US3511783A - Superfatted soap bar containing a synergistic preservative mixture of ehdp and edta - Google Patents

Superfatted soap bar containing a synergistic preservative mixture of ehdp and edta Download PDF

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Publication number
US3511783A
US3511783A US621248A US3511783DA US3511783A US 3511783 A US3511783 A US 3511783A US 621248 A US621248 A US 621248A US 3511783D A US3511783D A US 3511783DA US 3511783 A US3511783 A US 3511783A
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United States
Prior art keywords
ehdp
edta
iron
copper
percent
Prior art date
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Expired - Lifetime
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US621248A
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English (en)
Inventor
John Walter Waring
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Lever Brothers Co
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Lever Brothers Co
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Publication date
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/34—Organic compounds, e.g. vitamins containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00—Preserving by using additives, e.g. anti-oxidants
    • C11B5/0071—Preserving by using additives, e.g. anti-oxidants containing halogens, sulfur or phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00—Preserving by using additives, e.g. anti-oxidants
    • C11B5/0092—Mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/36—Organic compounds containing phosphorus
    • C11D3/361—Phosphonates, phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene

Definitions

  • This invention relates to detergent bars.
  • antioxidants frequently used act by absorbing free radicals and thus terminate chain reactions independently of the method of initiation. in this process, the antioxidant is itself destroyed. Thus it is desirable to include a sequestering agent to lower the rate of initiation of free radicals. Inaddition to the sequestering agent another antioxidant is often included to absorb free radicals'initiated by any residual metal ions, or by photochemical or thermal energy sources.
  • a particular problem is the prevention of deterioration of'base odour, spotting and discoloration in super-fatted detergent bars, for example, in soap bars containing significant amounts of free fatty acid.
  • a typical super-fatted soap contains 10% (calculated -as a percentage of the total fatty matter) of free fatty acids but soaps containing 20% of free fatty acid are known.
  • the presence of metal ions, particularly iron and copper ions, in these soaps can be particularly troublesome: Petrolatum, mineral oils, lanoline or other such super-fatting agents can be used as well as fatty acids added separately or specially released in the bar.
  • a super-fatted non-soap detergent bar can contain as glycols, fatty acid amides, long-chain alkanolamides, in
  • EHDP diphosphonic acid
  • EDTA ethylene-diaminetetraacetic acid
  • the EHDP, the EDTA or bo may be in the form of their esters or, preferably, in the form of their salts.
  • Particularly preferred salts are the alkali-metal, ammonium or triethanolammonium,salts.
  • the invention provides a detergent bar containing a' synergistic mixture of EHDP and EDTA.
  • EHDP and EDTA used will depend to some extent on the particular detergent used but bars according to the invention can be provided by incorporating as little as 0.005% of EHDP in admixture with as little as 0.005% of EDTA.
  • the quantity of EHDP will, in general, be from 0.005% to 0.3% or even higher and that of EDTA 0.005 to 0.3% or higher.
  • a preferred detergent bar according to the invention contains between 0.01% and 0.08% EHDP and 0.01% and 0.08% EDTA by weight.
  • a particularly preferred detergent bar according to the invention contains about 0.02% EHDP and about 0.02% EDTA by weight.
  • the invention is particularly applicable to toilet bars for personal washing.
  • the invention is even more particularly applicable to super-fatted toilet bars for personal washing. In such bars deterioration in odour and colour is least welcome and the effect of metal ions is most acute as explained above.
  • the invention is particularly applicable to a detergent bar in which the detergent is soap, it will be appreciated that the invention is applicable to any detergent bar that contains an ingredient that contains a long-chain fatty residue. Such ingredients are liableto cause the odour and colour of the bar to deteriorate when metal ions, particularly copper and iron, are also present.
  • an ingredient that contains a long-chain fatty residue is meant a compound containing a C to C preferably C to C group.
  • the chain may be branched but should preferably be straight.
  • the compound will normally contain functional groups, as illustrated below.
  • the C to C group may contain one or more double bonds.
  • the invention is, for example, applicable to detergent bars containing, as major active, such non-soap detergents as olefin sulphonates (prepared by the sulphonation of olefins followed by hydrolysis and neutralisation), fatty acyl isothionates, fatty acyl taurides and fatty alcohol sulphates.
  • non-soap detergents as olefin sulphonates (prepared by the sulphonation of olefins followed by hydrolysis and neutralisation), fatty acyl isothionates, fatty acyl taurides and fatty alcohol sulphates.
  • the invention is also applicable to bars containing mixtures of soap and non-soap detergents.
  • the invention is applicable to bars containing a major proportion of a non-soap detergent together with a minor proportion of soap.
  • Non-superfatted bars large batch of dried soap chips, manufacture from 30% Tallow/20% Palm Kernel Oil fat charge, was 'oughly mixed to ensure homogeneity. Special precaus were taken to minimise metallic contamination in chips.
  • the batch was sub-divided into 16 sub-batches to each of 15 of these .was added fixed quantities of lution of EDTA and/or a solution of EHDP. In this 16 batches were obtained with all possible combinas of any one of 4 levels of EDTA (0, 0.03, 0.12 or with any one of 4 levels of EHDP (0, 0.03, 0.12 0.48%).
  • he ratio of copper/iron chosen approximates to the age ratio found in practice. Up to 1 p.p.m. copper 10 p.p.m. iron are frequently found in practice.
  • Base level of copper 0.3 p.p.m.
  • Base level of iron 4.6 p.p.m.
  • Non-superfatted bars A large batch of dried soap chips, manufactured from an tallow/20% palm kerneloil fat charge was thoroughly mixed to ensure homogeneity. Special precautions were taken to minimise metallic contamination in the chips. The batch was sub-divided into 30 sub-batches;
  • Eflec't a EHDR and EDTA on Non-superfatted Toilet Bars containing 1 .00 e 10 .IronAdded Copper and Ir gontaminantg-Total Scores from Panel Test for w 0111' Storage conditions: 28 days exposed unwrapped in awindow to northern day ght. t +14 7 Bero r e Additign of furthes gopper and iron: ase eve 0 copper .m; 2 4
  • ExaMPLE HI Method-of manufacture Superfattedsoap A large batch of soap] was manufactured from a 5 0% tal1ow/50% palmkernel oil fat charge and -sup'erfatted 2 .114 byt e ti of .10 fattya (calculated b centage of total'tattey matter), prepared-by acidification of the same soap base.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
US621248A 1966-03-11 1967-03-07 Superfatted soap bar containing a synergistic preservative mixture of ehdp and edta Expired - Lifetime US3511783A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB40915/66A GB1169551A (en) 1966-03-11 1966-03-11 Detergent Bar
GB1092666 1966-03-11
US62124867A 1967-03-07 1967-03-07

Publications (1)

Publication Number Publication Date
US3511783A true US3511783A (en) 1970-05-12

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Family Applications (1)

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US621248A Expired - Lifetime US3511783A (en) 1966-03-11 1967-03-07 Superfatted soap bar containing a synergistic preservative mixture of ehdp and edta

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US (1) US3511783A (en))
BE (1) BE695342A (en))
DE (1) DE1617217C3 (en))
ES (1) ES337844A1 (en))
FR (1) FR1516489A (en))
GB (1) GB1169551A (en))
LU (1) LU53165A1 (en))
NL (2) NL6703756A (en))

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4190549A (en) * 1977-12-26 1980-02-26 Kao Soap Co., Ltd. Soap for scouring pad
US4853143A (en) * 1987-03-17 1989-08-01 The Procter & Gamble Company Bleach activator compositions containing an antioxidant
EP0305747A3 (en) * 1987-08-31 1989-10-25 Olin Corporation Process and composition for providing reduced discoloration of pyrithiones
US5891834A (en) * 1995-09-19 1999-04-06 Colgate Palmolive Company Composition
JP3347511B2 (ja) 1995-02-20 2002-11-20 株式会社資生堂 固形石鹸組成物
WO2005051343A1 (en) * 2003-11-27 2005-06-09 Unilever Plc Stable personal wash soap composition and process to prepare the same

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3312611A1 (de) * 1983-04-08 1984-10-11 Röhm GmbH, 6100 Darmstadt Verfahren zur herstellung uv-geschuetzter mehrschichtiger kunststoff-formkoerper
US4515707A (en) * 1983-06-27 1985-05-07 The Chemithon Corporation Intermediate product for use in producing a detergent bar and method for producing same
FR2580625B1 (fr) * 1985-04-18 1991-06-28 Oreal Composition detartrante et/ou inhibitrice de la formation de tartre, destinee notamment au nettoyage des surfaces emaillees
GB8614462D0 (en) * 1986-06-13 1986-07-16 Unilever Plc Cleaning composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US214454A (en) * 1879-04-15 Improvement in rope-sheaves
US224976A (en) * 1880-02-24 Child s carriage
US226330A (en) * 1880-04-06 Passenger-elevator
US3368978A (en) * 1964-12-28 1968-02-13 Monsanto Co Builder compositions and detergent compositions using same
US3380924A (en) * 1959-02-06 1968-04-30 Henkel & Cie Gmbh Surface-active products

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US214454A (en) * 1879-04-15 Improvement in rope-sheaves
US224976A (en) * 1880-02-24 Child s carriage
US226330A (en) * 1880-04-06 Passenger-elevator
US3380924A (en) * 1959-02-06 1968-04-30 Henkel & Cie Gmbh Surface-active products
US3368978A (en) * 1964-12-28 1968-02-13 Monsanto Co Builder compositions and detergent compositions using same

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4190549A (en) * 1977-12-26 1980-02-26 Kao Soap Co., Ltd. Soap for scouring pad
US4853143A (en) * 1987-03-17 1989-08-01 The Procter & Gamble Company Bleach activator compositions containing an antioxidant
EP0305747A3 (en) * 1987-08-31 1989-10-25 Olin Corporation Process and composition for providing reduced discoloration of pyrithiones
AU614982B2 (en) * 1987-08-31 1991-09-19 Olin Corporation Process and composition for providing reduced discoloration of pyrithiones
JP3347511B2 (ja) 1995-02-20 2002-11-20 株式会社資生堂 固形石鹸組成物
US5891834A (en) * 1995-09-19 1999-04-06 Colgate Palmolive Company Composition
WO2005051343A1 (en) * 2003-11-27 2005-06-09 Unilever Plc Stable personal wash soap composition and process to prepare the same
CN1886116B (zh) * 2003-11-27 2010-06-16 荷兰联合利华有限公司 稳定的个人洗涤皂组合物及其制备方法

Also Published As

Publication number Publication date
LU53165A1 (en)) 1967-05-10
NL6703756A (en)) 1967-09-12
DE1617217C3 (de) 1975-03-13
DE1617217A1 (de) 1971-02-18
BE695342A (en)) 1967-09-11
DE1617217B2 (de) 1974-07-18
GB1169551A (en) 1969-11-05
FR1516489A (fr) 1968-03-08
ES337844A1 (es) 1968-06-16
NL137165C (en))

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