US3537809A - Swelling agents used in conjunction with reducing agents in proteinaceous textile setting process - Google Patents

Swelling agents used in conjunction with reducing agents in proteinaceous textile setting process Download PDF

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Publication number
US3537809A
US3537809A US422311A US3537809DA US3537809A US 3537809 A US3537809 A US 3537809A US 422311 A US422311 A US 422311A US 3537809D A US3537809D A US 3537809DA US 3537809 A US3537809 A US 3537809A
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United States
Prior art keywords
swelling
fabric
water
conjunction
setting process
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Expired - Lifetime
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US422311A
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English (en)
Inventor
Ulla Margareta Cednas
Ebba Marianne Karrholm
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Stiftelsen Svensk Textil-Forskning
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Stiftelsen Svensk Textil-Forskning
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/01—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof
    • D06M11/05—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with hydrogen, water or heavy water; with hydrides of metals or complexes thereof; with boranes, diboranes, silanes, disilanes, phosphines, diphosphines, stibines, distibines, arsines, or diarsines or complexes thereof with water, e.g. steam; with heavy water
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/54—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur dioxide; with sulfurous acid or its salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/67—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with cyanogen or compounds thereof, e.g. with cyanhydric acid, cyanic acid, isocyanic acid, thiocyanic acid, isothiocyanic acid or their salts, or with cyanamides; with carbamic acid or its salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides

Definitions

  • the term setting a fabric is to be understood as a process of releasing the internal stresses in the material and thereby to stabilize goods in their desired shape or dimension.
  • a substantially permanent setting of the fabric is obtained. After its setting, the fabric is stable to wetting, and the mechanical properties of the fibers do not change appreciably.
  • the 3 cloth or yarns are set in a desired shape which may be smooth or creased, said shape then being the state of equilibrium of the goods desired to be maintained, since the threads in the fabric are set in their wavy state and the internal stresses are balanced.
  • Fabric which is treated in smooth state according to the invention maintains the smooth state even after weaving. After the treatment, an improvement with respect to dry, and particularly wet wrinkling can be observed.
  • the method of setting yarn and fabric of wool or material chemically similar in nature is generally characterized in that the material (FIG. 1) is treated with chemicals swelling the fibers (FIG. 2) in the material, the said chemicals being in a state of solution, such as an aqueous solution, whereafter the textile material is deswelled. During the deswelling, the fiber dimension (FIG. 3) reverts to the initial phase.
  • the material is treated with chemicals breaking the secondary valences, such as hydrogen bonds, together with reducing agents for breaking cystine bridges, said agents breaking the primary valences, and thereby increasing the weight of the goods by about 40 to 400% whereafter the material is deswelled by rinsing with a solvent, so that bridges are rebuilt in the form of both hydrogen bonds and covalent bonds.
  • the deswelling solution may, in addition, contain chemicals facilitating the bridge building, such as hydrogen dona-tors, which results in a setting resistant to renewed water treatment, for example washlng.
  • the textile material, subsequent to its treatment with the swelling chemicals is treated by mechanical means to form, for example, pleats, plaits, embossings, for instance by milling, stretching, folding, mangling, embossing, the said deformations being set during the deswelling step.
  • mechanical means for example, pleats, plaits, embossings, for instance by milling, stretching, folding, mangling, embossing, the said deformations being set during the deswelling step.
  • the swelling chemicals are preferably urea and reducing agent, for example bisulfite or sulfite in aqueous solution, or in aqueous solution mixed with organic solvent, or guanidine and bisulfite, or sulfite in aqueous solution or in aqueous solution mixed with organic solvent, or monoacetanolaminesulfite in high concentration in aqueous solution or sodiumor ammonium thiocyanate and bisulfite or sulfite in aqueous solution or reducing agent, such as bisulfite, sulfite or thioglycolate, in aqueous solution mixed with organic solvent, the fabric being treated with the swelling solution during all of the swelling time or impregnated with the same from about 40% of goods weight and above said weight whereafter it is stored before the deswelling is carried out.
  • urea and reducing agent for example bisulfite or sulfite in aqueous solution, or in aqueous solution mixed with organic solvent, or
  • the wool fabric is subjected to a special treatment with a swelling solution containing 20 to 150 g./l. sodium bisulfite or sulfite in a solvent, or 20 to 200 g./l. bisulfite or sulfite in water in combination with 10 to 400 g./l. urea in solvent, or 10 to 600 g./l. urea in water at a temperature of 0 to 100 C., specially 10 to 100 C. and at a pH of about 3 to 9, a maximum effect being obtained at about pH 7, the treatment preferably being carried out at room temperature when the concentration is 200 to 600 g./l. urea and 20 to 200 g./l.
  • the swelling bath preferably having a pH of 3 to 9 and containing preferably 20 to 200 g./l. bisulfite or sulfite in combination with 10 to 600 g./l. specially 50 to 500 g./l. guanidine, sodium thiocyanate or ammonium thiocyanate, or containing 50 to 500 g./l. monoethanolaminesulfite and the swelling taking place at 0 to 100 C.
  • the swelling is carried out for 2 seconds to 24 hours, the swelling period being inversely proportional to the temperature for example about 5 seconds at 80 to 100 C., and 2 minutes to 24 hours at room temperature, the solvents which may be used being, for example, ethanol, propanol, isopropylalcohol or dioxan.
  • the deswelling solutions are preferably water or water mixed with an acid, or water mixed with organic solvent, or water mixed with a reagent increasing crossbridge rebuilding of the type found in keratine, such as formaldehyde.
  • the deswelling preferably occurs at a temperature of 0 to 100 C. and with water or with water and acid, for example acetic acid having a concentration from 0.5 percent by weight to saturation, or with sulphuric acid having a concentration from 0.5 percent by weight to saturation, whereafter the fabric may be rinsed with organic solvents, such as petroleum, trichlorethylene, toluene, glycol or glycerol for driving off the deswelling agents.
  • organic solvents such as petroleum, trichlorethylene, toluene, glycol or glycerol
  • the deswelling may also be effected by drying when the swelling agents are volatile, for example at 0 to 100 C. for 5 seconds to .24 hours.
  • the setting effect varies according to the swelling agent, concentration, pH, temperature, swelling bath time and to the rinsing and drying conditions.
  • Binding serge, 2/2 twill.
  • Yarn number warp and weft No. 2/42, twisted 4S0 r.p.m.
  • Modulus length of warp 390 weft: 370p.
  • urea per liter water stored at about 20 C. in rolled or folded state for 1 hour (or for 15 minutes to hours), rinsed in water, the fabric being maintained flat during the first part of the rinsing, and dried.
  • EXAMPLE 2 W001 fabric is impregnated with setting solution of g. sodium bisulfite and 15 g. sodium sulfite and 500 g. urea per liter water and treated according to Example 1.
  • EXAMPLE 3 W001 fabric is impregnated with setting solution of 400 g. monoethanolaminesulfite (27% $0 per liter water and treated as in Example 1.
  • EXAMPLE 5 W001 fabric is treated in setting solution according to Examples 1-5, then rinsed in water containing formaldehyde, during which rinsing the fabric must be kept flat, and dried.
  • EXAMPLE 7 W001 fabric is swelled according to Examples 1-5, then rinsed in water or water containing formaldehyde, during which rinsing the fabric is embossed by mechanical means.
  • EXAMPLE 8 W001 fabric is swelled according to Examples 1-5, then rinsed in water or water containing formaldehyde, the fabric during the steps of rinsing and drying being over fed both in longitudinal and transverse direction, or being 4 over fed in one direction and stretched in transverse direction. In this way stretch fabric is obtained.
  • a method of setting yarn and fabric textile material containing or consisting of wool or related proteinaceous fibers comprising swelling the material with a solution in water, methanol, ethanol, propanol or dioxane or a mixture of two or more thereof, containing at least grams per liter of a hydrogen bond breaking agent selected from urea, guanidine and monoethanolamine and at least 20 grams per liter of a water soluble sulfite or bisulfite at a pH of from about 3 to about 9, deswelling the material in water while maintaining the desired shape and dimension thereof and rinsing the deswelled material with an organic solvent.
  • a hydrogen bond breaking agent selected from urea, guanidine and monoethanolamine
  • a water soluble sulfite or bisulfite at a pH of from about 3 to about 9

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US422311A 1964-01-08 1964-12-30 Swelling agents used in conjunction with reducing agents in proteinaceous textile setting process Expired - Lifetime US3537809A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE00183/64A SE357587B (zh) 1964-01-08 1964-01-08

Publications (1)

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US3537809A true US3537809A (en) 1970-11-03

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US422311A Expired - Lifetime US3537809A (en) 1964-01-08 1964-12-30 Swelling agents used in conjunction with reducing agents in proteinaceous textile setting process

Country Status (7)

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US (1) US3537809A (zh)
BE (1) BE657971A (zh)
DE (1) DE1469480A1 (zh)
FR (1) FR1419346A (zh)
GB (1) GB1097976A (zh)
NL (1) NL6500251A (zh)
SE (1) SE357587B (zh)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3619118A (en) * 1970-01-14 1971-11-09 Colgate Palmolive Co Treatment of keratinous substrates
US3619117A (en) * 1970-01-14 1971-11-09 Colgate Palmolive Co Treatment of keratinous substrates
US3619114A (en) * 1970-01-14 1971-11-09 Colgate Palmolive Co Treatment of keratinous substrates
US4102642A (en) * 1976-04-30 1978-07-25 Banks John B Treatment of fabric comprising cotton or keratinous fibers for shrink resistance
US4793993A (en) * 1987-07-06 1988-12-27 Chesebrough-Pond's Inc. Crosslinking of hair thiols
US20100028286A1 (en) * 2008-07-31 2010-02-04 Jose Antonio Carballada Method and Composition for Stabilizing Hair Moisture Levels
US20100028279A1 (en) * 2008-07-31 2010-02-04 Jose Antonio Carballada Method and Composition for Maintaining Hair Dye Color
US20100120871A1 (en) * 2008-11-10 2010-05-13 Dawson Jr Thomas Larry Hair care compositions, methods, and articles of commerce that can increase the appearance of thicker and fuller hair
CN103966842A (zh) * 2014-05-15 2014-08-06 蒋国琴 一种桑蚕丝蓬松剂
US9358197B2 (en) 2012-06-15 2016-06-07 The Procter & Gamble Company Method employing polyols when chemically modifying the internal region of a hair shaft
WO2017019045A1 (en) * 2015-07-28 2017-02-02 Unshrinkit, Inc. Compositions and methods for treating keratinous material
US9986809B2 (en) 2013-06-28 2018-06-05 The Procter & Gamble Company Aerosol hairspray product comprising a spraying device
US10024841B2 (en) 2014-08-29 2018-07-17 The Procter & Gamble Company Device for testing the properties of fibres
US10131488B2 (en) 2015-06-01 2018-11-20 The Procter And Gamble Company Aerosol hairspray product comprising a spraying device
US11230807B2 (en) 2014-04-19 2022-01-25 52 Launch Llc Compositions and methods for treating keratinous material
US11311749B2 (en) 2011-09-15 2022-04-26 The Procter And Gamble Company Aerosol hairspray for styling and/or shaping hair

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110044670B (zh) * 2019-03-27 2022-08-09 广州金域司法鉴定技术有限公司 毛发中毒品提取试剂盒、提取方法和检测方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB443359A (en) * 1934-06-20 1936-02-20 Ici Ltd Compositions for setting animal fibres such as wool or hair
US2806762A (en) * 1951-10-24 1957-09-17 Armour & Co Method of chemically curling animal hair with sulfur dioxide in aqueous solution
US2836185A (en) * 1954-05-27 1958-05-27 Little Inc A Process of permanently setting hair with a hair-swelling solution of a bisulfite and a nitrogen-containing component
US2850351A (en) * 1955-08-19 1958-09-02 Joseph E Moore Process of reacting reduced keratin with cross-linking polyimides or polyamides and chemically modified keratin containing the aforesaid crosslinkages
US2983569A (en) * 1957-05-20 1961-05-09 Oreal Deformation of keratinous fibers with sulfite-borohydride composition
US3051544A (en) * 1959-02-12 1962-08-28 Stevens & Co Inc J P Lustered wool product and method of making the same
GB968534A (en) * 1959-06-20 1964-09-02 Wool Ind Res Association Improvements in or relating to means for imparting durable pleats, creases or other predetermined deformations in slivers yarns or fabrics consisting of or containing wool or other keratinous fibres
US3151439A (en) * 1962-07-09 1964-10-06 Deering Milliken Res Corp Process for making elastic keratinous yarns

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB443359A (en) * 1934-06-20 1936-02-20 Ici Ltd Compositions for setting animal fibres such as wool or hair
US2806762A (en) * 1951-10-24 1957-09-17 Armour & Co Method of chemically curling animal hair with sulfur dioxide in aqueous solution
US2836185A (en) * 1954-05-27 1958-05-27 Little Inc A Process of permanently setting hair with a hair-swelling solution of a bisulfite and a nitrogen-containing component
US2850351A (en) * 1955-08-19 1958-09-02 Joseph E Moore Process of reacting reduced keratin with cross-linking polyimides or polyamides and chemically modified keratin containing the aforesaid crosslinkages
US2983569A (en) * 1957-05-20 1961-05-09 Oreal Deformation of keratinous fibers with sulfite-borohydride composition
US3051544A (en) * 1959-02-12 1962-08-28 Stevens & Co Inc J P Lustered wool product and method of making the same
GB968534A (en) * 1959-06-20 1964-09-02 Wool Ind Res Association Improvements in or relating to means for imparting durable pleats, creases or other predetermined deformations in slivers yarns or fabrics consisting of or containing wool or other keratinous fibres
US3151439A (en) * 1962-07-09 1964-10-06 Deering Milliken Res Corp Process for making elastic keratinous yarns

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3619118A (en) * 1970-01-14 1971-11-09 Colgate Palmolive Co Treatment of keratinous substrates
US3619117A (en) * 1970-01-14 1971-11-09 Colgate Palmolive Co Treatment of keratinous substrates
US3619114A (en) * 1970-01-14 1971-11-09 Colgate Palmolive Co Treatment of keratinous substrates
US4102642A (en) * 1976-04-30 1978-07-25 Banks John B Treatment of fabric comprising cotton or keratinous fibers for shrink resistance
US4793993A (en) * 1987-07-06 1988-12-27 Chesebrough-Pond's Inc. Crosslinking of hair thiols
US7981167B2 (en) 2008-07-31 2011-07-19 The Procter & Gamble Company Method and composition for maintaining hair dye color
US20100028279A1 (en) * 2008-07-31 2010-02-04 Jose Antonio Carballada Method and Composition for Maintaining Hair Dye Color
US20100028286A1 (en) * 2008-07-31 2010-02-04 Jose Antonio Carballada Method and Composition for Stabilizing Hair Moisture Levels
US20100120871A1 (en) * 2008-11-10 2010-05-13 Dawson Jr Thomas Larry Hair care compositions, methods, and articles of commerce that can increase the appearance of thicker and fuller hair
US11311749B2 (en) 2011-09-15 2022-04-26 The Procter And Gamble Company Aerosol hairspray for styling and/or shaping hair
US9358197B2 (en) 2012-06-15 2016-06-07 The Procter & Gamble Company Method employing polyols when chemically modifying the internal region of a hair shaft
US9986809B2 (en) 2013-06-28 2018-06-05 The Procter & Gamble Company Aerosol hairspray product comprising a spraying device
US11230807B2 (en) 2014-04-19 2022-01-25 52 Launch Llc Compositions and methods for treating keratinous material
CN103966842A (zh) * 2014-05-15 2014-08-06 蒋国琴 一种桑蚕丝蓬松剂
US10024841B2 (en) 2014-08-29 2018-07-17 The Procter & Gamble Company Device for testing the properties of fibres
US10131488B2 (en) 2015-06-01 2018-11-20 The Procter And Gamble Company Aerosol hairspray product comprising a spraying device
WO2017019045A1 (en) * 2015-07-28 2017-02-02 Unshrinkit, Inc. Compositions and methods for treating keratinous material

Also Published As

Publication number Publication date
DE1469480A1 (de) 1969-08-07
FR1419346A (fr) 1965-11-26
NL6500251A (zh) 1965-07-09
SE357587B (zh) 1973-07-02
GB1097976A (en) 1968-01-03
BE657971A (zh) 1965-04-30

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