US2548357A - Manufacture of textile fibers composed of casein - Google Patents

Manufacture of textile fibers composed of casein Download PDF

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Publication number
US2548357A
US2548357A US714130A US71413046A US2548357A US 2548357 A US2548357 A US 2548357A US 714130 A US714130 A US 714130A US 71413046 A US71413046 A US 71413046A US 2548357 A US2548357 A US 2548357A
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United States
Prior art keywords
bath
urea
casein
filaments
baths
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Expired - Lifetime
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US714130A
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English (en)
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Ferretti Antonio
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Individual
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Individual
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Publication of US2548357A publication Critical patent/US2548357A/en
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423Amino-aldehyde resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L89/00Compositions of proteins; Compositions of derivatives thereof
    • C08L89/005Casein
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F4/00Monocomponent artificial filaments or the like of proteins; Manufacture thereof

Definitions

  • a"processf composed of casein or partly or casein and pafift of? cellulose; comprisesspinning a solutionfmore especially an aque'oussqlutiong; of. casein or ..of
  • baths through which:the coagulated, iilament is passed-i1! :Qrfder to producefi i hedfibre may ciudezother baths.- additional to ,the baths- (a); and: Kb) mentioned above. for. example: deacidiflying and partially, hardening baths, as ingthe,
  • F t i ibiwm t zfr s est' o t dl r. going propertiesfantl a higheriorder of st'rength" with rynes and; moisture *o ffthe fibre are ob' .e, jr safeea a nuo i thiea i t rs'mslfi least th a or baths containing iorma'ldehyd'orafter *the" fila' it is out, it being: convenient to itreat in this manner a large number o'f filaments simultane ou'sly spunfin the coagulating?
  • a temperature above 28 C. may be employed in those baths or at least in the bath or one or more of the baths (1)) containing formaldehyde, as in the process forming the subject matter of the aforesaid U. S. patent applications No. 330,725, 348,992, both now abandoned and U. S. Patent No. 2,338,917, for example, if a temperature not above 25 C.
  • a temperature above 25 C. preferably a temperature of 70-75 C.
  • the fibre obtained will be much softer and larger after acid boiling than a urea-free fibre and from. this point of view, can be compared with a fibre treated with a chromium salt, but with the advantage, however, that the fibre retain a perfectly white appearance.
  • casein filaments alreadycoagulated but not yet insolubilized by formaldehyde cannot be treated with a simple solution of urea, as a simple solution of urea dissolves casein and in consequence the filament would at once dissolve in the solution.
  • a simple solution of urea dissolves casein and in consequence the filament would at once dissolve in the solution.
  • a saline solution of urea preferably concentrated and astringent
  • no dissolving of the filament occurs, but only a slight swelling of the filament, which can be adjusted at will by varyin the degree of concentration and/or the astringent capacity of the solution according to the amount of urea that has to be absorbed by the filament and to the degree of penetration of the urea that has to be obtained.
  • Urea may in some cases be present in the formaldehyde-free acid salt coagulating bath, but in general, coagulation of the filament is hindered and there tends to be a large loss of urea in the first de-acidifying bath following the coagulating bath.
  • An aqueous saline bath having the composition of the bath (1)) but containing in addition gms. of urea crystals per litre of the bath and more sodium chloride until the bath is saturated.
  • the fibres are now out to the required length after which they are treated, preferably in an autoclave, in an aqueous bath (e) containing gms. of aluminium sulphate, 200 gms. of sodium chloride and 40 gms. of 100% formaldehyde per litre, for 5-6 hours.
  • aqueous bath e
  • aluminium sulphate 200 gms. of sodium chloride
  • 40 gms. of 100% formaldehyde per litre for 5-6 hours.
  • the insolubilized fibres are now washed and treated in an aqueous bath or baths (1) of soluble phosphates, for instance such a bath containing 4 gms. of monosodium phosphate per litre, after which the fibres are washed again and dried.
  • the preferred temperature for the various baths are: 35 l0 C. for bath (a) 50-55 C. for bath (b):
  • Example II The procedure in this example is the same as in Example I, except that the filaments are out after bath (0) instead of after bath ((1), the out fibres being gathered together in a vessel containing bath ((1), in which they are treated for 3-4 hours at 35-40 C., then treated in bath (e) at 70-75 C. for 5-7 hours, then washed, then treated in the bath or baths (1) and finally, washed again and dried.
  • Example III The procedure in this example is the same again as in Example I, except that the filaments are out after the bath (b) instead of after bath (d), the cut filaments being gathered together in a vessel containing bath (0) in which they are treated for 2-3 hours at 35-40 C., and then, after having been squeezed out, in conformity with Example II, omitting bath (e).
  • urea as employed herein includes all soluble salts containing urea such for example as thio-urea.
  • the invention includes both the use of milkcasein and also the use of vegetable casein for example soya bean casein, either being used alone or the two in admixture with one another.
  • aqueous urea bath is rendered saline by the addition of sodium chloride and aluminum sulphate in the proportions, per liter, of about grams of urea crystals, about grams initially of sodium chloride, and about200 grams of aluminum sulphate; the sodium chloride content bein then increased unti]. substantial saturation is reached.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
US714130A 1941-03-06 1946-12-05 Manufacture of textile fibers composed of casein Expired - Lifetime US2548357A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT229823X 1941-03-06

Publications (1)

Publication Number Publication Date
US2548357A true US2548357A (en) 1951-04-10

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ID=11202548

Family Applications (1)

Application Number Title Priority Date Filing Date
US714130A Expired - Lifetime US2548357A (en) 1941-03-06 1946-12-05 Manufacture of textile fibers composed of casein

Country Status (7)

Country Link
US (1) US2548357A (fr)
BE (1) BE443631A (fr)
CH (1) CH229823A (fr)
DE (1) DE909491C (fr)
FR (1) FR921563A (fr)
GB (1) GB615305A (fr)
NL (1) NL66502C (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3179728A (en) * 1962-02-07 1965-04-20 Donini Sandro Process for the preparation of proteinureic fibres and mixed protein-ureic cellulosic fibres
DE1230967B (de) * 1961-02-07 1966-12-22 Sandro Donini Verfahren zum Herstellen von Textilfasern
US5431725A (en) * 1992-12-28 1995-07-11 Kiyoichi Matsumoto Casein molded article and method for preparing the same
US20040046277A1 (en) * 2000-11-28 2004-03-11 Horst Buerger Protein shaped body and method for the production thereof according to the nmmo method
US20130256942A1 (en) * 2010-12-15 2013-10-03 Qmilch Ip Gmbh Process for Producing Milk Protein Fibers and Milk Protein Fiber Products Obtained Therefrom
CN114351285A (zh) * 2022-03-09 2022-04-15 宜宾惠美纤维新材料股份有限公司 一种奶酪蛋白纤维及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB467812A (en) * 1935-10-22 1937-06-22 Albert Charles Chibnall Improvements in or relating to the production of artificial filaments, threads, films and the like
GB508781A (en) * 1937-11-25 1939-06-26 Eric Potter Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from phosphoproteins or conjugated proteins
US2211961A (en) * 1937-04-08 1940-08-20 Du Pont Artificial product and method for producing same
US2312998A (en) * 1938-03-01 1943-03-02 Kadt George Stephan De Process for hardening fibrous protein material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB467812A (en) * 1935-10-22 1937-06-22 Albert Charles Chibnall Improvements in or relating to the production of artificial filaments, threads, films and the like
US2211961A (en) * 1937-04-08 1940-08-20 Du Pont Artificial product and method for producing same
GB508781A (en) * 1937-11-25 1939-06-26 Eric Potter Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from phosphoproteins or conjugated proteins
US2312998A (en) * 1938-03-01 1943-03-02 Kadt George Stephan De Process for hardening fibrous protein material

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1230967B (de) * 1961-02-07 1966-12-22 Sandro Donini Verfahren zum Herstellen von Textilfasern
US3179728A (en) * 1962-02-07 1965-04-20 Donini Sandro Process for the preparation of proteinureic fibres and mixed protein-ureic cellulosic fibres
US5431725A (en) * 1992-12-28 1995-07-11 Kiyoichi Matsumoto Casein molded article and method for preparing the same
AU670123B2 (en) * 1992-12-28 1996-07-04 Kiyoichi Matsumoto Casein molded article and method for preparing the same
US20040046277A1 (en) * 2000-11-28 2004-03-11 Horst Buerger Protein shaped body and method for the production thereof according to the nmmo method
US20130256942A1 (en) * 2010-12-15 2013-10-03 Qmilch Ip Gmbh Process for Producing Milk Protein Fibers and Milk Protein Fiber Products Obtained Therefrom
CN114351285A (zh) * 2022-03-09 2022-04-15 宜宾惠美纤维新材料股份有限公司 一种奶酪蛋白纤维及其制备方法

Also Published As

Publication number Publication date
DE909491C (de) 1954-04-22
NL66502C (fr)
CH229823A (fr) 1943-11-30
FR921563A (fr) 1947-05-12
GB615305A (en) 1949-01-05
BE443631A (fr)

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