US4415699A - Extruded profiles - Google Patents

Extruded profiles Download PDF

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Publication number
US4415699A
US4415699A US06/276,640 US27664081A US4415699A US 4415699 A US4415699 A US 4415699A US 27664081 A US27664081 A US 27664081A US 4415699 A US4415699 A US 4415699A
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US
United States
Prior art keywords
composition
polyamide
weight
fibrous filler
extruded
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Expired - Lifetime
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US06/276,640
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English (en)
Inventor
Eric Nield
Martin K. Thompson
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EIDP Inc
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Imperial Chemical Industries Ltd
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Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Assigned to IMPERIAL CHEMICAL INDUSTRIES LIMITED reassignment IMPERIAL CHEMICAL INDUSTRIES LIMITED ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: NIELD, ERIC, THOMPSON, MARTIN K.
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04—Particle-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/05—Filamentary, e.g. strands

Definitions

  • This invention relates to filled compositions consisting of blends of thermoplastic polyesters and polyamides which are suitable for extrusion into profiles having good dimensional tolerance.
  • the use of a high molecular weight nylon is however subject to some disadvantages. The main disadvantage is that it is usually necessary in the preparation of the polyamide to increase the molecular weight of the polyamide after melt polymerisation in the reaction vessel by a further polymerisation process in the solid phase. This further stage adds to the cost of the polyamide for this type of application.
  • an extruded profiled section characterised in that it has been extruded from a composition comprising a blend of a linear polyamide, a linear polyester containing at least 80% by weight of ethylene terephthalate units and an inorganic fibrous filler wherein the composition contains 5 to 60% by weight of the composition of the filler and the weight ratio of polyamide to polyester is between 1:1 and 49:1, preferably between 2:1 and 19:1.
  • the preferred composition used for making the profile should have an MFI of not greater than 2 measured as hereinafter described.
  • the invention also includes a method of extruding a profiled section characterised in that a composition comprising a blend of a linear polyamide, a linear polyester containing at least 80% by weight of ethylene terephthalate units and an inorganic fibrous filler wherein the composition contains 5 to 60% by weight of the composition of the fibrous filler and the weight ratio of polyamide to polyester is between 1:1 and 49:1, preferably between 2:1 and 19:1, is intimately blended and extruded through a die of profiled section.
  • a particularly useful feature of the invention is that the viscosity characteristics of the composition are highly shear dependent. Thus under the high shear conditions pertaining in an extruder the melt viscosity is relatively low and can be processed without difficulty. On the other hand under low shear conditions such as experienced on passing through the profiled die the composition shows a high viscosity. The viscosity characteristics of the composition under low shear stress make the composition ideally suited for extrusion applications where low dimensional tolerances in the extruded profiled section are required.
  • a further surprising feature of the invention is the behaviour of the composition when compared to the same composition not containing glass or other fibrous filler, or when compared to a composition containing a particulate filler.
  • a composition made up of a blend of a polyamide and a polyester has a melt viscosity which shows a slight increase over the individual components but is not sufficiently high for successful profiled extrusion unless the molecular weights of the individual polymer components of the blend are high. As indicated previously this usually requires the use of an additional solid phase polymerisation step.
  • the compositions of the present invention have a melt viscosity which is very much higher than that of the blend of the polymeric constituents alone. In other words the invention provides a material with a melt viscosity high enough for extrusion into profile sections of narrow dimensional tolerance without the necessity of preparing high molecular weight polymers.
  • the polyamides for use in the invention are synthetic polyamides produced by polymerising mono-aminomonocarboxylic acids, or lactams thereof, or a mixture of a diamine and a dicarboxylic acid.
  • Suitable mono-aminomonocarboxylic acids or lactams thereof are, for example ⁇ -aminocaproic acid, caprolactam, 9-aminononanoic acid, 11-aminoundecanoic acid, 17-aminoheptadecanoic acid, dodecanolactam, capryllactam and enantholactam.
  • Preferred diamines are of general formula H 2 N(CH 2 ) m NH 2 wherein m is an integer of from 2 to 12 such as trimethylene diamine, tetramethylene diamine, pentamethylene diamine and in particular hexamethylene diamine.
  • Preferred dicarboxylic acids are of the formula HOOC.Y.COOH wherein Y is a divalent aliphatic radical containing at least 2 carbon atoms for example sebacic acid, octadecanoic acid, suberic acid, azelaic acid, undecanoic acid, glutaric acid, pimelic acid and in particular adipic acid.
  • Preferred polyamides are those known as nylon 6 (a polymer of caprolactam), nylon 66 (a polymer of hexamethylene adipamide), nylon 610 (a polymer of hexamethylene sebacamide), nylon 11 (a polymer of undecanolactam) and nylon 12 (a polymer of dodecanolactam). Mixtures of polyamides and copolymers formed from the monomers described are also included within the term "polyamide” as used in this specification. It is preferred that the polyamides should contain an excess of terminal amine groups over the number of terminal carboxyl groups. The melt viscosity of the composition is particularly high when the polyamide of the composition contains at least 20 g equivalents of terminal amino groups per 10 6 g of polyamide in excess of the carboxyl groups.
  • thermoplastics composition suitable for extrusion into extruded profiled sections comprising a blend of a linear polyamide, a linear polyester containing at least 80% by weight of ethylene terephthalate units, and an inorganic fibrous filler characterised in that the composition contains from 5 to 60% by weight of the composition of the inorganic fibrous filler, the weight ratio of polyamide to polyester is between 1:1 and 49:1, preferably between 2:1 and 19:1 and wherein the polyamide contains an excess, preferably at least 20 g equivalents of terminal amino groups per 10 6 g of polyamide in excess of the carboxyl groups.
  • polyesters suitable for use in the invention are linear thermoplastic polyesters containing at least 80% by weight of ethylene terephthalate units. Surprisingly, when polyesters consisting predominantly of tetramethylene terephthalate units are used in place of the ethylene terephthalate polymer unusually high viscosities are not obtained.
  • the inorganic fibrous filler for use in the invention is preferably glass fibre. Although finely divided mineral fillers have only a slight effect they may be present in addition to the fibrous filler. Suitable mineral fillers are glass ballotini, kaolin, mica, calcined clay, wollastonite and talc.
  • the concentration of fibrous filler should be between 15 and 45% by weight of the composition, particularly when glass fibre is used.
  • the composition of the invention can be made by a simple blending process in which granules of the polyamide and the polyester and inorganic fibres, for example, glass fibres of nominal length of, say, 3 mm are tumble blended. Such a composition may then be fed directly to the extruder where an intimate molten mixture of the polymeric ingredients is produced. In the course of this mixing process the glass fibre length will be significantly reduced. Alternatively, to avoid any problems of segregation of the glass fibre from the composition the glass may be incorporated in one or both of the polymeric components so that a dry blend of the two types of polymer granule can be employed. In preferred compositions containing about 30% by weight of the composition of glass fibre it is clearly easier to incorporate the glass fibre in the major polymer component, namely the polyamide.
  • compositions by a process in which the ingredients are compounded together under melt conditions in a screw extruder and the product extruded as lace which is subsequently cut into granules.
  • granules containing an intimate blend of the polyamide, the polyester and, for example, glass fibre provide a very suitable feed composition for extrusion of profiled section.
  • the glass fibre length in these completely compounded granules ranges from about 0.1 mm up to about 1.5 mm or more, with an average fibre length generally in the region 0.2 to 0.4 mm.
  • compositions containing the ingredients listed in Table 1 were prepared by compounding in a single screw extruder at a nominal melt temperature of 285° C.
  • the melt flow index of the compositions were determined according to ASTM-D 1238 using a standard die of bore 2.096 mm, length of 8 mm and a load of 2.16 kg at a temperature of 285° C.
  • the melt flow indices for the nylon and polyester used in the compositions were 43 and 66 respectively.
  • the nylon 66 used in the composition contained approximately equal numbers of amine and carboxyl end-groups.
  • the glass filled nylon/PET compositions listed in Table 1 were all suitable for producing profiled extrusions of good dimensional tolerance.
  • a profile suitable as a thermal barrier in double-glazed aluminum framed windows was extruded through a die of appropriate profile without using conventional sizing means using compositions A, D, F and K. Profiles from compositions D, F and K had significantly greater dimensional tolerance than the profile from composition A in that the dimensions more closely matched the profile of the die.
  • the blend was passed through a 2 inch diameter single screw extruder with a 311/2:1 length/diameter ratio and equipped with a devolatilisation zone to which vacuum was applied.
  • the barrel heating zones were set at 300° C. and the screw speed was 120 rpm.
  • a single cylindrical lace was extruded which was cooled in a water bath and cut into pellets.
  • the melt flow index of the product was measured after vacuum oven drying for 18 hours at 90° C.
  • the test conditions were, temperature 285° C., weight 2.16 kg and die 2.096 mm diameter, 8 mm length.
  • Example 1 The procedure of Example 1 was used to evaluate the effect of glass beads and the plate-like filler mica in comparison with glass fibre in the compositions of the invention. Table 3 below records the compositions produced.
  • the nylon 66 used in the composition contained 45 g equivalents of amine end-groups per 10 6 g polyamide in excess of the carboxyl groups.
  • the poly(ethylene terephthalate) was the same as that used in Example 1.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
US06/276,640 1980-07-14 1981-06-23 Extruded profiles Expired - Lifetime US4415699A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8022949 1980-07-14
GB8022949 1980-07-14

Publications (1)

Publication Number Publication Date
US4415699A true US4415699A (en) 1983-11-15

Family

ID=10514743

Family Applications (2)

Application Number Title Priority Date Filing Date
US06/276,640 Expired - Lifetime US4415699A (en) 1980-07-14 1981-06-23 Extruded profiles
US06/276,641 Expired - Lifetime US4414358A (en) 1980-07-14 1981-06-23 Filled compositions of thermoplastic polyamide and polyester

Family Applications After (1)

Application Number Title Priority Date Filing Date
US06/276,641 Expired - Lifetime US4414358A (en) 1980-07-14 1981-06-23 Filled compositions of thermoplastic polyamide and polyester

Country Status (9)

Country Link
US (2) US4415699A (enrdf_load_stackoverflow)
EP (1) EP0044141B1 (enrdf_load_stackoverflow)
JP (1) JPS5749657A (enrdf_load_stackoverflow)
AT (1) ATE12785T1 (enrdf_load_stackoverflow)
AU (1) AU537095B2 (enrdf_load_stackoverflow)
CA (2) CA1166377A (enrdf_load_stackoverflow)
DE (1) DE3169961D1 (enrdf_load_stackoverflow)
NZ (1) NZ197489A (enrdf_load_stackoverflow)
ZA (1) ZA814372B (enrdf_load_stackoverflow)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4562221A (en) * 1983-06-30 1985-12-31 Mitsubishi Rayon Co., Ltd. Polyamide resin composition excellent in plate adhesion
EP0331001A1 (de) * 1988-02-27 1989-09-06 BASF Aktiengesellschaft Thermoplastische Formmassen auf der Basis von Polyamiden
US4879341A (en) * 1987-06-03 1989-11-07 Ube Industries, Ltd. Polyester/polyamide resin compositions containing grafted polyolefin and molded products thereof

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6030706B2 (ja) * 1982-07-21 1985-07-18 宇部興産株式会社 ポリアミド組成物
JPS59143688A (ja) * 1983-02-07 1984-08-17 Toray Ind Inc 印刷用制電性スクリーン紗
DE3640875A1 (de) * 1986-11-29 1988-06-09 Basf Ag Thermoplastische formmassen auf der basis von polycarbonaten, polyestern und polyamiden
CA1335008C (en) * 1987-12-08 1995-03-28 Tetsuo Hamada Polyamide composition
JP2544645Y2 (ja) * 1989-05-24 1997-08-20 株式会社ニフコ 自動車の窓用モールディングの係止クリップ
DE3926895A1 (de) * 1989-08-16 1991-02-21 Basf Ag Flammfeste thermoplastische formmassen auf der basis von polyamiden und polyester-elastomeren
DE4127720A1 (de) * 1991-08-22 1993-02-25 Basf Ag Fliessfaehige thermoplastische formmassen
US6589653B2 (en) 2001-08-08 2003-07-08 E. I. Du Pont De Nemours And Company Filament having a quadrilobate exterior cross-section and a four-sided void
ATE496090T1 (de) * 2006-08-23 2011-02-15 Basf Se Polyamidformmassen mit verbesserter wärmealterungs- und hydrolysebeständigkeit

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3553288A (en) * 1966-01-29 1971-01-05 Teijin Ltd Polyamide-polyester composition of improved physical properties
US3644271A (en) * 1970-03-02 1972-02-22 Ethyl Corp Composition and process for injection molding thermoplastic material and glass fibers
GB1280780A (en) 1969-12-31 1972-07-05 Snia Viscosa Improvements in or relating to moulding compositions
JPS485791U (enrdf_load_stackoverflow) * 1971-03-02 1973-01-23
US4013613A (en) * 1971-10-01 1977-03-22 General Electric Company Reinforced intercrystalline thermoplastic polyester compositions
US4229340A (en) * 1979-08-27 1980-10-21 Celanese Corporation Glass fiber-reinforced polyethylene terephthalate/polyamide blends

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH529187A (it) * 1969-12-31 1972-10-15 Snia Viscosa Composizione da stampaggio e procedimento per la fabbricazione della stessa
JPS5740168B2 (enrdf_load_stackoverflow) * 1974-05-21 1982-08-25
JPS5154657A (en) * 1974-11-07 1976-05-13 Toray Industries Nannensei nosugureta horiamidososeibutsu
JPS51105355A (ja) * 1975-03-13 1976-09-17 Toray Industries Netsukasoseijushisoseibutsu
JPS6031222B2 (ja) * 1977-05-30 1985-07-20 ユニチカ株式会社 難燃性樹脂組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3553288A (en) * 1966-01-29 1971-01-05 Teijin Ltd Polyamide-polyester composition of improved physical properties
GB1280780A (en) 1969-12-31 1972-07-05 Snia Viscosa Improvements in or relating to moulding compositions
US3644271A (en) * 1970-03-02 1972-02-22 Ethyl Corp Composition and process for injection molding thermoplastic material and glass fibers
JPS485791U (enrdf_load_stackoverflow) * 1971-03-02 1973-01-23
US4013613A (en) * 1971-10-01 1977-03-22 General Electric Company Reinforced intercrystalline thermoplastic polyester compositions
US4229340A (en) * 1979-08-27 1980-10-21 Celanese Corporation Glass fiber-reinforced polyethylene terephthalate/polyamide blends

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Chemical Abstracts, vol. 84, No. 20, 1976, p. 54, Abstract 136732g. *
Columbus, Ohio (US) & J-A-75 148 496 (Dainippon Ink & Chemicals), 2-11-1975 (Abstract). *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4562221A (en) * 1983-06-30 1985-12-31 Mitsubishi Rayon Co., Ltd. Polyamide resin composition excellent in plate adhesion
US4879341A (en) * 1987-06-03 1989-11-07 Ube Industries, Ltd. Polyester/polyamide resin compositions containing grafted polyolefin and molded products thereof
EP0331001A1 (de) * 1988-02-27 1989-09-06 BASF Aktiengesellschaft Thermoplastische Formmassen auf der Basis von Polyamiden
US5034450A (en) * 1988-02-27 1991-07-23 Basf Aktiengesellschaft Thermoplastic molding materials based on polyamides and polyester elastomers

Also Published As

Publication number Publication date
EP0044141A3 (en) 1982-02-03
AU7213181A (en) 1982-01-21
ATE12785T1 (de) 1985-05-15
EP0044141A2 (en) 1982-01-20
EP0044141B1 (en) 1985-04-17
NZ197489A (en) 1983-12-16
JPH0239539B2 (enrdf_load_stackoverflow) 1990-09-06
CA1166377A (en) 1984-04-24
DE3169961D1 (en) 1985-05-23
ZA814372B (en) 1982-07-28
JPS5749657A (en) 1982-03-23
AU537095B2 (en) 1984-06-07
US4414358A (en) 1983-11-08
CA1165962A (en) 1984-04-24

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