US20160313076A1 - Air preheater and method for preventing corrosion and blockage of the same - Google Patents

Air preheater and method for preventing corrosion and blockage of the same Download PDF

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Publication number
US20160313076A1
US20160313076A1 US15/202,520 US201615202520A US2016313076A1 US 20160313076 A1 US20160313076 A1 US 20160313076A1 US 201615202520 A US201615202520 A US 201615202520A US 2016313076 A1 US2016313076 A1 US 2016313076A1
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United States
Prior art keywords
segment
ammonium bisulfate
air
curing
condensation
Prior art date
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Abandoned
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US15/202,520
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English (en)
Inventor
Xuelue Qian
Maoling LIU
Ronge HE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hotant Thermal Technology (jiangsu) Co Ltd
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Hotant Thermal Technology (jiangsu) Co Ltd
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Filing date
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Assigned to Hotant Thermal Technology (Jiangsu) Co., Ltd. reassignment Hotant Thermal Technology (Jiangsu) Co., Ltd. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HE, Ronge, LIU, Maoling, QIAN, XUELUE
Publication of US20160313076A1 publication Critical patent/US20160313076A1/en
Abandoned legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F19/00Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/06Arrangements of devices for treating smoke or fumes of coolers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L15/00Heating of air supplied for combustion
    • F23L15/02Arrangements of regenerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L15/00Heating of air supplied for combustion
    • F23L15/04Arrangements of recuperators
    • F23L15/045Arrangements of recuperators using intermediate heat-transfer fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • F28D15/02Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
    • F28D15/0266Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with separate evaporating and condensing chambers connected by at least one conduit; Loop-type heat pipes; with multiple or common evaporating or condensing chambers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/10Nitrogen; Compounds thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/10Catalytic reduction devices
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Definitions

  • the invention relates to an air preheater and a method for preventing corrosion and blockage of the same.
  • Conventional flue gas denitration technology employs ammonia gas as a reducing agent.
  • the reducing agent reacts with sulfur trioxide in the flue gas to yield ammonia bisulfate.
  • an air preheater is provided to recycle heat energy.
  • the air preheater is of a regenerative type, as shown in FIG. 1 , and includes a high temperature segment, a medium temperature segment, and a low temperature segment.
  • Ammonium bisulfate exhibits strong viscosity in the medium temperature segment and the low temperature segment, and tends to adsorb dust particles and, as a result, block the air preheater. This increases the gas flow resistance, lowers the heat transfer efficiency, and adversely affects operation of the air preheater.
  • the air preheater is particularly practicable following a selective catalytic reduction (SCR) denitration.
  • SCR selective catalytic reduction
  • an air preheater comprising a flue and an air channel disposed on a downstream of a denitration device, a first segment for producing secondary air, a second segment for producing primary air, a third segment for anti-condensation of ammonium bisulfate, and a fourth segment for curing of ammonium bisulfate.
  • the first segment for producing secondary air, the second segment for producing primary air, the third segment for anti-condensation of ammonium bisulfate and the fourth segment for curing of ammonium bisulfate are disposed in that order along a gas flow direction.
  • the second segment for producing primary air, the third segment for anti-condensation of ammonium bisulfate, and the fourth segment for curing of ammonium bisulfate each comprise a phase-change heat exchanger.
  • the phase-change heat exchanger comprises a heat absorption segment disposed in the flue, a heat release segment disposed in the air channel, an ascending tube and a downcomer which are configured to connect the heat absorption segment and the heat release segment.
  • the heat release segment is disposed higher than the heat absorption segment, and the phase-change heat exchangers are provided with a cycling medium.
  • a wall surface temperature of the third segment for anti-condensation of ammonium bisulfate is higher than a dew temperature of the ammonium bisulfate.
  • a wall surface temperature of the fourth segment for curing of ammonium bisulfate is lower than a solidification point temperature of the ammonium bisulfate.
  • the air preheater further comprises an acid-dew resistant segment disposed on a downstream of the fourth segment for curing of ammonium bisulfate.
  • the acid-dew resistant segment comprises the phase-change heat exchanger, and a wall surface temperature of the acid-dew resistant segment is higher than an acid dew point temperature.
  • the heat absorption segment in the second segment for producing primary air, the heat absorption segment in the third segment for anti-condensation of ammonium bisulfate, the heat absorption segment in the fourth segment for curing of ammonium bisulfate, the heat absorption segment in the acid-dew resistant segment are provided with a temperature sensor.
  • the cycling medium in the second segment for producing primary air, the third segment for anti-condensation of ammonium bisulfate, the fourth segment for curing of ammonium bisulfate, and the acid-dew resistant segment is water, Freon, or heat transfer oil.
  • the first segment for producing secondary air is a high temperature segment of a regenerative air preheater.
  • the first segment for producing secondary air comprises the phase-change heat exchanger
  • the cycling medium in the second segment for producing primary air is water, Freon, or heat transfer oil.
  • the reaction of the escaped ammonia and the sulfur trioxide only produces gaseous and solid ammonium bisulfate, and no liquid ammonium bisulfate is produced, thus the air preheater is effectively prevented from blockage and corrosion caused by liquid ammonium bisulfate. Therefore, the service life of the air preheater is prolonged; the heat transfer efficiency of the boiler is improved; thus ensuring the stable and safe operation of the machine set.
  • the air preheater is disposed on a downstream of a denitration device using SCR denitration technology.
  • the method can prevent the corrosion and blockage of the heating surface of the air preheater.
  • a method for preventing an air preheater from corrosion and blockage comprising:
  • the wall surface temperature of the third segment and the fourth segment can be accurately controlled, so that the ammonium bisulfate is cured on the wall surface of the pipe of the fourth segment and the wall surface of the downstream pipe of the fourth segment, then the solid ammonium bisulfate is eliminated by blowing equipment.
  • the air preheater is effectively prevented from blockage and corrosion, thus ensuring the safe, reliable, and stable operation of the boiler.
  • FIG. 1 is a schematic diagram of an existing air preheater
  • FIG. 2 is a schematic diagram of an air preheater in accordance with one embodiment of the invention.
  • FIG. 3 is a schematic diagram of an air preheater in accordance with another embodiment of the invention.
  • an air preheater comprises a flue 1 and an air channel 2 disposed on the downstream of a denitration device, a first segment for producing secondary air 3 , a second segment for producing primary air 4 , a third segment for anti-condensation of ammonium bisulfate 5 , and a fourth segment for curing of ammonium bisulfate 6 disposed in that order along a gas flow direction.
  • the second segment for producing primary air 4 , the third segment for anti-condensation of ammonium bisulfate 5 , and the fourth segment for curing of ammonium bisulfate 6 each comprise a phase-change heat exchanger.
  • the phase-change heat exchanger comprises a heat absorption segment 7 disposed in the flue 1 , a heat release segment 8 disposed in the air channel 2 , an ascending tube 9 and a downcomer 10 which are configured to connect the heat absorption segment 7 and the heat release segment 8 .
  • the heat release segment 8 is higher than the corresponding heat absorption segment 7 , and the phase-change heat exchanger is provided with a cycling medium.
  • a wall surface temperature of the third segment for anti-condensation of ammonium bisulfate 5 is higher than a dew temperature of the ammonium bisulfate.
  • a wall surface temperature of the fourth segment for curing of ammonium bisulfate 6 is lower than a solidification point temperature of the ammonium bisulfate.
  • High-temperature flue gas (between 350 and 440° C.) in the flue 1 enters an upstream of the assembled air preheater, and passes the first segment for producing secondary air 3 , the heat-absorbing segment 7 of the second segment for producing primary air 4 , the heat-absorbing segment 7 of the third segment for anti-condensation of ammonium bisulfate 5 , and the heat-absorbing segment 7 of the fourth segment for curing of ammonium bisulfate 6 .
  • the high-temperature flue gas releases heat when passing the air preheater and heats the cycling medium in the heat absorption segment 7 of all phase-change heat exchangers.
  • the cycling medium in all phase-change heat exchangers absorbs heat released by the flue gas and generates a lift force because of a density difference, thus the cycling medium in the heat absorption segment 7 enters the heat release segment 8 via the ascending tube 9 , and after releasing heat to the air, the cycling medium in the heat release segment 8 is back to the heat absorption segment 7 via the downcomer 10 , hereby a self-cycle is realized and no external power is needed.
  • the pipe wall temperature of the third segment for anti-condensation of ammonium bisulfate 5 and the pipe wall temperature of an upstream of the third segment for anti-condensation of ammonium bisulfate 5 are higher than the dew temperature of the ammonium bisulfate (between 0 and 200° C.)
  • the pipe wall temperature of the fourth segment for curing of ammonium bisulfate 6 and the pipe wall temperature of a downstream of the fourth segment for curing of ammonium bisulfate 6 are lower than the solidification point temperature (147° C.) of the ammonium bisulfate
  • the reaction of escaped ammonia and sulfur trioxide only generates gaseous and solid ammonium bisulfate in the air preheater, no liquid ammonium bisulfate is produced, and the air preheater is effectively prevented from blockage and corrosion caused by liquid ammonium bisulfate.
  • cycling media in the second segment for producing primary air 4 , the third segment for anti-condensation of ammonium bisulfate 5 , the fourth segment for curing of ammonium bisulfate 6 , the acid-dew resistant segment 11 is selected from water, Freon, or heat transfer oil. In actual operation, a suitable cycling medium solution is determined according to different temperatures.
  • the downstream of the fourth segment for curing of ammonium bisulfate 6 is provided with an acid-dew resistant segment 11 .
  • the acid-dew resistant segment 11 comprises the phase-change heat exchanger, comprising the heat absorption segment 7 , the heat release segment 8 , the ascending tube 9 and the downcomer 10 .
  • the wall surface temperature of the acid-dew resistant segment 11 is higher than an acid dew point temperature (between 0 and 100° C.), thereby effectively preventing the acid dew corrosion, decreasing an energy consumption of the boiler, and saving energy and reducing emission to the largest extent.
  • the air is divided into two paths after heated by the second segment for producing primary air 4 , as shown in FIGS. 2-3 , the first path is used as a primary air for a pulverizing system, and the second path is heated by the first segment for producing secondary air 3 and is used as secondary air of the boiler, which means the primary air is not heated by the first segment for producing secondary air 3 .
  • Heat saved by the primary air can be used to heat materials in the third segment for anti-condensation of ammonium bisulfate 5 , the fourth segment for curing of ammonium bisulfate 6 , the acid-dew resistant segment 11 , or a combination thereof.
  • the air in the acid-dew resistant segment 11 , the fourth segment for curing of ammonium bisulfate 6 , the third segment for anti-condensation of ammonium bisulfate 5 , and the second segment for producing primary air 4 is exhausted, so that no non-condensable gas exists in cycling pipes of the phase-change heat exchangers, and the blockage caused by water or gas is avoided.
  • the flue gas temperature after denitration is between 350 and 440° C.
  • the heat absorption segment 7 in the second segment for producing primary air 4 , the heat absorption segment 7 in the third segment for anti-condensation of ammonium bisulfate 5 , the heat absorption segment 7 in the fourth segment for curing of ammonium bisulfate 6 , the heat absorption segment 7 in the acid-dew resistant segment 11 are provided with a temperature sensor 12 adapted to detect the wall surface temperatures of the segments.
  • the first segment for producing secondary air 3 is a high temperature segment of a regenerative air preheater.
  • the first segment for producing secondary air 3 can also be a phase-change heat exchanger, as shown in FIG. 3
  • the first segment for producing secondary air 3 also comprises the heat absorption segment 7 , the heat release segment 8 , the ascending tube 9 , and the downcomer 10
  • the cycling medium in the first segment for producing secondary air 3 is water, Freon, or heat transfer oil.
  • a method for preventing the air preheater from corrosion and blockage after an SCR denitration is also provided in the invention, and the method comprises:
  • phase-change heat exchanger compensates for the shortcomings in the prior art, featuring high industrial value.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Air Supply (AREA)
  • Chimneys And Flues (AREA)
US15/202,520 2014-01-07 2016-07-05 Air preheater and method for preventing corrosion and blockage of the same Abandoned US20160313076A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201410006896.4A CN103982906B (zh) 2014-01-07 2014-01-07 适用于scr脱硝后的组合式空气预热器及防腐防堵方法
CN201410006896.4 2014-01-07
PCT/CN2014/075792 WO2015103823A1 (zh) 2014-01-07 2014-04-21 适用于scr脱硝后的组合式空气预热器及防腐防堵方法

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PCT/CN2014/075792 Continuation-In-Part WO2015103823A1 (zh) 2014-01-07 2014-04-21 适用于scr脱硝后的组合式空气预热器及防腐防堵方法

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US (1) US20160313076A1 (ko)
JP (1) JP6157757B2 (ko)
KR (1) KR101767365B1 (ko)
CN (1) CN103982906B (ko)
WO (1) WO2015103823A1 (ko)

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CN108413439A (zh) * 2018-04-23 2018-08-17 华北电力科学研究院有限责任公司 调整四分仓空气预热器出口烟气温度的装置及方法
CN116928690A (zh) * 2023-07-05 2023-10-24 山东中和泰节能环保科技有限公司 相变输热式旋流预热器

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CN109210555A (zh) * 2017-07-03 2019-01-15 大唐保定热电厂 电站锅炉脱硝投运空气预热器在线干烧清堵系统和技术
CN107198946B (zh) * 2017-07-04 2020-04-28 大唐环境产业集团股份有限公司 一种发电厂脱硝系统运行中空预器堵塞原因的判断方法
CN107191963B (zh) * 2017-07-10 2023-07-25 东方电气集团东方锅炉股份有限公司 一种回转式空气预热器及该回转式空气预热器防硫酸氢铵堵塞的方法
CN108019940B (zh) * 2017-12-05 2020-01-21 合山锌业科技有限公司 多燃料导热油炉
CN107940438B (zh) * 2017-12-26 2024-05-28 福建龙净环保股份有限公司 一种烟气热能利用系统及其控制方法
CN109028137A (zh) * 2018-08-06 2018-12-18 东方电气集团东方锅炉股份有限公司 一种预防硫酸氢铵沉积的管式预热器及其控制方法
CN109163351A (zh) * 2018-10-17 2019-01-08 中国电力工程顾问集团华北电力设计院有限公司 解决堵塞腐蚀问题的空气预热器组合结构
CN110455105A (zh) * 2019-09-10 2019-11-15 山东海汇环保设备有限公司 用于电厂烟气余热回收的被动式取热器
CN110793057B (zh) * 2019-10-18 2024-01-30 华电电力科学研究院有限公司 一种防止燃煤电厂空气预热器堵塞的系统及方法
KR102503254B1 (ko) * 2021-02-08 2023-02-24 주식회사 냄새뚝 배기가스 정화장치
CN113217941B (zh) * 2021-04-19 2022-07-29 华能铜川照金煤电有限公司 空预器堵塞预测与喷水喷氨优化防堵方法
CN113606969B (zh) * 2021-06-23 2024-02-09 上海志筠环保科技有限公司 可控型双相热媒强制循环换热系统
CN114440648A (zh) * 2022-01-14 2022-05-06 国能龙源催化剂江苏有限公司 一种脱硝催化剂生产窑炉管道废气净化方法
CN115539928A (zh) * 2022-02-24 2022-12-30 昊姆(上海)节能科技有限公司 一种自动控温避免烟气酸腐蚀的相变式换热器

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Publication number Priority date Publication date Assignee Title
CN108413439A (zh) * 2018-04-23 2018-08-17 华北电力科学研究院有限责任公司 调整四分仓空气预热器出口烟气温度的装置及方法
CN116928690A (zh) * 2023-07-05 2023-10-24 山东中和泰节能环保科技有限公司 相变输热式旋流预热器

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CN103982906A (zh) 2014-08-13
KR20160103101A (ko) 2016-08-31
JP2017501370A (ja) 2017-01-12
WO2015103823A1 (zh) 2015-07-16
JP6157757B2 (ja) 2017-07-05
KR101767365B1 (ko) 2017-08-10
CN103982906B (zh) 2016-04-06

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