US3884307A - Fire extinguisher - Google Patents
Fire extinguisher Download PDFInfo
- Publication number
- US3884307A US3884307A US414660A US41466073A US3884307A US 3884307 A US3884307 A US 3884307A US 414660 A US414660 A US 414660A US 41466073 A US41466073 A US 41466073A US 3884307 A US3884307 A US 3884307A
- Authority
- US
- United States
- Prior art keywords
- container
- explosive charge
- wall
- fire extinguishing
- opening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 claims abstract description 165
- 239000000126 substance Substances 0.000 claims abstract description 81
- 239000000463 material Substances 0.000 claims abstract description 63
- 238000013467 fragmentation Methods 0.000 claims abstract description 12
- 238000006062 fragmentation reaction Methods 0.000 claims abstract description 12
- 150000003839 salts Chemical class 0.000 claims description 21
- WETZJIOEDGMBMA-UHFFFAOYSA-L lead styphnate Chemical compound [Pb+2].[O-]C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C([O-])=C1[N+]([O-])=O WETZJIOEDGMBMA-UHFFFAOYSA-L 0.000 claims description 13
- IUKSYUOJRHDWRR-UHFFFAOYSA-N 2-diazonio-4,6-dinitrophenolate Chemical compound [O-]C1=C([N+]#N)C=C([N+]([O-])=O)C=C1[N+]([O-])=O IUKSYUOJRHDWRR-UHFFFAOYSA-N 0.000 claims description 9
- 150000001540 azides Chemical class 0.000 claims description 9
- 229910052709 silver Inorganic materials 0.000 claims description 9
- 239000004332 silver Substances 0.000 claims description 9
- ZGZLYKUHYXFIIO-UHFFFAOYSA-N 5-nitro-2h-tetrazole Chemical class [O-][N+](=O)C=1N=NNN=1 ZGZLYKUHYXFIIO-UHFFFAOYSA-N 0.000 claims description 7
- 230000000977 initiatory effect Effects 0.000 claims description 7
- HCSBTDBGTNZOAB-UHFFFAOYSA-N 2,3-dinitrobenzoic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O HCSBTDBGTNZOAB-UHFFFAOYSA-N 0.000 claims description 6
- USXDFAGDIOXNML-UHFFFAOYSA-N Fulminate Chemical compound [O-][N+]#[C-] USXDFAGDIOXNML-UHFFFAOYSA-N 0.000 claims description 6
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- -1 cadmium fulminate Chemical compound 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 4
- 229910052753 mercury Inorganic materials 0.000 claims description 4
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 4
- WTLKTXIHIHFSGU-UHFFFAOYSA-N 2-nitrosoguanidine Chemical compound NC(N)=NN=O WTLKTXIHIHFSGU-UHFFFAOYSA-N 0.000 claims description 3
- AGUIVNYEYSCPNI-UHFFFAOYSA-N N-methyl-N-picrylnitramine Chemical group [O-][N+](=O)N(C)C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O AGUIVNYEYSCPNI-UHFFFAOYSA-N 0.000 claims description 3
- XBDYBAVJXHJMNQ-UHFFFAOYSA-N Tetrahydroanthracene Natural products C1=CC=C2C=C(CCCC3)C3=CC2=C1 XBDYBAVJXHJMNQ-UHFFFAOYSA-N 0.000 claims description 3
- NPKGQBIUYHHPOT-UHFFFAOYSA-N [Cu+2].[C-]#[C-] Chemical compound [Cu+2].[C-]#[C-] NPKGQBIUYHHPOT-UHFFFAOYSA-N 0.000 claims description 3
- RSQMLYLGFXWLTB-UHFFFAOYSA-N [Cu](O[N+]#[C-])O[N+]#[C-] Chemical compound [Cu](O[N+]#[C-])O[N+]#[C-] RSQMLYLGFXWLTB-UHFFFAOYSA-N 0.000 claims description 3
- IMIZIIJWWKDIQJ-UHFFFAOYSA-N [N+](=O)([O-])C1=NN=NN1.[Ag] Chemical class [N+](=O)([O-])C1=NN=NN1.[Ag] IMIZIIJWWKDIQJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Chemical class 0.000 claims description 3
- 150000001447 alkali salts Chemical class 0.000 claims description 3
- NZJRLCPXRZLFGU-UHFFFAOYSA-N azidomercury Chemical class [Hg]N=[N+]=[N-] NZJRLCPXRZLFGU-UHFFFAOYSA-N 0.000 claims description 3
- AMLMJYSFCBXMRG-UHFFFAOYSA-N azidomercury Chemical compound [Hg]N=[N+]=[N-].[Hg]N=[N+]=[N-] AMLMJYSFCBXMRG-UHFFFAOYSA-N 0.000 claims description 3
- UUXFWHMUNNXFHD-UHFFFAOYSA-N barium azide Chemical compound [Ba+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] UUXFWHMUNNXFHD-UHFFFAOYSA-N 0.000 claims description 3
- DOXDQPGIFAJLKV-UHFFFAOYSA-N cadmium(2+);diazide Chemical compound [Cd+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] DOXDQPGIFAJLKV-UHFFFAOYSA-N 0.000 claims description 3
- UETLMBWMVIQIGU-UHFFFAOYSA-N calcium azide Chemical compound [Ca+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] UETLMBWMVIQIGU-UHFFFAOYSA-N 0.000 claims description 3
- XRKZTILYATXYGV-UHFFFAOYSA-N cobalt(2+);diazide Chemical compound [Co+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] XRKZTILYATXYGV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001879 copper Chemical class 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- MHVVRZIRWITSIP-UHFFFAOYSA-L lead(2+);2,4,6-trinitrophenolate Chemical compound [Pb+2].[O-]C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O.[O-]C1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O MHVVRZIRWITSIP-UHFFFAOYSA-L 0.000 claims description 3
- FYDIWJWWROEQCB-UHFFFAOYSA-L lead(2+);propanoate Chemical compound [Pb+2].CCC([O-])=O.CCC([O-])=O FYDIWJWWROEQCB-UHFFFAOYSA-L 0.000 claims description 3
- GUWHRJQTTVADPB-UHFFFAOYSA-N lithium azide Chemical compound [Li+].[N-]=[N+]=[N-] GUWHRJQTTVADPB-UHFFFAOYSA-N 0.000 claims description 3
- WALSOPOKLFYRNK-UHFFFAOYSA-N manganese(2+) diazide Chemical compound [Mn+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] WALSOPOKLFYRNK-UHFFFAOYSA-N 0.000 claims description 3
- TXLLUJCKTQWKKI-UHFFFAOYSA-N mercury;5-nitro-2h-tetrazole Chemical class [Hg].[O-][N+](=O)C=1N=NNN=1 TXLLUJCKTQWKKI-UHFFFAOYSA-N 0.000 claims description 3
- HURPOIVZCDCEEE-UHFFFAOYSA-N n-(2h-tetrazol-5-yl)nitramide Chemical compound [O-][N+](=O)NC=1N=NNN=1 HURPOIVZCDCEEE-UHFFFAOYSA-N 0.000 claims description 3
- JRUBGUVYQMKOMK-UHFFFAOYSA-N nickel(2+) diazide Chemical compound [Ni+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] JRUBGUVYQMKOMK-UHFFFAOYSA-N 0.000 claims description 3
- 150000003891 oxalate salts Chemical class 0.000 claims description 3
- LOMWRVTZROPEGG-UHFFFAOYSA-N potassium fulminate Chemical compound [K+].[O-][N+]#[C-] LOMWRVTZROPEGG-UHFFFAOYSA-N 0.000 claims description 3
- QBFXQJXHEPIJKW-UHFFFAOYSA-N silver azide Chemical compound [Ag+].[N-]=[N+]=[N-] QBFXQJXHEPIJKW-UHFFFAOYSA-N 0.000 claims description 3
- LIXWSNVLHFNXAJ-UHFFFAOYSA-N sodium;oxidoazaniumylidynemethane Chemical compound [Na+].[O-][N+]#[C-] LIXWSNVLHFNXAJ-UHFFFAOYSA-N 0.000 claims description 3
- PDEROVFZLWBVSG-UHFFFAOYSA-N strontium;diazide Chemical compound [Sr+2].[N-]=[N+]=[N-].[N-]=[N+]=[N-] PDEROVFZLWBVSG-UHFFFAOYSA-N 0.000 claims description 3
- QXTCFDCJXWLNAP-UHFFFAOYSA-N sulfidonitrogen(.) Chemical compound S=[N] QXTCFDCJXWLNAP-UHFFFAOYSA-N 0.000 claims description 3
- IFLREYGFSNHWGE-UHFFFAOYSA-N tetracene Chemical compound C1=CC=CC2=CC3=CC4=CC=CC=C4C=C3C=C21 IFLREYGFSNHWGE-UHFFFAOYSA-N 0.000 claims description 3
- 150000004655 tetrazenes Chemical class 0.000 claims description 3
- 150000003536 tetrazoles Chemical class 0.000 claims description 3
- 229910052716 thallium Inorganic materials 0.000 claims description 3
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 3
- GMUSFHMEMWCQIE-UHFFFAOYSA-N thallium azide Chemical compound [Tl+].[N-]=[N+]=[N-] GMUSFHMEMWCQIE-UHFFFAOYSA-N 0.000 claims description 3
- QFDUTPNKBRXHTC-UHFFFAOYSA-N zinc diazide Chemical compound [Zn++].[N-]=[N+]=[N-].[N-]=[N+]=[N-] QFDUTPNKBRXHTC-UHFFFAOYSA-N 0.000 claims description 3
- MHWLNQBTOIYJJP-UHFFFAOYSA-N mercury difulminate Chemical compound [O-][N+]#C[Hg]C#[N+][O-] MHWLNQBTOIYJJP-UHFFFAOYSA-N 0.000 claims description 2
- OUFSJHYBAWNCTB-UHFFFAOYSA-M 3-nitrobenzenediazonium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.[O-][N+](=O)C1=CC=CC([N+]#N)=C1 OUFSJHYBAWNCTB-UHFFFAOYSA-M 0.000 claims 1
- 239000004677 Nylon Substances 0.000 abstract description 4
- 229920001778 nylon Polymers 0.000 abstract description 4
- 238000007906 compression Methods 0.000 abstract description 2
- 230000006835 compression Effects 0.000 abstract description 2
- 239000000843 powder Substances 0.000 description 40
- 239000000020 Nitrocellulose Substances 0.000 description 6
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 6
- 229920001220 nitrocellulos Polymers 0.000 description 6
- 239000000123 paper Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011094 fiberboard Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 235000010420 locust bean gum Nutrition 0.000 description 2
- 239000000711 locust bean gum Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- SATHPVQTSSUFFW-UHFFFAOYSA-N 4-[6-[(3,5-dihydroxy-4-methoxyoxan-2-yl)oxymethyl]-3,5-dihydroxy-4-methoxyoxan-2-yl]oxy-2-(hydroxymethyl)-6-methyloxane-3,5-diol Chemical compound OC1C(OC)C(O)COC1OCC1C(O)C(OC)C(O)C(OC2C(C(CO)OC(C)C2O)O)O1 SATHPVQTSSUFFW-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000001904 Arabinogalactan Substances 0.000 description 1
- 229920000189 Arabinogalactan Polymers 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
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- 229920001353 Dextrin Polymers 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
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- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 235000006552 Liquidambar styraciflua Nutrition 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 101100168115 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-6 gene Proteins 0.000 description 1
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 235000019312 arabinogalactan Nutrition 0.000 description 1
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- DWPDSISGRAWLLV-JHZYRPMRSA-L calcium;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Ca+2].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O.C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O DWPDSISGRAWLLV-JHZYRPMRSA-L 0.000 description 1
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- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
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- 229960002154 guar gum Drugs 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- VRNINGUKUJWZTH-UHFFFAOYSA-L lead(2+);dithiocyanate Chemical compound [Pb+2].[S-]C#N.[S-]C#N VRNINGUKUJWZTH-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
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- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 239000006012 monoammonium phosphate Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
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- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
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- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
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- 230000001681 protective effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000011514 reflex Effects 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- UHCGLDSRFKGERO-UHFFFAOYSA-N strontium peroxide Chemical compound [Sr+2].[O-][O-] UHCGLDSRFKGERO-UHFFFAOYSA-N 0.000 description 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C35/00—Permanently-installed equipment
- A62C35/02—Permanently-installed equipment with containers for delivering the extinguishing substance
- A62C35/10—Containers destroyed or opened by flames or heat
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C3/00—Fire prevention, containment or extinguishing specially adapted for particular objects or places
- A62C3/006—Fire prevention, containment or extinguishing specially adapted for particular objects or places for kitchens or stoves
Definitions
- ABSTRACT The specification discloses a fire extinguisher comprising a fire extinguishing substance located in a closed 11 3,884,307 [451 May 20, 1975 container. A small amount of explosive charge is em ployed primarily for opening the container wall in the presence of high temperatures to allow the fire extinguishing substance to pass out of the container. in the preferred embodiment, the wall has weakened portions selectively formed to facilitate rupturing to form an opening in the wall without fragmentation.
- the small amount of explosive charge is located in the container in close proximity to the wall in the vicinity of the weakened portions for rupturing the wall at the weakened portions to fonn an opening therethrough.
- a heat sensitive fuse or firetrain is provided for actuating the explosive charge in the presence of heat above an undesired level.
- a secondary explosive charge is located in the fire extinguishing substance and spaced from the small amount of explosive charge and which is actuated by the fuse or firetrain after the small amount of explosive charge is actuated to force the fire extinguishing substance outward through the opening formed by the small amount of explosive charge.
- the fuse or firetrain comprises a metallic wire having a high thermal conductivity, a fast burning substance located around the wire, a confining cover comprising wires spirally wrapped around the fast burning substance, a nylon yarn counter wrapped, as added hoop compression, and a water-proof layer of highly flammable material deposited on and throughout the confining cover.
- This invention relates to a fire extinguisher employing an explosive charge for releasing fire extinguishing substance from a container and in addition to a fast burning and effective fuse or firetrain for use actuating the charge.
- Fire extinguishers have been built or proposed comprising a scored container wall having located therein a fire extinguishing powder with a single explosive charge embedded in the powder and which is ignited by a heat sensitive fuse to rupture the scored container wall and force the powder outward into the surrounding environment.
- the explosive charge is relatively large, problems have been observed to occur in that the explosive force tends at random to rupture one portion or the other of the container wall leaving a large amount of powder in the container. This is due in part to the fact that the scoring of the container wall may not be the same on all sides and hence certain sides may be more weakened than the others.
- the explosive force will seek the path of least resistance, through the powder, and the portion of the wall in this path will be ruptured and possibly fragmented, dispersing only a small portion of the powder in a random direction with the balance of the powder being tightly packed in the other side of the container. Improved rupture and dispersion of the powder may be obtained if the centered or embedded explosive charge is made relatively large. however, this presents safety problems particularly if the fire extinguisher is to be used indoors.
- the fire extinguisher comprises a closed container having a fire extinguishing substance located therein.
- the wall of the container has weakened portions selectively formed to facilitate rupturing to form an opening in the wall without fragmentation.
- a small amount of explosive charge is located in the container at a position outward from the center of the fire extinguishing substance and in close proximity to the wall in the vicinity of the weakened portions for rupturing the wall at the weakened portions to form an opening therethrough to allow the fire extinguishing material to pass out of the container.
- a heat sensitive fuse or firetrain is provided for actuating the explosive charge in the presence of heat above an undesired level.
- a magnet is attached to the container to allow the container to be attached in place to a metallic object.
- the fire extinguisher comprises a secondary explosive charge located or embedded in the fire extinguishing substance and spaced from the small amount of explosive charge.
- the fuse or firetrain extends from the exterior of the container to the small amount of explosive charge and to the secondary explosive charge to allow the small amount of explosive charge to be actuated by delayed action to force the fire extinguishing substance outward through the opening.
- the fuse or firetrain comprises a metallic wire having a high thermal conductivity, a first burning substance located around the wire, cover means wrapped around said fast burning substance to provide strength for said fuse and to hold said fast burning substance in place, and a water-proof layer of highly flammable material deposited on said cover means.
- the cover means comprises thin metallic wires spirally wrapped around the fast burning substance with a nylon yarn counter wrapping to bind these wires in place and provide a foundation for the water-proof layer of highly flammable cover material.
- FIG. 1 illustrates a fire extinguisher attached to the top of a vent-ahood of a cooking stove
- FIG. 2 is an enlarged partial cross sectional view of the fire extinguisher of FIG. 1 illustrating a thin lyaer of explosive charge deposited on the interior of its bottom wall for rupturing scored portions of the wall when the charge is ignited;
- FIG. 3 is a bottom view of the fire extinguisher of FIG. 2 illustrating scored lines on its bottom end;
- FIG. 4 is an enlarged cross sectional view of FIG. 3 taken through the lines 44 thereof illustrating scored lines;
- FIG. 5 is an enlarged partial cross sectional view of the container of FIG. 2 illustrating the double seam connecting the bottom end and the side walls;
- FIG. 6 illustrates the fire extinguisher of FIGS. 2 and 3 after its explosive charge has been ignited and its rupturable segments forced outward to form openings through the bottom end to allow its fire extinguishing powder to fall out for fire extinguishing purposes;
- FIG. 7 illustrates a ferrule and a push on friction nut for holding the fuse in place
- FIG. 8 is an enlarged partial cross sectional view of the bottom end of the fire extinguisher illustrating an embodiment for minimizing the amount of explosive charge required for rupturing the bottom wall of the fire extinguisher for releasing its powder;
- FIG. 9 is a view of the bottom end of the embodiment of FIG. 8 as seen from the inside of the fire extinguisher;
- FIG. 10 is a partial cross sectional view of another embodiment of the fire extinguisher employing a sec ondary charge embedded in the fire extinguishing powder;
- FIG. I I is a partial cross sectional view of a fire extinguisher of the type illustrated in FIG. 10 but having a dome shape;
- FIG. 12 is a bottom view of the fire extinguisher of FIG. 11;
- FIG. 13 illustrates the fire extinguisher of FIGS. 11 and 12 after its explosive charge has been ignited and its rupturable segments forced outward to form openmgs;
- FIG. 14 illustrates an enlarged and partial cross sec tional view of the fuse or firetrain employed in the fire extinguishers of FIGS. 1-13;
- FIG. 15 is a cross sectional view of FIG. 14 taken through the line 15l5 thereof;
- FIG. 16 is an enlarged cross sectional view of another embodiment of the fire extinguisher wherein its wall is formed of a material capable of being disintegrated by the explosive charge when exploded;
- FIG. 17 illustrates a further embodiment wherein the walls of the container are formed of a highly flammable material
- FIG. 18 illustrates a portion of a container wall of an embodiment wherein the container wall is layered having an inner sandwiched layer formed of a highly flammable, self-oxidizing material or an explosive material.
- the fire extinguisher illustrated therein is identified by reference numeral 11 and comprises a container 13 formed by a cup-shaped member 15 having a lower lid 17 sealed to the lower end 150 of the member 15 by a double seam illustrated in FIG. 5.
- a fire extinguishing substance 19 preferably a fire extinguishing powder which may be of the A.B.C. type or for example, of the B.C. type.
- the ABC. type is formed of about 90% monoammonium phosphate with about percent silicones and other materials (silica, ground mica) added to keep it free flowing to protect it from moisture.
- the BC. type is about 90-94 percent sodium bicarbonate. The balance of the material is stearates or silicones and other materials added to keep it free flowing and to protect the sodium bicarbonate from moisture.
- the top b of the container 13 has a magnet 21 attached thereto to allow the extinguisher to be attached to a metallic object and hung with its bottom end 17 downward.
- the tire extinguisher When used as illustrated in FIG. 1, the tire extinguisher will be attached to the top of a vent-ahood of a stove for protection against grease fires.
- the magnet 21 is encased in a case 23 which is movably attached to the container 13 by a ring 25. This ring is inserted through loop 230 ofthe case 23 and through aperture 27 formed member 29 attached to the top end 15b of the container 13.
- the bottom lid 17 has grooves or scored lines 3la-36a selectively formed on one side thereof to facilitate breaking or rupturing of the bottom end into separate tear-open segments 31-36 without fragmentation to form openings 31b-36b only in the bottom end or bottom wall portion when the free ends of the segments are forced outward to allow the fire extinguishing powder to fall or pass outward from the container onto the fire.
- the scoring is illustrated on the outside surface of the lid 17, preferably it will be on the inside surface thereof.
- the explosive charge for rupturing the bottom end along the weakened or scored lines for forcing the free ends of the segments outward comprises a small amount of explosive charge 41 deposited on the inside of the lid 17.
- the charge 41 is deposited as a thin layer in the area defined by the dotted circle 43, as seen in FIG. 3.
- Extending through the lid 17 and to the explosive layer 41 is a heat sensitive fuse or firetrain 51.
- the fuse SI is held in place by a ferrule 53 and a push on friction nut 55.
- the fuse 51 ignites when the temperature outside of the fire extinguisher reaches a certain level to explode the charge 41.
- the force of the explosion ruptures the scored or weakened lines and forces the tear open segments 31-36 outward to form the openings 31b-36b.
- the force of the charge pushes the fire extinguishing powder upward in the container loosening any caking.
- the fire extinguishing powder then gently falls out of the can by gravitational force to extinguish any fire below which may be in a frying pan, for examplev
- the non-erupting portions of the lid 17 control the flow so that the powder does not fall out in one lump, which might splash grease from the frying pan, but gently trickles out for about 10 seconds, in one embodiment.
- the fire extinguishing powder is not dispersed too widely but only on the flame area below the fire extinguisher.
- the explosive charge 41 Since the explosive charge 41 is located in close proximity to the grooves or weakened lines formed in the lid 17, the charge will form the openings where desired when ignited with a high degree of reliability thereby insuring proper release of the fire extinguishing powder. Moreover, the amount of explosive charge required is small, thereby reducing dangers or hazards which may be otherwise present if a large amount of charge were employed. For ease of assembly, the fuse or firetrain S1 is inserted in place through the lid and the explosive charge applied onto the interior side of the lid 17 before it is attached to the member 15.
- a small amount of explosive charge may be deposited on the inside of the lid 17 concentrated closely around the fuse 51, in effect to form a ball of more concentrated charge.
- a ball of charge having a diameter of about one fourth of an inch has been found to be sufficient to force the tear open segments outward when exploded even though it is not di rectly opposite the scored lines defining the tear open segments.
- the use of a small ball of charge has advantages over the thin layer of charge in that increased brisance is obtainable with less explosive material.
- FIGS. 8 and 9 there will be described another embodiment for minimizing the amount of explosive charge required for forcing the tear open segments 31-36 outward to form the desired openings for releasing the powder from the fire extinguisher.
- scoring is done on the inside surface of the lid to define the segments 31-36.
- a small plate 61 is held in place on the inside of the lid 17 by eyelets 63 and 65 which also hold the fuse in place.
- a plurality of pockets 67 are formed in the plate by punching portions 62 inwardly with the openings 67a facing the axis of the plate 61. As illustrated, the pockets are located next to the free corners or free ends of the rupturable segments 31-36.
- the pockets are filled with an explosive charge 69 which also is deposited on the plate 61 forming a firetrain 71 leading to the fuse 51.
- the firetrain 71 is ignited which in turn ignites and explodes the charge 69 in the pockets to rupture the lid at the scored lines and force the segments 31-36 outward forming the desired openings to allow the powder to fall outward.
- the portions 62 forming the pockets reflect the force of the explosion occurring in the pockets outward to increase the amount of force applied to force the segments 31-61 individually outward to form the desired openings.
- the container formed by member and lid 17 are formed of this aluminum.
- the container has a diameter of about 3 inches and a height of about 2 inches.
- the lid is attached to the member 15 by way of a double seam since this manner of attachment can be done rapidly and economically and in addition, provides a water-proof seal for the powder in the container.
- the purpose of the explosive charge 41 and 69 is to act solely on the container wall to form an opening or openings without forcing the bulk of the powder out of the container. After the opening or openings have been formed, the fire extinguishing powder then is allowed to fall out by the force of gravity.
- the explosive charges 41 and 69 are a primary or initiating type of exposive in that it does not require confinement or enclosure to develop brisance.
- this type of explosive are mercury fluminate, lead azide, nitrosoguanidine, lead styphnate. double salts of lead styphnate as with nitroaminotetrazole, or with lead hypophosphite, or with lead propionate, lead picrate, or its double salts, lead dinitroresorcinate, diazodinitrophenol, tetracene, mono-basic lead dinitrobenzoate, di-basic lead dinitrobenzoate.
- silver and mercury azides or combinations of explosives such as picric acid and silver azide or diazodinitrophenol primed with lead azide alone or with the addition of lead styphnate or tetrazene or with diazodinitrophenol as the primary explosive, tetryl, the lead salts of picric acid and trinitroresorcinal, mnitrophenyldiazonium perchlorate, nitrogen sulfide, copper acetylide. fulminating gold, the tartarates and oxalates of mercury and silver.
- explosives such as picric acid and silver azide or diazodinitrophenol primed with lead azide alone or with the addition of lead styphnate or tetrazene or with diazodinitrophenol as the primary explosive, tetryl, the lead salts of picric acid and trinitroresorcinal, mnitrophenyldiazonium perchlorate, nitrogen sulfide, copper acetylide.
- fulminate of silver cadmium azide, cuprous azide, thallium azide, cadmium fulminate, copper fulminate, thallium fulminate, sodium fulminate, potassium fulminate, cobalt azide, barium azide, calcium azide, strontium azide, nickel azide, manganese azide, lithium azide. mercurous azide, zinc azide, etc.
- a suitable binder is mixed with the explosive used and a protective coating such as nitrocellulose may be applied to protect it environmentally.
- the binder may be gum arabic, karaya gum. gum tragacanth, guar gum, locust bean gum, arabinogalactan derived from locust bean gum. glucose. gum yacca (red gum). or the following may be used alone or in combinations of two or more: methyl cellulose. hydroxyethyl cellulose, carboxymethyl cellulose. dextrin. poIyvinyl-pyrrolidone, linear high molecular weight poly (ethylene oxide), polyvinyl alcohol. and ureaformaldehyde or melamineformaldehyde polymers. as well as shellac. rosin, calcium resinate and ester gum, all of which are more or less commonly used explosive binders.
- FIG. 10 there will be described another embodiment of the fire extinguisher which is similar to that of FIGS. 1-9 except that it has embedded in the fire extinguishing powder 19, a secondary charge identified at 81.
- the container is similar to that of FIG. 1 in that it is formed of a cup shaped member 83 having a lid 85 sealed to the side walls by a double seam.
- the lid 85 forms the top of the fire extinguisher while the other end 87 forms the bottom thereof.
- Formed in the bottom end 87 are scored lines similar to that disclosed in FIG. 3 forming a plurality of rupturable segments 31-36.
- the side walls have scored lines 89 formed to provide rupturable but non-fragmenting segments 91.
- Both charges 81 and 93 may be formed of the same material as charges 41 and 69 described previously. However, since the explosive charge 81 is housed in a paper container. explosives such as black powder, flash powder commonly used in firecrackers and similarly used explosives may be effectively used for the charge 81.
- the explosive charge 81 is housed in a paper container 94 which is held centered within the powder 19 by member 95 which may be a polyethylene, closed cell. sponge material. Member 95 also may be formed metal or cardboard.
- the charge 81 is spaced from the primary charge 93 in that the container 94 has a lower insert 96 providing a space 97 between the secondary charge 81 and the primary charge 93.
- the upper end of the container also has an insert 101 which spaces the charge 81 from the upper end of the container.
- the fuse 51 extends through the primary charge 93 and to the secondary charge 81.
- the primary charge 93 will be actuated initially to force the segments 31-36 and 91 outward to form openings in the container wall.
- the explosion of the primary charge 93 also drives the powder 19 tightly around container 94 housing the secondary charge 81. Since the secondary charge is spaced from the primary charge. its ignition will be delayed subsequent to the ignition of the primary charge.
- the secondary charge is exploded by the fuse thus taking advantage of the reflex phenomena.
- the secondary charge then widely disperses the powder through the openings formed.
- FIG. 10 has a number of useful applications, for example, it may be used in the attics of homes for providing fire protection. It may be attached to the rafters with a nail, hook. or staple inserted through the ring 25.
- FIGS. 11 and 12 The embodiment of FIGS. 11 and 12 is similar to that of FIG. 10 except that the container is dome shaped and the scored lines 103 forming the tear open segments 105 are continuous.
- the primary charge 93 is deposited on the sides, as well as on the bottom of the container.
- the primary charge may be deposited on the inside of the rounded bottom end as illustrated or a small amount of explosive charge may be deposited on the inside of the bottom concentrated around the fuse or firetrain 51 in effect balling the charge so as to increase the brisance.
- a charge of lead styphnate having a diameter of about one half of an inch has been found to be sufficient in force to open the segments outward when exploded even though the charge is not opposite the scored tear open segments.
- the fuse or firetrain which is a fast burning, highly flammable, waterproof and explosion-proof fuse. In addition, it is readily ignited by a low temperature flame or an ambient temperature of approximately 3lOF.
- the fuse or primary firetrain SI comprises a thin copper wire 121 heavily coated with a fast burning substance or material 123 which may comprise 2-3 micron size fine silicon powder for the fuel ranging from 30 to 60 percent (40 percent preferred), and lead peroxide (PbO ranging from 30 to 60 percent (58 percent preferred) as the oxidizer plus 0.5 to [0 percent (20 percent preferred) fine zinc powder to add to the heat and vigor of the burning.
- Acetone wetted cellulose nitrate may be used to bind these materials together.
- the ratios of this for mulation may be varied to produce different burning rates and this formulation is extremely stable.
- Wrapped around the material 123 is a protective covering comprising five spirally wrapped wires 125 to prevent the fuse from being extinguished or destroyed by the substance 123 when ignited or by the explosive charge of the fire extinguisher before the fuse can effectively perform its function. This is particularly important in the embodiments of FIGS. -13 wherein the fuse is employed to ignite the secondary charge after the primary charge is exploded.
- a nylon yarn illustrated at 127 for providing additional protection.
- the purpose of the wire 12] is to provide support for the fuse firetrain or fuse material and assist its continuity of burning since the wire I21 has a high thermal conductivity. It is noted that the ends of the fuse are cut at an oblique angle of about 45relative to the axis of the fuse to provide a sharp pointed tip to allow the highly flammable coating 129 to ignite easily and to provide a large surface exposure on the end to facilitate ignition of the fuse material 123 by the burning of the highly flammable coating 129 whereby the fuse may be readily and reliably ignited by a low temperature flame.
- the wire 121 has a diameter of lo mils while the wrapped wire 125 has a diameter of 8 mils and is formed of galvanized soft iron.
- the total diameter of the fuse is 0.068 of an inch. Its burn rate was three forth of an inch in 227 milliseconds.
- the fuse may be common black powder preferably fine meal size powder, prepared as what is commonly known in pyrotechnics as a black match and utilized in the tube provided by the eyelet 65 of FIG. 8 as a quick match (see the lower portion of page 67, reference 21 of The Chemistry of Powder and Explosives, by Tenney L. Davis, volume l). Also, a regular commerically available fusing may be used, if desired.
- the fuse 51 Since the fuse 51 has a core I21 formed of copper wire, it may employed to actuate the fire extinguisher remotely by applying electrical current through the fuse for remote ignition thereof. This application is particularly useful, for example, in the embodiments of FIGS. 1042.
- two separate electrical leads may be attached to the outside end of the fuse end 5I at spaced positions such that when an electrical current is applied through the leads, the wires in the fuse will heat to a point where the fuse 51 will ignite to actuate the primary explosive charge and the secondary charge.
- the fuse 51 may be looped in a hairpin manner into the primary and secondary charges. Electrical leads then may be attached to the two ends of the fuse extending from the casement or housing of the fire extinguisher. The fire extinguisher will be able to automatically release its fire extinguishing powder in the presence of heat from a fire or may be actuated remotely to release its powder by closing an electrical switch to pass an electrical current through the fuse 51 for ignition.
- FIGS. l6-l8 there will be described other embodiments of the fire extinguisher.
- the fire extinguisher illustratted is the same as that disclosed in FIG. 2, except that the lid 17 has a central aperture formed therethrough which is covered by a circular disc 137 of a material capable of being disintegrated by the explosive charge 41 to form an open ing in the bottom of the container 13 when exploded, thereby allowing the fire extinguishing powder to fall out of the container by gravitational force onto the fire below.
- the disc 137 in one embodiment, may be formed of a thin sheet of fiber board sealed to the lid portion 17.
- the fuse Sl is attached to the disc 137, as illustrated.
- the container 141 is domed shaped and has located therein the fire extinguishing powder. All or a portion of the wall of the container is formed ofa highly flammable material such as nitrocellulose plastic. Thus the container in the presence of heat above an undesired level will ignite and rapidly burn through to free the fire extinguishing powder and allow it to fall by gravitational force onto the fire below.
- the container I41 has fusing means consisting of projections shaped as small points I43 formed of nitrocellulose or other fusing material randomly attached over the area of the container.
- the burning rate of such a container may be increased by adding to the nitrocellulose material, when in a liquid state, oxidizing agents (5 to 50 percent by weight) such as barium nitrate and lead peroxide.
- oxidizing agents such as barium nitrate and lead peroxide.
- barium nitrate and lead peroxide such as sodium nitrate, potassium chlorate, potassium perchlorate, potassium permangmate, ammonium nitrate, ammonium perchlorate, barium peroxide, strontium peroxide, lead monoxide, or ferric oxide.
- a fuel component also may be added generally to the extent of 5-25 by weight and which may comprise as one example, one or more finely powdered metals, metal alloy, or other combustible elements or compounds such as aluminum, magnesium, zirconium, titanium, iron, antimony sulfide, lead hypophosphite, or lead thiocyanate.
- the highly flammable material from which the container wall is constructed may be chemically treated paper such as paper treated with an oxidizing agent such as potassium chlorate, potassium perchlorate, barium nitrate, etc., as disclosed above.
- all or a portion of the wall of the container is formed of an inner layer l5l sandwiched in between two other layers I53 and 155.
- the layer 15] may be formed of the highly flammable material mentioned above while the layers 153 and 155 are also combustible and may be formed for example, of paper.
- the layer 151 may be an explosive layer.
- layers I53 and 155 being formed of a material which will disintegrate when the charge layer 151 is exploded.
- the charge of layer 151 may be the primary or initiating charge mentioned above while the layer 153 and 155 may be formed of thin fiber board.
- the fuse extends through the outer layer 155 to the inner layer 151 for igniting or actuating this layer in the presence of heat to release the tire extinguishing powder.
- a fire extinguisher comprising:
- heat sensitive means for actuating said force producing means in the presence of heat above an unde sired level to form said opening to allow said fire extinguishing substance to pass out of said container
- said heat sensitive means comprising:
- cover means wrapped around said substance to provide strength for said heat sensitive means and to hold said substance in place
- the fire extinguisher of claim 1 comprising:
- said force producing means being located at the bottom end of said container for forming said opening in the bottom of said container when actuated to allow said fire extinguishing substance to fall out of said container through said opening, when formed, by the force of gravity.
- the wall of said container has weakened portions selectively formed to facilitate rupturing to form an opening in said wall without fragmentation
- said force producing means being located in close proximity to said weakened portions for rupturing said wall at said weakened portions to form an opening therethrough to allow said fire extinguishing material to pass out of said container.
- a fire extinguisher comprising:
- a small amount of explosive charge located only at a position outward from the center of said fire extinguishing substance in close proximity to the wall of said container for forming an opening in the container wall when exploded without forcing the bulk of said fire extinguishing substance out of said con- 6 tainer, and heat sensitive means for actuating said explosive charge in the presence of heat above an undesired level to form said opening to allow said fire extinguishing substance to pass out of said container,
- said explosive charge being characterized as capable of developing brisance without confinement.
- the fire extinguisher of claim 4 comprising:
- said explosive charge being located at the bottom end of said container for forming said opening in the bottom of said container when actuated to allow said fire extinguishing substance to fall out of said container through said opening, when formed, by the force of gravity.
- said explosive charge is deposited on the wall of said container.
- the interior zone of said fire extinguishing substance is free of explosive.
- a fire extinguisher comprising:
- a small amount of explosive charge located in said container for use primarily for opening the container wall
- said explosive charge being located in close proximity to a given portion of the wall of said container for forming an opening only through said given portion
- heat sensitive means for actuating said small amount of explosive charge in the presence of heat above an undesired level to form said opening to allow said fire extinguishing substance to pass out of said container
- said heat sensitive means extending from the exterior of said container to said small amount of explosive and to said secondary explosive charge to allow said small amount of explosive to be actuated initially to form an opening through Said container and then to allow said secondary explosive charge to be actuated to force said fire extinguishing substance outward through said opening.
- the wall of said container has weakened portions selectively formed to facilitate rupturing to form an opening in said wall without fragmentation
- said small amount of explosive charge being located in close proximity to said weakened portions for rupturing said wall at said weakened portions to form an opening therethrough to allow said fire extinguishing material to pass out of said container.
- a fire extinguisher comprising:
- said explosive being characterized as a primary initiating explosive capable of developing brisance without confinement.
- said explosive charge is selected from the class consisting of mercury fulminate, lead azide, nitrosoguanidine, lead styphnate, double salts of lead styphnate as with nitroaminotetrazole, or with lead hypophosphite, or with lead propionate, lead picrate, or its double salts, lead dinitroresorcinate, diazodinitrophenol.
- tetracene mono-basic lead dinitrobenzoate, di-basic lead dinitrobenzoate, double salt of lead trinitroresorcinate, basic salts of tetrazole and basic lead salts of nitrotetrazole, nitrotetrazole, salts of mercury nitrotetrazole, salts of silver nitrotetrazole, acid copper salt of C nitrotetrazole, silver and mercury azides, or combinations of explosives such as picric acid and silver azide or diazodinitrophenol primed with lead azide alone or with the addition of lead styphnate or tetrazene or with diazodinitrophenol as the primary explosive, tetryl, the lead salts of picric acid and trinitroresorcinal, mnitrophenyldiazonium perchlorate, nitrogen sulfide, copper acetylide, fulminating gold, the tartarates and oxalates of mercury and silver, fulm
- the fire extinguisher of claim 12 comprising:
- said heat sensitive means extends from the exterior of said container to said small amount of explosive and to said secondary explosive charge to allow said small amount of explosive to be actuated intially to form an opening through said container and then to allow said secondary explosive charge to be actuated to force said fire extinguishing sub' stance outward through said opening.
- the wall of said container has weakened portions selectively formed to facilitate rupturing to form an opening in said wall without fragmentation
- said small amount of explosive charge being located in close proximity of said weakened portions for rupturing said wall at said weakened portions to form an opening therethrough to allow said fire extinguishing material to pass out of said container.
- said heat sensitive means extends from the exterior of said container to said small amount of explosive and to said secondary explosive charge to allow said small amount of explosive charge to be actuated initially to form an opening through said con tainer and then to allow said secondary explosive charge to be actuated to force said fire extinguish ing substance outward through said opening.
- a heat sensitive fuse for igniting an explosive charge comprising:
- said water-proof layer of highly flammable material being deposited on the cut end of said fuse.
- a fire extinguisher comprising:
- said container having a bottom end and a top end
- a magnet coupled to said top end to allow said container to be attached in place to a metallic object to locate said bottom end in a downward direction
- said bottom end having weakened portions selectively formed to facilitate rupturing to form an opening in said bottom end without fragmentation
- heat sensitive fuse means for igniting said explosive charge in the presence of heat above an undesired level.
- a fire extinguisher comprising:
- At least a portion of the wall of said container comprising a layer of highly combustible material sandwiched between two layers of combustible mate rial, and
- ignitable fuse means extending from the outside to said layer of highly combustible material for igniting said layer of highly combustible material and hence said two layers of combustible material in container to an object.
- said fire extinguisher container wall being formed at least in part of an explosive material
- said explosive material is sandwiched between two layers capable of being disintegrated when said explosive material is exploded.
- fuse means for actuating said explosive material in the presence of undesirable high temperatures.
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US414660A US3884307A (en) | 1973-11-12 | 1973-11-12 | Fire extinguisher |
JP744466A JPS6055142B2 (ja) | 1973-11-12 | 1973-12-26 | 消火器 |
DE19742407790 DE2407790A1 (de) | 1973-11-12 | 1974-02-19 | Feuerloescher |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US414660A US3884307A (en) | 1973-11-12 | 1973-11-12 | Fire extinguisher |
Publications (1)
Publication Number | Publication Date |
---|---|
US3884307A true US3884307A (en) | 1975-05-20 |
Family
ID=23642389
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US414660A Expired - Lifetime US3884307A (en) | 1973-11-12 | 1973-11-12 | Fire extinguisher |
Country Status (3)
Country | Link |
---|---|
US (1) | US3884307A (enrdf_load_stackoverflow) |
JP (1) | JPS6055142B2 (enrdf_load_stackoverflow) |
DE (1) | DE2407790A1 (enrdf_load_stackoverflow) |
Cited By (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2159707A (en) * | 1984-06-08 | 1985-12-11 | Abg Semca | Rapid discharge extinguisher |
US4854389A (en) * | 1987-04-29 | 1989-08-08 | Systron Donner Corp. | Linear fire extinguisher |
US4893679A (en) * | 1988-03-01 | 1990-01-16 | Grinnell Corporation | Heat-responsive element for fire protection sprinklers or the like |
US4938293A (en) * | 1987-04-29 | 1990-07-03 | Systron Donner Corp. | Linear fire extinguisher |
US5038866A (en) * | 1986-11-21 | 1991-08-13 | Santa Barbara Research Center | Powder discharge apparatus |
WO1995019815A1 (en) * | 1994-01-21 | 1995-07-27 | Williams Robert A | Fire extinguisher |
US5466386A (en) * | 1993-05-03 | 1995-11-14 | Powsus, Inc. | Fire extinguishing compositions |
US5697450A (en) * | 1993-04-28 | 1997-12-16 | Twenty First Century International Fire Equipement And Services Corp. | Fire extinguishing systems and methods |
US5871057A (en) * | 1993-04-28 | 1999-02-16 | Twenty First Century International Fire Equipment And Service Corp. | Fire extinguishing systems and methods |
WO2000029068A1 (es) * | 1998-11-12 | 2000-05-25 | Benigno Garcia Calvo | Dispositivo para la extincion de incendios en instalaciones de hidrocarburos |
US6105677A (en) * | 1998-05-07 | 2000-08-22 | Stager; Daniel J. | Method of extinguishing stovetop grease fires and fire extinguisher therefor |
US6651563B2 (en) | 1994-09-13 | 2003-11-25 | Dynamit Nobel Artiengesellschaft | Ignition elements and finely graduatable ignition components |
US20080314602A1 (en) * | 2007-06-20 | 2008-12-25 | Byron Lohnes | Portable fire extinguisher with manual and heat-responsive operators |
US7472758B1 (en) | 2005-07-11 | 2009-01-06 | Williams-Pyro, Inc. | Initiator for stovetop fire extinguisher |
US7610966B1 (en) * | 2007-01-18 | 2009-11-03 | Williams-Pyro, Inc. | Stovetop fire extinguisher |
US20110297402A1 (en) * | 2010-06-03 | 2011-12-08 | Cesar Belmonte | Fire-Suppressing Ceiling Panels |
US8261843B2 (en) * | 1998-10-14 | 2012-09-11 | Willfire Hc, Llc | Portable wall-attachable fire fighting apparatus and method |
US20130175058A1 (en) * | 2012-01-09 | 2013-07-11 | Warren Watts Technology, LLC | Initiator for Fire Suppressant Canister |
US9044627B1 (en) | 2009-04-02 | 2015-06-02 | Williamsrdm, Inc. | Back wall fire suppressor system and method |
WO2015126608A1 (en) * | 2014-02-21 | 2015-08-27 | Murray Donald W | Distribution of a fire suppressing agent in a stovetop fire suppressor and method |
US20160151652A1 (en) * | 2014-11-27 | 2016-06-02 | Williamsrdm, Inc. | Stovetop fire suppressor with shuttle actuator and method |
US9421405B1 (en) | 2013-03-18 | 2016-08-23 | Williamsrdm, Inc. | Stovetop fire extinguisher initiator with fuse device and method |
US9597534B1 (en) | 2013-08-12 | 2017-03-21 | Williamsrdm, Inc. | Stovetop fire suppressor initiator device and method |
US9636529B1 (en) | 2013-02-26 | 2017-05-02 | Williamsrdm, Inc. | Stovetop fire suppressor mounting device and method |
US9636530B2 (en) | 2014-02-21 | 2017-05-02 | Williamsrdm, Inc. | Stovetop fire suppressor with thermal glass bulb actuation and method |
WO2018020493A1 (en) * | 2016-07-28 | 2018-02-01 | Alroee Yariv | Fire extinguishing apparatus |
US20180078800A1 (en) * | 2015-11-12 | 2018-03-22 | Suppressor, LLC | Stove top fire extinguishing device |
US10232202B1 (en) * | 2016-09-07 | 2019-03-19 | WilliamsRDM, Inc | Self contained stovetop fire suppressor with alert signal and method |
US10363443B2 (en) * | 2016-06-30 | 2019-07-30 | Superposed Associates Llc | Passive ductwork intumescent fire damper |
US10821312B2 (en) | 2015-11-12 | 2020-11-03 | Suppressor, LLC | Stove top fire extinguishing device |
US11040229B2 (en) * | 2012-01-18 | 2021-06-22 | Acell Industries Limited | Fire suppression system |
US11439850B2 (en) * | 2018-07-20 | 2022-09-13 | Williamsrdm, Inc. | Self contained stovetop fire suppressor with alert signal and method |
EP4230269A1 (en) * | 2022-02-18 | 2023-08-23 | Kidde Technologies, Inc. | Optical firing cartridge for fire extinguisher |
EP4230268A1 (en) * | 2022-02-18 | 2023-08-23 | Kidde Technologies, Inc. | Addressing optical firing cartridge using chromatic aberration |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5151195A (ja) * | 1974-10-29 | 1976-05-06 | Daihatsu Kosan Kk | Jidoshokasochi |
DE3340652C2 (de) * | 1983-11-10 | 1986-11-06 | Heinz G. 3017 Pattensen Schulz | Feuerlöscheinrichtung |
EP0390384A1 (en) * | 1989-03-31 | 1990-10-03 | Kidde-Graviner Limited | Fire extinguishers |
JPH05317437A (ja) * | 1992-05-26 | 1993-12-03 | Takayuki Ishida | 消火装置 |
DE19706207B4 (de) * | 1996-02-15 | 2008-04-03 | Dynamit Nobel Defence Gmbh | Abdeckkappe für einen unter Druck öffnenden Behälter |
RU2407571C1 (ru) * | 2009-12-02 | 2010-12-27 | Закрытое акционерное общество "Источник Плюс" | Модуль порошкового пожаротушения |
DE102017112605A1 (de) * | 2017-06-08 | 2018-12-13 | Erbstösser Gmbh | Lagerungssystem zur Lagerung von Lithium-Batterien |
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US1708869A (en) * | 1926-06-04 | 1929-04-09 | Buddecke Hartmut | Fire extinguisher |
US2754913A (en) * | 1954-03-31 | 1956-07-17 | Robert W Mcfarlin | Fire extinguisher |
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US1080068A (en) * | 1913-01-03 | 1913-12-02 | Alphonse La Breche | Automatic fire-extinguisher. |
GB450132A (en) * | 1935-11-25 | 1936-07-10 | Carl Wilhelm Hartmann | Improvements in the production of casings for fire extinguishing grenades |
AT152612B (de) * | 1936-08-28 | 1938-02-25 | Nitrochemie Industrieanlagen A | Löschvorrichtung zum Löschen rasch brennender Stoffe. |
-
1973
- 1973-11-12 US US414660A patent/US3884307A/en not_active Expired - Lifetime
- 1973-12-26 JP JP744466A patent/JPS6055142B2/ja not_active Expired
-
1974
- 1974-02-19 DE DE19742407790 patent/DE2407790A1/de active Granted
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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US750416A (en) * | 1904-01-26 | Fire-extinguishing device | ||
US1067803A (en) * | 1912-08-07 | 1913-07-22 | Paul Daniel | Fire-extinguisher. |
US1489703A (en) * | 1921-10-29 | 1924-04-08 | Joseph G Seel | Automatic fire extinguisher |
US1708869A (en) * | 1926-06-04 | 1929-04-09 | Buddecke Hartmut | Fire extinguisher |
US2754913A (en) * | 1954-03-31 | 1956-07-17 | Robert W Mcfarlin | Fire extinguisher |
US3773111A (en) * | 1971-04-05 | 1973-11-20 | B Dunn | Fire extinguishing apparatus |
US3710855A (en) * | 1971-08-10 | 1973-01-16 | G Osorio | Fire extinguisher |
Cited By (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2159707A (en) * | 1984-06-08 | 1985-12-11 | Abg Semca | Rapid discharge extinguisher |
US4637472A (en) * | 1984-06-08 | 1987-01-20 | Abg Semca | Rapid discharge extinguisher |
US5038866A (en) * | 1986-11-21 | 1991-08-13 | Santa Barbara Research Center | Powder discharge apparatus |
US4854389A (en) * | 1987-04-29 | 1989-08-08 | Systron Donner Corp. | Linear fire extinguisher |
US4938293A (en) * | 1987-04-29 | 1990-07-03 | Systron Donner Corp. | Linear fire extinguisher |
US4893679A (en) * | 1988-03-01 | 1990-01-16 | Grinnell Corporation | Heat-responsive element for fire protection sprinklers or the like |
US5697450A (en) * | 1993-04-28 | 1997-12-16 | Twenty First Century International Fire Equipement And Services Corp. | Fire extinguishing systems and methods |
US5871057A (en) * | 1993-04-28 | 1999-02-16 | Twenty First Century International Fire Equipment And Service Corp. | Fire extinguishing systems and methods |
US5466386A (en) * | 1993-05-03 | 1995-11-14 | Powsus, Inc. | Fire extinguishing compositions |
WO1995019815A1 (en) * | 1994-01-21 | 1995-07-27 | Williams Robert A | Fire extinguisher |
US5518075A (en) * | 1994-01-21 | 1996-05-21 | Williams; Robert A. | Fire extinguisher |
US6651563B2 (en) | 1994-09-13 | 2003-11-25 | Dynamit Nobel Artiengesellschaft | Ignition elements and finely graduatable ignition components |
US6105677A (en) * | 1998-05-07 | 2000-08-22 | Stager; Daniel J. | Method of extinguishing stovetop grease fires and fire extinguisher therefor |
US8261843B2 (en) * | 1998-10-14 | 2012-09-11 | Willfire Hc, Llc | Portable wall-attachable fire fighting apparatus and method |
WO2000029068A1 (es) * | 1998-11-12 | 2000-05-25 | Benigno Garcia Calvo | Dispositivo para la extincion de incendios en instalaciones de hidrocarburos |
ES2162721B1 (es) * | 1998-11-12 | 2004-05-01 | Benigno Garcia Calvo | Dispositivo para la extincion de incendios en instalaciones de hidrocarburos. |
ES2162721A1 (es) * | 1998-11-12 | 2002-01-01 | Calvo Benigno Garcia | Dispositivo para la extincion de incendios en instalaciones de hidrocarburos. |
US7472758B1 (en) | 2005-07-11 | 2009-01-06 | Williams-Pyro, Inc. | Initiator for stovetop fire extinguisher |
US7610966B1 (en) * | 2007-01-18 | 2009-11-03 | Williams-Pyro, Inc. | Stovetop fire extinguisher |
US20080314602A1 (en) * | 2007-06-20 | 2008-12-25 | Byron Lohnes | Portable fire extinguisher with manual and heat-responsive operators |
US9044627B1 (en) | 2009-04-02 | 2015-06-02 | Williamsrdm, Inc. | Back wall fire suppressor system and method |
US20110297402A1 (en) * | 2010-06-03 | 2011-12-08 | Cesar Belmonte | Fire-Suppressing Ceiling Panels |
US20130175058A1 (en) * | 2012-01-09 | 2013-07-11 | Warren Watts Technology, LLC | Initiator for Fire Suppressant Canister |
US9827453B2 (en) * | 2012-01-09 | 2017-11-28 | Warren Watts Technology, LLC | Initiator for fire suppressant canister |
US9339672B2 (en) * | 2012-01-09 | 2016-05-17 | Warren Watts Technology, LLC | Initiator for fire suppressant canister |
US11040229B2 (en) * | 2012-01-18 | 2021-06-22 | Acell Industries Limited | Fire suppression system |
US9636529B1 (en) | 2013-02-26 | 2017-05-02 | Williamsrdm, Inc. | Stovetop fire suppressor mounting device and method |
US9421405B1 (en) | 2013-03-18 | 2016-08-23 | Williamsrdm, Inc. | Stovetop fire extinguisher initiator with fuse device and method |
US9597534B1 (en) | 2013-08-12 | 2017-03-21 | Williamsrdm, Inc. | Stovetop fire suppressor initiator device and method |
US20150238788A1 (en) * | 2014-02-21 | 2015-08-27 | Williamsrdm, Inc. | Distribution of fire suppressing agent in a stovetop fire suppressor and method |
US9636530B2 (en) | 2014-02-21 | 2017-05-02 | Williamsrdm, Inc. | Stovetop fire suppressor with thermal glass bulb actuation and method |
AU2015219465B2 (en) * | 2014-02-21 | 2016-02-11 | Donald W. Murray | Distribution of a fire suppressing agent in a stovetop fire suppressor and method |
US9517370B2 (en) * | 2014-02-21 | 2016-12-13 | Williamsrdm, Inc. | Distribution of fire suppressing agent in a stovetop fire suppressor and method |
US10226652B2 (en) * | 2014-02-21 | 2019-03-12 | Williams Rdm Inc | Stovetop fire suppressor with thermal glass bulb actuation and method |
WO2015126608A1 (en) * | 2014-02-21 | 2015-08-27 | Murray Donald W | Distribution of a fire suppressing agent in a stovetop fire suppressor and method |
US20160151652A1 (en) * | 2014-11-27 | 2016-06-02 | Williamsrdm, Inc. | Stovetop fire suppressor with shuttle actuator and method |
US10478647B2 (en) * | 2014-11-27 | 2019-11-19 | Williams Rdm, Inc | Stovetop fire suppressor with shuttle actuator and method |
US10821312B2 (en) | 2015-11-12 | 2020-11-03 | Suppressor, LLC | Stove top fire extinguishing device |
US20180078800A1 (en) * | 2015-11-12 | 2018-03-22 | Suppressor, LLC | Stove top fire extinguishing device |
US9999791B2 (en) * | 2015-11-12 | 2018-06-19 | Suppressor, LLC | Stove top fire extinguishing device |
US10272275B2 (en) * | 2015-11-12 | 2019-04-30 | Suppressor, LLC | Stove top fire extinguishing device |
US10363443B2 (en) * | 2016-06-30 | 2019-07-30 | Superposed Associates Llc | Passive ductwork intumescent fire damper |
WO2018020493A1 (en) * | 2016-07-28 | 2018-02-01 | Alroee Yariv | Fire extinguishing apparatus |
US10232202B1 (en) * | 2016-09-07 | 2019-03-19 | WilliamsRDM, Inc | Self contained stovetop fire suppressor with alert signal and method |
US11439850B2 (en) * | 2018-07-20 | 2022-09-13 | Williamsrdm, Inc. | Self contained stovetop fire suppressor with alert signal and method |
EP4230269A1 (en) * | 2022-02-18 | 2023-08-23 | Kidde Technologies, Inc. | Optical firing cartridge for fire extinguisher |
EP4230268A1 (en) * | 2022-02-18 | 2023-08-23 | Kidde Technologies, Inc. | Addressing optical firing cartridge using chromatic aberration |
US12157027B2 (en) | 2022-02-18 | 2024-12-03 | Kidde Technologies, Inc. | Optical firing cartridge for fire extinguisher |
Also Published As
Publication number | Publication date |
---|---|
JPS5079996A (enrdf_load_stackoverflow) | 1975-06-28 |
JPS6055142B2 (ja) | 1985-12-03 |
DE2407790C2 (enrdf_load_stackoverflow) | 1989-03-23 |
DE2407790A1 (de) | 1975-05-15 |
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