US2368277A - Wetting agent for mercerizing and a process for increasing the wetting power of mercerizing lyes - Google Patents

Wetting agent for mercerizing and a process for increasing the wetting power of mercerizing lyes Download PDF

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Publication number
US2368277A
US2368277A US369984A US36998440A US2368277A US 2368277 A US2368277 A US 2368277A US 369984 A US369984 A US 369984A US 36998440 A US36998440 A US 36998440A US 2368277 A US2368277 A US 2368277A
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US
United States
Prior art keywords
wetting
mercerizing
lyes
phenol
wetting agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US369984A
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English (en)
Inventor
Becker Burkhard Von
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHERKA CHEMICAL CO Inc
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SHERKA CHEMICAL CO Inc
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Filing date
Publication date
Application filed by SHERKA CHEMICAL CO Inc filed Critical SHERKA CHEMICAL CO Inc
Application granted granted Critical
Publication of US2368277A publication Critical patent/US2368277A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/342Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41Phenol-aldehyde or phenol-ketone resins
    • D06M15/412Phenol-aldehyde or phenol-ketone resins sulfonated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S516/00Colloid systems and wetting agents; subcombinations thereof; processes of
    • Y10S516/01Wetting, emulsifying, dispersing, or stabilizing agents
    • Y10S516/03Organic sulfoxy compound containing
    • Y10S516/05Organic amine, amide, or n-base containing

Definitions

  • This invention relates to a new and useful wetting agent and more particularly to a wetting agent for mercerizing purposes which is capable of increasing the wetting power of mercerizing lyes, and a method of using the same in mercerizing.
  • Mercerization has, among others, the purpose of imparting a silky luster to vegetable fibers, especially to cotton.
  • Such a wetting agent in order to fulfill its purpose, must show the following properties:
  • wetting power of mercerizing lyes can be essentially increased, by adding thereto isopropylated phenols, especially isopropyl phenol or isopropyl cresol, such as 1- methy1-3-isopropylphenol-(5), either alone or together with condensation products of aminoaryl sulfonic acids, aldehydes and phenols, such of phenols or cresols and 242% hydrogenated phenols as wetting agents in mercerisation.-.
  • twisted yarn or a dense fabric of raw-cotton is completely wetted within two seconds in a solution of sodium hydroxide of 30 to which 0.7 vol. of p-isopropylphenol is added, while, in contrast thereto, an addition of 1.4 vol.
  • cresol or phenol itself does not show any wetting effect after seconds.
  • Example 1 Ezamplle 2 To a mercerisation lye of 28 B., there is added 1' vol. (0.8 weight of a mixture of 67% of isothymol and 33% of the condensation product obtainable from butylphenol, sulfanilic' acid andformaldehyde. The clear solution shows ning as after standing for 2-3 weeks inan open vessel (1.5 seconds for dense cotton fabric or yarn) 7
  • Example 3 1.4 vol.
  • the volume of the foam consisting of large hubbles which is obtained on strongly shaking the mixture for 10 seconds amounts to about70-80% of the usedvolume of the liquid; after 1 minvolume of the liquid.
  • Sucha, wetting agent may also contain other additions, such as, for instance, ethereal oils, i.'e.,
  • terpineol aromatic hydrocarbons, i. e., xylene, or
  • Ezramplee Q I I 1 1 I 1.0 weight of a mixture of 70% of isothymol and 30% of cresol (German Pharmacopoeia, 6th I edition), dissolved in a solution of sodium hydroxide of,28 B.,.Sh0WS excellent wetting effects similar to those shown by the preceding a phenol.
  • WhatI'claimisf 1 A mercerizing wetting agent, comprising an isopropylated phenol and a condensation prod not of an aminoarylsulfonic andaphenol.
  • a process for improving vegetable textile fibers comprising treating said fibers with a mercerizing lye of causticalkali' containing: anisopropylated phenol, and ,a condensation product of anaminoarylsulfonic acid, an aldehyde and a 4.
  • a process for improving Vegetable "textile fibers comprising treating said fibers with a mer I and a condensation product of an aminoarylsul cerizing lye of caustic alkali containing isothymol fonic acid, an aldehyde and a. phenol.
  • a mercerizing wetting agent comprising. a
  • a mercerizing wetting agent comprising a ,-mixture of isothymol, a member of the group acid, an aldehyde I

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
US369984A 1939-12-14 1940-12-13 Wetting agent for mercerizing and a process for increasing the wetting power of mercerizing lyes Expired - Lifetime US2368277A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2368277X 1939-12-14

Publications (1)

Publication Number Publication Date
US2368277A true US2368277A (en) 1945-01-30

Family

ID=7995542

Family Applications (1)

Application Number Title Priority Date Filing Date
US369984A Expired - Lifetime US2368277A (en) 1939-12-14 1940-12-13 Wetting agent for mercerizing and a process for increasing the wetting power of mercerizing lyes

Country Status (4)

Country Link
US (1) US2368277A (fr)
BE (1) BE440031A (fr)
FR (1) FR867835A (fr)
NL (1) NL62787C (fr)

Also Published As

Publication number Publication date
NL62787C (fr)
BE440031A (fr)
FR867835A (fr) 1941-11-29

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