US2368277A - Wetting agent for mercerizing and a process for increasing the wetting power of mercerizing lyes - Google Patents
Wetting agent for mercerizing and a process for increasing the wetting power of mercerizing lyes Download PDFInfo
- Publication number
- US2368277A US2368277A US369984A US36998440A US2368277A US 2368277 A US2368277 A US 2368277A US 369984 A US369984 A US 369984A US 36998440 A US36998440 A US 36998440A US 2368277 A US2368277 A US 2368277A
- Authority
- US
- United States
- Prior art keywords
- wetting
- mercerizing
- lyes
- phenol
- wetting agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009736 wetting Methods 0.000 title description 17
- 239000000080 wetting agent Substances 0.000 title description 12
- 238000000034 method Methods 0.000 title description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 26
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 13
- 229930003836 cresol Natural products 0.000 description 10
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 9
- 150000002989 phenols Chemical class 0.000 description 8
- 238000007792 addition Methods 0.000 description 7
- 239000007859 condensation product Substances 0.000 description 7
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- RECUKUPTGUEGMW-UHFFFAOYSA-N carvacrol Chemical compound CC(C)C1=CC=C(C)C(O)=C1 RECUKUPTGUEGMW-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- DSTPUJAJSXTJHM-UHFFFAOYSA-N isothymol Natural products CC(C)C1=CC(C)=CC=C1O DSTPUJAJSXTJHM-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- CRBJBYGJVIBWIY-UHFFFAOYSA-N 2-isopropylphenol Chemical compound CC(C)C1=CC=CC=C1O CRBJBYGJVIBWIY-UHFFFAOYSA-N 0.000 description 2
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 description 2
- YQUQWHNMBPIWGK-UHFFFAOYSA-N 4-isopropylphenol Chemical compound CC(C)C1=CC=C(O)C=C1 YQUQWHNMBPIWGK-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 244000019194 Sorbus aucuparia Species 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- -1 aminoaryl sulfonic acids Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000005517 mercerization Methods 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000006414 serbal de cazadores Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229950000244 sulfanilic acid Drugs 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
- D06M15/412—Phenol-aldehyde or phenol-ketone resins sulfonated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/05—Organic amine, amide, or n-base containing
Definitions
- This invention relates to a new and useful wetting agent and more particularly to a wetting agent for mercerizing purposes which is capable of increasing the wetting power of mercerizing lyes, and a method of using the same in mercerizing.
- Mercerization has, among others, the purpose of imparting a silky luster to vegetable fibers, especially to cotton.
- Such a wetting agent in order to fulfill its purpose, must show the following properties:
- wetting power of mercerizing lyes can be essentially increased, by adding thereto isopropylated phenols, especially isopropyl phenol or isopropyl cresol, such as 1- methy1-3-isopropylphenol-(5), either alone or together with condensation products of aminoaryl sulfonic acids, aldehydes and phenols, such of phenols or cresols and 242% hydrogenated phenols as wetting agents in mercerisation.-.
- twisted yarn or a dense fabric of raw-cotton is completely wetted within two seconds in a solution of sodium hydroxide of 30 to which 0.7 vol. of p-isopropylphenol is added, while, in contrast thereto, an addition of 1.4 vol.
- cresol or phenol itself does not show any wetting effect after seconds.
- Example 1 Ezamplle 2 To a mercerisation lye of 28 B., there is added 1' vol. (0.8 weight of a mixture of 67% of isothymol and 33% of the condensation product obtainable from butylphenol, sulfanilic' acid andformaldehyde. The clear solution shows ning as after standing for 2-3 weeks inan open vessel (1.5 seconds for dense cotton fabric or yarn) 7
- Example 3 1.4 vol.
- the volume of the foam consisting of large hubbles which is obtained on strongly shaking the mixture for 10 seconds amounts to about70-80% of the usedvolume of the liquid; after 1 minvolume of the liquid.
- Sucha, wetting agent may also contain other additions, such as, for instance, ethereal oils, i.'e.,
- terpineol aromatic hydrocarbons, i. e., xylene, or
- Ezramplee Q I I 1 1 I 1.0 weight of a mixture of 70% of isothymol and 30% of cresol (German Pharmacopoeia, 6th I edition), dissolved in a solution of sodium hydroxide of,28 B.,.Sh0WS excellent wetting effects similar to those shown by the preceding a phenol.
- WhatI'claimisf 1 A mercerizing wetting agent, comprising an isopropylated phenol and a condensation prod not of an aminoarylsulfonic andaphenol.
- a process for improving vegetable textile fibers comprising treating said fibers with a mercerizing lye of causticalkali' containing: anisopropylated phenol, and ,a condensation product of anaminoarylsulfonic acid, an aldehyde and a 4.
- a process for improving Vegetable "textile fibers comprising treating said fibers with a mer I and a condensation product of an aminoarylsul cerizing lye of caustic alkali containing isothymol fonic acid, an aldehyde and a. phenol.
- a mercerizing wetting agent comprising. a
- a mercerizing wetting agent comprising a ,-mixture of isothymol, a member of the group acid, an aldehyde I
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2368277X | 1939-12-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2368277A true US2368277A (en) | 1945-01-30 |
Family
ID=7995542
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US369984A Expired - Lifetime US2368277A (en) | 1939-12-14 | 1940-12-13 | Wetting agent for mercerizing and a process for increasing the wetting power of mercerizing lyes |
Country Status (4)
Country | Link |
---|---|
US (1) | US2368277A (fr) |
BE (1) | BE440031A (fr) |
FR (1) | FR867835A (fr) |
NL (1) | NL62787C (fr) |
-
0
- NL NL62787D patent/NL62787C/xx active
- BE BE440031D patent/BE440031A/xx unknown
-
1940
- 1940-11-28 FR FR867835D patent/FR867835A/fr not_active Expired
- 1940-12-13 US US369984A patent/US2368277A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
NL62787C (fr) | |
BE440031A (fr) | |
FR867835A (fr) | 1941-11-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
PT95351B (pt) | Processo para a obtencao de uma composicao molhante aquosa, estavel em armazenagem,para o tratamento de texteis, a qual, quando utilizada, origina uma pequena quantidade de espuma | |
US2249757A (en) | Alkyl hydroxy aromatic sulphonate | |
US2368277A (en) | Wetting agent for mercerizing and a process for increasing the wetting power of mercerizing lyes | |
US2064883A (en) | Mercerizing | |
US1776052A (en) | Process for treating cellulosic fibers with alkali | |
PT91875B (pt) | Processo para a preparacao de composicoes veiculares para o tingimento de materiais de poliester contendo uma mistura de n-alquil-ftalamidas e esteres e/ou eteres aromaticos | |
GB343901A (en) | Improvements in the manufacture and production of wetting, cleansing and dispersing agents | |
GB703666A (en) | Improved process for the chemical retting of lengths of vegetable fibres | |
US2000559A (en) | Wetting preparations and their manufacture | |
US2045074A (en) | Mercerizing liquors | |
GB414485A (en) | Improvements in or relating to mercerisation of textile materials and like processes | |
US2010176A (en) | Wetting assistant for mercerizing cotton | |
DE722601C (de) | Verfahren zum Mercerisieren | |
US2050969A (en) | Fatty substances soluble in concentrated alkaline baths | |
US1877933A (en) | Manufacture of artificial textiles | |
GB190928701A (en) | A Process of Preparing Vegetable Silk and like Fibres for Dyeing and Spinning. | |
GB280110A (en) | Improvements in soap preparations and in treating articles therewith | |
AT144357B (de) | Verfahren zur Erhöhung der Netzfähigkeit von Mercerisierlaugen. | |
US2066371A (en) | Method of desulphurizing artificial filaments of viscose | |
GB581985A (en) | Manufacture of sulphonated ethers containing at least one aralkyl residue | |
US1920585A (en) | Condensation product of alkali | |
US1929654A (en) | Mercerizing liquor | |
US2257148A (en) | Capillary active product | |
US1534382A (en) | Spinning viscose | |
DE660135C (de) | Verfahren zur Erhoehung der Benetzbarkeit vegetabilischer Fasern |