US6887823B2 - Process for production of titanium-containing silicon oxide catalysts - Google Patents

Process for production of titanium-containing silicon oxide catalysts Download PDF

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US6887823B2
US6887823B2 US10/470,381 US47038103A US6887823B2 US 6887823 B2 US6887823 B2 US 6887823B2 US 47038103 A US47038103 A US 47038103A US 6887823 B2 US6887823 B2 US 6887823B2
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template
catalyst
titanium
solid
carbon atoms
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US20040067846A1 (en
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Jun Yamamoto
Junpei Tsuji
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Sumitomo Chemical Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)

Definitions

  • the present invention relates to a process for producing a titanium-containing silicon oxide catalyst and said catalyst. More particularly, the present invention relates to a process for producing a titanium-containing silicon oxide catalyst which can be used for reaction of a hydroperoxide with an olefin type compound for obtaining an oxirane compound, and which can exhibit high activity.
  • the subject to be solved by the present invention relates to a process for producing a titanium-containing silicon oxide catalyst which can be used for obtaining an oxirane compound from, for example, a hydroperoxide and an olefin type compound, and can exhibit high activity.
  • the present invention relates to a process for producing a titanium-containing silicon oxide catalyst satisfying all of the following conditions (1) to (4), which comprises the following first to third steps:
  • a quaternary ammonium ion represented by the following general formula (I) is used as a template and then the template is removed by solvent extraction, [NR 1 R 2 R 3 R 4 ] + (I) (wherein, R 1 represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R 2 to R 4 represent an alkyl group having 1 to 6 carbon-atoms)
  • first step a step for obtaining a solid containing a catalyst component and a template by mixing and stirring a silica source, a titanium source and, as the template, the quaternary ammonium ion,
  • second step a step of drying the solid obtained in the first step under a condition of a temperature of 120° C. or less
  • third step a step for removing the template by subjecting the solid dried in the second step to solvent extraction.
  • the catalyst obtained by the present invention is a titanium-containing silicon oxide catalyst satisfying all of the following conditions (1) to (4).
  • the condition (1) is that an average pore diameter of the catalyst is 10 ⁇ or more.
  • the condition (2) is that a pore diameter of 90% or more of the total pore volume of the catalyst is 5 to 200 ⁇ .
  • the condition (3) is that a specific pore volume of the catalyst is 0.2 cm 3 /g or more.
  • the specific pore volume means pore volume per 1 g of the catalyst.
  • Measurements of these conditions (1) to (3) can be conducted by ordinary methods such as a physical absorption method using gas such as nitrogen, argon or the like.
  • the condition (4) is that the catalyst is obtained by using a quaternary ammonium ion represented by the following general formula (I) as the template and then removing the template by solvent extraction; [NR 1 R 2 R 3 R 4 ] + (I) (wherein, R 1 represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R 2 to R 4 represent an alkyl group having 1 to 6 carbon atoms).
  • a quaternary ammonium ion represented by the following general formula (I) as the template and then removing the template by solvent extraction; [NR 1 R 2 R 3 R 4 ] + (I) (wherein, R 1 represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R 2 to R 4 represent an alkyl group having 1 to 6 carbon atoms).
  • condition (4) will be illustrated in detail in a part of a process for producing said catalyst.
  • the catalyst of the present invention may or may not have a peak showing an interplanar spacing (d) in a X-ray diffraction (XRD).
  • the peak showing an interplanar spacing (d) as herein referred to means a peak derived from the crystallinity and regularity of a solid, and a broad peak derived from an amorphous part may exist.
  • the catalyst obtained in the present invention preferably has an absorption peak in the region of 960 ⁇ 5 cm ⁇ 1 in the infrared absorption spectrum from the viewpoint of high activity. This peak is assumed to correspond to that of titanium introduced into the silica skeleton.
  • the production process of the present invention has the following steps:
  • first step a step for obtaining a solid containing a catalyst component and a template by mixing and stirring a silica source, a titanium source, and, as the template, a quaternary ammonium ion,
  • second step a step of drying the solid obtained in the first step under a condition of a temperature of 120° C. or less
  • third step a step of removing the template by subjecting the solid dried in the second step to solvent extraction.
  • the first step is a step for obtaining a solid containing a catalyst component and a template by mixing and stirring a silica source, a titanium source, and, as the template, a quaternary ammonium ion in the liquid state.
  • a silica source a titanium source
  • a quaternary ammonium ion a quaternary ammonium ion in the liquid state.
  • the reagent to be used is solid, it is preferable to be used by dissolving or dispersing it in a solvent.
  • the silica source includes amorphous silica and alkoxysilane such as tetramethyl orthosilicate, tetraethyl orthosilicate, tetrapropyl orthosilicate and the like.
  • the titanium source includes titanium alkoxides such as tetramethyl titanate, tetraethyl titanate, tetrapropyl titanate, tetraisopropyl titanate, tetrabutyl titanate, tetraisobutyl titanate, tetra-2-ethylhexyl titanate, tetraoctadecyl titanate; and titanium (IV) oxyacetylacetonate, titanium (IV) diisopropoxybisacetyl acetonate and the like; and titanium halides such as titanium tetrachloride, titanium tetrabromide, titanium tetraiodide and the like.
  • titanium alkoxides such as tetramethyl titanate, tetraethyl titanate, tetrapropyl titanate, tetraisopropyl titanate, tetrabutyl titanate, tetraisobutyl titan
  • a quaternary ammonium ion represented by the general formula (I) is used as the template.
  • [NR 1 R 2 R 3 R 4 ] + (I) (wherein, R 1 represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, and R 2 to R 4 represent an alkyl group having 1 to 6 carbon atoms).
  • R 1 represents a linear or branched hydrocarbon group having 2 to 36 carbon atoms, preferably 10 to 18 carbon atoms.
  • R 2 to R 4 represent an alkyl group having 1 to 6 carbon atoms, and preferably each of R 2 to R 4 is a methyl group.
  • quaternary ammonium ion represented by the general formula (I) include cations such as hexadecyltrimethylammonium, dodecyltrimethylammonium, benzyltrimethylammonium, dimethyldidodecylammonium, hexadecylpyridinium, and the like.
  • quaternary ammonium ions represented by the general formula (I) may be used alone or may be used as a mixture of two or more kinds.
  • the solvent examples include water and alcohols such as methanol, ethanol, n-propanol, 2-propanol, n-butanol, sec-butanol, t-butanol, allyl alcohol, cyclohexanol, benzyl alcohol and the like, and diols such as ethylene glycol and the like, a mixture thereof and the like.
  • alcohols such as methanol, ethanol, n-propanol, 2-propanol, n-butanol, sec-butanol, t-butanol, allyl alcohol, cyclohexanol, benzyl alcohol and the like, and diols such as ethylene glycol and the like, a mixture thereof and the like.
  • the amount used of the titanium source based on the silica source is preferably from 10 ⁇ 5 to 1, more preferably from 0.00008 to 0.4 in terms of molar ratio.
  • the amount used of the quaternary ammonium ion based on the total amount of silica source and titanium source is preferably from 10 ⁇ 2 to 2 in terms of molar ratio.
  • alkalinity or acidity for promoting the reaction of the silica source with the titanium source, it is preferable to impart alkalinity or acidity to the mixed solution.
  • alkali source quaternary ammonium hydroxides are preferable, and examples thereof include tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrapropylammonium hydroxide and the like, and a hydroxide of the quaternary ammonium ion represented by the general formula (I) is more preferably used.
  • the acid include inorganic acids such as hydrochloric acid, sulfuric acid, nitric acid and the like, and organic acids such as formic acid, acetic acid, propionic acid and the like.
  • the mixing and stirring temperature is usually from ⁇ 30 to 100° C. Solid is formed by mixing and stirring, and the solid may be aged for further growth thereof.
  • the aging time is usually 180 hours or less, and the aging temperature is usually from 0 to 200° C.
  • heating it is preferable that the mixture is transferred into a pressure vessel and heating is conducted in a closed pressure vessel for avoiding vaporization of the solvent.
  • the second step is a step of drying the solid obtained in the first step.
  • the solid obtained in the first step is filtered and dried.
  • the temperature during drying is 120° C. or lower, preferably 100° C. or lower. When the temperature is too higher, the object of the present invention, for obtaining a catalyst having an extremely high activity, can not be attained.
  • the atmosphere for drying includes air or inert gas such as nitrogen and the like.
  • a drying apparatus a conical dryer or plate dryer, equipped with a warm current device or vacuum device can be listed. Besides, in vacuum drying, it is preferable to dry under a vacuum of 200 mmHg or lower from the viewpoint of improving of drying efficiency at low temperature.
  • the third step of the present invention is a step of removing the template by subjecting the solid dried in the second step to solvent extraction.
  • a technique for extracting a template with a solvent is reported by Whitehurst et al. (see U.S. Pat. No. 5,143,879)
  • the solvent used in extraction may include a solvent which can dissolve a compound used as the template, and oxa- and/or oxo-substituted hydrocarbons having carbon atoms of 1 to about 12 in the liquid state at room temperature can be generally used.
  • Suitable examples of such solvents include alcohols, ketones, (acyclic and cyclic)ethers and esters.
  • Examples thereof include hydroxy-substituted hydrocarbons such as methanol, ethanol, ethylene glycol, propylene glycol, isopropanol, n-butanol or octanol; oxo-substituted hydrocarbons such as acetone, diethyl ketone, methyl ethyl ketone or methyl isobutyl-ketone; an ether of a hydrocarbon such as diisobutyl ether or tetrahydrofuran; esters of a hydrocarbon such as methyl acetate, ethyl acetate, butyl acetate or butyl propionate, and the like.
  • hydroxy-substituted hydrocarbons such as methanol, ethanol, ethylene glycol, propylene glycol, isopropanol, n-butanol or octanol
  • oxo-substituted hydrocarbons such as acetone, dieth
  • the weight ratio of the solvent to the catalyst is usually from 1 to 1000, preferably from 5 to 300.
  • acids or salts thereof may be added to these solvents.
  • acids used include inorganic acids such as hydrochloric acid, sulfuric acid, nitric acid, bromic acid and the like, organic acids such as formic acid, acetic acid, propionic acid and the like.
  • salts thereof include alkali metal salts, alkaline earth metal salts, ammonium salts and the like.
  • the concentration in the solvent of the acid or salt thereof to be added is preferably 10 mol/l or less, further preferably 1 mol/l or less.
  • concentration in the solvent of the acid or salt to be added exceeds 10 mol/l, catalytic activity may be lowered by elution of titanium in the catalyst.
  • the liquid portion is separated by filtration, decantation or the like. This operation is repeated required times. Extraction can be also conducted by a method of flowing a solvent for washing into a catalyst layer. The completion of washing can be known by, for example, analyzing the liquid portion.
  • the extraction temperature is preferably 0 to 200° C., further preferably 20 to 100° C.
  • extraction can be also conducted by using a super critical fluid.
  • a super critical fluid carbon dioxide is preferable.
  • the critical temperature of carbon dioxide is about 31° C. or more. Therefore, the extraction temperature is preferably 31 to 100° C., further preferably 35 to 60° C.
  • the critical pressure of carbon dioxide is about 7.4 MPa, so the extraction pressure is preferably 10 to 30 MPa.
  • the amount of super critical carbon dioxide used for extraction is preferably 50 to 500 g/min. per 1 liter of catalyst, and the extraction time is preferably 4 to 20 hours.
  • the resulted solid after the extraction may be dried. Namely, it is preferable to heat at a temperature of 10 to 800° C., further preferably 50 to 300° C. under a reduced pressure or an atmosphere of non-reducing gas such as nitrogen, argon, carbon dioxide or oxygen-containing gas such as air.
  • non-reducing gas such as nitrogen, argon, carbon dioxide or oxygen-containing gas such as air.
  • the quaternary ammonium ion represented by the general formula (I) in the solution obtained after the extraction, is recovered and can be also reused as a template material in the first step.
  • the template can be efficiently recycled because a loss caused to pyrolysis is controlled to low by carrying out drying at 120° C. or lower.
  • the catalyst it is preferable to conduct a step for subjecting the catalyst to silylation from the viewpoint of heightening of the catalyst activity.
  • the silylation is conducted by contacting the catalyst obtained in the third step with a silylation agent thereby converting a hydroxyl group existing on the surface of the catalyst into a silyl group.
  • silylation agent examples include organic silanes, organic silylamines, organic silylamides and derivatives thereof, and organic silazanes and other silylation agents.
  • organic silane examples include chrolotrimethylsilane, dichlorodimethylsilane, chlorobromodimethylsilane, nitrotrimethylsilane, chlorotriethylsilane, iododimethylbutylsilane, chlorodimethylphenylsilane, chlorodimethylsilane, dimethyl-n-propylchlorosilane, dimethylisopropylchlorosilane, t-butyldimethylchlorosilane, tripropylchlorosilane, dimethyloctylchlorosilane, tributylchlorosilane, trihexylchlorosilane, dimetylethylchlorosilane, dimethyloctadecylchlorosilane, n-butyldimethylchlorosilane, bromomethyldimethylchlorosilane, chloromethyldimethylchlor
  • organic silylamine examples include N-trimethylsilylimidazole, N-t-butyldimethylsilylimidazole, N-dimethylethylsilylimidazole, N-dimethyl-n-propylsilylimidazole, N-dimethylisopropylsilylimidazole, N-trimethylsilyldimethylamine, N-trimethylsilyldiethylamine, N-trimethylsilylpyrrole, N-trimethylsilylpyrrolidine, N-trimethylsilylpiperidine, 1-cyanoethyl(diethylamino)dimethylsilane, pentafluorophenyldimethylsilylamine.
  • organic silylamide and derivatives examples include N,O-bistrimethylsilylacetamide, N,O-bistrimethylsilyltrifluoroacetamide, N-trimethylsilylacetamide, N-methyl-N-trimethylsilylacetamide, N-methyl-N-trimethylsilyltrifluoroacetamide, N-methyl-N-trimethylsilylheptafluorobutylamide, N-(t-butyldimethylsilyl)-N-trifluoroacetamide, N,O-bis(diethylhydrosilyl)trifluoroacetamide.
  • organic silazane examples include hexamethyldisilazane, heptamethyldisilazane, 1,1,3,3-tetramethyldisilazane, 1,3-bis(chloromethyl)tetramethyldisilazane, 1,3-divinyl-1,1,3,3-teteramethyldisilazane, 1,3-diphenyltetramethyldisilazane.
  • Examples of the other silylation agent include N-methoxy-N,O-bistrimethylsilyltrifluoroacetamide, N-methoxy-N,O-bistrimethylsilyl carbamate, N,O-bistrimethylsilyl sulfamate, trimethylsilyltrifluoromethane sulfonate, N,N′-bistrimethylsilylurea.
  • the preferable silylation agent is hexamethyldisilazane.
  • the catalyst of the present invention is usually used as a molded catalyst via a step for molding a solid containing the catalyst component.
  • the molding step may be conducted in any stage, before or after the above-mentioned template-removing step, or after the silylation step, it is preferable to conduct before the template-removing step from the viewpoint of suppression of degradation of catalyst properties such as specific surface area, pore volume and the like.
  • the molding method any method such as compression molding, extrusion molding or the like may be used.
  • An organic or inorganic binder usually used can be used in the extrusion molding, but lowering of catalyst activity may be caused by addition of a binder.
  • the compression molding method is the most preferable from the viewpoint of strength and physical properties of the catalyst.
  • a roll press molding (briquetting, compacting), oil hydraulic press molding, tabletting and the like can be listed.
  • the pressure in compression is usually 0.1 to 10 ton/cm 2 , preferably 0.2 to 5 ton/cm 2 , further preferably 0.5 to 2 ton/cm 2 .
  • the pressure is too low, the strength of a molded body is sometimes inadequate.
  • the pressure is too high, the physical properties of the catalyst sometimes become inadequate because pores are broken.
  • it is preferable that a solid containing a catalyst component contains water in a proper amount, and a molded body having a sufficient strength can be produced by this.
  • the water content of the material to be subjected to the compression molding is preferably 1 to 70% by weight, further preferably 5 to 40% by weight.
  • the water amount may be adjusted by a dryness degree during drying of a wet solid, and may be adjusted by adding water to an adequately dried solid.
  • a binder usually used and the like may be added within a range of no obstacle to a desired performance.
  • the shape of the molded body may be any shape such as tablet, sphere, ring or the like.
  • the molded body may be used as it is or after pulverizing to a proper size.
  • the catalyst of the present invention can be used for selective oxidation, for example, in addition to epoxidation of an olefin type compound, various oxidation reactions of organic compounds because the catalyst has a high specific surface area and highly dispersed titanium active sites. Further, if desired, it is also possible to intensify acid sites of the catalyst with addition of a third component such as alumina, etc., and the catalyst can be used for alkylation, catalytic reforming, etc.
  • the catalyst of the present invention can be optimally can be used for production of an oxirane compound in which an olefin type compound is reacted with a hydroperoxide, in particular.
  • the olefin type compound may be acyclic, mono-cyclic, di-cyclic or poly-cyclic compounds, and mono-olefin type, di-olefin type or poly-olefin type compounds. When the number of olefin bonds is two or more, these may be a conjugated bond or non-conjugated bond. Olefin type compounds having 2 to 60 carbon atoms are usually preferred. These may have a substituent, and the substituent is preferably a relatively stable substituent.
  • hydrocarbon examples include ethylene, propylene, 1-butene, isobutylene, 1-hexene, 2-hexene, 3-hexene, 1-octane, 1-decene, styrene, cyclohexene, and the like.
  • Apt examples of the di-olefin type compound include butadiene and isoprene.
  • a substituent may exist, and as the example thereof, a halogen is listed, further various substituents containing an oxygen, sulfur or nitrogen atom together with a hydrogen and/or carbon atom, may exist.
  • a particularly preferable olefin type compound is an olefin type unsaturated alcohol and an olefin type unsaturated hydrocarbon substituted with a halogen, and as examples thereof, allyl alcohol, crotyl alcohol, allyl chloride are listed.
  • Particularly preferable compound is an alkene having 3 to 40 carbon atoms, and this compound may be substituted with a. hydroxy group or halogen atom.
  • organic hydroperoxides can be listed.
  • the organic hydroperoxide is a compound represented by the general formula
  • R represents a hydrocarbyl group
  • R represents a hydrocarbyl group
  • the group R is a group having 3 to 20 carbon atoms.
  • this is a hydrocarbyl group having 3 to 10 carbon atoms, particularly a secondary or tertiary alkyl group or aralkyl group.
  • tertiary alkyl groups, and secondary or tertiary aralkyl groups are particularly preferable, and specific examples thereof include a t-butyl group, t-pentyl group, cyclopentyl group, and 2-phenylpropyl-2-group.
  • various tetralinyl groups formed by eliminating hydrogen from an aliphatic side chain of a tetralin molecule are also listed.
  • the resulting hydroxyl compound is 2-phenyl-2-propanol. This can be converted to ⁇ -methyl styrene by dehydration reaction. ⁇ -methyl styrene is a industrially useful substance.
  • Tertiary amylene formed by dehydration of tertiary pentyl alcohol obtained by using tertiary pentyl hydroperoxide as the organic hydroperoxide is a useful substance as a precursor of isoprene.
  • Tertiary pentyl alcohol is useful as a precursor of methyl tertiary pentyl ether which is an octane booster.
  • Tertiary butyl alcohol obtained by using t-butyl hydroperoxide as an organic hydroperoxide is useful as a precursor of methyl tertiary butyl ether which is an octane booster.
  • Hydrogen peroxide can be listed as an example other than organic hydroperoxides.
  • Hydrogen peroxide is a compound represented by the chemical formula, HOOH, and can be obtained usually in the form of an aqueous solution. It reacts with an olefin type compound to form an oxirane compound and water.
  • the organic hydroperoxide and hydrogen peroxide, which are used as a raw material, may be a thin or dense purified or non-purified material.
  • the epoxidation can be carried out in a liquid phase by using a solvent and/or a diluent.
  • the solvent and diluent are a substance which are liquid under the pressure and temperature under which the reaction is conducted, and must be substantially inert against the reactants and products.
  • the solvent may be a substance existing in the hydroperoxide solution to be used.
  • cumene hydroperoxide is a mixture of cumene hydroperoxide and cumene, which is a raw material thereof, said cumene hydroperoxide can be used as a substitute for the solvent without especially adding a solvent.
  • the epoxidation temperature is usually from 0 to 200° C., preferably from 25 to 200° C.
  • the pressure may be a pressure enough to keep the reaction mixture liquid. Usually, the pressure is advantageously from 100 to 10000 kPa.
  • a liquid mixture containing desired product is easily separated from a catalyst composition.
  • the liquid mixture is purified by a suitable method. Purification includes fractional distillation, selective extraction, filtration, washing and the like. The solvent, catalyst, non-reacted propylene and non-reacted hydroperoxide can be used again by recycling.
  • the reaction in which the catalyst of the present invention is used, can be carried out in the form of a slurry or a fixed bed, and, in the case of a large scale of industrial operation, it is preferable to use a catalyst in the form of a fixed bed.
  • the present process can be carried out by a batchwise method, semi-continuous method or continuous method. When a solution containing a reactant is introduced through a fixed bed, a liquid mixture obtained from a reaction zone does not contain catalyst at all or contains substantially no catalyst.
  • the present invention is illustrated by the following Examples.
  • the obtained tablets were pulverized, then molded catalysts of 1.0 to 2.0 mm were obtained using sieves. Solid less than 1.0 mm was recycled to conduct compression molding again.
  • the obtained molded catalyst of 1.0 to 2.0 mm was dried at 70° C. for 8 hours under vacuum.
  • the molded catalyst obtained as described above was evaluated with a fixed bed flowing reaction apparatus using 26% of cumene hydroperoxide (CHPO) and propylene (C3′).
  • a catalyst layer was an inside diameter of 10 mm ⁇ and a length of 500 mm, a reaction condition was a LHSV of 30 h ⁇ 1 , a molar ratio of C3′/CHPO of 8, a reaction pressure of 5.5 MPa and a reaction temperature of 80° C.
  • a sampling was carried out for 30 minutes after 5 hours from the beginning of the reaction.
  • the reaction result was shown in Table 1.
  • Example 2 An experiment was carried out in the same manner as in Example 1 except that the molded body obtained in the molding step of Example 1 was dried at 150° C. for 8 hours under vacuum.
  • the obtained molded catalyst had a specific surface area of 907 m 2 /g, an average pore diameter of 22.5 ⁇ and a pore volume of 0.51 cc/g.
  • a titanium-containing silicone oxide catalyst which can be used for a reaction obtaining, for example, an oxirane compound from a hydroperoxide and an olefin type compound and which can exhibit high activity.

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DE102010046245A1 (de) * 2010-09-22 2012-03-22 Süd-Chemie AG Herstellung von Alumo-Phosphaten unter Rückgewinnung von Templaten
US10011575B2 (en) 2016-07-25 2018-07-03 Oriental Union Chemical Corp. Method for fabricating titanium-containing silicon oxide material and application of the same
US10493430B2 (en) 2016-11-28 2019-12-03 Oriental Union Chemical Corp. Method for fabricating a titanium-containing silicon oxide material with high thermal stability and applications of the same

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JP2002239381A (ja) * 2001-02-22 2002-08-27 Sumitomo Chem Co Ltd チタン含有珪素酸化物触媒の製造方法及び触媒
US6884743B2 (en) * 2002-09-16 2005-04-26 Basf Aktiengesellschaft Catalyst for epoxidation reactions
JP4265212B2 (ja) * 2002-12-19 2009-05-20 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法
CN100430318C (zh) * 2004-09-24 2008-11-05 中国石油化工股份有限公司 含钛多孔材料的合成方法
CN102600820A (zh) * 2004-12-06 2012-07-25 住友化学株式会社 含钛氧化硅催化剂的制造方法、该催化剂、以及使用该催化剂的烯化氧化合物的制造方法
CN101307039B (zh) * 2007-05-16 2010-12-01 中国石油化工股份有限公司 生产环氧化物的方法
CN101429176B (zh) * 2007-11-07 2011-05-18 中国石油化工股份有限公司 烯烃环氧化的方法
CN102295533B (zh) * 2010-06-24 2013-12-18 中国石油化工股份有限公司 α，α-二甲基苄醇的制备方法
TWI426050B (zh) * 2011-04-19 2014-02-11 China Petrochemical Dev Corp Taipei Taiwan A method for preparing titanium-silicon molecular sieve and method for producing cyclohexanone oxime using the molecular sieve
CN102872847B (zh) * 2011-07-12 2014-11-26 中国石油化工股份有限公司 钛氧化硅材料的改性方法
CN109721064B (zh) * 2017-10-31 2020-10-27 中国石油化工股份有限公司 钛硅分子筛的生产方法以及由该方法生产的钛硅分子筛和氨肟化反应方法
JP7128884B2 (ja) * 2018-03-15 2022-08-31 住友化学株式会社 チタン含有珪素酸化物成型体の製造方法、及びチタン含有珪素酸化物成型体

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DE102010046245A1 (de) * 2010-09-22 2012-03-22 Süd-Chemie AG Herstellung von Alumo-Phosphaten unter Rückgewinnung von Templaten
US10011575B2 (en) 2016-07-25 2018-07-03 Oriental Union Chemical Corp. Method for fabricating titanium-containing silicon oxide material and application of the same
US10493430B2 (en) 2016-11-28 2019-12-03 Oriental Union Chemical Corp. Method for fabricating a titanium-containing silicon oxide material with high thermal stability and applications of the same

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EP1364705A1 (de) 2003-11-26
JP2002224563A (ja) 2002-08-13
DE60212082D1 (de) 2006-07-20
US20040067846A1 (en) 2004-04-08
ES2266460T3 (es) 2007-03-01
WO2002060580A1 (fr) 2002-08-08
EP1364705B1 (de) 2006-06-07
JP4889865B2 (ja) 2012-03-07
CA2436581A1 (en) 2002-08-08
CN1219596C (zh) 2005-09-21
EP1364705A4 (de) 2004-11-10
ATE328659T1 (de) 2006-06-15
CN1500004A (zh) 2004-05-26
KR100827943B1 (ko) 2008-05-13
BR0206810A (pt) 2004-02-03
KR20030077603A (ko) 2003-10-01

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