US3587220A - Differential shrinkage yarn and fabric made therefrom - Google Patents

Differential shrinkage yarn and fabric made therefrom Download PDF

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Publication number
US3587220A
US3587220A US757479A US3587220DA US3587220A US 3587220 A US3587220 A US 3587220A US 757479 A US757479 A US 757479A US 3587220D A US3587220D A US 3587220DA US 3587220 A US3587220 A US 3587220A
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US
United States
Prior art keywords
fibers
shrinkage
percent
fabric
polyester
Prior art date
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Expired - Lifetime
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US757479A
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English (en)
Inventor
Philip William Eggleston
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Imperial Chemical Industries Ltd
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Imperial Chemical Industries Ltd
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Publication of US3587220A publication Critical patent/US3587220A/en
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Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/18Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by combining fibres, filaments, or yarns, having different shrinkage characteristics

Definitions

  • woven or knitted fabrics comprising 65-90 percent by weight of polyester staple fibers of which l5-40 percent expressed on weight of the fabric are fibers having a shrinkage as hereinafter defined of at least 25 percent and 75-25 percent by weight are polyester fibers of normal shrinkage, at least some of either kind of polyester fibers being melt colored polyester fibers and 35-10 percent expressed on the weight of the fabric of wool or cellulosic fibers.
  • yarns comprising at least 65 percent by weight of polyester staple fibers of which -40 percent expressed on weight of the fabric are fibers having a shrinkage as hereinafter defined of at least percent and 75-25 percent by weight are polyester fibers of normal shrinkage, at least some of either kind of polyester fibers being melt colored polyester fibers and 10 percent expressed on the weight of the fabric of wool or cellulosic fibers.
  • Fabrics according to the invention have an attractive handle and bulkiness. Moreover, if the polyester fibers have an intrinsic viscosity of about 0.40-0.50 (measured in solution in ochlorophenol at 25 C.) the fabrics will show a reduced tendency to pilling in addition to the other desirable properties.
  • the fabric may be composed wholly of yarns which are a uniform blend of melt colored polyester fibers and polyester fibers having a shrinkage of at least 25 percent.
  • the fabric may be composed wholly of yams which are a uniform blend of melt colored polyester fibers of normal shrinkage, polyester fibres having a shrinkage of at least 25 percent and wool or cellulosic fibers.
  • the high shrinkage polyester fibers and the wool or cellulosic fibers may both be uncolored or they may be dyed to a color which is the same as dr different from the melt colored fibers.
  • the fabrics may be composed of yarns containing a uniform blend of melt colored polyester fibers having a high shrinkage, polyester fibers of normal shrinkage which may also be melt colored and cellulosic or wool fibers.
  • Yet another alternative is to produce fabric comprising yarns of at least two of the three foregoing types. In finishing such fabrics a treatment in hot water or hot air is given to produce bulk in the fabric by shrinkage of the high shrinkage components and consequent buckling of the lower shrinkage components. These heat treatments may take the form of the normal scouring or drying processes and the fabric is treated under conditions which allow the shrinkage to occur.
  • the temperature of treatment is at least 55 C. for
  • lf fabrics according to the invention are to be produced from yarns differing in their propensity to bulk when heat treated the yarns may be mixed according to a specified pattern in the weaving or knitting operation.
  • a fabric may be produced from yarns which are a mixture of melt colored high or low shrinkage polyester fibers and low or high shrinkage polyester fibers and cellulosic or wool fibers, such that there are both high and low shrinkage components therein and yarns of lower or little bulking propensity which may include melt colored polyester and cellulosic or wool fibers. In this way a fabric having a pattern of bulked and unbulked parts may be produced.
  • Fabrics according to the invention exhibit good handle and bulkiness up to the highest proportion of polyester staple fibers so long as there is present sufficient high shrinkage polyester fibers to produce the desired bulking effect.
  • proportion of normal shrinkage polyester fibers is increased the proportion of high shrinkage polyester fibers should also be increased.
  • the proportion of melt colored polyester fibers in the yarns depends upon whether these fibers are also of high shrinkage, in which case the foregoing considerations apply and on what degree of patterning effect, as herein described, is desired.
  • melt colored polyester fibers which also have a shrinkage of at least 25 percent, are blended with low shrinkage uncolored or white pigmented polyester fibers and cellulosic or wool fibers to produce a yarn from which a fabric is constructed.
  • the fabric is then subjected to a heat treatment, preferably at about 60 C., in water, which causes shrinkage of the colored fibers and a lightening of the fabric color by concentration of these fibers within the yarn.
  • a heat treatment preferably at about 60 C., in water, which causes shrinkage of the colored fibers and a lightening of the fabric color by concentration of these fibers within the yarn.
  • color patterning of a fabric may be achieved by using yarns containing high shrinkage melt colored polyester fibers with uncolored or white low shrinkage fibers and yarns containing low shrinkage melt colored or dyed polyester fibers.
  • the fabric is constructed in the form of the pattern from yarns containing melt colored polyester staple fibers of shrinkage at least 25 percent blended with uncolored or white low shrinkage polyester and/or wool or cellulosic staple fibers and yarns containing low shrinkage melt colored or dyed polyester staple fibers and the fabric is subjected to a shrinkage treatment.
  • the fabric contains 65-90 percent by weight of polyester staple fibers of which 15-40 percent by weight of the fabric have a shrinkage of at least 25 percent and 75-25 percent by weight of the fabric have a normal shrinkage and 35-10 percent by weight of the fabric of cellulosic or wool fibers.
  • the yarns containing low shrinkage melt colored polyester staple fibers may be composed wholly of such fibers or may also contain low shrinkage polyester or cellulosic or wool fibers.
  • low or normal shrinkage fibers as used herein is meant fibers of low shrinkage usually less than about 5 percent and frequently in the case of polyester staple fibers less than I percent.
  • the term includes cellulosic and wool fibers.
  • Shrinkage of the high shrinkage fibers used in this invention should be at least 25 percent and is preferably of the order of 40-50 percent or even higher and the proportion of these fibers in the yarns depends upon their shrinkage and also upon the effect desired. In general the higher the shrinkage the lower the proportion of high shrinkage fibers required.
  • cellulosic fibers as used herein means natural or regenerated cellulosic staple fibers, as for example cotton, viscose and fiax fibers and staple fibers of cellulose derivatives such as cellulose triacctate.
  • polyester fibers which may be produced in melt colored and high shrinkage forms may be used in this invention, as for example poly(ethylene terephthalate).
  • Melt coloration is a known process wherein uncolored or white polymer is colored before conversion into fibers by intimate mixture of the powdered or granular olymer with a finely divided pigment or dyestuff composition which is stable in the fibre spinning process.
  • polyester fibers by melt or solution spinning it is usual to heat treat the fibers so as to reduce their subsequent shrinkage propensity, as for example, by heat treatment of the running yarn at constant length during drawing or heat treatment in the relaxed state after drawing, the temperature of treatment being in excess of that to which the fibers are to be exposed later.
  • this heat stabilization treatment is omitted and the strains of drawing remain in the fibers to produce shrinkage on subsequent heat treatment.
  • the shrinkage propensity of the drawn fibers may also be enhanced by using a low draw ratio.
  • shrinkage when mentioned herein means the shrinkage of the fibers in the substantially free state.
  • the measurement may be made either using a length of the fibrous material before cutting into staple lengths or using a number of staple fibers (as for example ten) secured at one end and immersed for minutes in boiling water; the shrinkage is the reduction in length expressed as a percentage of the initial length of the length of material or of the total length of the individual fibers.
  • a small weight is attached to the free end which is sufficient to cause the specimen to sink but insufficient to impede shrinkage.
  • Fabrics according to the invention have the important advantage of not requiring to be dyed, which allows a greater degree of control over the point in fabric finishing at which shrinkage is incurred, some additional control of coloration effects in that melt colored, uncolored and dyed fibers may be mixed in various ways and according to the process hereinbe fore described novel patterned efi'ects to be obtained.
  • the fabrics also have a very attractive bulk and soft handle.
  • a blend consisting of percent by weight of melt colored black poly(ethylene terephthalate) staple fibers (intrinsic viscosity 0.45) of denier 3, length 87 mm. and shrinkage 40 percent; 50 percent white (pigmented with titanium dioxide) poly(ethylene terephthalate) staple fibers (intrinsic viscosity 0.45) of denier 4, length 87 mm. and shrinkage less than 1 percent and 25 percent uncolored 70 wool is spun to 2/30's worsted count with singles and ply twists of 430 turns per meter 2" and 430 turns per meter 8 respectively.
  • a 2/2 twill fabric with a loom sett of l8 ends per cm. by 20 picks per cm. is woven from this yarn and the fabric is relaxed in water at 60 C., and then given a conventional scouring and cropping to finish it.
  • the loomstate fabric is grey which after relaxing and finishing is a lighter shade of grey. This fabric has an attractive soft handle and 20 percent greater. bulk (measured by the fabric thickness) than a similar fabric in which the high shrinkage melt colored fibers are replaced by melt colored fibers of shrinkage less than 1 percent.
  • a fabric having a patterned effect is produced by weaving a 2/2 twill fabric from warp yarns composed of 25 percent by weight melt colored blue poly(ethylene terephthalate) staple fibers (intrinsic 'viscosity 0.45) of denier 3, length 87 mm.
  • the fabric having a loom sctt of 22 ends per cm. by 22 picks per cm. is finished as in the foregoing embodiment to produce a bulky fabric of attractive appearance and good handle.
  • Yarn comprising at least 65 percent by weight of polyester staple fibers of which l5-40 percent expressed on weight of the yarn are fibers having a shrinkage of at least 25 percent and 7525 percent by weight of the yarn are polyester fibers having a shrinkage of less than about 5 percent, at least some of either kind of polyester fibers being melt colored polyester fibers and 35-10 percent expressed on the weight of the yarn of wool or cellulosic fibers.
  • Fabrics according to claim 2 comprising 6590 percent by weight expressed on the weight of the fabric of said staple fibers of which l540 percent expressed on weight of the fabric are fibers having a shrinkage of at least 25 percent and 7525 percent by weight are fibers of low shrinkage, at least some of either kind of said fibers being melt colored fibers and 35-l0 percent expressed on the weight of the fabric of fibers selected from the group consisting of wool fibers and cellulosic fibers.
  • Fabrics according to claim 2 comprising 75 percent by weight of said fibers and 25 percent by weight of wool.
US757479A 1967-09-13 1968-09-04 Differential shrinkage yarn and fabric made therefrom Expired - Lifetime US3587220A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB4179567 1967-09-13
GB3336668 1968-07-12

Publications (1)

Publication Number Publication Date
US3587220A true US3587220A (en) 1971-06-28

Family

ID=26261841

Family Applications (2)

Application Number Title Priority Date Filing Date
US757479A Expired - Lifetime US3587220A (en) 1967-09-13 1968-09-04 Differential shrinkage yarn and fabric made therefrom
US57845A Expired - Lifetime US3676906A (en) 1967-09-13 1970-06-16 Process for making a patterned fabric by using differential shrinkage yarns

Family Applications After (1)

Application Number Title Priority Date Filing Date
US57845A Expired - Lifetime US3676906A (en) 1967-09-13 1970-06-16 Process for making a patterned fabric by using differential shrinkage yarns

Country Status (5)

Country Link
US (2) US3587220A (xx)
BE (1) BE720751A (xx)
DE (1) DE1785349A1 (xx)
FR (1) FR1583329A (xx)
NL (1) NL6813078A (xx)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3686850A (en) * 1969-12-19 1972-08-29 Ici Ltd Staple fibers for blends
US3797221A (en) * 1970-04-06 1974-03-19 Teijin Ltd False twist-crimped polyester yarns and process for their production
US3936999A (en) * 1970-04-06 1976-02-10 Teijin Ltd. False twist-crimped polyester yarns production
US4384450A (en) * 1979-08-13 1983-05-24 Celanese Corporation Mixed fiber length yarn
US4466237A (en) * 1980-12-16 1984-08-21 Celanese Corporation Mixed fiber length yarn
US4600644A (en) * 1982-06-10 1986-07-15 Monsanto Company Polyester yarn, self-texturing in fabric form
US4809493A (en) * 1985-11-01 1989-03-07 Kuraray Company Limited Water-absorbing shrinkable yarn
US4839211A (en) * 1988-03-31 1989-06-13 Monsanto Company Saxony carpet having improved appearance retention
US4882222A (en) * 1988-03-31 1989-11-21 Monsanto Company Carpet fiber blends
US4991387A (en) * 1988-03-30 1991-02-12 Teijin Limited Polyester and cotton blended yarn and polyester staple fiber stock used therein
US5888914A (en) * 1996-12-02 1999-03-30 Optimer, Inc. Synthetic fiber fabrics with enhanced hydrophilicity and comfort
US20150068254A1 (en) * 2013-09-06 2015-03-12 Paul Urban Geiwald Environmentally friendly non-bleed polyester fabric and method of manufacturing the same
US9845555B1 (en) 2015-08-11 2017-12-19 Parkdale, Incorporated Stretch spun yarn and yarn spinning method

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3831233A (en) * 1972-02-09 1974-08-27 Richen Co Process for heat treating multi-component yarns
JPS4985204A (xx) * 1972-12-20 1974-08-15
BG39917A1 (en) * 1982-10-29 1986-09-15 Bakhchevanov Method for manufacture of fabric
CA1235044A (en) * 1983-05-04 1988-04-12 Fumio Shibata High density, water-repellent textile fabric
US6063473A (en) * 1993-02-26 2000-05-16 Xymid L.L.C. Abrasion-resistant composite sheet
US5983470A (en) * 1998-06-26 1999-11-16 Milliken & Company Method to produce bulked deep dyed fabric
JP2004104261A (ja) * 2002-09-05 2004-04-02 Sharp Corp 通信端末機
US20190053653A1 (en) * 2017-08-17 2019-02-21 The Boeing Company Light transmissive carpet for vehicle

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3251097A (en) * 1963-10-07 1966-05-17 Eastman Kodak Co Methods for producing blended yarn
BE664663A (xx) * 1964-06-01 1965-11-29
US3335466A (en) * 1965-04-23 1967-08-15 Du Pont Process for the manufacture of highbulk blended yarns
US3438193A (en) * 1965-09-14 1969-04-15 Mitsubishi Rayon Co Composite yarn and its manufacturing method
US3371475A (en) * 1965-09-20 1968-03-05 Du Pont Bulky, high-strength polyethylene terephthalate yarns
US3444681A (en) * 1966-03-08 1969-05-20 Du Pont Bulkable composite polyester yarn of continuous filaments having different residual shrinkage after boiloff
US3468121A (en) * 1966-08-09 1969-09-23 Toray Industries Method of producing sprinkly colored fibrous material
US3458986A (en) * 1968-04-12 1969-08-05 Eastman Kodak Co Composite yarn

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3686850A (en) * 1969-12-19 1972-08-29 Ici Ltd Staple fibers for blends
US3797221A (en) * 1970-04-06 1974-03-19 Teijin Ltd False twist-crimped polyester yarns and process for their production
US3936999A (en) * 1970-04-06 1976-02-10 Teijin Ltd. False twist-crimped polyester yarns production
US4384450A (en) * 1979-08-13 1983-05-24 Celanese Corporation Mixed fiber length yarn
US4466237A (en) * 1980-12-16 1984-08-21 Celanese Corporation Mixed fiber length yarn
US4600644A (en) * 1982-06-10 1986-07-15 Monsanto Company Polyester yarn, self-texturing in fabric form
US4809493A (en) * 1985-11-01 1989-03-07 Kuraray Company Limited Water-absorbing shrinkable yarn
US4991387A (en) * 1988-03-30 1991-02-12 Teijin Limited Polyester and cotton blended yarn and polyester staple fiber stock used therein
US4839211A (en) * 1988-03-31 1989-06-13 Monsanto Company Saxony carpet having improved appearance retention
US4882222A (en) * 1988-03-31 1989-11-21 Monsanto Company Carpet fiber blends
AU608964B2 (en) * 1988-03-31 1991-04-18 Monsanto Company Carpet fiber blends
US5888914A (en) * 1996-12-02 1999-03-30 Optimer, Inc. Synthetic fiber fabrics with enhanced hydrophilicity and comfort
US20150068254A1 (en) * 2013-09-06 2015-03-12 Paul Urban Geiwald Environmentally friendly non-bleed polyester fabric and method of manufacturing the same
US9845555B1 (en) 2015-08-11 2017-12-19 Parkdale, Incorporated Stretch spun yarn and yarn spinning method

Also Published As

Publication number Publication date
NL6813078A (xx) 1969-03-17
BE720751A (xx) 1969-03-12
DE1785349A1 (de) 1972-01-13
US3676906A (en) 1972-07-18
FR1583329A (xx) 1969-10-24

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