US4782120A - Non-polluting thinning adjuvant for sea-water and/or fresh water based drilling muds - Google Patents

Non-polluting thinning adjuvant for sea-water and/or fresh water based drilling muds Download PDF

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Publication number
US4782120A
US4782120A US07/038,483 US3848387A US4782120A US 4782120 A US4782120 A US 4782120A US 3848387 A US3848387 A US 3848387A US 4782120 A US4782120 A US 4782120A
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United States
Prior art keywords
adjuvant
acid
group
ethylenic
thinning
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US07/038,483
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Jacky Rousset
Jean-Bernard Egraz
Gilles Letetour
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Coatex SAS
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Coatex SAS
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Assigned to COATEX, S.A. reassignment COATEX, S.A. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: EGRAZ, JEAN-BERNARD, LETETOUR, GILLES, ROUSSET, JACKY
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02—Well-drilling compositions
    • C09K8/04—Aqueous well-drilling compositions
    • C09K8/14—Clay-containing compositions
    • C09K8/18—Clay-containing compositions characterised by the organic compounds
    • C09K8/22—Synthetic organic compounds
    • C09K8/24—Polymers

Definitions

  • the present invention concerns a non-polluting adjuvant for drilling fluids, consisting in the copolymers resulting from the copolymerization of ethylenic acids, acrylamids and ethylenic esters of phosphoric acid.
  • This adjuvant acts as a thinning agent for sea-water and/or fresh-water based muds used in extreme conditions of temperature and pressure.
  • the invention also concerns drilling muds in which the thinning adjuvant is used.
  • Rotary drilling systems have been known for a long time--in oil search--to be used to drill oil and/or gas production wells. These rotary drilling systems consist of a drilling bit fitted with appropriate "teeth", then a set of pipes assembled rigidly together end to end (called “drill pipe string”), the diameter of which is smaller than the one of the drilling bit. This whole solidary equipment--drill bit and drill pipe string--is driven into rotation from a platform situated above the well being drilled. As the drill bit attacks and goes through the geological strata, the crushed mineral materials must be cleared away from the bottom of the hole to enable the drilling operation to carry on.
  • colloidal mineral materials such as "swelling" clays and in particular bentonites and attapulgites, thickening mineral materials such as for example barite, calcium carbonate, ilmenite
  • thickening mineral materials such as for example barite, calcium carbonate, ilmenite
  • the expert has therefore added chemical adjuvants of mineral and/or organic origin in order to try and give these muds a minimum level of stability, whatever the geological site being drilled.
  • Phosphates and polyphosphates-- which are meant to act as thinning agents of the drilling mud--cause a deflocculation of colloidal clay and enable the use of a mud of greater density and lower viscosity, ensuring at the same time of certain reduction in the filtrate.
  • phosphates and polyphosphates are generally unstable, even at a low temperature such as 50° C. for example, and consequently a reduction in or even a disappearance of their role as a stabilizer occurs.
  • lignine used in watery drilling fluids has the reputation to control the thixotropy of these fluids; but the introduction into the fluid during the drilling process of contaminating agents such as NaCl or CaSO 4 causes its gradual precipitation, thus rendering its action inefficient. Facing such a drawback the expert has used in drilling fluids the following chemicals: lignosulfonates in the form of salt of Calcium, Sodium, Iron, Chromium or simultaneously salt of Iron and Chromium, to act as a thinning agent, i.e. an agent for the stabilization of mud viscosity at the value desired by the user.
  • acrylic derivatives such as copolymers of sulfonic methylacrylamido-alkyl acid and a methyl-acrylamide are, as taught by French Pat. No. 2,450,864, capable of acting as a reducer of filtrate.
  • salts of polyacrylic acids show little efficiency as thinning agents in environments with a high electrolytes content such as for example saline aqueous phases.
  • the thinning adjuvant meant to be used in aqueous drilling muds--whether saline or not--with the aim to preserve their rheological characteristics in extreme conditions of temperature and pressure prevailing at the bottom of holes drilled to great depths is characterized by the fact that it is a hydrosoluble copolymer resulting from the copolymerization of ethylenic acids, acrylamides and ethylenic esters of phosphoric acid, of general formula: ##STR2## in which the indices m, n, p,--expressed in % in mole--are chosen from the intervals:
  • radicals R 1 , R 2 and R 4 can be chosen from the group made up by H and the alkyles, while radical R 3 is either an alkylene, or an oxide and/or a polyalkylene oxide or finally a combination of alkylene and alkylene oxide and/or polyalkylene oxide.
  • radicals, R 1 , R 2 and R 4 are chosen from the group made up by H and/or alkyles from C 1 to C 18
  • radical R 3 is either an alkylene of structural unit (--CH 2 --) q in which q can take the values of the interval 1 to 18 and preferably the values of the interval 2 to 4, or it is an oxide or a polyalkylene oxide of structural unit (--R 5 --O) r in which R 5 is an alkylene radical of C 1 to C 4 where r can take the values of the interval 1 to 30 and preferably the values of the interval 1 to 10, or it is, finally, a combination of the two structural units, such as (--R 5 --O) r --(CH 2 ) q .
  • the preparation of the copolymer according to the invention demands the presence of the monomers necessary for the forming of the structural units making up the previously quoted formula.
  • the first monomer--an ethylenic acid-- is preferably chosen from the group of the following acids: acrylic and/or methacrylic, itaconic, crotonic, isocrotonic, aconitic, fumaric, mesaconic, sinapic, undecylenic, angelic, hydroxyacrylic, and maleic-anhydride.
  • the second monomer--an acrylamide-- is preferably chosen from the group made up by acrylamide, methacrylamide, sulphonic-acrylamide-alkyl acid such as the sulphonic 2-acrylamide-2-methyl-propane.
  • the third monomer--an ethylenic ester of phosphoric acid-- is for instance prepared by the reaction of phosphoric anhydride with an ethylenic alcohol according to the reaction: ##STR3## in which the ethylenic alcohol can be the monomethacrylate or the monoacrylate of ethyleneglycol, propyleneglycol, polyglycol, or their mix.
  • This monomer is a polymerizable ethylenic ester of phosphoric acid.
  • the thinning adjuvant for drilling fluids results from the copolymerization of the previously quoted monomers--with the help of the initiators and regulators and according to the processes well known by the expert--in an aqueous, alcoholic, hydroalcoholic, aromatic or aliphatic environment, resulting in a copolymer whose molecular weight is generally situated between 500 and 50 000.
  • the polymerization environment can be: water, methanol, ethanol, propanol, isopropanol, butanols, dimethylformamide, dimethylsulfoxide, tetrahydrofurane, acetone, methylethylcetone, ethyl acetate, butyl acetate, hexane, heptane, benzene, toluene, xylene, mercaptoethanol, tertiododecylmercaptan, thioglycolic esters, n-dodecylmercaptan; the following acids: acetic, tartric, lactic, citric, gluconic, glucoheptonic, 2-mercaptopropionic; thiodiethanol, carbon tetrachloride chloroform, methylene chloride, methyl chloride, monopropyleneglycol esters and/or esters, ethyleneglycol esters and/or ethylene
  • the solution of the obtained polymerizate can be partially or totally neutralized by an adequate neutralizing agent such as sodium-, potassium-, ammonium-, calcium-, hydroxide, or by a primary, secondary or tertiary aliphatic and/or cyclic amine such as for example ethanolamines (mono-, di-, tri-, ethanolamine), mono- and diethylamine, cyclohexylamine, methylcyclohexylamine . . . .
  • an adequate neutralizing agent such as sodium-, potassium-, ammonium-, calcium-, hydroxide
  • a primary, secondary or tertiary aliphatic and/or cyclic amine such as for example ethanolamines (mono-, di-, tri-, ethanolamine), mono- and diethylamine, cyclohexylamine, methylcyclohexylamine . . . .
  • the aqueous phase containing the copolymer as invented can be used in this aqueous form as a thinning agent for drilling muds, but it can also be processed--using all known methods--so as to eliminate this aqueous phase and to isolate the copolymer in the form of a fine powder which can be used under this other form as a thinning adjuvant.
  • This example illustrates the preparation of the phosphoric monomer.
  • This monomer is used in the preparation of the copolymers.
  • This example illustrates one way of preparing a copolymer of the phosphatic monomer (obtained in example 1) and acrylic acid.
  • the obtained copolymer contained the following--in % in weight--:
  • This example illustrates the preparation of a terpolymer of acrylic acid, acrylamide and phosphoric ethyleneglycol methacrylate, using the same process as described in example 2.
  • the final composition of the obtained terpolymer was as follows, expressed in % in weight:
  • the molecular weight of the said terpolymer was between 5000 and 7000.
  • This example illustrates the thinning action of the invented adjuvant used in a drilling mud whose aqueous phase was sea-water.
  • a drilling mud was prepared according to the following procedure:
  • the thus prepared mud was then submitted to a shearing action using a L.R2 type Sylverson stirrer fitted with a high-shearing grate of 35 mm in diameter.
  • Trial 1 concerns the base mud exempt from any thinning agent.
  • Trial 2 concerns the same mud containing an adjuvant consisting of 7.5 g of an iron and chromium lignosulfonate--reputed to be the best thinning agent in the prior art.
  • Trial 3 concerns the same mud containing 7.5 g of active ingredient of the invented thinning adjuvant as obtained in example 3.
  • the checked rheological characteristics were: apparent viscosity (AV), plastic viscosity (PV), Yield Value (YV), 0-Gel, 10-Gel, and the filtrate expressed in cm 3 --as they are defined in the "Manuel de Rheologie des fluides de forage et laitiers de ciment" (Handbook on the rheology of drilling fluids and cements slurry fluids) Technip 1979.
  • Table II when compared with Table I shows that the rheological characteristics of the invented mud have been improved--or at least maintained--when the characteristics of the mud containing the best adjuvant of the prior art are already seriously badly affected.
  • the invented thinning adjuvant preserves or improves the efficiency of the drilling mud when the mud is submitted to a rise--even an important one--in temperature.
  • This example illustrates the thinning action of the invented adjuvant used in a drilling mud whose aqueous phase is natural fresh water of hardness equal to 25° French TH.
  • the drilling mud prepared according to the process described in example 4, had the following composition:
  • the pH was checked to be 9.5-10.
  • Trial 4 concerns the reference mud sample exempt from any thinning agent.
  • Trial 5 concerns the same mud containing an adjuvant consisting of 10 g of an iron and chromium lignosulfonate--reputed to be the best thinning adjuvant of the prior art.
  • Trial 6 concerns the same mud containing 10 g of active ingredient of the invented thinning agent, as obtained in example 3.
  • the three Trials were submitted to a 10-minute stirring period using a Hamilton-Beach in the Low position.
  • This example illustrates the thinning action of the invented adjuvant used in a drilling mud whose aqueous phase is a NaCl-saturated water.
  • Trial 7 concerns the reference mud sample exempt from any thinning agent.
  • Trial 8 concerns the same mud containing 7.5 g of iron and chromium lignosulfonate--reputed to be the best thinning agent of the prior art.
  • Trial 9 concerns the same mud containing 7.5 g of active ingredient of the invented thinning adjuvant--as obtained in example 3.
  • This example shows the shale inhibiting action, when used with sea-water, of the invented adjuvant prepared as per example 3 and used in a drilling mud.
  • the drilling mud was prepared according to the process described in example 4 and had the following composition:
  • the pH of this mud was checked to be 9.5-10.
  • Trial 10 concerns the reference mud sample exempt from any thinning agent.
  • Trial 11 concerns the same mud containing 7.5 g of iron and chromium lignosulfonate--reputed to be the best adjuvant of the prior art.
  • Trial 12 concerns the same mud containing 7.5 g of active ingredient of the invented adjuvant--as obtained in example 3.
  • each one of the muds (Trial 10, 11 and 12)--under the same stirring action--received a mineral load of 75 g of calcic bentonite (C), i.e. a total load of 150 g per liter, thus defining Trials 13, 14 and 15.
  • the three muds (Trials 13, 14 and 15) were heat-rolled to 150° C. in an oven and maintained at this temperature for 16 hours. They were then cooled down to 20° C. and finally, after they had been stirred for 5 minutes and their pH adjusted to 9.5-10, they were submitted to the same rheology and filtrate checks.
  • This example illustrates the dispersing--and therefore thinning action of the invented adjuvant when CaCO 3 is put in suspension in sea-water (taken from the Golfe du Lion).
  • the pH of the solution is then adjusted to 9 using a NaOH solution
  • Viscosities at 10 rpm and 100 rpm are then measured at a temperature of 20° C. using a Brookfield RVS viscosimeter fitted with spindle no. 2.
  • Trial 16 is a reference sample free from any adjuvant.
  • Trial 17 concerns the dispersion mixture containing a sodium polyacrylate as an adjuvant, of molecular weight 5000, normally used in the prior art for this type of application in fresh water.
  • Trial 18 concerns the dispersion mixture containing the invented adjuvant, as per example 2.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Bulkheads Adapted To Foundation Construction (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Lubricants (AREA)
  • Treatment Of Sludge (AREA)
US07/038,483 1982-11-30 1987-04-13 Non-polluting thinning adjuvant for sea-water and/or fresh water based drilling muds Expired - Lifetime US4782120A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8220241 1982-11-30
FR8220241A FR2536758A1 (fr) 1982-11-30 1982-11-30 Adjuvant fluidifiant non polluant pour boues de forage a base d'eau saline et /ou d'eau douce

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US06556314 Continuation 1983-11-30

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US (1) US4782120A (enExample)
JP (1) JPS59113083A (enExample)
AU (1) AU575546B2 (enExample)
BR (1) BR8306574A (enExample)
CA (1) CA1191675A (enExample)
DE (1) DE3343053C2 (enExample)
DK (1) DK159019C (enExample)
FI (1) FI76366C (enExample)
FR (1) FR2536758A1 (enExample)
GB (1) GB2133021B (enExample)
NL (1) NL190782C (enExample)
NO (1) NO158302C (enExample)
SE (1) SE459257B (enExample)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4849129A (en) * 1988-05-06 1989-07-18 Betz Laboratories, Inc. Water treatment polymers and methods of use thereof
US4851490A (en) * 1983-10-26 1989-07-25 Betz Laboratories, Inc. Water soluble phosphonated polymers
US4863614A (en) * 1983-10-26 1989-09-05 Betz Laboratories, Inc. Water treatment polymers and methods of use thereof
US4886617A (en) * 1983-10-26 1989-12-12 Betz Laboratories, Inc. Water soluble phosphonated polymers
US5032295A (en) * 1989-04-25 1991-07-16 National Starch And Chemical Investment Holding Corporation Polymers for use in drilling muds
DE4024192A1 (de) * 1990-07-30 1992-02-06 Uhu Gmbh Waessrige klebstoffloesung ohne organisches loesungsmittel
US5292367A (en) * 1990-04-18 1994-03-08 Atlantic Richfield Company Dispersant compositions for subterranean well drilling and completion
US5558171A (en) * 1994-04-25 1996-09-24 M-I Drilling Fluids L.L.C. Well drilling process and clay stabilizing agent
US6107256A (en) * 1998-08-27 2000-08-22 Fritz Industries, Inc. Method of and additive for controlling fluid loss from a drilling fluid
US6130179A (en) * 1998-11-12 2000-10-10 Itc, Inc. Purified attapulgite clay
WO2002000350A1 (en) * 2000-06-23 2002-01-03 Itc, Inc. Purified attapulgite clay
US20030073586A1 (en) * 2001-10-03 2003-04-17 Martin Crossman Scale control composition for high scaling environments
US20100292347A1 (en) * 2006-06-09 2010-11-18 Yves Kensicher Process to thicken aqueous compositions, notably with an acid ph, by means of organophosphate polymers, and the aqueous compositions obtained
CN111454392A (zh) * 2020-03-18 2020-07-28 滨州德润化工有限责任公司 一种钻井液用抗温抗复合盐降失水剂
CN119331164A (zh) * 2024-12-21 2025-01-21 石家庄华莱鼎盛科技有限公司 钻井液用防泥包剂丙烯烷基醇酯及其制备方法和应用

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FR2571715B1 (fr) * 1984-10-16 1986-12-26 Coatex Sa Composition cimentaire hydraulique a prise retardee pour cimentation a haute temperature et pression
CA1244997A (en) * 1985-08-30 1988-11-15 Calgon Corporation Acrylic acid/2-acrylamido-2-methylpropyl-sulfonic acid/2-acrylamido-2-methylpropyl phosphonic polymers
FR2630728B1 (fr) * 1988-05-02 1991-07-05 Coatex Sa Agent inhibiteur d'entartrage et de corrosion pour le traitement des eaux et/ou milieux aqueux
CA2080906C (en) * 1990-04-18 2004-06-29 James B. Bloys Dispersant compositions for subterranean well drilling and completion
GB9215228D0 (en) * 1992-07-17 1992-09-02 Oilfield Chem Tech Ltd Drilling fluid loss additive
US6384111B1 (en) * 1996-12-20 2002-05-07 Basf Aktiengesellschaft Polymers containing carboxyl groups and polyalkylene ether side- chains as additives in mineral building materials
CN117986458B (zh) * 2024-04-02 2024-06-14 成都劳恩普斯科技有限公司 一种耐高温深穿透分子隔膜酸共聚物及其制备方法

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US4487859A (en) * 1983-11-21 1984-12-11 Scm Corporation Self-curing water dispersed polymers
US4518745A (en) * 1982-12-24 1985-05-21 Cassella Aktiengesellschaft Metal chelates of water soluble copolymers

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Publication number Priority date Publication date Assignee Title
US4177179A (en) * 1977-08-26 1979-12-04 Toyo Soda Manufacturing Co., Ltd. Aqueous cold setting paint
JPS58147412A (ja) * 1982-02-26 1983-09-02 Nippon Shokubai Kagaku Kogyo Co Ltd 新規水溶性共重合体及びその製造方法
US4518745A (en) * 1982-12-24 1985-05-21 Cassella Aktiengesellschaft Metal chelates of water soluble copolymers
US4487859A (en) * 1983-11-21 1984-12-11 Scm Corporation Self-curing water dispersed polymers

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851490A (en) * 1983-10-26 1989-07-25 Betz Laboratories, Inc. Water soluble phosphonated polymers
US4863614A (en) * 1983-10-26 1989-09-05 Betz Laboratories, Inc. Water treatment polymers and methods of use thereof
US4886617A (en) * 1983-10-26 1989-12-12 Betz Laboratories, Inc. Water soluble phosphonated polymers
US4849129A (en) * 1988-05-06 1989-07-18 Betz Laboratories, Inc. Water treatment polymers and methods of use thereof
US5032295A (en) * 1989-04-25 1991-07-16 National Starch And Chemical Investment Holding Corporation Polymers for use in drilling muds
US5292367A (en) * 1990-04-18 1994-03-08 Atlantic Richfield Company Dispersant compositions for subterranean well drilling and completion
DE4024192A1 (de) * 1990-07-30 1992-02-06 Uhu Gmbh Waessrige klebstoffloesung ohne organisches loesungsmittel
US5558171A (en) * 1994-04-25 1996-09-24 M-I Drilling Fluids L.L.C. Well drilling process and clay stabilizing agent
US6107256A (en) * 1998-08-27 2000-08-22 Fritz Industries, Inc. Method of and additive for controlling fluid loss from a drilling fluid
US6130179A (en) * 1998-11-12 2000-10-10 Itc, Inc. Purified attapulgite clay
WO2002000350A1 (en) * 2000-06-23 2002-01-03 Itc, Inc. Purified attapulgite clay
US20030073586A1 (en) * 2001-10-03 2003-04-17 Martin Crossman Scale control composition for high scaling environments
US20050282712A1 (en) * 2001-10-03 2005-12-22 Martin Crossman Scale control composition for high scaling environments
US6995120B2 (en) * 2001-10-03 2006-02-07 National Starch And Chemical Investment Holding Corporation Scale control composition for high scaling environments
US20100292347A1 (en) * 2006-06-09 2010-11-18 Yves Kensicher Process to thicken aqueous compositions, notably with an acid ph, by means of organophosphate polymers, and the aqueous compositions obtained
US8637579B2 (en) * 2006-06-09 2014-01-28 Coatex S.A.S. Process to thicken aqueous compositions by means of organophosphate polymers
CN111454392A (zh) * 2020-03-18 2020-07-28 滨州德润化工有限责任公司 一种钻井液用抗温抗复合盐降失水剂
CN119331164A (zh) * 2024-12-21 2025-01-21 石家庄华莱鼎盛科技有限公司 钻井液用防泥包剂丙烯烷基醇酯及其制备方法和应用

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CA1191675A (fr) 1985-08-13
NO834391L (no) 1984-06-01
SE459257B (sv) 1989-06-19
AU575546B2 (en) 1988-08-04
FI834367A7 (fi) 1984-05-31
SE8306530L (sv) 1984-05-31
FI834367A0 (fi) 1983-11-29
DK545783D0 (da) 1983-11-29
JPS59113083A (ja) 1984-06-29
NL8304088A (nl) 1984-06-18
AU2184183A (en) 1984-06-07
FR2536758A1 (fr) 1984-06-01
JPH0377834B2 (enExample) 1991-12-11
BR8306574A (pt) 1984-07-03
GB2133021B (en) 1986-08-28
DE3343053C2 (de) 1995-04-13
NL190782C (nl) 1994-08-16
GB2133021A (en) 1984-07-18
DK545783A (da) 1984-05-31
DE3343053A1 (de) 1984-06-28
FR2536758B1 (enExample) 1985-03-15
FI76366C (fi) 1988-10-10
NO158302B (no) 1988-05-09
NO158302C (no) 1988-08-17
DK159019B (da) 1990-08-20
NL190782B (nl) 1994-03-16
GB8331429D0 (en) 1984-01-04
FI76366B (fi) 1988-06-30
SE8306530D0 (sv) 1983-11-25
DK159019C (da) 1991-01-28

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