US5713987A - Method as well as active substance for preventing microbial growth on surfaces, as well as compound for surface coating or finishing - Google Patents

Method as well as active substance for preventing microbial growth on surfaces, as well as compound for surface coating or finishing Download PDF

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Publication number
US5713987A
US5713987A US08/577,871 US57787195A US5713987A US 5713987 A US5713987 A US 5713987A US 57787195 A US57787195 A US 57787195A US 5713987 A US5713987 A US 5713987A
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US
United States
Prior art keywords
resin
flour
active substance
group
finely divided
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US08/577,871
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English (en)
Inventor
Toni Gradl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE4445881A external-priority patent/DE4445881C2/de
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of US5713987A publication Critical patent/US5713987A/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991Coated

Definitions

  • the invention relates to a method for preventing microbial growth on a surface by applying or making available a substance inhibiting or preventing such growth on or at the surface to an active substance that prevents growth of microorganisms on surfaces and to a compound such as varnish, paint, coating compound or similar compound for surface treatment or finish, having an active substance admixed with the compound for preventing the growth of microorganisms on surfaces.
  • bulwarks and other surfaces including those of concrete and metal, for example in hydraulic structures or even drinking water and industrial water tanks, as well as other elements such as sails, nets or structures consisting of cork and rubber, very quickly become coated with a slimy layer of microorganisms, which acts as a base for the growth of additional organisms. This leads to destruction of the material and to corrosion, etc. Especially in ships, this leads to an increase in drag resistance in the water and hence to an increase in fuel consumption. Many other objects, such as textiles or seeds, must likewise be protected against microbial attack.
  • the object of the invention is to provide a method by which prevention of microbial growth on surfaces of structures to be protected is possible without the use of toxic substances.
  • a method has been developed to accomplish this object.
  • This method can be defined as a method for preventing microbial growth on a surface by applying or making available to the surface an active substance which inhibits or prevents the growth of the microbe on or at the surface.
  • the active substance comprises a mineral flour having at least one catalyst which has been precipitated on or bound to the mineral flour.
  • the catalyst is a brownstone (manganese dioxide), a finely divided elementary palladium, or a finely divided elementary ruthenium.
  • the active substance for preventing microbial growth on surfaces is a mineral flour having a catalyst precipitated on or bound to the mineral flour wherein the catalyst has at least one substance of the group brownstone (manganese dioxide), finely divided elementary palladium, or finely divided ruthenium.
  • a compound for surface coating (surface sealing) or surface finishing has also been developed.
  • This surface coating compound is a varnish, a paint, a coating compound, or similar compound which is used for surface treatment or finishing in which the active substance has been admixed into the varnish, paint, coating compound, or other similar compound.
  • the active substance for inhibiting or preventing growth is applied to the surface to be protected in a great variety of ways. Specifically, said active substance is applied to the surface to be protected as a constituent of a paint, a lacquer, a coating compound, a finish (including a textile finish) as well as a dressing (including for dressing seeds). Alternatively, the active substance is applied to the surface to be protected by being admixed with the compound of which the structure to be protected is made of.
  • Varnishes, coatings, etc. which contain the active substance according to the invention are suitable for exterior finishes or coatings of ship and boat hulls, as underwater coatings of structures, as well as for coating storage tanks.
  • the active substance is used in wood preservatives which are applied to wood, as well as in dressings applied to seeds.
  • the varnishes, coatings, etc. which contain the active substance are formed by admixing the active substance with the varnishes and coatings.
  • suitable mineral flour includes at least one substance of the group
  • the mineral flour treated with the catalyst is admixed with a resin to form a resinous emulsion.
  • the resin is at least one resin of the group
  • the invention provides effective prevention of microbial growth on surfaces, without the use of toxic substances.
  • the active substance can also be combined with a synthetic material or a rubber compound used in the production of products.
  • the invention relates to a compound for surface coating or finishing which contains a percentage of the active substance in admixed form, where the percentage of active substance amounts for example to about 5 to 25 weight percent, referred to 100 weight percent of the total compound.
  • brownstone manganese dioxide
  • montmorillonite montmorillonite
  • the powder obtained was dried.
  • This powder (active substance) was added in a percentage of 5 weight percent to a nutrient agar (1.5% agar, Merck nutrient broth) and poured into a first group of Petri dishes.
  • This agar, without the active substance, was placed in a second group of Petri dishes as control specimen. In both cases, the agar was sterilized or autoclaved in every instance.
  • a cold-setting two-component epoxy varnish was mixed with ten weight percent of a brownstone precipitated on montmorillonite (intermixed with a natural resinous emulsion) and applied to glass slides. After solidifying, the slides were placed in a beaker with nutrient broth. The nutrient solution or broth had been inoculated four days previously with a suspension of earth. Glass slides which had likewise been coated with epoxy varnish, but without the active substance, were used as comparison or control specimens. The slides were incubated at 25° C. After 24, 48 and 96 hours, the coated glass slides were compared. While the controls had become coated with a slimy layer after 48 and 96 hours, no such growth was observed on the glass slides coated with epoxy varnish and active substance.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Materials Engineering (AREA)
  • Dentistry (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Catalysts (AREA)
US08/577,871 1994-12-22 1995-12-22 Method as well as active substance for preventing microbial growth on surfaces, as well as compound for surface coating or finishing Expired - Fee Related US5713987A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4445881.9 1994-12-22
DE4445881A DE4445881C2 (de) 1994-12-22 1994-12-22 Mittel zur Verhinderung von mikrobiellem Wachstum an Oberflächen

Publications (1)

Publication Number Publication Date
US5713987A true US5713987A (en) 1998-02-03

Family

ID=6536646

Family Applications (1)

Application Number Title Priority Date Filing Date
US08/577,871 Expired - Fee Related US5713987A (en) 1994-12-22 1995-12-22 Method as well as active substance for preventing microbial growth on surfaces, as well as compound for surface coating or finishing

Country Status (8)

Country Link
US (1) US5713987A (fr)
EP (1) EP0717929B1 (fr)
JP (1) JPH08231326A (fr)
AT (1) ATE206009T1 (fr)
CA (1) CA2165753A1 (fr)
DE (1) DE59509637D1 (fr)
DK (1) DK0717929T3 (fr)
NO (1) NO312323B1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101159634B1 (ko) * 2010-01-20 2012-06-26 소철수 계란 표면 멸균 코팅제 조성물
DE102010022658A1 (de) * 2010-06-04 2012-06-28 Rainer Seiz Textilbeschichtung mit alpinen Gesteinen zur Erzielung höchster Hitze-, Schnitt- und Abriebfestigkeiten

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2361157A1 (de) * 1972-12-07 1974-08-01 Simada Seiko Kunststoff-film, sowie verfahren und vorrichtung zu dessen herstellung
DE2752773A1 (de) * 1976-11-25 1978-06-01 Extensor Ab Schiffsbodenfarbe u.dgl.
EP0247019A2 (fr) * 1986-05-13 1987-11-25 Fina Research S.A. Revêtement anti-salissures et anti-corrosion pour structures immergées
JPS6379719A (ja) * 1986-09-22 1988-04-09 Kanebo Ltd 抗菌、防カビならびに結露防止機能を有するゼオライト成形体の製造方法
JPH0296508A (ja) * 1988-09-16 1990-04-09 Teika Corp 抗菌性組成物
EP0427858A1 (fr) * 1989-02-28 1991-05-22 Kanebo Ltd. Composition antibacterienne ou electro-conductrice et application d'une telle composition
JPH04275376A (ja) * 1991-03-01 1992-09-30 Teikoku Piston Ring Co Ltd 水中防汚塗料用顔料及び水中防汚塗料組成物
JPH04288006A (ja) * 1991-03-14 1992-10-13 Sangi Co Ltd 抗菌性リン酸カルシウム系セラミックス
JPH04325571A (ja) * 1991-04-24 1992-11-13 Suzuki Sogyo Co Ltd 水生生物の付着防止材料
JPH051245A (ja) * 1991-06-25 1993-01-08 Hiroharu Kawasaki 防錆・防貝塗料
JPH0578218A (ja) * 1991-07-19 1993-03-30 Matsushita Electric Ind Co Ltd 抗菌・防錆組成物とその混合物
EP0552071A1 (fr) * 1992-01-13 1993-07-21 Institut Français du Pétrole Utilisation d'un produit antidérapant et antifongique pour les sols et revêtements de sol
US5266105A (en) * 1991-01-30 1993-11-30 Dai Nippon Toryo Co., Ltd. Antifouling coating composition
US5284682A (en) * 1992-09-03 1994-02-08 American Marine Coatings, Inc. Copper/nickel epoxy coating and application process as antifouling agent

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2066271A (en) * 1935-05-27 1936-12-29 Whyt Rox Chemical Company Filter material and method of making same
GB1542684A (en) * 1976-03-15 1979-03-21 British Petroleum Co Biocidal compositions
JPH0768094B2 (ja) * 1988-02-26 1995-07-26 新東工業株式会社 抗菌抗カビ性層間化合物およびその製法
JP2686638B2 (ja) * 1988-03-17 1997-12-08 石原産業株式会社 抗菌性粉末及びその製造方法
JPH01268764A (ja) * 1988-04-20 1989-10-26 Ishihara Sangyo Kaisha Ltd 抗菌性顔料粉末
JP3008125B2 (ja) * 1990-10-12 2000-02-14 株式会社間組 コンクリート、モルタル又は高分子材料の劣化防止方法
US5681575A (en) * 1992-05-19 1997-10-28 Westaim Technologies Inc. Anti-microbial coating for medical devices
WO1994015463A1 (fr) * 1993-01-15 1994-07-21 E.I. Du Pont De Nemours And Company Compositions antimicrobiennes, et procede de preparation et d'utilisation de ces compositions
JPH07173022A (ja) * 1993-12-17 1995-07-11 Asahi Chem Ind Co Ltd 抗菌剤

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2361157A1 (de) * 1972-12-07 1974-08-01 Simada Seiko Kunststoff-film, sowie verfahren und vorrichtung zu dessen herstellung
DE2752773A1 (de) * 1976-11-25 1978-06-01 Extensor Ab Schiffsbodenfarbe u.dgl.
EP0247019A2 (fr) * 1986-05-13 1987-11-25 Fina Research S.A. Revêtement anti-salissures et anti-corrosion pour structures immergées
JPS6379719A (ja) * 1986-09-22 1988-04-09 Kanebo Ltd 抗菌、防カビならびに結露防止機能を有するゼオライト成形体の製造方法
JPH0296508A (ja) * 1988-09-16 1990-04-09 Teika Corp 抗菌性組成物
EP0427858A1 (fr) * 1989-02-28 1991-05-22 Kanebo Ltd. Composition antibacterienne ou electro-conductrice et application d'une telle composition
US5266105A (en) * 1991-01-30 1993-11-30 Dai Nippon Toryo Co., Ltd. Antifouling coating composition
JPH04275376A (ja) * 1991-03-01 1992-09-30 Teikoku Piston Ring Co Ltd 水中防汚塗料用顔料及び水中防汚塗料組成物
JPH04288006A (ja) * 1991-03-14 1992-10-13 Sangi Co Ltd 抗菌性リン酸カルシウム系セラミックス
JPH04325571A (ja) * 1991-04-24 1992-11-13 Suzuki Sogyo Co Ltd 水生生物の付着防止材料
JPH051245A (ja) * 1991-06-25 1993-01-08 Hiroharu Kawasaki 防錆・防貝塗料
JPH0578218A (ja) * 1991-07-19 1993-03-30 Matsushita Electric Ind Co Ltd 抗菌・防錆組成物とその混合物
EP0552071A1 (fr) * 1992-01-13 1993-07-21 Institut Français du Pétrole Utilisation d'un produit antidérapant et antifongique pour les sols et revêtements de sol
US5284682A (en) * 1992-09-03 1994-02-08 American Marine Coatings, Inc. Copper/nickel epoxy coating and application process as antifouling agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Chemical Abstracts, vol. 113, 1990, Ref. Nr. 2005f. *

Also Published As

Publication number Publication date
NO955235D0 (no) 1995-12-21
DE59509637D1 (de) 2001-10-31
NO312323B1 (no) 2002-04-29
ATE206009T1 (de) 2001-10-15
DK0717929T3 (da) 2002-01-21
JPH08231326A (ja) 1996-09-10
NO955235L (no) 1996-06-24
EP0717929A3 (fr) 1997-03-19
EP0717929A2 (fr) 1996-06-26
EP0717929B1 (fr) 2001-09-26
CA2165753A1 (fr) 1996-06-23

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