GB343901A - Improvements in the manufacture and production of wetting, cleansing and dispersing agents - Google Patents

Improvements in the manufacture and production of wetting, cleansing and dispersing agents

Info

Publication number
GB343901A
GB343901A GB2666/31A GB266631A GB343901A GB 343901 A GB343901 A GB 343901A GB 2666/31 A GB2666/31 A GB 2666/31A GB 266631 A GB266631 A GB 266631A GB 343901 A GB343901 A GB 343901A
Authority
GB
United Kingdom
Prior art keywords
sulphuric
salts
agents
esters
aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2666/31A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Publication of GB343901A publication Critical patent/GB343901A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01CCHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C5/00Carbonising rags to recover animal fibres
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/24Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262Sulfated compounds thiosulfates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621Compounds without nitrogen
    • D06P1/627Sulfates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Coloring (AREA)

Abstract

Sulphuric esters of primary hydroxy-alkylethers of aliphatic or cycloaliphatic alcohols or phenols, containing at least eight carbon atoms in the molecule but no free or combined carboxy groups or amino groups, obtained by sulphonation of the parent ethers at a temperature of 35 DEG C. or below, are used as dispersing agents for insoluble substances and as cleansing agents. According to an example, the sulphuric acid ester of ethyleneglycolmonocresylether is obtained by treating the latter with sulphuric acid monohydrate while cooling. It is stable to baths containing salts and alkalies and may be used in the same way as the products obtained in the examples of Specification 343,872. The sulphuric esters or their salts may be used alone or in association with other dispersing agents, e.g. soaps, turkey-red oils, aliphatic or aromatic sulphonic acids, particularly polynuclear aromatic sulphonic acids, protective colloids, e.g. glue, gelatine or vegetable mucilages or gums, salts, e.g. soda, sodium bicarbonate, waterglass, common salt or normal or acid sodium sulphate, organic solvents, e.g. monocresylethyleneglycolether, cyclohexanol, cyclohexanone, trichlorethylene or bleaching agents, e.g. perborates, percarbonates or sodium p-toluenesulphonichloramide.ALSO:Sulphuric esters of primary hydroxyalkylethers of aliphatic or cycloaliphatic alcohols or phenols, containing at least eight carbon atoms in the molecule but no free or combined carboxy or amino group are obtained by sulphonation of the parent ethers at a temperature of 35 DEG C. or below. Sulphuric monohydrate may be used for the sulphonation or stronger agents such as chlorsulphonic acid or sulphur trioxide. According to an example, the sulphuric acid ester of ethyleneglycol monocresylether (prepared from ethylenechlorhydrin and sodium o-cresolate) is obtained by treating the latter with sulphuric acid monohydrate while cooling. It is stable to baths containing salts and alkalies and may be used in the same way as the products obtained in the examples of Specification 343,872. The sulphuric esters are described as assistants in processes for the treatment of single fibres, yarns and vegetable, animal or synthetic textiles or fabrics, and in particular as wetting, emulsifying, dispersing and cleansing agents. They, or their salts, may be used alone or in association with other emulsifying agents, e.g. soaps, turkey-red oils, aliphatic or aromatic sulphonic acids or particularly polynuclear aromatic sulphonic acids, protective colloids, e.g. glue, gelatine or vegetable mucilages or gums, salts, e.g. soda, sodium bicarbonate, waterglass, common salt or normal or acid sodium sulphate, organic solvents, e.g. monocresylethyleneglycolether, cyclohexanol, cyclohexanone, trichlorethylene or bleaching agents, e.g. perborates, percarbonates or sodium p-toluenesulphonicchloramide. In washing processes, e.g. of wool, the sulphuric esters may be used without alkali, and they serve as emulsifying and dispersing agents in the preparation of inks, coating compositions and emulsions or oiling fabrics. They may be added to sizes and they may be used to soften textile materials. Organsin silk treated with a 0,5 per cent aqueous solution of one of the sulphuric esters is rendered soft to the touch and is at the same time weighted. In the formation of metal compounds of dyestuffs upon wool, the latter is softened by addition of the esters to the treatment baths. When dyeing mixed fabrics containing wool or silk and cotton or artificial silk, with substantive dyestuffs, dyeing of the animal fibre is prevented by the presence of the sulphuric esters, the dyeing of the cellulose or cellulose derivatives, e.g. nitrocellulose or viscose not being injuriously influenced. Valuable fulling and washing agents are obtained by mixing the esters, after or during their production, with normal or basic salts of the alkali metals, of ammonia or amines, e.g. sodium sulphate or bisulphate, carbonate, phosphate, chloride, acetate tartrate or benzoate. Specifications 247,714, 294,572, 302,258, 303,281, 307,709, 308,824, 317,039 and 318,610, [all in Class 2 (iii), Dyes &c.], also are referred to.ALSO:Sulphuric esters of primary hydroxy alkylethers of aliphatic or cycloaliphatic alcohols or phenols, containing at least eight carbon atoms in the molecule but no free or combined carboxy groups or amino groups, obtained by sulphonation of the parent ethers at a temperature of 35 DEG C. or below are added to sizes. According to an example, the sulphuric acid ester of ethyleneglycolmonocresylether is obtained by treating the latter with sulphuric acid monohydrate while cooling. The sulphuric esters, or their salts, may be used alone or in association with other emulsifying agents, e.g. soaps, turkey red oils, aliphatic or aromatic sulphonic acids, particularly polynuclear aromatic sulphonic acids, protective colloids, e.g. glue, gelatine or vegetable mucilages or gums, salts, e.g. soda, sodium bicarbonate, waterglass, common salt or normal or acid sodium sulphate, organic solvents, e.g. monocresylethyleneglycolether, cyclohexanol, cyclohexanone, trichlorethylene or bleaching agents, e.g. perborates, percarbonates or sodium p-toluenesulphonichloramide.
GB2666/31A 1936-02-29 1929-08-07 Improvements in the manufacture and production of wetting, cleansing and dispersing agents Expired GB343901A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB343901T
DE477499X 1936-02-29

Publications (1)

Publication Number Publication Date
GB343901A true GB343901A (en) 1931-02-09

Family

ID=6542130

Family Applications (3)

Application Number Title Priority Date Filing Date
GB24177/29A Expired GB343872A (en) 1936-02-29 1929-08-07 Improvements in the manufacture and production of wetting, cleansing and dispersing agents
GB2666/31A Expired GB343901A (en) 1936-02-29 1929-08-07 Improvements in the manufacture and production of wetting, cleansing and dispersing agents
GB6137/37A Expired GB477499A (en) 1936-02-29 1937-03-01 Improvements in the manufacture and production of wetting, cleansing, dispersing agents, solvents and the like

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB24177/29A Expired GB343872A (en) 1936-02-29 1929-08-07 Improvements in the manufacture and production of wetting, cleansing and dispersing agents

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB6137/37A Expired GB477499A (en) 1936-02-29 1937-03-01 Improvements in the manufacture and production of wetting, cleansing, dispersing agents, solvents and the like

Country Status (3)

Country Link
FR (2) FR693814A (en)
GB (3) GB343872A (en)
NL (1) NL30719C (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE763234C (en) * 1935-06-09 1953-01-19 Wacker Chemie Gmbh Process for the production of sulfuric acid or phosphoric acid esters of higher molecular weight, monohydric, saturated, aliphatic, primary alcohols
US2422613A (en) * 1937-07-09 1947-06-17 Colgate Palmolive Peet Co Normal secondary tridecyl sulphates
US2423692A (en) * 1937-07-09 1947-07-08 Colgate Palmolive Peet Co Normal secondary nonadecyl sulphates
DE764950C (en) * 1940-05-12 1952-08-04 Maerkische Seifen Ind Process for the manufacture of sulphonation products
DE767428C (en) * 1940-12-12 1952-08-07 Maerkische Seifen Ind Process for the preparation of sulfonates of secondary alcohols
DE766546C (en) * 1940-12-21 1952-05-23 Maerkische Seifen Ind Process for the manufacture of sulphonation products
DE767014C (en) * 1941-08-15 1951-07-26 Henkel & Cie Gmbh Process for the preparation of alkylated aromatic sulfonic acid salts
US2477869A (en) * 1946-10-03 1949-08-02 Visking Corp Nitro sulfonates from beta-nitro alkanols
DE947161C (en) * 1949-07-04 1956-08-09 Bataafsche Petroleum Process for the production of sulfuric acid alkyl esters by reacting alkenes having 5 or more carbon atoms with sulfuric acid
WO2011131719A1 (en) * 2010-04-23 2011-10-27 Basf Se Method for producing mineral oil by using surfactants, in particular based on c35 secondary alcohol-containing alkyl alkoxylates

Also Published As

Publication number Publication date
FR693814A (en) 1930-11-25
FR48173E (en) 1937-11-03
GB477499A (en) 1937-12-31
GB343872A (en) 1931-02-09
NL30719C (en) 1933-09-15

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