US3893955A - Aqueous concentrate detergent component - Google Patents
Aqueous concentrate detergent component Download PDFInfo
- Publication number
- US3893955A US3893955A US298989A US29898972A US3893955A US 3893955 A US3893955 A US 3893955A US 298989 A US298989 A US 298989A US 29898972 A US29898972 A US 29898972A US 3893955 A US3893955 A US 3893955A
- Authority
- US
- United States
- Prior art keywords
- acid
- sulphate
- salt
- concentrate
- concentrate according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000012141 concentrate Substances 0.000 title claims abstract description 72
- 239000003599 detergent Substances 0.000 title description 7
- 150000003839 salts Chemical class 0.000 claims abstract description 48
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 30
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002253 acid Substances 0.000 claims abstract description 11
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 11
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims abstract description 10
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims abstract description 10
- 235000015165 citric acid Nutrition 0.000 claims abstract description 10
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims abstract description 10
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011975 tartaric acid Substances 0.000 claims abstract description 9
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 8
- 235000019253 formic acid Nutrition 0.000 claims abstract description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 5
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims abstract description 5
- NAOLWIGVYRIGTP-UHFFFAOYSA-N 1,3,5-trihydroxyanthracene-9,10-dione Chemical compound C1=CC(O)=C2C(=O)C3=CC(O)=CC(O)=C3C(=O)C2=C1 NAOLWIGVYRIGTP-UHFFFAOYSA-N 0.000 claims abstract description 5
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims abstract description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract description 5
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims abstract description 5
- RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 claims abstract description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims abstract description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000174 gluconic acid Substances 0.000 claims abstract description 5
- 235000012208 gluconic acid Nutrition 0.000 claims abstract description 5
- 239000004310 lactic acid Substances 0.000 claims abstract description 5
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 5
- 239000011976 maleic acid Substances 0.000 claims abstract description 5
- 239000001630 malic acid Substances 0.000 claims abstract description 5
- 235000011090 malic acid Nutrition 0.000 claims abstract description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 5
- 239000001384 succinic acid Substances 0.000 claims abstract description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 47
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 45
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 43
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- -1 alkyl ether sulphate Chemical class 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 7
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 14
- 150000001298 alcohols Chemical class 0.000 abstract description 13
- 239000012895 dilution Substances 0.000 abstract description 10
- 238000010790 dilution Methods 0.000 abstract description 10
- 238000009472 formulation Methods 0.000 abstract description 8
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract description 5
- 239000002453 shampoo Substances 0.000 abstract description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 9
- 125000001931 aliphatic group Chemical group 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000013020 final formulation Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000051 modifying effect Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- FKKAGFLIPSSCHT-UHFFFAOYSA-N 1-dodecoxydodecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC FKKAGFLIPSSCHT-UHFFFAOYSA-N 0.000 description 1
- BCFOOQRXUXKJCL-UHFFFAOYSA-N 4-amino-4-oxo-2-sulfobutanoic acid Chemical class NC(=O)CC(C(O)=O)S(O)(=O)=O BCFOOQRXUXKJCL-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- MSJMDZAOKORVFC-UAIGNFCESA-L disodium maleate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C/C([O-])=O MSJMDZAOKORVFC-UAIGNFCESA-L 0.000 description 1
- 235000019524 disodium tartrate Nutrition 0.000 description 1
- IZZSMHVWMGGQGU-UHFFFAOYSA-L disodium;2-methylidenebutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(=C)C([O-])=O IZZSMHVWMGGQGU-UHFFFAOYSA-L 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
Definitions
- ABSTRACT Concentrates of sulphates of alkoxylated alcohols are diluted only with difficulty as a result of a viscosity peak being encountered during the dilution.
- a water soluble salt of an acid of the general formula A(COOH) is incorporated in the concentrate.
- said acid is one of the following: Glycollic acid, lactic acid, malic acid, glyceric acid, tartaric acid, citric acid, gluconic acid, saccharic acid, formic acid, acetic acid, butyric acid, oxalic acid, maleic acid, succinic acid or itaconic acid.
- the formulations may be employed in shampoos.
- the present invention relates to detergent components, in particular it relates to the sulphates of alkoxylated alcohols in particular to sulphates of alkoxylated C to C alcohols such as sulphated ethoxylated lauryl alcohol or mixtures containing lauryl alcohol derivatives.
- alkoxylated alcohols such as sulphated ethoxylated lauryl alcohol or mixtures containing lauryl alcohol derivatives.
- the alkyl derivative has a chain with a carbon number ranging from C to C
- Such a feedstock can readily be obtained from coconut or PK oil, or commercially available Ziegler or oxo alcohols.
- Aqueous solutions of these compounds are employed in cosmetic, toiletry and detergent compositions for example shampoos and bubble baths and liquid cleaning compositions. Normally these materials are supplied at 29% active ingredient but in the interests of economy in transport and packaging high concentrations of the order to 50 70% are also commercially available. At these high concentrations they have the texture of a thick paste. In the final formulation they are normally present in an amount less than 30% active in an aqueous solution.
- viscosity modifiers have been incorporated in aqueous concentrates of sulphates of ethoxylated alcohol so as to maintain the viscosity of a solution at high concentrations at a level such that the solutions are reasonably free flowing and are easily diluted to any required concentration.
- any additive employed should not prevent or hinder the effect of thickeners conventionally used such as sodium chloride or ammonium salts, which it may be desired to incorporate in the finished formulation in order to give it an acceptable consis' tency.
- A is hydrogen or a saturated or unsaturated aliphatic residue having from I to 8 carbon atoms, optionally containing hydroxy substituents or may be nothing if n is 2, and n is an integer from 1 to 4. Normally the residue A will have no more than 5 hydroxy substituents.
- the present invention provides an aqueous concentrate comprising at least 30% preferably 50% by weight of a sulphate of an alkoxylated alcohol and from 1 10% preferably 2 4% by weight of a salt of an aliphatic carboxylic acids hereinbefore defined.
- Concentrates which are particularly suitable for modification according to the present invention are normally commercially available materials such as the sodium salt of the sulphate of an ethoxylated commercial lauryl alcohol having nominally l 4 oxyethylene groups.
- Commercial lauryl alcohol is normally a mixture of compounds having an average chain length of about 12 carbon atoms.
- Other compounds such as the equivalent propoxylated derivatives or mixed ethoylated propoxylated derivatives or the derivatives of other C C15 alcohols may also be employed.
- Such compounds are frequently in the form of their sodium salts although concentrates according to the invention may also be of use for salts such as potassium, magnesium, lithium, ammonium or alkylolamine salts.
- detergent sulphosuccinates sulphosuccinamates, alkyl sulphate salts or nonionic surface active agents such as polyoxy alkylene ethers and esters.
- the concentrate according to the invention may be diluted by the formulator at any convenient temperature, preferably in the range l5- 70C, to the final concentration required for the formulation. After such dilution other ingredients required for the final product may also be added as desired.
- the present invention comprises making an aqueous solution of a sulphated ethoxylated alcohol as previously described of a concentration below 30% by weight by the addition of water to an aqueous concentrate having a content of at least 30% 30% weight of the sulphated ethoxylated alcohol and from 1 10% by weight of a salt of an aliphatic hydroxylic carboxylic acid.
- compositions according to the invention are illustrated by the following examples.
- EXAMPLE 4 Commercial sodium lauryl ether sulphate was prepared at a concentration of 50% by neutralising lauryl ether sulphuric acid with aqueous sodium hydroxide in a continuous mixer. The product was a gel having a viscosity of 200,000 cp.
- the product was a free flowing mobile liquid crystalline system having a viscosity of 10,000 cp when measured by the procedure given in Example 1.
- An aqueous concentrate comprising 30-75% by weight of a sulphate of an alkoxylated aliphatic C -C alcohol and form 2 to l0% by weight of a water soluble salt of a carboxylic acid of the general formula A (COOH), wherein n is an integer of l to 4, and A is selected from the group consisting of hydrogen, a saturated aliphatic residue having from 1 to 8 carbon atoms, an unsaturated aliphatic residue of 2 to 8 carbon atoms, and when n is 2 the said formula also may be (COOH) 2.
- a concentrate according to claim 3 wherein said salt is a salt of an acid selected from the group consisting of glycollic acid, lactic acid, malic acid, glyceric acid, tartaric acid, citric acid, gluconic acid or saccharic acid.
- a concentrate according to claim 1 wherein said salt is a salt of an acid selected from the group consist ing of formic acid, acetic acid, butyric acid, oxalic acid, maleic acid, succinic acid or itaconic acid.
- a concentrate according to claim 3 wherein the sulphate of the alkoxylated alcohol is the sulphate of the reaction product of from 1 to 4 mols of ethylene oxide per mole of commercial lauryl alcohol.
- a concentrate according to claim 5 wherein the sulphate of the alkoxylated alcohol is the sulphate of the reaction product of from 1 to 4 mols of ethylene oxide per mole of commercial lauryl alcohol.
- a concentrate according to claim 2 which also contains sodium chloride or sodium sulphate in an amount of up to 10 by weight of the alkyl ether sulphate.
- a concentrate according to claim 3 which contains free alkoxylated alcohol.
- a concentrate according to claim 5 which contains free alkoxylated alcohol.
- a concentrate according to claim 1 which contains at least 50% by weight of sulphate of alkoxylated alcohol.
- a concentrate according to claim 14 wherein said water-soluble salt of a carboxylic acid is a salt of citric acid; wherein said sulphate of the alkoxylated alcohol is the sulphate of the reaction product of from 1 to 4 moles of ethylene oxide per mole of commercial lauryl alcohol; and wherein said concentrate contains at least 50% by weight of said sulphate of alkoxylated alcohol.
- a concentrate according to claim 1 which does not contain isopropyl alcohol or ethanol in amounts sufficient to render said concentrate free-flowing in the absence of said salt.
- a free-flowing aqueous concentrate comprising an admixture of i. between 2 and 10% by weight of a water soluble salt of a carboxylic acid of general formula A(- COOH),., wherein n is an integer of l to 4, and A is selected from the group consisting of hydrogen, a saturated aliphatic residue of l to 8 carbon atoms, an unsaturated aliphatic residue of 2 to 8 carbon atoms, and when n is 2, the said formula also may be (COOH) and ii.
- an aqueous concentrate comprising between 30 and by weight of a sulphate of an alkoxylated aliphatic C -C alcohol which aqueous concentrate would be a thick paste or gel in the absence of admixture with component (i). 19.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4869971 | 1971-10-20 | ||
| GB2505172*[A GB1399339A (en) | 1971-10-20 | 1972-05-26 | Detergent components |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3893955A true US3893955A (en) | 1975-07-08 |
Family
ID=26257460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US298989A Expired - Lifetime US3893955A (en) | 1971-10-20 | 1972-10-19 | Aqueous concentrate detergent component |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3893955A (enrdf_load_stackoverflow) |
| JP (1) | JPS5550997B2 (enrdf_load_stackoverflow) |
| BE (1) | BE790362A (enrdf_load_stackoverflow) |
| CA (1) | CA1001553A (enrdf_load_stackoverflow) |
| DE (1) | DE2251405A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2156825B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1399339A (enrdf_load_stackoverflow) |
| IT (1) | IT996557B (enrdf_load_stackoverflow) |
| NL (1) | NL7214082A (enrdf_load_stackoverflow) |
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3957671A (en) * | 1974-11-13 | 1976-05-18 | The Procter & Gamble Company | Acid mix compositions containing benzoic acid |
| US4003857A (en) * | 1973-12-17 | 1977-01-18 | Ethyl Corporation | Concentrated aqueous olefins sulfonates containing carboxylic acid salt anti-gelling agents |
| US4092273A (en) * | 1974-10-03 | 1978-05-30 | Colgate-Palmolive Company | Liquid detergent of controlled viscosity |
| EP0008060A1 (de) * | 1978-08-03 | 1980-02-20 | BASF Aktiengesellschaft | Verwendung von mehrwertigen Alkoholen, (Hydroxy)carbonsäuren und/oder deren Estern mit den mehrwertigen Alkoholen als Viskositätsregler |
| US4259216A (en) * | 1979-10-11 | 1981-03-31 | The Lion Fat & Oil Co., Ltd. | Process for producing liquid detergent composition |
| US4294718A (en) * | 1980-03-10 | 1981-10-13 | Colgate-Palmolive Company | Non-gelling inorganic salt crutcher slurries |
| US4298493A (en) * | 1979-10-04 | 1981-11-03 | Colgate-Palmolive Company | Method for retarding gelation of bicarbonate-carbonate-silicate crutcher slurries |
| US4305837A (en) * | 1980-10-30 | 1981-12-15 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| US4311607A (en) * | 1980-03-10 | 1982-01-19 | Colgate Palmolive Company | Method for manufacture of non-gelling, stable zeolite - inorganic salt crutcher slurries |
| US4311606A (en) * | 1980-03-10 | 1982-01-19 | Colgate Palmolive Company | Method for manufacture of non-gelling, stable inorganic salt crutcher slurries |
| US4318818A (en) * | 1979-11-09 | 1982-03-09 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| US4321156A (en) * | 1977-03-30 | 1982-03-23 | S. C. Johnson & Son, Inc. | Shampoo composition |
| US4368134A (en) * | 1980-03-10 | 1983-01-11 | Colgate Palmolive Company | Method for retarding gelation of bicarbonate-carbonate-zeolite-silicate crutcher slurries |
| US4368147A (en) * | 1974-10-03 | 1983-01-11 | Colgate-Palmolive Company | Liquid detergent of controlled viscosity |
| US4375421A (en) * | 1981-10-19 | 1983-03-01 | Lever Brothers Company | Viscous compositions containing amido betaines and salts |
| US4384978A (en) * | 1979-09-01 | 1983-05-24 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous concentrates of a tenside of the sulfate and sulfonate type and process for the improvement of the flow behavior of difficultly pourable aqueous tenside concentrates |
| US4412943A (en) * | 1981-02-23 | 1983-11-01 | Kao Soap Co., Ltd. | Liquid detergent composition |
| US4482470A (en) * | 1981-12-28 | 1984-11-13 | Henkel Kommanditgesellschaft Auf Aktien | Viscosity modifiers for concentrated surfactants |
| US4532076A (en) * | 1982-02-11 | 1985-07-30 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous anionic surfactant concentrates containing viscosity reducing agents |
| US4675128A (en) * | 1984-12-31 | 1987-06-23 | Henkel Kommanditgesellschaft Auf Aktien | Alkane sulfonates as viscosity regulators |
| US4732703A (en) * | 1984-02-16 | 1988-03-22 | Lever Brothers Company | Liquid detergent compositions containing stabilizers to prevent phase separation |
| US4744916A (en) * | 1985-07-18 | 1988-05-17 | Colgate-Palmolive Company | Non-gelling non-aqueous liquid detergent composition containing higher fatty dicarboxylic acid and method of use |
| US5057246A (en) * | 1986-07-25 | 1991-10-15 | Cotelle S.A. | Viscous detergent composition capable of being diluted and process for producing it |
| US5415798A (en) * | 1994-01-14 | 1995-05-16 | Betz Paperchem Inc. | Concentrated high flash point surfactant compositions |
| US5474713A (en) * | 1994-03-23 | 1995-12-12 | Amway Corporation | High actives cleaning compositions and methods of use |
| US5620952A (en) * | 1992-03-16 | 1997-04-15 | The Procter & Gamble Company | Fluid compositions containing polyhydroxy fatty acid amides |
| US5922664A (en) * | 1995-01-30 | 1999-07-13 | Colgate-Palmolive Co. | Pourable detergent concentrates which maintain or increase in viscosity after dilution with water |
| WO2012126630A1 (en) * | 2011-03-24 | 2012-09-27 | Sasol Germany Gmbh | Highly-concentrated flowable salts of alkyl polyalkoxy sulphates |
| EP3004305B1 (en) | 2013-05-24 | 2021-01-13 | The Procter and Gamble Company | Concentrated surfactant composition |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50116383A (enrdf_load_stackoverflow) * | 1973-10-29 | 1975-09-11 | ||
| GB1547361A (en) * | 1975-03-24 | 1979-06-13 | Unilever Ltd | Hair shampoos |
| GB1569617A (en) * | 1976-03-08 | 1980-06-18 | Procter & Gamble | Liquid detergent composition |
| DE2853136C3 (de) * | 1977-12-09 | 1994-04-14 | Albright & Wilson | Wäßriges, oberflächenaktives Mittel |
| JPS5647496A (en) * | 1979-09-26 | 1981-04-30 | Asahi Denka Kogyo Kk | Liquid detergent composition |
| DE3542970A1 (de) * | 1985-12-05 | 1987-06-11 | Benckiser Gmbh Joh A | Fluessige sanitaerreinigungs- und entkalkungsmittel und verfahren zu deren herstellung |
| DE4019172A1 (de) * | 1990-06-15 | 1991-12-19 | Henkel Kgaa | Verwendung von salzen der sulfonierungsprodukte ungesaettigter fettsaeuren als viskositaetsminderer |
| DE4032909A1 (de) * | 1990-10-17 | 1992-04-23 | Henkel Kgaa | Verfahren zur herstellung von alkylsulfatpasten mit verbesserter fliessfaehigkeit |
| ATE522594T1 (de) * | 2008-06-02 | 2011-09-15 | Procter & Gamble | Tensidkonzentrat |
| WO2014072840A1 (en) | 2012-11-12 | 2014-05-15 | Galaxy Surfactants Ltd. | Flowable, high active, aqueous fatty alkyl sulfates |
| WO2025076732A1 (en) * | 2023-10-11 | 2025-04-17 | The Procter & Gamble Company | A biodegradable flexible package with a personal care composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2941950A (en) * | 1954-09-30 | 1960-06-21 | Procter & Gamble | Concentrated liquid detergent |
| US3038862A (en) * | 1957-05-21 | 1962-06-12 | Chemische Fabriek Andrelon Nv | Shampoo composition |
| US3574125A (en) * | 1966-12-29 | 1971-04-06 | Chem Y | Detergent concentrate |
| US3661787A (en) * | 1970-10-09 | 1972-05-09 | Pollutrol Group The | Saturated aliphatic dicarboxylic acid salts as detergent builders |
-
0
- BE BE790362D patent/BE790362A/xx unknown
-
1972
- 1972-05-26 GB GB2505172*[A patent/GB1399339A/en not_active Expired
- 1972-10-18 NL NL7214082A patent/NL7214082A/xx not_active Application Discontinuation
- 1972-10-19 US US298989A patent/US3893955A/en not_active Expired - Lifetime
- 1972-10-19 IT IT70282/72A patent/IT996557B/it active
- 1972-10-19 DE DE2251405A patent/DE2251405A1/de active Pending
- 1972-10-19 FR FR7237066A patent/FR2156825B1/fr not_active Expired
- 1972-10-20 JP JP10517872A patent/JPS5550997B2/ja not_active Expired
- 1972-10-20 CA CA154,628A patent/CA1001553A/en not_active Expired
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2941950A (en) * | 1954-09-30 | 1960-06-21 | Procter & Gamble | Concentrated liquid detergent |
| US3038862A (en) * | 1957-05-21 | 1962-06-12 | Chemische Fabriek Andrelon Nv | Shampoo composition |
| US3574125A (en) * | 1966-12-29 | 1971-04-06 | Chem Y | Detergent concentrate |
| US3661787A (en) * | 1970-10-09 | 1972-05-09 | Pollutrol Group The | Saturated aliphatic dicarboxylic acid salts as detergent builders |
Cited By (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4003857A (en) * | 1973-12-17 | 1977-01-18 | Ethyl Corporation | Concentrated aqueous olefins sulfonates containing carboxylic acid salt anti-gelling agents |
| US4092273A (en) * | 1974-10-03 | 1978-05-30 | Colgate-Palmolive Company | Liquid detergent of controlled viscosity |
| US4368147A (en) * | 1974-10-03 | 1983-01-11 | Colgate-Palmolive Company | Liquid detergent of controlled viscosity |
| US3957671A (en) * | 1974-11-13 | 1976-05-18 | The Procter & Gamble Company | Acid mix compositions containing benzoic acid |
| US4321156A (en) * | 1977-03-30 | 1982-03-23 | S. C. Johnson & Son, Inc. | Shampoo composition |
| US4239641A (en) * | 1978-08-03 | 1980-12-16 | Basf Aktiengesellschaft | Use of polyhydric alcohols, carboxylic acids, hydroxy-carboxylic acids and/or their esters with polyhydric alcohols as viscosity regulators |
| EP0008060A1 (de) * | 1978-08-03 | 1980-02-20 | BASF Aktiengesellschaft | Verwendung von mehrwertigen Alkoholen, (Hydroxy)carbonsäuren und/oder deren Estern mit den mehrwertigen Alkoholen als Viskositätsregler |
| US4384978A (en) * | 1979-09-01 | 1983-05-24 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous concentrates of a tenside of the sulfate and sulfonate type and process for the improvement of the flow behavior of difficultly pourable aqueous tenside concentrates |
| US4476037A (en) * | 1979-09-01 | 1984-10-09 | Henkel Kommanditgesellschaft Auf Aktien | Free flow, readily dilutable aqueous concentrates of a tenside of the sulfate and sulfonate type |
| US4298493A (en) * | 1979-10-04 | 1981-11-03 | Colgate-Palmolive Company | Method for retarding gelation of bicarbonate-carbonate-silicate crutcher slurries |
| US4259216A (en) * | 1979-10-11 | 1981-03-31 | The Lion Fat & Oil Co., Ltd. | Process for producing liquid detergent composition |
| US4318818A (en) * | 1979-11-09 | 1982-03-09 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| US4294718A (en) * | 1980-03-10 | 1981-10-13 | Colgate-Palmolive Company | Non-gelling inorganic salt crutcher slurries |
| US4311607A (en) * | 1980-03-10 | 1982-01-19 | Colgate Palmolive Company | Method for manufacture of non-gelling, stable zeolite - inorganic salt crutcher slurries |
| US4311606A (en) * | 1980-03-10 | 1982-01-19 | Colgate Palmolive Company | Method for manufacture of non-gelling, stable inorganic salt crutcher slurries |
| US4368134A (en) * | 1980-03-10 | 1983-01-11 | Colgate Palmolive Company | Method for retarding gelation of bicarbonate-carbonate-zeolite-silicate crutcher slurries |
| US4305837A (en) * | 1980-10-30 | 1981-12-15 | The Procter & Gamble Company | Stabilized aqueous enzyme composition |
| US4412943A (en) * | 1981-02-23 | 1983-11-01 | Kao Soap Co., Ltd. | Liquid detergent composition |
| US4375421A (en) * | 1981-10-19 | 1983-03-01 | Lever Brothers Company | Viscous compositions containing amido betaines and salts |
| US4482470A (en) * | 1981-12-28 | 1984-11-13 | Henkel Kommanditgesellschaft Auf Aktien | Viscosity modifiers for concentrated surfactants |
| US4532076A (en) * | 1982-02-11 | 1985-07-30 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous anionic surfactant concentrates containing viscosity reducing agents |
| US4732703A (en) * | 1984-02-16 | 1988-03-22 | Lever Brothers Company | Liquid detergent compositions containing stabilizers to prevent phase separation |
| US4675128A (en) * | 1984-12-31 | 1987-06-23 | Henkel Kommanditgesellschaft Auf Aktien | Alkane sulfonates as viscosity regulators |
| US4744916A (en) * | 1985-07-18 | 1988-05-17 | Colgate-Palmolive Company | Non-gelling non-aqueous liquid detergent composition containing higher fatty dicarboxylic acid and method of use |
| AU591146B2 (en) * | 1985-07-18 | 1989-11-30 | Colgate-Palmolive Company, The | Non-gelling liquid detergent composition containing higher fatty dicarboxylic acid and method of use |
| US5057246A (en) * | 1986-07-25 | 1991-10-15 | Cotelle S.A. | Viscous detergent composition capable of being diluted and process for producing it |
| US5620952A (en) * | 1992-03-16 | 1997-04-15 | The Procter & Gamble Company | Fluid compositions containing polyhydroxy fatty acid amides |
| US5415798A (en) * | 1994-01-14 | 1995-05-16 | Betz Paperchem Inc. | Concentrated high flash point surfactant compositions |
| EP0663237A1 (en) * | 1994-01-14 | 1995-07-19 | Betz Europe, Inc. | Concentrated high flash point surfactant compositions |
| US5474713A (en) * | 1994-03-23 | 1995-12-12 | Amway Corporation | High actives cleaning compositions and methods of use |
| US5922664A (en) * | 1995-01-30 | 1999-07-13 | Colgate-Palmolive Co. | Pourable detergent concentrates which maintain or increase in viscosity after dilution with water |
| WO2012126630A1 (en) * | 2011-03-24 | 2012-09-27 | Sasol Germany Gmbh | Highly-concentrated flowable salts of alkyl polyalkoxy sulphates |
| EP3004305B1 (en) | 2013-05-24 | 2021-01-13 | The Procter and Gamble Company | Concentrated surfactant composition |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2156825B1 (enrdf_load_stackoverflow) | 1977-04-01 |
| CA1001553A (en) | 1976-12-14 |
| AU4791572A (en) | 1974-04-26 |
| BE790362A (fr) | 1973-02-15 |
| FR2156825A1 (enrdf_load_stackoverflow) | 1973-06-01 |
| NL7214082A (enrdf_load_stackoverflow) | 1973-04-25 |
| JPS4849808A (enrdf_load_stackoverflow) | 1973-07-13 |
| JPS5550997B2 (enrdf_load_stackoverflow) | 1980-12-22 |
| GB1399339A (en) | 1975-07-02 |
| DE2251405A1 (de) | 1973-04-26 |
| IT996557B (it) | 1975-12-10 |
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