US2131137A - Washing process for textile materials - Google Patents
Washing process for textile materials Download PDFInfo
- Publication number
- US2131137A US2131137A US702031A US70203133A US2131137A US 2131137 A US2131137 A US 2131137A US 702031 A US702031 A US 702031A US 70203133 A US70203133 A US 70203133A US 2131137 A US2131137 A US 2131137A
- Authority
- US
- United States
- Prior art keywords
- washing
- washing process
- impurities
- pitch
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005406 washing Methods 0.000 title description 15
- 239000000463 material Substances 0.000 title description 8
- 239000004753 textile Substances 0.000 title description 6
- 239000002253 acid Substances 0.000 description 11
- 239000012535 impurity Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 8
- 235000002639 sodium chloride Nutrition 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 210000002268 wool Anatomy 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000002791 soaking Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 3
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000011295 pitch Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 210000001732 sebaceous gland Anatomy 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid group Chemical class S(N)(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- -1 sulfur ester acids Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Definitions
- This invention relates to a washing process for iawlsemimanufactured and finished textile maeri s.
- the process according to the invention is suited particularly for cleaning very dirty textiles, containing pitch, tar, oil, wax, resins or color. As the process does not injure thematerials, it can be applied alsofor cleaning sensitive animal and vegetable textiles including silk, hair and wool.
- the pitch referred to involves the colors used for marking animals to prevent the theft thereof and comprising, as a rule, linseed oil, pitch, resins, asphalt; etc., usuallymixed with pigments. Most marking colors contain red lead or colored earths.
- the suint is a secretion of abnormally functioning sebaceous glands and in most cases due to improper treatment of the animals, though it may also indicate degeneration. With respect .to their-chemical and physical be havior, the most essential constituents of suint are waxes.
- the invention provides a which impuretextilematerials are'treated with high-boiling chemical compounds which saturate the impurities, soak and partially dissolve them.
- ethane sulfo acid the ricinoleic and diricinoleic sulfo acids as well as the stearyl alcohol sulfuric acid, the oleylalcohol sulfuric acidand their esters and salts; if the compounds mentioned are not oily, they are used in concentrated aqueous solution.
- concentrated aqueous solution To this class belong also the sulfonated fats and oils like Turkey red oil and sulionated tallow.
- the corresponding phosphoric acids or phosphoric acid esters may also be used, especially in the form of their acid salts or acid esters.
- the compounds as such or in the form of their concentrated aqueous solutions possess a high, penetrating capacity, so that they penetrate the impurities, soften them and dissolve them partly. After this soaking step, the high-boiling chemical compounds together with the impurities are removed from the fibers, preferably and as much as possible by mechanical means, e. .g.,
- the substances concerned may themselves act as emulsifiers for aqueous suspensions like the sulfo acids, the sulfuric acid esters, the. phosphoric acids and esters,
- alkaline washing'waters are used, which is absolutely necessary if free carboxylic acids have been employed,-as the latter, unlike their salts, the soaps, possess only slight emulsifying properties.
- the impurities are thus removed from the textiles and .remain as suspension in water while the compounds used for To simplify the process the squeezed or hydro-extracted material may be placed di rectly in the usual washing liquors which are slightly alkaline and normal stuff.
- the substances used for soaking can be recovered-from the finish it together with the washing liquors either by salting out or adding mineral acids.
- the separated compound is purified in the usual way,
- Example 1 weight of commercial olein After five to twenty hours, according to temperatur the impurities can be ground with the fingers. is then'removed by squeezing or hydro-extracting, and the wool placed in a weakly alkaline washing bath wherein the washing process is c. nple'ted in the usual manner at 50 C. By adding sulfuric acid to the washing water the olein can be recovered and used for the same process after having been purified by one of the customary methods, e. g. filtration.
- the customary methods e. g. filtration.
- Example 2 Example 3 Wool containing waxlike suint and picked out of normally washed'lots is saturated with Turkey red oil (50% quality), which requires about 2 or 3 The excess olein.
- Example 4 Raw cotton containing resinous or color impurities is saturated with twice the amount of ground nut oil acid. lifter the cotton has remained therein for 20 hours, it is squeezed and placed in a bath of 5% potash lye, whereupon it is hydro-extracted and Washed in an alkaline washing liquor until the washing process is completed.
- the process of removing pitch from a textile material comprising steeping the material in a liquid higher fatty acid softener for pitch of a quantity exceeding the material in weightvuntil the pitch has become friable when the material is rubbed between fingers, removing so much of theaoid as can be mechanically removed, rendering the remaining acid water-soluble by introducing an aqueous alkaline solution to saponify the same, and then washing off the saponified acid together with the pitch emulsified therein.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2131137X | 1932-12-13 | ||
GB35111/33A GB432018A (en) | 1933-12-13 | 1933-12-13 | Washing process for textile materials |
Publications (1)
Publication Number | Publication Date |
---|---|
US2131137A true US2131137A (en) | 1938-09-27 |
Family
ID=32044205
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US702031A Expired - Lifetime US2131137A (en) | 1932-12-13 | 1933-12-12 | Washing process for textile materials |
Country Status (2)
Country | Link |
---|---|
US (1) | US2131137A (enrdf_load_stackoverflow) |
BE (1) | BE416044A (enrdf_load_stackoverflow) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2717824A (en) * | 1951-09-18 | 1955-09-13 | Floyd N Avery | Method for removing water-soluble stains in dry cleaning garments |
US4489455A (en) * | 1982-10-28 | 1984-12-25 | The Procter & Gamble Company | Method for highly efficient laundering of textiles |
US4489574A (en) * | 1981-11-10 | 1984-12-25 | The Procter & Gamble Company | Apparatus for highly efficient laundering of textiles |
US4555019A (en) * | 1981-11-10 | 1985-11-26 | The Procter & Gamble Company | Packaged detergent composition with instructions for use in a laundering process |
US20220000736A1 (en) * | 2018-12-19 | 2022-01-06 | Conopco, Inc., D/B/A Unilever | Hair conditioning composition for improved deposition |
-
0
- BE BE416044D patent/BE416044A/xx unknown
-
1933
- 1933-12-12 US US702031A patent/US2131137A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2717824A (en) * | 1951-09-18 | 1955-09-13 | Floyd N Avery | Method for removing water-soluble stains in dry cleaning garments |
US4489574A (en) * | 1981-11-10 | 1984-12-25 | The Procter & Gamble Company | Apparatus for highly efficient laundering of textiles |
US4555019A (en) * | 1981-11-10 | 1985-11-26 | The Procter & Gamble Company | Packaged detergent composition with instructions for use in a laundering process |
US4489455A (en) * | 1982-10-28 | 1984-12-25 | The Procter & Gamble Company | Method for highly efficient laundering of textiles |
US20220000736A1 (en) * | 2018-12-19 | 2022-01-06 | Conopco, Inc., D/B/A Unilever | Hair conditioning composition for improved deposition |
Also Published As
Publication number | Publication date |
---|---|
BE416044A (enrdf_load_stackoverflow) |
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