US4472186A - pH-Adjusting and chlorine reducing composition - Google Patents

pH-Adjusting and chlorine reducing composition Download PDF

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Publication number
US4472186A
US4472186A US06/419,428 US41942882A US4472186A US 4472186 A US4472186 A US 4472186A US 41942882 A US41942882 A US 41942882A US 4472186 A US4472186 A US 4472186A
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US
United States
Prior art keywords
water
present
chlorine
fertilizer composition
adjusting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US06/419,428
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English (en)
Inventor
Ernst G. E. von Haartman
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Individual
Original Assignee
Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Application granted granted Critical
Publication of US4472186A publication Critical patent/US4472186A/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • C05D9/02Other inorganic fertilisers containing trace elements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S71/00Chemistry: fertilizers
    • Y10S71/02Chelating agent
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S71/00Chemistry: fertilizers
    • Y10S71/904Carrier

Definitions

  • the present invention relates to a pH-adjusting and chlorine reducing composition to be used in the adjustment of feeding-water for plants, which composition preferably contains the mineral nutrients necessary for the plants.
  • the object of the present invention is to obtain an improved fertilizer, pH-adjusting and chlorine reducing composition which in dry form, can be added to the water used for watering of plants, and then particularly house plants.
  • pH-adjusting agents which in the form of a solution are added to a watering water to adjust the pH to about 6.5.
  • Such agents are preferably used in alkaline, calcium-rich water, where the pH very often exceeds 7. The adjustment is thereby carried out possibly together with calcium-precipitation.
  • the present invention is characterized in that the composition comprises mineral nutrients in such an amount to give nutrition to the plants to which the water is added, whereby one or more of the mineral nutrients are added in the form of two or polyvalent acids or acid salts to adjust pH; 0.01-5% by weight of water soluble thiosulphate; and moreover a disintegration agent being swellable in water; and that the composition is present in the form of a dry dosage unit soluble in water.
  • starting material A First a micronutrient peparation in dry form was prepared, which was called starting material A:
  • the a macronutrient preparation in dry form was prepared, which was called starting material B:
  • preparation B is mixed and ground in a mill suited hereto.
  • micro-crystalline cellulose (AVICEL sold by Mont Oil)
  • the components are thoroughly mixed and tabletted in a tabletting machine to yield 100 tablets having a weight of 1 g each.
  • the tablets are intended to be dissolved in 2 liters of water, and are thus provided with a score to be able to be readily divided into two pieces, each to be added to 1 liter of water.
  • the tablet dissolves very rapidly in water, whereby it has also surprisingly turned out that the micronutrients present dissolve without flocculation as they immediately form chelates at the dissolution in water.
  • the reason why the tablet dissolves so fast in water is that the micro-crystalline cellulose present in the tablet, absorbs water, swells, and thereby breaks the tablet, so that the water-soluble substances present will become more rapidly and more easily available for dissolution.
  • the composition according to EX. 1 above gives at the dissolvation in water having a normal pH a final pH of 6.5. pH can however vary somewhat depending on the pH of the ingoing water, but will be somewhere between 5.5 and 7.0, preferably 6.2-6.8.
  • the pH-adjustment in the fertilizer is obtained by means of buffering compounds present in the composition, such as K 2 HPO 4 , KH 2 PO 4 , Na 2 HPO 4 , NaH 2 PO 4 , H 3 PO 4 , NH 4 H 2 PO 4 , (NH 4 ) 2 HPO 4 , H 3 BO 3 , the two first mentioned being the most suitable ones.
  • the components are thoroughly mixed and are tabletted into tablets having a weight of 1 g each in accordance with Ex. 1 above.
  • This tablet having a weight of 1 g is intended to be dissolved in 1 liter of water, whereby the pH of the water will be 6.5.
  • pH can, as mentioned above, vary between 5.5-7.0, whereby partly the ingoing water has an influence on the final pH, partly the amounts of buffering compounds
  • Some waters are more acid or alkaline than others, e.g. they may have a strong alkalinity, whereby a greater buffering capacity is needed than if the alkalinity is weaker.
  • Some plants can and will have another pH than most other plants and thus require another buffer composition.
  • the amount of thiosulphate has been said to be 0.01-5% by weight, but is preferably 0.1-0.5% by weight, which will take care of most occuring chlorine concentrations in standard tap water delivered in our cities.
  • the amount of thiosulphate in the final preparation of watering water should be 0.5-5 mg/liter, whereby 1-1.5 mg/liter is a standard value. Having a water with very high concentrations of chlorine the upper value should be used to guarantee a total reduction of chlorine present.
  • micronutrients and macronutrients present in a dosage unit are so selected that a suitable concentration of fertilizer is maintained in the growth medium of the plant and is present in such an amount that corresponds to the need of the plant between waterings, i.e. in such an amount that neither an impoverishment or an accumulation of nutrients is obtained, which is detrimental to the plants.
  • the stearic acid present in the tablet preparation above is present in order to obtain a greasing of the tablet punches during the tabletting operation and to bind the tablets together.
  • the substance can be replaced by other substances known in the art of tabletting and for that purpose.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
US06/419,428 1981-09-28 1982-09-17 pH-Adjusting and chlorine reducing composition Expired - Fee Related US4472186A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8105705A SE430982B (sv) 1981-09-28 1981-09-28 Godselmedel i tablettform innehallande ett klorreducerande medel
SE8105705 1981-09-28

Publications (1)

Publication Number Publication Date
US4472186A true US4472186A (en) 1984-09-18

Family

ID=20344639

Family Applications (1)

Application Number Title Priority Date Filing Date
US06/419,428 Expired - Fee Related US4472186A (en) 1981-09-28 1982-09-17 pH-Adjusting and chlorine reducing composition

Country Status (5)

Country Link
US (1) US4472186A (da)
DK (1) DK427982A (da)
FI (1) FI70403C (da)
NO (1) NO157778C (da)
SE (2) SE430982B (da)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5817600A (en) * 1993-05-01 1998-10-06 British Technology Group Limited Composition for treatment of plant material

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3003911A (en) * 1958-04-07 1961-10-10 Little Inc A Fibrous aggregates and process and apparatus for making them
US3186826A (en) * 1963-10-09 1965-06-01 Rendon Margarita Del Muro De Soil improver and process for preparing same
US3197302A (en) * 1962-11-02 1965-07-27 Grace W R & Co Soluble fertilizer composition
US3661953A (en) * 1967-11-02 1972-05-09 Hooker Chemical Corp Synergistic metal sequestrant
DE2215634A1 (de) * 1972-03-30 1973-10-04 Henkel & Cie Gmbh Granulierte duengemittel auf basis von ammoniumsulfat
JPS5056087A (da) * 1973-09-18 1975-05-16
US3912490A (en) * 1974-01-14 1975-10-14 Malcolm P Boghosian Plant and soil oxygenating composition and method
DE2537617A1 (de) * 1975-08-23 1977-03-17 Kolloidtechnik Gmbh Verfahren zur aktivierung der naehrstoffaufnahme durch kulturpflanzen und zur aktivierung der biologischen umsetzungen im boden mit hilfe organischer phosphatkolloide
US4174957A (en) * 1978-03-06 1979-11-20 Hydrosoil Corporation Synthetic growing medium and method of preparing it
US4210437A (en) * 1978-12-14 1980-07-01 Standard Oil Company (Indiana) Liquid fertilizer for supply of sulfur, nitrogen and micronutrient metals

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3003911A (en) * 1958-04-07 1961-10-10 Little Inc A Fibrous aggregates and process and apparatus for making them
US3197302A (en) * 1962-11-02 1965-07-27 Grace W R & Co Soluble fertilizer composition
US3186826A (en) * 1963-10-09 1965-06-01 Rendon Margarita Del Muro De Soil improver and process for preparing same
US3661953A (en) * 1967-11-02 1972-05-09 Hooker Chemical Corp Synergistic metal sequestrant
DE2215634A1 (de) * 1972-03-30 1973-10-04 Henkel & Cie Gmbh Granulierte duengemittel auf basis von ammoniumsulfat
JPS5056087A (da) * 1973-09-18 1975-05-16
US3912490A (en) * 1974-01-14 1975-10-14 Malcolm P Boghosian Plant and soil oxygenating composition and method
DE2537617A1 (de) * 1975-08-23 1977-03-17 Kolloidtechnik Gmbh Verfahren zur aktivierung der naehrstoffaufnahme durch kulturpflanzen und zur aktivierung der biologischen umsetzungen im boden mit hilfe organischer phosphatkolloide
US4174957A (en) * 1978-03-06 1979-11-20 Hydrosoil Corporation Synthetic growing medium and method of preparing it
US4210437A (en) * 1978-12-14 1980-07-01 Standard Oil Company (Indiana) Liquid fertilizer for supply of sulfur, nitrogen and micronutrient metals

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5817600A (en) * 1993-05-01 1998-10-06 British Technology Group Limited Composition for treatment of plant material

Also Published As

Publication number Publication date
NO823241L (no) 1983-03-29
DK427982A (da) 1983-03-29
NO157778B (no) 1988-02-08
FI70403C (fi) 1986-09-19
SE430982B (sv) 1983-12-27
SE8205493L (sv) 1983-03-29
SE8205493D0 (sv) 1982-09-27
FI823306L (fi) 1983-03-29
FI823306A0 (fi) 1982-09-27
NO157778C (no) 1988-06-01
FI70403B (fi) 1986-03-27
SE8105705L (sv) 1983-03-29

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