US2813512A - Method of improving the life of ballpoint writing instruments - Google Patents
Method of improving the life of ballpoint writing instruments Download PDFInfo
- Publication number
- US2813512A US2813512A US355536A US35553653A US2813512A US 2813512 A US2813512 A US 2813512A US 355536 A US355536 A US 355536A US 35553653 A US35553653 A US 35553653A US 2813512 A US2813512 A US 2813512A
- Authority
- US
- United States
- Prior art keywords
- ball
- socket
- ink
- writing
- point
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 14
- 239000000976 ink Substances 0.000 description 26
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 238000005530 etching Methods 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000007747 plating Methods 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000007769 metal material Substances 0.000 description 5
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 238000003490 calendering Methods 0.000 description 4
- 238000005498 polishing Methods 0.000 description 4
- 229910001369 Brass Inorganic materials 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910052762 osmium Inorganic materials 0.000 description 3
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 239000010948 rhodium Substances 0.000 description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910001340 Leaded brass Inorganic materials 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- UTYIBAVCADPQIQ-UHFFFAOYSA-N [Pb].[Zn].[Sn].[Cu] Chemical compound [Pb].[Zn].[Sn].[Cu] UTYIBAVCADPQIQ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010961 commercial manufacture process Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K1/00—Nibs; Writing-points
- B43K1/08—Nibs; Writing-points with ball points; Balls or ball beds
Definitions
- This invention relates to improvements in the construction of ball-pointed writing instruments and is particularly directed to means and methods whereby the writing characteristics and effective life of ball-point pens are improved and prolonged.
- ball-point writing instruments have been known for many years (see Patents No. 189,304, No. 370,599, No. 853,156, No. 1,046,821, No. 1,179,086, No. 1,426,200, No. 2,192,479, etc.) the commercial manufacture of such pens at the rate of several million per month while maintaining the quality and performance characteristics which the purchasing public requires has presented problems which have not been solved heretofore.
- This invention is directed to means and methods whereby readily available metals and materials can be utilized in the construction of the pens and whereby commonly employed and inexpensive mechanical operations can be employed in the solution of the problems, thereby permitting the attainment of the desired objectives without greatly disturbing existing manufacturing procedures and without appreciable increase in cost.
- the present invention provides means and methods whereby the traction between the small ball (which transfers ink or writing fluid from a supply carried in a cartridge to a writing surface) and the writing surface is increased and enhanced so that the ball does not slide or skip upon a calendered or slightly oily surface and thereby fail to write, but instead deposits ink as soon as contact and relative motion is established. Furthermore, it has been discovered that some of the dilficulties encountered heretofore have been due to a galvanic or electrolytic action and resulting corrosion between parts of a writing instrument, which impaired or destroyed the carefully predetermined clearances and required tolerances and affected the rate at which ink was supplied to the ball, its ink-carrying power, its free rotatability, etc. This invention provides means and methods whereby such galvanic action may be inhibited and permits the use of inks which could not be employed heretofore.
- Fig. 1 is an enlarged sectional view of a socket point for use in a ball-point pen.
- Fig. 2 is an enlarged sectional view of a socket point provided with a ball.
- Fig. 3 is a diagram of fiow chart illustrating operations which may be carried out pursuant to this invention.
- FIG. 4 is an end view of the socket or cavity of the point illustrated in Fig. 1.
- a typical ball-retaining socket point for use with writing instruments of the character here contemplated is indicated in Fig. l and generally comprises a relatively long, small diameter shank 10 carried by a larger head 11, said head being adapted for attachment to one end or a cartridge tube 12, in which a supply of writing fluid is contained.
- Extending axially through the head and shank is an ink supply bore 15 leading to an enlarged socket or recess 16, the outer walls of the shank being tapered as indicated at 17 in order to leave a thin lip around the edge of the socket.
- the diameter of the recess or socket 16 is adequate to receive the writing ball.
- the bottom 18 of the socket 16 is generally formed with a series of radial grooves 18'.
- the socket points are preferably made from a malleable, readily machinable metal or alloy, such as for example, a leaded brass (copper-tin-zinc-lead). lt is necessary to use a readily machinable, free-cutting metal in order to be able to produce the socket points in the very large quantities necessary and still maintain the very close tolerances which must be maintained in view of the minute size of the parts. It is to be remembered that the ball which is seated and rotatably held by the socket point is only 0.039 in. in diameter.
- socket points of the character illustrated in Fig. l are lightly plated with a metal from the group consisting of nickel, copper, silver, platinum, gold, rhodium, osmium and chromium. A very light film of any one of such metals is applied to the previously machined socket point, the film generally ranging from 0.0001 to 0.001 inch, but not over 0.01 inch in thickness. Any normal or usual plating procedure is employed.
- a ball 20 is forcibly seated upon the tapered bottom 18 of the recess 16 and the thin edge portion 19 of the wall of the recess is swedged or rolled around the ball, the marginal edge portion of the wall extending slightly beyond a plane passing through the center of the ball 20.
- a suitable method for swedging and rollably holding the ball 20 within the recess of the socket point in described in U. S. Patent No. 2,498,009. It will be noted that in accordance with the present invention, the malleability of the metal of the socket point is utilized so as to facilitate the seating and swedging operations while the surface plating prevents or inhibits subsequent galvanic, electrolytic, or other corrosion.
- this surface plating is to provide an ink-contacting surface that has substantially the same potential as the writing ball so that any tendency toward electrolysis or undesirable electrolytic effect is virtually eliminated.
- the plating since the plating has been applied to the internal surfaces of the socket, a smoother surface is presented to the ball and the ball rolls and rotates within its socket more readily.
- the plating imparts wearing characteristics to the internal surfaces of the recess or socket, thereby preventing departure from tolerances established during the rolling and swedging, even though the pen or writing instrument is used for very prolonged periods of time.
- ballpoint writing instruments write by reason of the fact that ink is actually carried by the surface of the ball 20 and as the ball 20 rotates in its socket it picks up ink from the supply channel 15 and deposits or lays it down upon the surface over which the ball is rolled. If, however, the surface is highly calendered, excessively smooth, or slightly oily, the ball may not roll, but instead slide or skip, thcrcby failing to deposit ink in a continuous manner.
- the above objectional characteristics may be obviated by enhancing the traction of the ball without imparing its freely rotatable characteristics.
- the traction and rollability of the ball when used in writing upon a surface can be facilitated and enhanced by imparting a matte finish to the surface of the ball. This can be readily accomplished by subjecting the ball to an etching bath before it is seated and swedged into rollable retention within the socket point. Any suitable etching solution may be employed.
- Solutions of sulfuric acid, l%25% H2504, mixed acid solutions such as mixtures of hydrochloric and nitric acids or mixtures of hydrochloric and sulfuric acids, hydrochloric solutions such as a 50% HCl or solutions of nitric acid in ethyl or amyl alcohol may be employed.
- the etching bath should not be pro longed for a sufiicient time to impart a microscopically visible etch, it being sufficient if the etching solution imparts a microscopically visibly etched surface to the steel ball which now produces diffuse light reflection.
- the time during which balls are subjected to the etching bath will, or course, depend upon the temperatures employed and the activity of the etching solution.
- the etching time may vary from ten minutes to one hour, one hour with lll% sulfuric acid at room temperature being adequate.
- the balls may be subjected to a light polishing operation of short duration, although in most instances such polishing can be dispensed with. These etched balls can then be seated in a socket point in the same manner as unetched balls.
- the etching operation not only increases the traction between the ball and a writing surface (thereby insuring immediate rotation of a ball upon relative movement of a writing instrument in contact with a writing surface) but also appears to facilitate the distribution of ink. It is believed that the etched surfaces have a tendency to retain and carry slightly greater quantities of ink than the highly polished surfaces of normal balls. Any suitable method of etching the ball may be used.
- the later stages of manufacture include a series of tumbling steps during which the balls are polished; when an etched or matte finish is dcsired some of these last finishing steps may be eliminated or a matte finish obtained by changing the grade, fineness and hardness of the abrasive employed.
- the end result is a writing ball having a matte finish including polished areas conforming to a spherical surface and a multiplicity of fine ink-receiving craters indenting this surface and extending therebelow. such finish resulting from the light polishing of a pitted steel ball.
- the balls may be provided with a matte finish by very light plating under suitable conditions, or such matte finish may be imparted to the balls by mechanical means, as by being subjected to a high velocity stream of rouge or other fine abrasive.
- the present invention describes methods of improving the writing characteristics and life of ball-pointed writing instruments without interfering with normal manufacturing operations or the use of relatively soft, readily machinable materials.
- a tubular ball socket element made of readily machinable metal; ink in contact with said socket element; a metallic ball of a dissimilar metal from said socket element rotatably confined within a forward portion of said element and projecting therefrom; and a metallic material coating the inner wall of said socket element which is not reactive with said ink in the presence of said ball, said metallic material having substantially the same potential as said ball.
- a ball socket element made of a readily machinable metal; ink in contact with said socket element; a metallic ball of dissimilar metal from said socket element rotatably confined within a forward portion of said element and projecting therefrom, the surface of said ball having a matte finish including polished areas conforming to a spherical surface and a multiplicity of fine ink-receiving craters extending therebelow; and a metallic material coating the inner wall of said socket element which is not reactive with said ink in the presence of said ball, said metallic material having substantially the same potential as said ball and providing a smooth, wearresistant bearing-surface for said matte finished ball.
- An improved writing tip for ballpoint writing instruments comprising a metallic socket element rotatably mounting a steel ball and containing a quantity of ink, the surface of said ball having a matte finish including polished areas conforming to a spherical surface and a multiplicity of fine, ink receiving craters extending therebclow, and a metallic material coating the inner wall of the socket element and having a lower potential with respect to said ball than the socket element.
- said metallic coating being nonreactive with said ink in the presence of said steel ball and providing a relatively smooth, wear-resistant bearing surface for said ball.
- a tubular ball socket element made of readily machinable metal; ink in contact with said socket element; a metallic hail of a dissimilar metal from said socket clement rotatably confined within a forward portion of said element and projecting therefrom; at least the inner all of said socket element being of a material which is not reactive with said ink in the presence of said ball, said material having substantially the same potential as said ball.
Landscapes
- Pens And Brushes (AREA)
- Coating Apparatus (AREA)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US355536A US2813512A (en) | 1953-05-18 | 1953-05-18 | Method of improving the life of ballpoint writing instruments |
GB31285/57A GB828276A (en) | 1953-05-18 | 1957-10-07 | A writing instrument of the ball point type |
FR1184220D FR1184220A (fr) | 1953-05-18 | 1957-10-11 | Stylographe à bille |
CH344021D CH344021A (fr) | 1953-05-18 | 1957-10-15 | Stylographe à bille |
BE561706D BE561706A (enrdf_load_stackoverflow) | 1953-05-18 | 1957-10-17 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US355536A US2813512A (en) | 1953-05-18 | 1953-05-18 | Method of improving the life of ballpoint writing instruments |
Publications (1)
Publication Number | Publication Date |
---|---|
US2813512A true US2813512A (en) | 1957-11-19 |
Family
ID=10320849
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US355536A Expired - Lifetime US2813512A (en) | 1953-05-18 | 1953-05-18 | Method of improving the life of ballpoint writing instruments |
Country Status (5)
Country | Link |
---|---|
US (1) | US2813512A (enrdf_load_stackoverflow) |
BE (1) | BE561706A (enrdf_load_stackoverflow) |
CH (1) | CH344021A (enrdf_load_stackoverflow) |
FR (1) | FR1184220A (enrdf_load_stackoverflow) |
GB (1) | GB828276A (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2969030A (en) * | 1958-10-22 | 1961-01-24 | Kahn David Inc | Production of writing tips |
US5520473A (en) * | 1992-06-26 | 1996-05-28 | The Gillette Company | Ball point pen |
US20090094843A1 (en) * | 2007-10-16 | 2009-04-16 | James Keith Brannam Brannam | Escape cap |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH250923A (fr) * | 1945-06-07 | 1947-09-30 | Martin Henry George | Stylographe à bille rotative et procédé pour la fabrication de ce stylographe. |
DE829414C (de) * | 1950-09-05 | 1952-01-24 | Schneider G M B H Geb | Mine fuer Kugelschreiber |
US2646761A (en) * | 1947-08-13 | 1953-07-28 | W A Sheaffer Pen Co | Method of making ball-type writing tips |
-
1953
- 1953-05-18 US US355536A patent/US2813512A/en not_active Expired - Lifetime
-
1957
- 1957-10-07 GB GB31285/57A patent/GB828276A/en not_active Expired
- 1957-10-11 FR FR1184220D patent/FR1184220A/fr not_active Expired
- 1957-10-15 CH CH344021D patent/CH344021A/fr unknown
- 1957-10-17 BE BE561706D patent/BE561706A/xx unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH250923A (fr) * | 1945-06-07 | 1947-09-30 | Martin Henry George | Stylographe à bille rotative et procédé pour la fabrication de ce stylographe. |
US2646761A (en) * | 1947-08-13 | 1953-07-28 | W A Sheaffer Pen Co | Method of making ball-type writing tips |
DE829414C (de) * | 1950-09-05 | 1952-01-24 | Schneider G M B H Geb | Mine fuer Kugelschreiber |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2969030A (en) * | 1958-10-22 | 1961-01-24 | Kahn David Inc | Production of writing tips |
US5520473A (en) * | 1992-06-26 | 1996-05-28 | The Gillette Company | Ball point pen |
US20090094843A1 (en) * | 2007-10-16 | 2009-04-16 | James Keith Brannam Brannam | Escape cap |
Also Published As
Publication number | Publication date |
---|---|
FR1184220A (fr) | 1959-07-17 |
CH344021A (fr) | 1960-01-15 |
BE561706A (enrdf_load_stackoverflow) | 1958-04-17 |
GB828276A (en) | 1960-02-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102965719A (zh) | 薄膜金属和合金的低速率电化学蚀刻 | |
DE2008664A1 (en) | Galvanically or chemically assisted mechanic | |
US2813512A (en) | Method of improving the life of ballpoint writing instruments | |
US3052582A (en) | Process of chemical milling and acid aqueous bath used therefor | |
DE10207632A1 (de) | Verfahren zum Plasmapolieren von Titan und Titanlegierungen | |
AU1776097A (en) | Process for conditioning the copper or copper-alloy external surface of an element of a mould for the continuous casting of metals, of the type including a nickel plating step and a nickel removal step | |
DE2605177A1 (de) | Lagerteil und verfahren zu dessen herstellung | |
JP2001082481A (ja) | すべり軸受及びその製造方法 | |
GB966604A (en) | Improvements in or relating to the production of wear-resistant surfaces of measuring tools or gauges | |
US3502418A (en) | Heat-treated beryllium copper tip for a ball-point writing instrument and the method of producing same | |
US3661402A (en) | Piston ring | |
US2992904A (en) | Method of etching metallic writing balls | |
CN109321953B (zh) | 一种用于无氰碱性镀银的硬化剂及其应用 | |
JPS5830160B2 (ja) | ボ−ルペンヒツキセンタン ノ タメノ ボ−ルシシヨウケ−シング | |
US2506582A (en) | Electrolytic polishing of metals | |
Jett | A study of the gilding of Chinese Buddhist bronzes | |
GB711438A (en) | Improvements in or relating to plain bearings | |
GB873007A (en) | Method of manufacturing ball points for ball point pens | |
Clifford et al. | The incidence and avoidance of gassing defects in chemical and electropolishing of aluminium | |
JP3163785B2 (ja) | ボ−ルペンチップの製造方法 | |
Ratych et al. | Influence of Inhibitors in Static Corrosion Crack Resistance Tests of 40 Kh Steel Specimens | |
DE10060931A1 (de) | Verfahren zur Erzeugung von Oberflächenölreservoirs auf beschichtetem Eisen | |
JPS6465274A (en) | Production of antiqued external parts for timepiece | |
JPS5945517B2 (ja) | 硬質耐磨耗性装飾用外装部品及び製造方法 | |
Vyazovikina et al. | Use of the Rotating Disc Electrode With Ring for Studying Selective Dissolution of Brasses and Other Alloys |