US3826632A - Petroleum fuel oil and black liquor combustion - Google Patents

Petroleum fuel oil and black liquor combustion Download PDF

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Publication number
US3826632A
US3826632A US00220674A US22067472A US3826632A US 3826632 A US3826632 A US 3826632A US 00220674 A US00220674 A US 00220674A US 22067472 A US22067472 A US 22067472A US 3826632 A US3826632 A US 3826632A
Authority
US
United States
Prior art keywords
black liquor
dimethylamide
petroleum fuel
burning
fuel oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00220674A
Other languages
English (en)
Inventor
F Morgan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Buckman Laboratories International Inc
Original Assignee
Buckman Labor Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE791548D priority Critical patent/BE791548A/xx
Application filed by Buckman Labor Inc filed Critical Buckman Labor Inc
Priority to US00220674A priority patent/US3826632A/en
Priority to CA155,884A priority patent/CA970156A/en
Priority to NO4029/72A priority patent/NO135531C/no
Priority to AU48584/72A priority patent/AU462105B2/en
Priority to ZA727944A priority patent/ZA727944B/xx
Priority to DE2255214A priority patent/DE2255214A1/de
Priority to FI3189/72A priority patent/FI54951C/fi
Priority to FR7243435A priority patent/FR2169034B1/fr
Priority to BR73165A priority patent/BR7300165D0/pt
Priority to JP665773A priority patent/JPS5418282B2/ja
Priority to SE7300985A priority patent/SE391751B/xx
Application granted granted Critical
Publication of US3826632A publication Critical patent/US3826632A/en
Assigned to BULAB HOLDINGS, INC. reassignment BULAB HOLDINGS, INC. CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: BUCKMAN LABORATORIES, INC.,
Assigned to BUCKMAN LABORATORIES INTERNATIONAL, INC. reassignment BUCKMAN LABORATORIES INTERNATIONAL, INC. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: BULAB HOLDINGS, INC.
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/224—Amides; Imides carboxylic acid amides, imides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/12—Combustion of pulp liquors
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • This invention relates to the burning of petroleum fuel oils and high solids content black liquor and, more particularly, it constitutes an improvement over known processes involving the burning of the heavier grades of petroleum fuel oils such as those designated No. and No. 6 fuel oils and high solids content black liquor.
  • black liquor is the spent cooking liquor from the digesters plus the filtrate from the Washing operation. It is concentrated first in a multiple effect evaporator, next in a cascade or cyclone evaporator (a direct heat transfer device), then further concentrated by adding thereto a salt cake makeup and collected dust from the flue gas and hoppers, and finally heated prior to firing in the furnace. Inorganic components (sodium salts) in the concentrated black liquor are recovered in this burning operation as molten ash or smelt for reuse in the cooking liquor. Since all of these operations are well known in the art, a discussion thereof will not be repeated here.
  • Suitable N,N-dirnethylamides of straight chain carboxylic acids are those prepared from carboxylic acids containing 18 carbon atoms. The acids are further characterized by having at least one carbon to carbon double bond. Specific acids classified within this category include: oleic, linoleic, linolenic, ricinoleic, and mixtures thereof.
  • the N,N-dimethylamides of the foregoing acids are identified as N,N-dirnethyloleamide, N,N-dimethyllinoleamide, N,N-dimethyllinolenamide, and N,N-dimethylncinoleamide, respectively.
  • these amides may be added to the cyclone, to the venturi scrubber, or preferably to the salt cake mixer.
  • suitable quantities vary from about 10 to about 500 parts per million parts of black liquor or fuel oil.
  • the amount used varies from about to 100 parts per million parts of black liquor or fuel oil.
  • EXAMPLE 1 In this example the effectiveness of dimethylamide as an aid in processes involving the burning of high solids black liquor was determined by comparing the results of a series of runs in the presence of dimethylamide to a similar series of runs in the absence of that compound.
  • Example 2 Relative viscosity, Decrease in parts per million ccntipoises viscosity, percent EXAMPLE 2
  • the experimental procedures summarized in Example 1 were repeated in which the N,N-dimethylamides of the mixed acids found in castor, corn, cottonseed, linseed, olive, peanut, and soybean oils were used instead of the N,N-dimethylamides of tall oil fatty acids.
  • the results were similar to those obtained in Example 1.
  • a process of burning a viscous liquid fuel selected from the group consisting of petroleum fuel oil and black liquor comprising:
  • straight chain carboxylic acid is a mixture of straight chain carboxylic acids containing 18 carbon atoms and at least one carbon to carbon double bond.
  • N,N-dimethylamide is N,N-dimethyllinoleamide.
  • N,N-dimethy1 amide is N,N-dimethyllinolenamide.
  • N,N-dimethy1- amide is N,N-dimethylricinoleamide.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)
US00220674A 1972-01-25 1972-01-25 Petroleum fuel oil and black liquor combustion Expired - Lifetime US3826632A (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
BE791548D BE791548A (fr) 1972-01-25 Combustion amelioree d'huile combustible de petrole et de liqueur noir
US00220674A US3826632A (en) 1972-01-25 1972-01-25 Petroleum fuel oil and black liquor combustion
CA155,884A CA970156A (en) 1972-01-25 1972-11-06 Petroleum fuel oil and black liquor combustion
AU48584/72A AU462105B2 (en) 1972-01-25 1972-11-07 Petroleum fuel oil and black liquor combustion
NO4029/72A NO135531C (ja) 1972-01-25 1972-11-07
DE2255214A DE2255214A1 (de) 1972-01-25 1972-11-10 Verbrennung von mineralischem heizoel und pulperablaugen
ZA727944A ZA727944B (en) 1972-01-25 1972-11-10 Petroleum fuel oil and black liquor combustion
FI3189/72A FI54951C (fi) 1972-01-25 1972-11-14 Foerfarande foer framstaellning av ett viskoest flytande braensle naemligen tung braennolja och/eller svartlut
FR7243435A FR2169034B1 (ja) 1972-01-25 1972-12-06
BR73165A BR7300165D0 (pt) 1972-01-25 1973-01-09 Combustao do oleo combustivel de petroleo e do licor negr
JP665773A JPS5418282B2 (ja) 1972-01-25 1973-01-16
SE7300985A SE391751B (sv) 1972-01-25 1973-01-24 Sett vid forbrenning av ett viskost flytande brensle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00220674A US3826632A (en) 1972-01-25 1972-01-25 Petroleum fuel oil and black liquor combustion

Publications (1)

Publication Number Publication Date
US3826632A true US3826632A (en) 1974-07-30

Family

ID=22824499

Family Applications (1)

Application Number Title Priority Date Filing Date
US00220674A Expired - Lifetime US3826632A (en) 1972-01-25 1972-01-25 Petroleum fuel oil and black liquor combustion

Country Status (12)

Country Link
US (1) US3826632A (ja)
JP (1) JPS5418282B2 (ja)
AU (1) AU462105B2 (ja)
BE (1) BE791548A (ja)
BR (1) BR7300165D0 (ja)
CA (1) CA970156A (ja)
DE (1) DE2255214A1 (ja)
FI (1) FI54951C (ja)
FR (1) FR2169034B1 (ja)
NO (1) NO135531C (ja)
SE (1) SE391751B (ja)
ZA (1) ZA727944B (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4734103A (en) * 1987-07-22 1988-03-29 Nalco Chemical Company Viscosity/drag reducing additive for high solids black liquor

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0122143Y2 (ja) * 1980-04-17 1989-06-29
US5388644A (en) * 1993-02-08 1995-02-14 Buckman Laboratories International, Inc. Application of N,N-dialkylamides to reduce precipitation of asphalt from crude oil

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4734103A (en) * 1987-07-22 1988-03-29 Nalco Chemical Company Viscosity/drag reducing additive for high solids black liquor

Also Published As

Publication number Publication date
BR7300165D0 (pt) 1973-09-25
BE791548A (fr) 1973-03-16
FI54951C (fi) 1979-04-10
JPS5418282B2 (ja) 1979-07-06
SE391751B (sv) 1977-02-28
NO135531C (ja) 1977-04-20
ZA727944B (en) 1973-07-25
FR2169034A1 (ja) 1973-09-07
NO135531B (ja) 1977-01-10
FI54951B (fi) 1978-12-29
CA970156A (en) 1975-07-01
AU462105B2 (en) 1975-06-12
JPS4883428A (ja) 1973-11-07
DE2255214A1 (de) 1973-07-26
FR2169034B1 (ja) 1976-06-04
AU4858472A (en) 1974-05-09

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Legal Events

Date Code Title Description
AS Assignment

Owner name: BUCKMAN LABORATORIES INTERNATIONAL, INC., 1256 NOR

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:BULAB HOLDINGS, INC.;REEL/FRAME:004772/0269

Effective date: 19871016

Owner name: BULAB HOLDINGS, INC.

Free format text: CHANGE OF NAME;ASSIGNOR:BUCKMAN LABORATORIES, INC.,;REEL/FRAME:004800/0892

Effective date: 19870924

Owner name: BUCKMAN LABORATORIES INTERNATIONAL, INC.,TENNESSEE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:BULAB HOLDINGS, INC.;REEL/FRAME:004772/0269

Effective date: 19871016

Owner name: BULAB HOLDINGS, INC., DISTRICT OF COLUMBIA

Free format text: CHANGE OF NAME;ASSIGNOR:BUCKMAN LABORATORIES, INC.,;REEL/FRAME:004800/0892

Effective date: 19870924