US8815456B2 - Fuel cell system - Google Patents

Fuel cell system Download PDF

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US8815456B2
US8815456B2 US11/572,258 US57225805A US8815456B2 US 8815456 B2 US8815456 B2 US 8815456B2 US 57225805 A US57225805 A US 57225805A US 8815456 B2 US8815456 B2 US 8815456B2
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fuel
flow rate
fuel cells
gas
fuel gas
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US20070281115A1 (en
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Takashi Shigehisa
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Kyocera Corp
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Kyocera Corp
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/043—Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04537—Electric variables
    • H01M8/04574—Current
    • H01M8/04589—Current of fuel cell stacks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04746—Pressure; Flow
    • H01M8/04753—Pressure; Flow of fuel cell reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
    • H01M8/2425—High-temperature cells with solid electrolytes
    • H01M8/243—Grouping of unit cells of tubular or cylindrical configuration
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04858—Electric variables
    • H01M8/04865—Voltage
    • H01M8/0488—Voltage of fuel cell stacks
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y02E60/525—

Definitions

  • the present invention relates to a fuel cell system equipped with power control means for controlling the amount of electric power produced by fuel cells and with generation control means for controlling the flow rate of a fuel gas and the flow rate of an oxygen-containing gas fed to the fuel cells.
  • a fuel cell system has been proposed and placed in practical use to generate electricity by putting a hydrogen-rich fuel gas and an oxygen-containing gas which may be the air to the electrode reaction.
  • a representative example of the fuel cell system includes a generation chamber, a plurality of fuel cells arranged in the generation chamber, fuel gas feeding means for feeding a fuel gas to the fuel cells, oxygen-containing gas feeding means for feeding an oxygen-containing gas to the fuel cells, and power converter means for converting a DC output of the fuel cells into an alternating current.
  • the power converter means feeds AC power to the load such as electric appliances in a general household in cooperation with a system power source such as a commercial power source.
  • the fuel cell system further includes power control means for suitably controlling the amount of electric power output to the power converter means from the fuel cells depending upon variations in the load, and generation control means for controlling the generation of the fuel cells by controlling the flow rate of the fuel gas and the flow rate of the oxygen-containing gas fed to the fuel cells. It is desired that the amount of generation of the fuel cells is suitably controlled depending upon variations in the load. Accordingly, the power control means and the generation control means work in cooperation with each other.
  • the amount of output power of the fuel cells is instantaneously increased in response to an increase instruction involving, however, a time lag of several milliseconds.
  • the fuel gas to be fed to the fuel cells is obtained from a fuel gas to be reformed, such as a city gas that must be reformed into a hydrogen-rich fuel gas. Therefore, the flow rate of the fuel gas cannot be instantaneously increased despite of having received the increase instruction, and increases involving a time lag of several seconds. Therefore, when the amount of output power must be increased at a large rate, the fuel gas becomes in short supply in the fuel cells giving rise to the occurrence of a so-called fuel depletion phenomenon. If the fuel depletion phenomenon occurs, the electric power is not obtained as required and, besides, the fuel cells are deteriorated.
  • JP-A-7-14598 discloses a fuel cell system wherein when the load has increased, the flow rate of the fuel gas and the flow rate of the oxygen-containing gas are readily increased in response thereto, but the amount of the output power is increased being suitably lagged behind.
  • JP-A-7-57753 discloses a fuel cell system wherein when the load has increased, the rate of increasing the output power is limited to be not larger than a predetermined value to thereby avoid the occurrence of the fuel depletion phenomenon.
  • the rate of following up the variations in the load becomes relatively sluggish since the output power is increased in a delayed manner or the rate of increasing the output power is limited to be not larger than a predetermined value.
  • the load varies vigorously, the electric power in many cases is generated without properly following the variation in the load, and the effective generation efficiency decreases considerably.
  • controlling the output power by the power control means must be suitably related to controlling the flow rate of the fuel gas and the flow rate of the oxygen-containing gas by the generation control means, and it becomes necessary to execute these control operations systematically. Therefore, when it is desired to change the load for which the fuel cell system is to be provided or when the fuel cell system is to be added to a single load, the control system as a whole must be greatly modified.
  • Another object of the present invention is to provide a novel and improved fuel cell system which is capable of coping with the requirements very easily without requiring a great modification in the control system even when it is desired to change the load for which the fuel cell system is to be provided or when the fuel cell system is to be added to a single load.
  • the present inventors have discovered the fact that the occurrence of fuel depletion phenomenon can be avoided even when the output power of the fuel cells is quickly controlled to meet a variation in the load if the flow rate of the fuel gas and the flow rate of the oxygen-containing gas are set based on an electric current of the fuel cells by selecting a fuel gas buffer amount specific to the fuel cells to be not smaller than a fuel gas amount that is needed within a maximum period of increase-needing time until the flow rate of the fuel gas is increased to a required amount when the amount of increase in the flow rate of the fuel gas is set to be a maximum and have, thus, accomplished the above principal object.
  • fuel gas buffer specific to the fuel cells stands for the fuel gas amount present in the fuel cells (e.g., in the gas passages formed in the electrode support board) due to the constitution of the fuel cells themselves in the normal state.
  • the fuel gas buffer amount can be increased to a sufficient degree without involving any problem.
  • a fuel cell system comprising a generation chamber, a plurality of fuel cells arranged in the generation chamber, fuel gas feeding means for feeding a fuel gas to the fuel cells, oxygen-containing gas feeding means for feeding an oxygen-containing gas to the fuel cells, power converter means for converting the DC output of the fuel cells into an alternating current, power control means for controlling the electric power output to the power converter means from the fuel cells, and generation control means for controlling the flow rate of the fuel gas fed to the fuel cells and the flow rate of the oxygen-containing gas fed to the fuel cells, the electric power being generated by the electrode reaction in the fuel cells, wherein:
  • a fuel gas buffer amount specific to the fuel cells is not smaller than a fuel gas amount that is needed within a maximum period of increase-needing time that is necessary until the flow rate of the fuel gas increases to a required amount when the amount of increase in the flow rate of the fuel gas is set to be a maximum;
  • the generation control means sets the flow rate of the fuel gas and the flow rate of the oxygen-containing gas based on an electric current of the fuel cells.
  • the fuel cells are of the solid electrolyte type.
  • the fuel gas feeding means includes reforming means, to-be-reformed gas feeding means for feeding, to the reforming means, a fuel gas that is to be reformed into a hydrogen-rich fuel gas, and water feeding means for feeding water to the reforming means, wherein the generation control means controls the flow rate of the to-be-reformed fuel gas fed to the reforming means and the flow rate of water fed to the reforming means to thereby control the flow rate of the fuel gas.
  • the power control means controls the electric power output from the fuel cells relying upon neither the flow rate of the fuel gas fed to the fuel cells nor the flow rate of the oxygen-containing gas fed to the fuel cells, which are controlled by the generation control means.
  • the generation control means and the power control means can be constituted independently from each other to achieve the above another object.
  • the generation control means sets the flow rate of the fuel gas to a predetermined maximum value. It is desired that the flow rate of the fuel gas set by the generation control means is not smaller than a predetermined minimum amount and that the flow rate of the oxygen-containing gas set by the generation control means, too, is not smaller than a predetermined minimum amount. It is desired that when a temperature exceeds a predetermined value at a predetermined portion in the generation chamber, the generation control means sets the flow rate of the oxygen-containing gas to a predetermined maximum value. It is desired that the power control means maintains the DC voltage of the fuel cells output to the power converter means to be not smaller than one-half the open-circuit electromotive voltage.
  • FIG. 1 is a view schematically illustrating the principal constituent elements in a preferred embodiment of a fuel cell system constituted according to the present invention
  • FIG. 2 is a sectional view illustrating fuel cell stacks in the fuel cell system of FIG. 1 ;
  • FIG. 3 is a flowchart illustrating a control mode in a state where the fuel cell system of FIG. 1 is normally operating.
  • FIG. 4 is a diagram illustrating a relative relationship among the current, voltage and electric power of the fuel cells.
  • FIG. 1 simply illustrates the principal constituent elements of the fuel cell system constituted according to the present invention.
  • the fuel cell system that is illustrated includes a generation chamber 2 which may be of a rectangular parallelepiped shape. It is desired that the generation chamber 2 is constituted by an outer frame made of a heat resisting metal plate and a heat insulating member arranged along the inner surfaces of the outer frame.
  • a fuel gas tank 4 of the shape of a box is arranged in the lower part of the generation chamber 2 .
  • Fuel cell stacks 6 a , 6 b and 6 c are arranged on the fuel gas tank 4 . If described with reference to FIG. 1 as well as FIG.
  • the fuel cell stacks 6 a , 6 b and 6 c are, respectively, constituted by a plurality of (five in the illustrated embodiment) fuel cells 8 of the solid electrolyte type that are slenderly extending in the vertical direction, i.e., in the up-and-down direction in FIG. 1 or in a direction perpendicular to the surface of the paper in FIG. 2 , and are arranged in a direction perpendicular to the surface of the paper in FIG. 1 or in the up-and-down direction in FIG. 2 .
  • the fuel cells 8 are, respectively, constituted by an electrode support board 10 , a fuel electrode layer 12 (anode) which is an inner electrode layer, a solid electrolyte layer 14 (cathode), an oxygen electrode layer 16 which is an outer electrode layer and an interconnector 18 .
  • the electrode support board 10 is a plate-like piece which slenderly extends in the vertical direction, and has both surfaces which are flat and both side surfaces which are of a semicircular shape.
  • the electrode support board 10 has a plurality of (four in the illustrated embodiment) gas passages 20 that penetrate therethrough in the vertical direction.
  • the electrode support boards 10 are joined to the upper wall surface of the fuel gas tank 4 by using, for example, a ceramic adhesive having excellent heat resisting property.
  • a plurality of (fifteen in the illustrated embodiment) slits are formed in the upper wall surface of the fuel gas tank 4 extending in the right-and-left direction in FIG. 1 and in the right-and-left direction maintaining a distance perpendicularly to the surface of the paper. Gas passages 20 formed in the electrode support boards 10 are communicated with these slits and are, therefore, communicated with the interior of the fuel gas tank 4 .
  • the interconnector 18 is arranged on one surface of the electrode support board 10 (on the upper surface of the fuel cell stack 6 a in FIG. 2 ).
  • the fuel electrode layer 12 is arranged on the other surface of the electrode support board 10 (on the lower surface of the fuel cell stack 6 a in FIG.
  • the solid electrolyte layer 14 is so arranged as to cover the whole fuel electrode layer 12 , and is joined at both ends thereof to both ends of the interconnector 18 .
  • the oxygen electrode layer 16 is arranged on the main portion of the solid electrolyte layer 14 , i.e., on a portion covering the other surface of the electrode support board 10 , and is positioned facing the interconnector 18 with the electrode support board 10 held therebetween.
  • Collector members 22 are arranged among the fuel cells 8 neighboring to one another in the fuel cell stacks 6 a , 6 b and 6 c , and are connecting the interconnector 18 of one fuel cell 8 to the oxygen electrode layer 16 of another fuel cell 8 .
  • the collector members 22 are also arranged at both ends of the fuel cell stacks 6 a , 6 b and 6 c , i.e., on the one surface and on the other surface of the fuel cells 8 positioned at the upper ends and at the lower ends thereof in FIG. 2 .
  • the fuel cell stacks 6 a and 6 b have the collector members 22 that are connected together through a conducting member 24 at the lower ends thereof in FIG.
  • the fuel cell stacks 6 b and 6 c have the collector members 22 that are connected together through a conducting member 24 at the upper ends thereof in FIG. 2 .
  • the fuel cell stack 6 a has the collector member 22 that is connected to a terminal member 26 at the upper end in FIG. 2
  • the fuel cell stack 6 c has the collector member 22 that is connected to a terminal member 26 at the lower end in FIG. 2 .
  • the fuel cells 8 are all electrically connected in series, and the terminal members 26 are present at both ends of the series connection.
  • the fuel cell system further includes fuel gas feeding means 28 for feeding the fuel gas to the fuel cell stacks 6 a , 6 b and 6 c , oxygen-containing gas feeding means 30 for feeding the oxygen-containing gas to the fuel cell stacks 6 a , 6 b and 6 c , and exhaust gas discharging means 32 for discharging the exhaust gas from the generation chamber 2 .
  • the fuel gas feeding means 28 includes a city gas feeder line or a feeder line 36 connected to a to-be-reformed fuel gas supply 34 which may be a propane gas cylinder, and the feeder line 36 includes a cut-off valve 38 and flow rate control means 40 disposed therein.
  • the fuel gas feeding means 28 includes reforming means 42 arranged at an upper end portion of the generation chamber 2 and vaporizing means 44 attached to the reforming means 42 .
  • the reforming means 42 has a reforming chamber (not shown) containing a known catalyst which is necessary for partly reforming and steam-reforming the fuel gas.
  • the feeder line 36 extends into the generation chamber 2 and is connected to the inlet of the reforming means 42 .
  • the outlet of the reforming means 42 is connected to the fuel gas tank 4 via a communication passage (not shown) formed in the side wall of the generation chamber 2 .
  • Blower means 48 is connected, through a cut-off valve 46 , to the feeder line 36 downstream of the flow rate control means 40 .
  • the fuel gas feeding means 28 further includes a feeder line 52 connected to a water supply 50 which may be a city water feeder line, and the feeder line 52 includes a cut-off valve 54 , water purifying means 56 and flow rate control means 58 .
  • the feeder line 52 too, extends into the generation chamber 2 and is connected to the inlet of the vaporizing means 44 .
  • the outlet of the vaporizing means 44 is connected to the feeder line 36 on the upstream of the reforming means 42 and is, therefore, connected to the reforming means 42 via the feeder line 36 .
  • the to-be-reformed fuel gas which may be a city gas or a propane gas is fed to the reforming means 42 through the feeder line 36 , is reformed into a hydrogen-rich fuel gas through the reforming means 42 , is fed into the fuel gas tank 4 , and is fed to the fuel cells 8 or, more closely, to the gas passages 20 formed in the electrode support boards 10 .
  • the blower means 48 is operated, as required, at the start (or, further closely, is operated until the temperature in the generation chamber 2 is sufficiently elevated to assume a state where the vaporizing means 44 is allowed to execute the predetermined vaporization) to thereby feed the air to the reforming means 42 .
  • the fuel cell system is normally operating (i.e., when the temperature in the generation chamber 2 is sufficiently elevated assuming a state where the vaporizing means 44 is allowed to execute the predetermined vaporization)
  • water which may be the city water is subjected to a predetermined purification treatment through the water purifying means 56 , and is fed to the vaporizing means 44 where steam is formed and is fed to the reforming means 42 to effect the so-called steam reforming.
  • the oxygen-containing gas feeding means 30 includes a feeder line 60 extending into the generation chamber 2 .
  • Blower means 62 is arranged at an upstream end of the feeder line 60 .
  • the feeder line 60 further has a flow meter 64 and heat-exchanging means 66 arranged therein.
  • the oxygen-containing gas which may be the air is fed into the generation chamber 2 flowing through the feeder line 60 , diffused in the generation chamber 2 through oxygen-containing gas diffusing means (not shown) arranged in the generation chamber 2 and is, thus, fed into the fuel cells 8 .
  • the hydrogen-rich fuel gas is fed from the fuel gas tank 4 into the gas passages 20 in the electrode support boards 10 of the fuel cells 8 , and rises through the gas passages 20 .
  • the oxygen-containing gas is diffused in the generation chamber 2 .
  • the electrode reaction of the following formula (1) takes place on the oxygen electrode layers 16 while the electrode reaction of the following formula (2) takes place on the fuel electrode layers 12 to generate electricity.
  • the generated electric power is taken out through a pair of terminal members 26 .
  • the fuel gas flowing through the gas passages 20 in the electrode support boards 10 of the fuel cells 8 the fuel gas that was not used for the electrode reaction flows into the generation chamber 2 from the upper ends of the electrode support boards 10 and burns as it flows in.
  • the oxygen in the oxygen-containing gas diffused in the generation chamber 2 the oxygen that was not used for the electrode reaction is used for the burning.
  • the temperature in the generation chamber 2 becomes as high as, for example, about 800 to about 1000° C. due to the generation of electricity in the fuel cells 8 and the burning of the fuel gas.
  • the exhaust gas discharging means 32 is constituted by a discharge line extending from the generation chamber 2 , the discharge line extending through the heat-exchanging means 66 .
  • the heat of the exhaust gas is conducted to the oxygen-containing gas that is fed into the generation chamber 2 .
  • the heat of the exhaust gas may be utilized for heating the water in a hot water supply system (not shown).
  • the above-mentioned constitution and action of the illustrated fuel cell system are not to constitute novel features of the fuel cell system contemplated by the present invention, and may be those which are substantially the same as the fuel cell system disclosed in, for example, JP-A-2005-5213. Therefore, details thereof should be referred to in JP-A-2005-5213 and are not described in this specification.
  • power converter means 70 is connected, via current detector means 68 , to the fuel cells 8 that are connected in series ( FIG. 2 ).
  • the current detector means 68 detects a direct current value output from the fuel cells 8 . Being controlled by the power converter means 70 , the direct current is output to the power converter means 70 from the fuel cells 8 .
  • the power converter means 70 converts the direct current and supplies an alternating current to a load 72 which is, for example, an electric appliance in a household.
  • the power converter means 70 incorporates voltage detector means 74 which detects the output voltage of the fuel cells 8 .
  • a system power source 78 which may be a commercial power source is connected to the load 72 through system power detector means 76 .
  • the system power detector means 76 detects the electric power fed to the load 72 from the system power source 78 .
  • the fuel cell system constituted according to the present invention further, includes generation control means 80 and power control means 82 .
  • the generation control means 80 controls the flow rate of the fuel gas fed to the fuel cells 8 or, more closely, controls the flow rate control means 40 disposed in the feeder line 36 for feeding the to-be-reformed fuel gas and the flow rate control means 58 disposed in the feeder line 52 for feeding water and, further, controls the flow rate of the oxygen-containing gas or, more closely, controls the blower means 62 disposed in the feeder line 60 for feeding the oxygen-containing gas.
  • a fuel gas buffer amount specific to the fuel cells 8 is set to be a fuel gas amount that is needed within a maximum period of increase-needing time (which is about one second in the case of a fuel cell system produced by the present inventors on an experimental basis) until the flow rate of the fuel gas increases to a required amount, i.e., to a maximum amount when the amount of increase in the flow rate of the fuel gas is set to be a maximum, i.e., when the flow rate of the fuel gas is varied from a minimum amount to a maximum amount (in the fuel cell system produced by the present inventors on an experimental basis, the fuel gas buffer amount specific to the fuel cells 8 is an amount corresponding to the fuel gas amount needed in about 3 seconds).
  • the generation control means 80 and the power control means 82 execute the control operations as described below.
  • the fuel gas buffer amount specific to the fuel cells 8 is the fuel gas amount present in the gas passages 20 in the electrode support boards 10 of all fuel cells 8 and in the voids of various porous materials constituting the fuel cells 8 .
  • the steam in the fuel gas does not contribute to generating electricity. Therefore, if a ratio ⁇ of the steam is subtracted, the fuel gas of M ⁇ (1 ⁇ ) contributes to generating electricity.
  • M stands for the total volume of the gas passages 20 in the fuel cells 8 and of voids of the porous materials.
  • the utilization factor of the fuel gas is denoted by U
  • the utilization factor at the start of feeding into the fuel cells 8 is 0 and the final utilization factor is U. Therefore, the average utilization factor during a time lag t becomes U/2.
  • the amount of electric charge of the fuel gas buffer amount becomes M ⁇ (1 ⁇ ) ⁇ U ⁇ F (Faraday constant)/(2 ⁇ 22.4).
  • the required amount of electric charge during the time lag t becomes W/V ⁇ t/2. Therefore, M ⁇ (1 ⁇ ) ⁇ U ⁇ F (Faraday constant)/(2 ⁇ 22.4)>W/V ⁇ t/2 may be satisfied.
  • FIG. 3 is a flowchart.
  • the power control means 82 drives the power converter means 70 which, therefore, connects the fuel cells 8 to the load 72 .
  • a DC power is taken out from the fuel cells 8 , converted into an AC power and is fed to the load 72 .
  • the power control means 82 controls the power converter means 70
  • the generation control means 80 controls the generation, i.e., controls the flow rate of the fuel gas and the flow rate of the oxygen-containing gas in parallel therewith.
  • the system power detector means 76 detects the electric power that is fed to the load 72 from the system power source 78 .
  • the voltage detector means 74 incorporated in the power converter means 70 detects the output voltage of the fuel cells 8 , and the routine proceeds to step n- 4 .
  • the power control means 82 operates the output electric power of the fuel cells 8 based on the electric power detected at step n- 2 and on the output voltage detected at step n- 3 .
  • the output voltage of the fuel cells 8 is so set that the output of the fuel cells 8 becomes as large as possible or, in other words, that the electric power from the system power source 78 becomes as small as possible.
  • the output power of the fuel cells 8 can be set to be about 700 to about 790 W. It can be contrived to set the output power of the fuel cells 8 to 800 W and to set the electric power from the system power source 78 to be 0 W. In this case, however, it is probable that the so-called reverse current may occur (electric power flows into the system power source 78 ).
  • the lower limit of electric power fed to the load 72 from the system power source 78 is set to be about 10 to about 100 W.
  • it is desired to maintain the output voltage of the fuel cells 8 to be not less than one-half the open-circuit electromotive voltage E (voltage of when no current is flowing) or, in other words, to maintain the output voltage to be not less than one-half thereof. If this is described in further detail, there exists a relationship V E ⁇ IR between the electric current I and the voltage V of the fuel cells 8 as shown in FIG. 4 .
  • R is an internal resistance of the fuel cells 8 .
  • the voltage V at this moment is E ⁇ IR, i.e., E/2.
  • E ⁇ IR i.e., E/2.
  • the generation efficiency becomes high if the control is limited to the left side only of the maximum electric power since the current is smaller than that on the right side.
  • the control mode of the power converter means 70 maintains such a relationship that the output electric power increases with a decrease in the voltage and the output electric power decreases with an increase in the voltage; i.e., a simple control mode can be employed.
  • the power converter means 70 varies the output current I of the fuel cells 8 to maintain the input voltage of not smaller than E/2.
  • step n- 5 the electric power to be fed to the load 72 is compared with the output electric power of the fuel cells 8 .
  • the routine proceeds to step n- 6 where the power control means 82 sends a signal to the generation control means 80 so as to maximize the flow rate of the fuel gas.
  • the cooperation between the power control means 82 and the generation control means 80 is based on the transmission of the above signal only.
  • step n- 7 it is judged whether halting means (not shown) is turned on for halting the operation of the fuel cell system.
  • the routine returns back to step n- 1 .
  • predetermined halting step is executed to halt the operation of the fuel cell system (the operation-halting step may be the step taught in the above JP-A-2005-5213, particularly, FIG. 9 thereof).
  • step n- 8 current detector means 68 detects an output current of the fuel cell 8 .
  • step n- 9 the flow rate of the fuel gas and the flow rate of the oxygen-containing gas to be fed to the fuel cells 8 are operated based on the output current of the fuel cells 8 .
  • A air utilization factor (e.g., 30%)
  • step n- 10 it is judged whether the flow rate of the fuel gas and the flow rate of the oxygen-containing gas that are operated are larger than the minimum flow rates.
  • the amount of generation becomes too small, the temperature drops greatly and it becomes difficult to maintain the normal operation. It is therefore important to feed the fuel gas and the oxygen-containing gas at flow rates not smaller than the predetermined minimum flow rates.
  • the routine proceeds to step n- 11 where the flow rate of the fuel gas and/or the flow rate of the oxygen-containing gas are set to be the predetermined minimum flow rates.
  • step n- 12 it is judged whether the power control means 82 is transmitting a signal for setting the flow rate of the fuel gas to a maximum value.
  • step n- 13 the flow rate of the fuel gas is set to a maximum value.
  • the routine proceeds to step n- 14 where it is judged whether the temperature detected by temperature detector means (not shown) disposed at a particular portion of the generation chamber 2 is lower than a predetermined temperature, for example, not higher than 830° C. When the detected temperature is exceeding 830° C., the routine proceeds to n- 15 where the flow rate of the oxygen-containing gas is set to a predetermined maximum value (this is to cool the interior of the generation chamber 2 by feeding the oxygen-containing gas in a sufficient amount). When the detected temperature is not higher than 830° C.
  • step n- 17 the flow rate of the oxygen-containing gas is set or, in further detail, the operating condition of blower means 62 is so set that a value indicated by a flow meter 64 becomes as operated (becomes the preset minimum value or maximum value).
  • step n- 18 the flow rate of the fuel gas to be reformed is so set as operated (to assume the preset minimum value or maximum value) or, more specifically, flow rate control means 40 is set.
  • step n- 19 flow rate control means 58 is so set that the flow rate of water becomes as operated.
  • the routine proceeds to step n- 20 where it is judged whether halting means (not shown) is turned on for halting the operation of the fuel cell system. When the halting means has not been turned on, the routine returns back to step n- 8 .
  • halting means predetermined halting step is executed to halt the operation of the fuel cell system.
  • control mode in the fuel cell system constituted according to the present invention. That is, the cooperation between the generation control means 80 and the power control means 82 is limited to a minimum required degree; i.e., the generation control means 80 and the power control means 82 work independently in most of the control steps. Therefore, the control mode needs to be modified to a minimum degree when, for example, the form of load to which the fuel cell system is attached is to be changed or when a plurality of fuel cell systems are to be provided for a common load, making it possible to realize the fuel cell system very easily and inexpensively.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)
US11/572,258 2004-07-21 2005-07-15 Fuel cell system Active 2030-05-14 US8815456B2 (en)

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JP2004213419 2004-07-21
PCT/JP2005/013520 WO2006009264A1 (fr) 2004-07-21 2005-07-15 Système à pile à combustible

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JP5597628B2 (ja) * 2009-04-24 2014-10-01 京セラ株式会社 燃料電池装置
JP2010257751A (ja) * 2009-04-24 2010-11-11 Honda Motor Co Ltd 燃料電池システムの制御方法
DE102011087802A1 (de) 2011-12-06 2013-06-06 Robert Bosch Gmbh Brennstoffzellensystem und Verfahren zum Betrieb desselben
JP2016177932A (ja) * 2015-03-19 2016-10-06 三浦工業株式会社 燃料電池用系統連系システム
JP2018060627A (ja) * 2016-10-03 2018-04-12 三浦工業株式会社 多段式燃料電池システム
CN113841273B (zh) * 2019-05-27 2024-11-05 京瓷株式会社 燃料电池装置
JP2021005534A (ja) * 2019-06-27 2021-01-14 株式会社東芝 燃料電池システムおよびその制御方法
JP2020074274A (ja) * 2019-09-30 2020-05-14 三浦工業株式会社 多段式燃料電池システム

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CA2574395A1 (fr) 2006-01-26
JP5208417B2 (ja) 2013-06-12
CN1989645B (zh) 2011-10-26
DE112005001725T5 (de) 2007-06-06
DE112005001725B4 (de) 2018-09-06
JPWO2006009264A1 (ja) 2008-05-01
US20070281115A1 (en) 2007-12-06
CN1989645A (zh) 2007-06-27
WO2006009264A1 (fr) 2006-01-26

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