GB508781A - Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from phosphoproteins or conjugated proteins - Google Patents
Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from phosphoproteins or conjugated proteinsInfo
- Publication number
- GB508781A GB508781A GB32746/37A GB3274637A GB508781A GB 508781 A GB508781 A GB 508781A GB 32746/37 A GB32746/37 A GB 32746/37A GB 3274637 A GB3274637 A GB 3274637A GB 508781 A GB508781 A GB 508781A
- Authority
- GB
- United Kingdom
- Prior art keywords
- added
- acid
- artificial
- acids
- protein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F4/00—Monocomponent artificial filaments or the like of proteins; Manufacture thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
508,781. Artificial silk &c. POTTER, E. (Akt.-Ges. f³r Verm÷geusverwertung) Nov. 26, 1937, No. 32746. [Class 2 (ii)] Artificial silk, spun fibres, and horsehair, and also bands, films and the like, are prepared from alkaline solutions of phosphoproteins or conjugated proteins to which have been added saturated or olefinic unsubstituted aliphatic carboxylic acids having 3 to 9 carbon atoms, or their derivatives such as eaters or amides, with or without aliphatic amines or amino acids. Propionic, heptylic, n-caprylic and n-caproic Acids are specifically mentioned as acids, which are added in proportions of from 0À5 to 3À5 per cent by weight of the protein, while n-propylamine, allylamine, or n-butylamine in proportion of 8 per cent may be used as the amines.. A small quantity of carbondisulphide in the-proportion of 2 to 5 per cent by weight of the protein may be added. Numerous other additions and after-treatments are referred to. Thus, vinyl acetate, polyvinyl chloride, poly. vinyl alcohol, titanium dioxide, butadiene, olefines, sulphonated olefinic alcohols, aldehydes, phthalic anhydride and glycerine, form; aldehyde and urea, phenols, and other substances which form condensation products with one another or with the protein may be added to the spinning solution or, case of dry spinning, may be passed as vapours in countercurreht to the thread or film.. Acid vapours, for example of hydrochloric acid, may be similarly employed in dry spinning. The threads &c, may be hardened by formaldehyde or synthetic or natural tanning agents or by subjecting them to the action of light from a mercury vapour lamp, and their capacity for dyeing may be increased by .treatment with amines or amino acids. In an example, potash lye is added slowly to a paste of. acid casein and carbon disulphide, propionic acid, and n-propylamine added. The solution is then spun into a precipitating bath of sulphuric acid, and the thread dried under tension and hardened in a formalin bath.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH217499D CH217499A (en) | 1937-11-25 | 1937-11-25 | Process for the production of artificial structures, such as rayon, man-made staple fibers, horsehair, ribbons, films and the like from protein, especially casein. |
GB12256/39A GB508840A (en) | 1937-11-25 | 1937-11-26 | Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from soya bean casein |
GB32746/37A GB508781A (en) | 1937-11-25 | 1937-11-26 | Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from phosphoproteins or conjugated proteins |
BE424878D BE424878A (en) | 1937-11-25 | 1937-11-27 | |
NL85252A NL57669C (en) | 1937-11-25 | 1937-11-29 | |
FR830439D FR830439A (en) | 1937-11-25 | 1937-11-29 | Process for preparing artificial bodies, such as artificial silk, artificial fibers for spinning, horsehair, ribbons, films, etc., starting from an albuminoid, and more particularly from casein |
NL60236D NL60236C (en) | 1937-11-25 | 1944-04-19 |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH217499T | 1937-11-25 | ||
GB32746/37A GB508781A (en) | 1937-11-25 | 1937-11-26 | Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from phosphoproteins or conjugated proteins |
BE424878T | 1937-11-27 | ||
NL85252A NL57669C (en) | 1937-11-25 | 1937-11-29 | |
FR830439T | 1937-11-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB508781A true GB508781A (en) | 1939-06-26 |
Family
ID=10343395
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12256/39A Expired GB508840A (en) | 1937-11-25 | 1937-11-26 | Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from soya bean casein |
GB32746/37A Expired GB508781A (en) | 1937-11-25 | 1937-11-26 | Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from phosphoproteins or conjugated proteins |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12256/39A Expired GB508840A (en) | 1937-11-25 | 1937-11-26 | Process for the preparation of artificial silk, artificial spun fibres, horsehair, bands, films and the like from soya bean casein |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE424878A (en) |
CH (1) | CH217499A (en) |
FR (1) | FR830439A (en) |
GB (2) | GB508840A (en) |
NL (2) | NL57669C (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2441859A (en) * | 1945-06-12 | 1948-05-18 | Alrose Chemical Company | Treatment of textile materials with aldehydes |
US2519978A (en) * | 1945-10-11 | 1950-08-22 | Jack J Press | Generated proteins and process for preparation thereof |
US2548357A (en) * | 1941-03-06 | 1951-04-10 | Ferretti Antonio | Manufacture of textile fibers composed of casein |
US2552130A (en) * | 1946-12-13 | 1951-05-08 | John R Evans & Company | Tanning proteinaceous fibers with a mixture of an aldehyde and a polyhydric phenol in a molecular ratio of at least 2 to 1 |
US2614025A (en) * | 1948-04-26 | 1952-10-14 | Ici Ltd | Formaldehyde and uranyl salt treatment of protein filaments |
US2614024A (en) * | 1948-03-03 | 1952-10-14 | Ici Ltd | Thioformaldehyde and mercuric chloride treatment of protein filaments |
US3189401A (en) * | 1963-05-29 | 1965-06-15 | Ethicon Inc | Simultaneous aldehyde, chrome and aromatic alcohol or quinone tannage of spun collagen fiber |
CN113622044A (en) * | 2021-09-09 | 2021-11-09 | 西湖大学 | Method for preparing silk protein-based fiber by dry spinning, silk protein-based fiber prepared by same and application thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL30150C (en) * | 1945-09-07 |
-
1937
- 1937-11-25 CH CH217499D patent/CH217499A/en unknown
- 1937-11-26 GB GB12256/39A patent/GB508840A/en not_active Expired
- 1937-11-26 GB GB32746/37A patent/GB508781A/en not_active Expired
- 1937-11-27 BE BE424878D patent/BE424878A/xx unknown
- 1937-11-29 NL NL85252A patent/NL57669C/xx active
- 1937-11-29 FR FR830439D patent/FR830439A/en not_active Expired
-
1944
- 1944-04-19 NL NL60236D patent/NL60236C/xx active
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2548357A (en) * | 1941-03-06 | 1951-04-10 | Ferretti Antonio | Manufacture of textile fibers composed of casein |
US2441859A (en) * | 1945-06-12 | 1948-05-18 | Alrose Chemical Company | Treatment of textile materials with aldehydes |
US2519978A (en) * | 1945-10-11 | 1950-08-22 | Jack J Press | Generated proteins and process for preparation thereof |
US2552130A (en) * | 1946-12-13 | 1951-05-08 | John R Evans & Company | Tanning proteinaceous fibers with a mixture of an aldehyde and a polyhydric phenol in a molecular ratio of at least 2 to 1 |
US2614024A (en) * | 1948-03-03 | 1952-10-14 | Ici Ltd | Thioformaldehyde and mercuric chloride treatment of protein filaments |
US2614025A (en) * | 1948-04-26 | 1952-10-14 | Ici Ltd | Formaldehyde and uranyl salt treatment of protein filaments |
US3189401A (en) * | 1963-05-29 | 1965-06-15 | Ethicon Inc | Simultaneous aldehyde, chrome and aromatic alcohol or quinone tannage of spun collagen fiber |
CN113622044A (en) * | 2021-09-09 | 2021-11-09 | 西湖大学 | Method for preparing silk protein-based fiber by dry spinning, silk protein-based fiber prepared by same and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CH217499A (en) | 1941-10-31 |
NL60236C (en) | 1947-11-15 |
NL57669C (en) | 1946-06-15 |
FR830439A (en) | 1938-07-28 |
BE424878A (en) | 1938-01-31 |
GB508840A (en) | 1939-06-26 |
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