US20180250752A1 - Method for producing nickel powder - Google Patents

Method for producing nickel powder Download PDF

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US20180250752A1
US20180250752A1 US15/755,147 US201615755147A US2018250752A1 US 20180250752 A1 US20180250752 A1 US 20180250752A1 US 201615755147 A US201615755147 A US 201615755147A US 2018250752 A1 US2018250752 A1 US 2018250752A1
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nickel
nickel powder
solution
reduction
producing
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Yoshitomo Ozaki
Shin-ichi Heguri
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Sumitomo Metal Mining Co Ltd
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Sumitomo Metal Mining Co Ltd
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Priority claimed from PCT/JP2016/074694 external-priority patent/WO2017038589A1/fr
Assigned to SUMITOMO METAL MINING CO., LTD. reassignment SUMITOMO METAL MINING CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HEGURI, SHIN-ICHI, OZAKI, YOSHITOMO
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/16—Making metallic powder or suspensions thereof using chemical processes
    • B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
    • B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
    • B22F9/26—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions using gaseous reductors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00—Metallic composition of the powder or its coating
    • B22F2301/15—Nickel or cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Definitions

  • the present invention relates to a method for obtaining high purity nickel powder having a low sulfur content from a nickel ammine sulfate complex solution and briquettes prepared by pressing the powder.
  • the present invention can be applied to the treatment of an in-process intermediate solution generated from a nickel hydrometallurgical process.
  • a method for industrially producing nickel powder using a hydrometallurgical process includes a method for producing nickel powder by dissolving a raw material in a sulfuric acid solution followed by removing impurities to obtain a nickel sulfate solution, adding ammonia to the resulting nickel sulfate solution to form an ammine complex of nickel, and feeding hydrogen gas into the produced nickel ammine sulfate complex solution to reduce nickel.
  • POWDER METALLURGY 1958, No. 1/2, pp. 40-52 describes a process for producing nickel powder by adding an iron compound as seed crystals during the reduction reaction to precipitate nickel on the iron compound, but the process is problematic in that iron derived from the seed crystals is mixed into the product.
  • Japanese Patent Laid-Open No. 2005-240164 discloses nickel powder which is inexpensive, is excellent in weatherability, has low electric resistance in a state where it is kneaded with a resin, reduces initial electric resistance and electric resistance in use, can be stably used over a long period of time, and is suitable as conductive particles for a conductive paste and a conductive resin, and a method for producing the same.
  • the nickel powder disclosed in Japanese Patent Laid-Open No. 2005-240164 contains 1 to 20% by mass of cobalt with the balance consisting of nickel and unavoidable impurities, includes secondary particles in which primary particles are aggregated, and has an oxygen content of 0.8% by mass or less. Cobalt is contained only in the surface layer part of the secondary particles, and it is said that the cobalt content in the surface layer part is preferably 1 to 40% by mass.
  • the nickel powder is intended to be obtained by the disclosed production method, cobalt will coexist. Therefore, the method is not suitable for an application in which nickel and cobalt are present in combination, for example, in a nickel oxide ore; these metals are separated; and each metal is intended to be economically recovered as high purity metal.
  • Japanese Patent Laid-Open No. 2010-242143 provides a method for producing metal powder by a liquid phase reduction method that is improved so that a particle aggregate may be hardly produced.
  • the method for producing metal powder includes a first step of dissolving a metal compound, a reducing agent, a complexing agent, and a dispersant to prepare an aqueous solution containing metal ions derived from the metal compound and a second step of adjusting the pH of the aqueous solution to reduce the metal ions with the reducing agent to precipitate the metal powder.
  • the present invention intends to provide a method for producing coarse particles of so-called high purity nickel powder containing a smaller amount of impurities and particularly having a low sulfur content from a nickel ammine sulfate complex solution using industrially inexpensive hydrogen gas and using fine nickel powder.
  • the first aspect of the present invention to solve the above problem is a method for producing nickel powder containing a small amount of impurities from a nickel sulfate solution containing the impurities, including the following process steps (1) to (4):
  • the second aspect of the present invention is a method for producing nickel powder according to the first aspect, wherein repeated operation of sieving the nickel powder recovered in the solid-liquid separation step (4) by particle size, and adding a nickel powder having particles smaller than a predetermined size as seed crystals to either or both of the complexing step (2) and the reduction step (3) provides a nickel powder coarser than the nickel powder of seed crystals.
  • the third aspect of the present invention is a method for producing nickel powder according to the second aspect, wherein seed crystals to be added to either or both of the complexing step (2) and the reduction step (3) have an average particle size of 0.1 to 100 ⁇ m.
  • the fourth aspect of the present invention is a method for producing nickel powder according to the first to the third aspects, wherein, in the complexing step (2), when the mixture slurry containing the nickel ammine sulfate complex solution, the seed crystals, and nickel hydroxide is formed, a dispersant is further added to the mixture slurry.
  • the fifth aspect of the present invention is a method for producing nickel powder according to the first to the fourth aspects, wherein, in the complexing step (2), the amount of the seed crystals added is 1 to 100% based on the weight of nickel in the nickel ammine sulfate complex solution.
  • the sixth aspect of the present invention is a method for producing nickel powder according to the first to the fifth aspects, wherein the reduced slurry is sieved, and the undersize nickel powder and the undersize reduced slurry of the resulting post-reduction solution are repeatedly used as parts of the nickel powder as seed crystals and the post-reduction solution in the complexing step (2).
  • the seventh aspect of the present invention is a method for producing nickel powder according to the sixth aspect, wherein the complexing step (2) is composed of two steps: a dissolution step of adding the post-reduction solution to obtain the nickel ammine sulfate complex solution: and a seed crystal addition step of adding the mixture slurry containing either nickel powder or nickel powder and the post-reduction solution.
  • the eighth aspect of the present invention is a method for producing nickel powder according to the first aspect, wherein the nickel sulfate solution is obtained by dissolving, in a sulfuric acid solution, at least one of nickel and cobalt mixed sulfide, nickel sulfide, coarse nickel sulfate, nickel oxide, nickel hydroxide, nickel carbonate, and metallic nickel powder which is recovered by leaching a nickel oxide ore.
  • the ninth aspect of the present invention is a method for producing nickel powder according to the first aspect, wherein the nickel sulfate solution is obtained by: a leaching step of dissolving a nickel-containing material having cobalt as an impurity; and a solvent extraction step of adjusting pH of the leachate containing nickel and cobalt obtained in the leaching step and then separating the leachate into a nickel sulfate solution and a cobalt-recovering solution by solvent extraction.
  • a tenth aspect of the present invention is a method for producing nickel powder according to the first aspect, wherein the concentration of ammonium sulfate in the nickel ammine sulfate complex solution is 100 to 500 g/L, and the ammonium concentration is 1.9 or more in a molar ratio based on the nickel concentration in the nickel ammine sulfate complex solution.
  • the eleventh aspect of the present invention is a method for producing nickel powder according to the first aspect, wherein in the reduction step (3) hydrogen gas is blown while maintaining the temperature in the range of 100 to 200° C. and the pressure in the range of 0.8 to 4.0 MPa.
  • the twelfth aspect of the present invention is a method for producing nickel powder according to the fourth aspect, wherein the dispersant contains a polyacrylate salt.
  • a thirteenth aspect of the present invention is a method for producing nickel powder according to the first aspect, including: a nickel powder briquetting step of processing the nickel powder obtained in the reduction step (3) into nickel briquettes in a block form using a briquetting machine; and a briquette sintering step of subjecting the resulting nickel briquettes in the block form to sintering treatment under holding conditions at a temperature of 500 to 1200° C. in a hydrogen atmosphere to form nickel briquettes as a sintered compact.
  • the fourteenth aspect of the present invention is a method for producing nickel powder according to the first aspect, including an ammonium sulfate recovery step of concentrating the post-reduction solution from the solid-liquid separation step (4) to crystallize ammonium sulfate and recovering ammonium sulfate crystals.
  • the fifteenth aspect of the present invention is a method for producing nickel powder according to the first aspect, including an ammonia recovery step of adding an alkali to the post-reduction solution from the solid-liquid separation step (4), heating the resulting mixture to volatilize ammonia gas and recovering the ammonia gas.
  • FIG. 1 is a production flow chart of nickel powder according to the present invention.
  • the present invention is characterized in that high purity nickel powder containing a smaller amount of impurities is produced from a nickel ammine sulfate complex solution by subjecting a process solution of the hydrometallurgical process to steps (1) to (4) as shown below, in the method for obtaining nickel powder from a nickel ammine sulfate complex solution.
  • the leaching step is a step of dissolving a nickel-containing material, serving as a starting material, such as an industrial intermediate including one or a mixture of two or more selected from nickel and cobalt mixed sulfide, crude nickel sulfate, nickel oxide, nickel hydroxide, nickel carbonate, nickel powder, and the like with sulfuric acid to leach nickel to produce a leachate (sulfuric acid solution containing nickel), and is performed by a known method, for example, disclosed in Japanese Patent Laid-Open No. 2005-350766.
  • the pH of the leachate is adjusted, and the resulting leachate is subjected to the solvent extraction step.
  • This step is a step of bringing an organic phase into contact with the leachate, which is obtained in the leaching step and then subjected to pH adjustment, to exchange the components in each phase, thereby increasing the concentration of some components and reducing the concentration of other different components in an aqueous phase.
  • 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester or di-(2,4,4-trimethylpentyl)phosphinic acid is used as the organic phase to selectively extract impurity elements, particularly cobalt, in the leachate as a cobalt recovering solution to obtain a nickel sulfate solution having a low cobalt concentration.
  • aqueous ammonia produced in the ammonia recovery step to be described below can be also used as the aqueous ammonia used for pH adjustment during this step.
  • an alkali is added to a nickel sulfate solution obtained through the above steps to produce a precipitate of nickel hydroxide, thereby separating a precipitate of the solid component from the liquid component.
  • sodium hydroxide, calcium hydroxide, or the like that can be industrially inexpensively obtained in large amounts is preferably used.
  • the complexing step is composed of two steps, specifically a dissolution step and a seed crystal addition step, wherein first, in the dissolution step, ammonia in the form of a post-reduction solution obtained by subjecting the reduced slurry obtained in the reduction step (3) to solid-liquid separation is added to the precipitate of nickel hydroxide obtained in the hydroxylation step (1), so as to form a mixed solution of nickel hydroxide and the post-reduction solution, thereby complexing treatment is performed to produce a nickel ammine sulfate complex which is an ammine complex of nickel, and thus a nickel ammine sulfate complex solution thereof is formed.
  • the ammonium concentration can be adjusted by adding ammonia gas or aqueous ammonia.
  • the ammonia is added so that the ammonium concentration at that time may be 1.9 or more in a molar ratio based on the concentration of nickel in the solution. If the ammonium concentration of the ammonia to be added is less than 1.9, nickel will not form an ammine complex, but a precipitate of nickel hydroxide will be produced.
  • ammonium sulfate can be added in this step.
  • the concentration of ammonium sulfate at this time is preferably 100 to 500 g/L. If the concentration is more than 500 g/L, solubility will be exceeded to precipitate crystals, and it is difficult to achieve a concentration of less than 100 g/L in terms of the metal balance in the process.
  • ammonia gas or aqueous ammonia produced in the ammonia recovery step to be described below can be also used as the ammonia gas or aqueous ammonia used in this step.
  • a seed crystal addition step is performed by adding the nickel powder having an average particle size of 0.1 to 5 ⁇ m as seed crystals in the form of a nickel powder slurry to the produced nickel ammine sulfate complex solution, so as to form a mixture slurry containing the seed crystals, the nickel ammine sulfate complex solution, and nickel hydroxide.
  • the weight of the seed crystals added at this time is preferably 1 to 100% based on the weight of nickel in the nickel ammine sulfate complex solution. If the weight of the seed crystals is less than 1%, the reaction efficiency during the reduction in the next step will be significantly reduced. Further, if the weight of the seed crystals is more than 100%, the amount of the seed crystals used will be a large amount, which requires much cost for producing seed crystals and is not economical.
  • a dispersant may be added at the same time. Since the seed crystals are dispersed by adding the dispersant, the efficiency of the subsequent reduction step can be increased.
  • the dispersant used here is not particularly limited as long as it has a sulfonate, but a lignosulfonate is preferred as a dispersant that can be industrially inexpensively obtained.
  • the reduction step is a step of forming a reduced slurry containing nickel powder that is formed by blowing hydrogen gas into the obtained mixture slurry to reduce and precipitate a nickel component in the solution on the seed crystals.
  • reaction temperature is preferably 100 to 200° C. If the temperature is lower than 100° C., and more preferably lower than 150° C., reduction efficiency will be reduced, and even if the temperature is higher than 200° C., there will be no influence on the reaction, and the loss of thermal energy and the like will increase.
  • the pressure during the reaction is preferably 0.8 to 4.0 MPa. If the pressure is less than 0.8 MPa, reaction efficiency will be reduced, and even if the pressure exceeds 4.0 MPa, there will be no influence on the reaction, and the loss of hydrogen gas will increase.
  • magnesium ions, sodium ions, calcium ions, sulfate ions, and ammonium ions are mainly present as impurities, but since all the ions remain in the solution, high purity nickel powder can be produced.
  • nickel hydroxide in the liquid of the mixture slurry reacts with ammonium ions produced by reduction reaction, is dissolved as a nickel ammine complex in the solution, reacts with hydrogen gas, and is thus reduced, so that nickel is precipitated on the seed crystals.
  • the reduced slurry produced in the previous reduction step (3) is subjected to solid-liquid separation, thereby separately recovering high purity nickel powder containing a small amount of impurities and a post-reduction solution.
  • the high purity nickel powder is repeatedly fed to either or both of the complexing step (2) as seed crystals and the reduction step (3) as nickel powder to be subjected to particle growth.
  • the recovered post-reduction solution is repeatedly used as a substitute for aqueous ammonia in the complexing step (2).
  • the recovered high purity nickel powder containing a small amount of impurities and having a small size or the same pulverized to have a smaller size is repeatedly fed as seed crystals to the complexing step (2).
  • the nickel powder is further added to a nickel ammine sulfate complex solution obtained in the complexing step (2).
  • Hydrogen gas is then fed in the reduction step (3) to reduce and precipitate nickel on the high purity nickel powder, so as to be able to grow particles.
  • the resulting high purity nickel powder may be finished into the shape of briquettes that are coarser, not easily oxidized, and easily handled through the nickel powder briquetting step and briquette firing step as described below.
  • an ammonia recovery step may be provided.
  • the high purity nickel powder produced by the present invention is dried and then processed for shaping with a briquetting machine or the like to obtain nickel briquettes in a block form as a product form.
  • a material that does not impair the product quality such as water may be added as a binder to the nickel powder depending on the case.
  • the nickel briquettes prepared in the briquetting step is subjected to roasting and sintering in a hydrogen atmosphere to prepare a briquette sintered compact.
  • This treatment is performed for increasing the strength and removing ammonia and a sulfur component remaining in a very small amount, and the roasting and sintering temperature of the treatment is preferably 500 to 1200° C. If the temperature is lower than 500° C., the sintering will be insufficient, and even if the temperature exceeds 1200° C., the efficiency will hardly change but the loss of energy will increase.
  • the post-reduction solution produced by the solid-liquid separation step (4), in which the nickel powder is separated as a solid phase, after the reduction step (3) contains ammonium sulfate and ammonia.
  • ammonium sulfate can be recovered as ammonium sulfate crystals by subjecting the post-reduction solution to the ammonium sulfate recovery step, in which the post-reaction solution is heated and concentrated to precipitate ammonium sulfate.
  • ammonia can be recovered by adding an alkali to the post-reduction solution to adjust the pH to 10 to 13 and then heating the resulting solution to volatilize ammonia gas.
  • the alkali used here suitably includes, but is not limited to, caustic soda and slaked lime, because they are industrially inexpensive.
  • the recovered ammonia gas can produce aqueous ammonia by bringing it into contact with water, and the resulting aqueous ammonia can be repeatedly used in the process.
  • the nickel hydroxide was added together with 12.8 g of nickel powder having an average particle size of 2 ⁇ m as seed crystals to 1700 ml of a mixture of a nickel sulfate solution having a nickel concentration of 30 g/L and an ammonium sulfate solution having an ammonia concentration of 40 g/L, and then the mixture was stirred to prepare a mixture slurry.
  • the mixture slurry was heated to 185° C. in an autoclave with stirring, and hydrogen gas was blown and fed into the slurry so that the pressure in the autoclave became 3.5 MPa to subject the mixture slurry to the reduction step.
  • the reduced slurry was subjected to the solid-liquid separation step by filtration to recover nickel powder having grown particles.
  • the recovered nickel powder had an average particle size of 65 ⁇ m and the amount of the nickel powder recovered was 119 g.
  • the recovered nickel powder was washed with pure water and then analyzed for the impurity content in the nickel powder.
  • the 116 g of nickel hydroxide was mixed with a nickel ammine sulfate solution having a nickel concentration of 30 g/L, 232 ml of 25% aqueous ammonia and 225 g of ammonium sulfate, and then pure water was added to the mixture to prepare 1000 ml of a solution.
  • 20 g of nickel powder having an average particle size of 1 ⁇ m was added as seed crystals to the solution, to prepare a mixture slurry.
  • the prepared mixture slurry was heated to 120° C. with stirring in an autoclave, and hydrogen gas was blown and fed into the slurry so that the pressure in the autoclave became 3.5 MPa to subject the slurry to nickel powder production treatment which is reduction treatment.
  • the feed of hydrogen gas was stopped, and the autoclave was cooled.
  • a reduced slurry obtained after cooling was subjected to solid-liquid separation by filtration to recover high purity nickel powder having a small size.
  • the nickel powder recovered at this time was 70 g.
  • the mixture slurry was heated to 120° C. with stirring in an autoclave, and hydrogen gas was blown and fed into the slurry so that the pressure in the autoclave became 3.5 MPa.
  • the post-reduction solution obtained in the solid-liquid separation step of Example 1 was used for a part of an ammonia source to prepare a mixture slurry.
  • the slurry was subjected to the reduction step under the same conditions as those in Example 1, and then subjected to the solid-liquid separation step, so as to recover nickel powder having grown particles. Nickel powder similar to that in Example 1 was recovered.
  • Example 2 To a solution containing the nickel powder prepared under the same conditions as in Example 1, 336 g of nickel sulfate and 330 g of ammonium sulfate, was added 191 ml of 25% aqueous ammonia, and the total volume of the mixture was adjusted to 1000 ml. The resultant was subjected again to the reduction step and the solid-liquid separation step under the same conditions as in Example 1 to prepare nickel powder having grown particles. This operation was repeated 10 times using the prepared nickel powder to further grow particles of the nickel powder.
  • the recovered nickel powder had an average particle size of 111 ⁇ m, such that the particle size grew to a size 1.7 times the size of the nickel powder of Example 1.
  • the nickel powder obtained by the repeated operation had a sulfur content of 0.04%.
  • Sodium and magnesium were at a minimum limit of determination or lower levels similar to Table 1 above.
  • Nickel powder obtained after the holding had a sulfur content of 0.008%, and the sulfur content could be further reduced by roasting.
  • nickel ammine sulfate solution prepared by mixing 135 g of nickel sulfate hexahydrate, 191 ml of 25% aqueous ammonia, 169 g of ammonium sulfate and pure water, was added 75 g of nickel hydroxide. Pure water was added thereto so that the total volume of the solution was adjusted to 1000 ml. 15 g of nickel powder having an average particle size of 1 ⁇ m was added as seed crystals, to prepare a mixture slurry.
  • the mixture slurry was heated to 100° C. with stirring in an autoclave, and hydrogen gas was fed into the mixture slurry so that the pressure in the autoclave became 3.5 MPa to subject the slurry to nickel powder production treatment.
  • Example 6 With the use of the same mixture slurry as in Example 6, the same operation as in Example 6 was performed under conditions of the temperature of 100° C., and the pressure within an autoclave of 0.8 MPa. The resulting rate of nickel reduction was 56%.
  • Example 6 With the use of the same mixture slurry as in Example 6, the same operation as in Example 6 was performed under conditions of the temperature of 120° C., and the pressure within an autoclave of 3.5 MPa. The resulting rate of nickel reduction was 74%.
  • Example 6 With the use of the same mixture slurry as in Example 6, the same operation as in Example 6 was performed under conditions of the temperature of 120° C., and the pressure within an autoclave of 2.0 MPa. The resulting rate of nickel reduction was 74%.
  • Example 6 With the use of the same mixture slurry as in Example 6, the same operation as in Example 6 was performed under conditions of the temperature of 120° C., and the pressure within an autoclave of 1.5 MPa. The resulting rate of nickel reduction was 74%.
  • Example 6 100 3.5 58
  • Example 7 100 0.8 56
  • Example 8 120 3.5 74
  • Example 9 120 2.0 74
  • Example 10 120 1.5 74
  • Nickel powder was prepared under the same conditions as in Example 1 except that the hydroxylation step in Example 1 was not performed, 191 ml of 25% aqueous ammonia was added to a nickel sulfate solution containing 75 g of nickel and, a solution containing 330 g of ammonium sulfate, the solution was adjusted to have a total volume of 1000 ml, and then to the solution was added 7.5 g of nickel powder having an average particle size of 1 ⁇ m as seed crystals, so as to prepare a mixture slurry.
  • the recovered nickel powder was washed with pure water and then analyzed for the impurity content in the nickel powder.
  • nickel powder was prepared without performing the hydroxylation step.
  • the nickel powder was repeatedly subjected to the same method as in the above Example 3 for 10 times, to grow particles.
  • the sulfur content in the nickel powder obtained by the repeated operation was 0.1%.
  • high purity nickel powder equivalent to that having a sulfur content of 0.04% obtained in Example 3 of the present invention could not be obtained.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Powder Metallurgy (AREA)
US15/755,147 2015-08-31 2016-08-24 Method for producing nickel powder Abandoned US20180250752A1 (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP2015170115 2015-08-31
JP2015-170115 2015-08-31
JP2016032519 2016-02-23
JP2016-032519 2016-02-23
JP2016100070A JP6610425B2 (ja) 2015-08-31 2016-05-19 ニッケル粉の製造方法
JP2016-100070 2016-05-19
PCT/JP2016/074694 WO2017038589A1 (fr) 2015-08-31 2016-08-24 Procédé de fabrication d'une poudre de nickel

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US (1) US20180250752A1 (fr)
EP (1) EP3345701A4 (fr)
JP (1) JP6610425B2 (fr)
CN (1) CN107921544A (fr)
AU (1) AU2016314002B2 (fr)
CA (1) CA2996277C (fr)
PH (1) PH12018500435A1 (fr)

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JP2017155265A (ja) * 2016-02-29 2017-09-07 住友金属鉱山株式会社 ニッケル粉の製造方法
CN109689257A (zh) * 2016-09-27 2019-04-26 住友金属矿山株式会社 镍粉的制造方法
JP6624464B2 (ja) * 2017-12-21 2019-12-25 住友金属鉱山株式会社 ニッケル粉の製造方法
JP7035735B2 (ja) * 2018-04-03 2022-03-15 住友金属鉱山株式会社 低ニッケル品位酸化鉱石からのニッケルコバルト混合硫化物の製造方法
JP7272761B2 (ja) * 2018-07-27 2023-05-12 住友金属鉱山株式会社 ニッケル粉の製造方法
MX2021006120A (es) * 2018-11-26 2021-06-23 Basf Se Reciclaje de baterias mediante inyeccion de gas hidrogeno en lixiviacion.
KR20220038023A (ko) * 2019-07-31 2022-03-25 스미토모 긴조쿠 고잔 가부시키가이샤 니켈 분말, 니켈 분말의 제조 방법
JP7552450B2 (ja) 2021-01-13 2024-09-18 住友金属鉱山株式会社 硫酸コバルトの製造方法
CN117773096B (zh) * 2024-01-09 2024-08-02 长沙立优金属材料有限公司 一种高纯度球形镍粉及其制备方法与用途

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EP3345701A1 (fr) 2018-07-11
EP3345701A4 (fr) 2019-03-20
CA2996277C (fr) 2020-04-21
CN107921544A (zh) 2018-04-17
JP6610425B2 (ja) 2019-11-27
PH12018500435A1 (en) 2018-08-29
AU2016314002B2 (en) 2019-12-05
AU2016314002A1 (en) 2018-03-15
CA2996277A1 (fr) 2017-03-09

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