catalyst was prepared and acetylene was polymerized in the same manner as in Example 14 except that hexane was used.
- heptane 200 was used as a polymerization solution according to a conventional method, and tetrabutoxytitanium was used as a catalyst.
- 0.1 mmol of ethynoleum aluminum was charged in the chamber to prepare a catalyst solution.
- the catalyst solution was a homogeneous 10 solution.
- the reactor was cooled with liquid oxygen and the gas in the system was evacuated with a vacuum pump.
- the reactor was cooled to -78 C, the catalyst solution was stirred with a magnetic stirrer, and acetylene gas at a pressure of 1 atm was blown.
- acetylene gas at a pressure of 1 atm was blown.
- black-brown acetylene high polymerization started to precipitate in powder form.
- the polymerization reaction was carried out for 24 hours with stirring at 178 C while maintaining the pressure of the acetylene gas at 1 atm, but the resulting acetylene high polymer was in powder form.
- This powdery acetylene high polymer is washed four times with purified w-heptane 200 four times and then vacuumed! Then, a powdery acetylene high polymer was obtained.
- This powdery acetylene high polymer has a humidified appearance. Pressed in a room at 100 1 in a room ⁇
- the product was extremely thin and could not be obtained in the form of a film.
- 1-n-heptane 20 Q ⁇ was purified as a polymerization solution according to a conventional method, and tetrahydroxititanium was used as a catalyst.
- the catalyst solution was prepared by charging lyethylaluminum 80 milliliters.
- the catalyst solution was a homogeneous solution.o
- acetylene was polymerized in the same manner as in Example 13 using the obtained catalyst solution, the acetylene high polymer " ⁇ 3 ⁇ 4 was in a gel state, acetylene high polymer majority had @ phase partial ⁇ 3 ⁇ 4 a high polymer solid mass 0
- Example 13 After the post-treatment was carried out satisfactorily as in Example 13, and then the sword was formed in the same manner as in Example 13, a uniform film could not be obtained.
- Toluene 20 Q ⁇ £ which was purified by a conventional method, was used as the polymerization solvent in the 1 glass reactor completely exchanged with the nitrogen gas, and 2.94 milimol of tetrabutoxytitanium and triethyl were used as the catalyst. 7.34 mmol of aluminum was sequentially charged at room temperature to prepare a catalyst solution. The catalyst solution was a homogeneous solution. The reactor was cooled with liquid nitrogen and the room gas in the system was evacuated with a vacuum pump.
- the solution was repeatedly washed four times with toluene, and after the washing, the solution was slightly brown and the touch was completely removed.
- the gel-like acetylene polymer swollen in toluene is one in which fibrils are entangled improperly]), and a powdery, rose-like polymer was generated.
- a porous acetylene high polymer was obtained and observed with a scanning electron microscope. As a result, the polymer had a fibril structure with a diameter of 200 to 300 A.
- This porous acetylene high polymer has a cis content of 94% and an electric conductivity of 4.7 XI 0 — 9 ⁇ — —-cm — 1 ? ) Type ⁇ body.
- This porous acetylene high polymer is usually press-molded at a pressure of 100 ° to obtain a tough film-like acetylene high polymer having a bulk density of 0.80 ° C.
- Electrical conductivity is 1.2 X 10 — 8 ⁇ — 1 - ⁇ ⁇ ⁇ : p-type semiconductor.
- Example 1 8 toluene gel in completion acetylene high polymer was de benzene ⁇ a Shirui, it chamber ⁇ Deyutsuku and dried in vacuo, bulk density of 0.5 4 ⁇ Bruno Hiroshi
- the acetylene high polymer obtained was a film-like acetylene high polymer which was tough and had no formability. .
- the reactor was cooled down with a target element, and the room gas in the system was evacuated with a vacuum bomb.
- the temperature of the reactor was lowered to room temperature, and while stirring the catalyst solution with a magnetic stirrer, acetylene gas at a pressure of 1 atm was injected.
- acetylene gas at a pressure of 1 atm was injected.
- This gel is freeze-dried at room temperature and the shape and dimensions of the gel
- the obtained porous acetylene high polymer was obtained.
- the obtained highly-co-porous polystyrene copolymer has the same fibril structure as that obtained in Example 18, has a bulk density of 0.0 ⁇ no cd, and a cis-a content of 60 «3 ⁇ 4, ' 3 ⁇ 4Air conduction ⁇ is 5.7 X 10 " 8
- the polymerization reaction was continued for 24 hours while maintaining the acetylene gas pressure 3 ⁇ 41.
- the system was red-purple agar-like.
- unreacted acetylene gas was removed, and the system was washed four times with 200 parts of toluene while maintaining the system temperature at 178C. After washing, the solution was still brown and the catalyst was not completely removed.
- the gel-like styrene polymer swollen in toluene is a uniform 3 ⁇ 4 gel-like substance in which fibrils with a diameter of 200 to 500 A are intertwined irregularly!
- a powdery or polymer is formed, and a uniform gel-like " ⁇ " is extracted and dried to form a gel ⁇ /
- the acetylene high polymer was contained in 10% by weight in the gel.
- the film-shaped product was put in a flask, and air was evacuated with a pump. Then, iodine gas was introduced at room temperature vapor pressure of iodine, and the film-shaped molded product was formed for 1 hour. 1 I noticed unsulfur iodine with a pump and iodine; This film-shaped molded product had a gas conductivity of 20 mm and was 95 ⁇ - 1 cm ⁇ ⁇ D-type semiconductor.
- Example 21 The homogenous gel obtained by polymerization in Example 21 (containing 10% by weight of acetylene high polymer) was vacuum-dried to obtain a gel of 50 heavy acetylene high polymer.
- This product has an electrical conductivity of 20 and 4.1 X 10 _ S a _ 1 ⁇ cm- 1 ? It was a type semiconductor.
- arsenic pentafluoride® molded product had an electric conductivity of 20 C and was' cm ⁇ : P-type semiconductor.
- Example 21 Replacement of toluene used as polymerization solvent in 1! The catalyst was prepared and acetylene was weighed in the same manner as in Example 21 except that Rysol was used in (2) to obtain a uniform gel. ⁇ 4 of the acetylene high polymer in the gel extraction was 12 doubles. ⁇
- Example 21 The preparation of the catalyst and the polymerization of acetylene were carried out in the same manner as in Example 21 except that the polymerization of acetylene was carried out at room temperature in Example 21 to obtain a uniform gel.
- the high acetylene polymer content in this gel is 18 wt. 7 o (Press molding method for gel autumn)
- Acetylene having a fipril structure produced by the method of the present invention
- the porous acetylene highly polymerized book obtained by drying is obtained by the pressure molding method of the present invention. It is very useful because it can make any meat and make any shape with high mechanical strength.
- the molded article of the acetylene high polymer obtained in this way has a very low resistance and exhibits various semiconductor-specific aerodynamic properties.
- acetylene high polymer utilizes the above-mentioned various electrical properties], for example, an electric resistance element, a heat-sensitive element, a photosensitive element, or an organic semiconductor material for manufacturing electric machine parts. Can be used as
- electron-accepting compounds ⁇ include iodine, bromine, bromine iodide, pentafluorine, pentafluoride antimony, silicon tetrafluoride, phosphorus pentachloride, phosphorus pentafluoride, and phosphorus salt Lumi, Odoriya Noremi, Pakishi Xisulfuryl Difluoride Sulfur, Nitrogen, Full Sulfur ⁇ , Trifluoromethansulfone, Chromium Sulfur ⁇ , Boron Trichloride, Boron Tribromide, Three He can be cited as ⁇ , ⁇ , or ⁇ .
- the conductive acetylene high polymer obtained in this manner exhibits high air conductivity depending on the type of electron-accepting compound and the type of the child. -9 ⁇ :! .
- P-type or w-type semiconductor that can be freely controlled in the range of 3 ⁇ — 1 -an ⁇ ⁇ ?, As it is Flexible and useful as an electronic device It can be used as a conductive material It is not possible to use a D-type semiconductor, and it can be easily combined with a w-type or p-type semiconductor to form a heterojunction device.
- the band gap energy of acetylene high polymer is 1.6 e to 1.9 e and photoconductivity with visible light.] 5
- As a material for heavy 'electrical transducers such as solar cells and optical sensors Is also useful.
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Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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DE19803041421 DE3041421C2 (de) | 1979-03-29 | 1980-03-28 | Verfahren zur Herstellung sowohl einer leicht formbaren Masse aus einem Acetylenhochpolymeren als auch eines por¦sen Acetylenhochpolymeren |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
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JP3628379A JPS55129404A (en) | 1979-03-29 | 1979-03-29 | Preparation of homogeneous gel of acetylene high polymer |
JP3628879A JPS55128419A (en) | 1979-03-29 | 1979-03-29 | Forming method for acetylene high polymer |
JP79/36288 | 1979-03-29 | ||
JP5024479A JPS6028300B2 (ja) | 1979-04-25 | 1979-04-25 | フイブリル構造を有する多孔質アセチレン高重合体の製造方法 |
JP5401779A JPS55145710A (en) | 1979-05-04 | 1979-05-04 | Preparation of gellike material of high-molecular acetylene polymer |
JP5401879A JPS55145711A (en) | 1979-05-04 | 1979-05-04 | Preparation of gellike material of high-molecular acetylene polymer |
Publications (1)
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WO1980002143A1 true WO1980002143A1 (en) | 1980-10-16 |
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PCT/JP1980/000053 WO1980002143A1 (en) | 1979-03-29 | 1980-03-28 | Process for preparing gel-like composition of acetylene high polymer,and process for fabrication thereof |
Country Status (5)
Country | Link |
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US (2) | US4410640A (ja) |
EP (1) | EP0026235B1 (ja) |
DE (1) | DE3041421C2 (ja) |
GB (1) | GB2058096B (ja) |
WO (1) | WO1980002143A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0049970A1 (en) * | 1980-10-06 | 1982-04-21 | Rohm And Haas Company | High drain battery |
EP0058469B1 (en) * | 1981-01-22 | 1987-07-22 | Showa Denko Kabushiki Kaisha | Battery having acetylene high polymer electrode |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4487709A (en) * | 1979-03-29 | 1984-12-11 | Showa Denko K.K. | Process for producing electrically conductive high polymer of acetylene |
EP0076119B1 (en) * | 1981-09-25 | 1986-07-23 | Showa Denko Kabushiki Kaisha | Reinforced acetylene high polymers, process for preparing same and battery having same |
DE3147476A1 (de) * | 1981-12-01 | 1983-07-14 | Bayer Ag, 5090 Leverkusen | Dotierte polymere organische leiter und verfahren zu ihrer herstellung |
US4394304A (en) * | 1982-01-29 | 1983-07-19 | Massachusetts Institute Of Technology | Electrically conducting polymer blends |
US4600756A (en) * | 1982-08-03 | 1986-07-15 | Enichimica S.P.A. | High-orientability polyacetylene films and process for their production |
DE3421993C1 (de) * | 1984-06-14 | 1985-12-12 | Zipperling Kessler & Co (Gmbh & Co), 2070 Ahrensburg | Verfahren zur Herstellung von Formteilen aus elektrisch leitfaehigen organischen Polymeren und/oder organischen Leitern,Vorrichtung zur Durchfuehrung des Verfahrens sowie Verwendung der Formteile |
US4866147A (en) * | 1985-07-30 | 1989-09-12 | The United States Of America As Represented By The United States Department Of Energy | Soluble silylated polyacetylene derivatives and their use as percursors to novel polyacetylene-type polymers |
DE3617505A1 (de) * | 1986-05-24 | 1987-11-26 | Basf Ag | Hochleitfaehiges filmfoermiges polyacethylen |
US5216102A (en) * | 1988-08-05 | 1993-06-01 | Matsushita Electric Industrial Co., Ltd. | Process for producing polyacetylene |
US5716708A (en) * | 1995-01-17 | 1998-02-10 | Lagow; Richard J. | Acetylenic carbon allotrope |
JP3162313B2 (ja) * | 1997-01-20 | 2001-04-25 | 工業技術院長 | 薄膜製造方法および薄膜製造装置 |
ES2165280B1 (es) * | 1999-07-21 | 2003-05-01 | Univ Valencia Politecnica | Un material util como conductor electrico que comprende poliacetileno o poliacetilenos sustituidos incorporados en un soporte mesoporoso, procedimiento para obtener el material y conductores que comprenden el material. |
DE502005000455D1 (de) * | 2005-04-21 | 2007-04-19 | Inpro Innovations Gmbh | Verfahren zur Herstellung polymerer elektrisch leitender Schichten |
Family Cites Families (7)
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LU34238A1 (ja) * | 1955-03-18 | |||
NL125099C (ja) * | 1956-06-27 | |||
GB1294406A (en) * | 1969-05-05 | 1972-10-25 | Polymer Corp | Porous compositions and process for making thereof |
JPS4832581A (ja) * | 1971-08-31 | 1973-04-28 | ||
US3933722A (en) * | 1973-04-20 | 1976-01-20 | General Electric Company | Meet extrudable polyacetylene copolymer blends |
US4228060A (en) * | 1978-11-03 | 1980-10-14 | Allied Chemical Corporation | Polymerization of acetylene |
US4362680A (en) * | 1980-03-21 | 1982-12-07 | Showa Denko K.K. | Process for production of molded articles of acetylene polymer |
-
1980
- 1980-03-28 GB GB8036773A patent/GB2058096B/en not_active Expired
- 1980-03-28 WO PCT/JP1980/000053 patent/WO1980002143A1/ja active IP Right Grant
- 1980-03-28 DE DE19803041421 patent/DE3041421C2/de not_active Expired
- 1980-10-23 EP EP80900610A patent/EP0026235B1/en not_active Expired
-
1981
- 1981-09-11 US US06/301,890 patent/US4410640A/en not_active Expired - Lifetime
-
1985
- 1985-07-12 US US06/755,210 patent/US4596852A/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0049970A1 (en) * | 1980-10-06 | 1982-04-21 | Rohm And Haas Company | High drain battery |
EP0058469B1 (en) * | 1981-01-22 | 1987-07-22 | Showa Denko Kabushiki Kaisha | Battery having acetylene high polymer electrode |
Also Published As
Publication number | Publication date |
---|---|
GB2058096B (en) | 1983-04-20 |
EP0026235A1 (en) | 1981-04-08 |
US4410640A (en) | 1983-10-18 |
EP0026235A4 (fr) | 1981-10-13 |
DE3041421T1 (ja) | 1981-04-23 |
EP0026235B1 (en) | 1986-12-10 |
GB2058096A (en) | 1981-04-08 |
US4596852A (en) | 1986-06-24 |
DE3041421C2 (de) | 1987-03-12 |
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