US20160076173A1 - Spun yarn and woven or knitted fabric - Google Patents

Spun yarn and woven or knitted fabric Download PDF

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Publication number
US20160076173A1
US20160076173A1 US14/779,587 US201414779587A US2016076173A1 US 20160076173 A1 US20160076173 A1 US 20160076173A1 US 201414779587 A US201414779587 A US 201414779587A US 2016076173 A1 US2016076173 A1 US 2016076173A1
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Prior art keywords
cross
flat
spun yarn
polyester
section
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US14/779,587
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Masahiro Taninomiya
Teruhiko Kasahara
Michiaki Chiba
Shunma Miyauchi
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Toray Industries Inc
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Toray Industries Inc
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Assigned to TORAY INDUSTRIES, INC. reassignment TORAY INDUSTRIES, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MIYAUCHI, Shunma, KASAHARA, Teruhiko, CHIBA, Michiaki, TANINOMIYA, Masahiro
Publication of US20160076173A1 publication Critical patent/US20160076173A1/en
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D03D15/0027
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/30Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments
    • D03D15/37Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the fibres or filaments with specific cross-section or surface shape
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/02Moisture-responsive characteristics
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/02Underwear
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2973Particular cross section
    • Y10T428/2978Surface characteristic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065Including strand which is of specific structural definition
    • Y10T442/3089Cross-sectional configuration of strand material is specified
    • Y10T442/3114Cross-sectional configuration of the strand material is other than circular
    • Y10T442/3122Cross-sectional configuration is multi-lobal

Definitions

  • This disclosure relates to a spun yarn having good water absorbability, quick drying properties and anti-transparent properties and soft touch feeling and, particularly, to a spun yarn which makes it possible to obtain a woven or knitted fabric suitable for clothing uses, for example, uses for inner shirts, pants, sports shirts and the like and a woven or knitted fabric using the same.
  • a blended yarn including polyester short fibers having a modified shape cross section having 3 or more projections in a cross-sectional shape thereof and a modified shape ratio of 1.8 or more, natural fibers and cellulose-based fibers has been proposed (see JP 2008-133584 A).
  • JP 2008-133584 A a blended yarn including polyester short fibers having a modified shape cross section having 3 or more projections in a cross-sectional shape thereof and a modified shape ratio of 1.8 or more, natural fibers and cellulose-based fibers.
  • a woven or knitted fabric particularly suitable for clothing uses for example, uses for inner shirts, pants, sports shirts, white coats, sweaters, national costumes and the like.
  • polyester-based fibers having a specific flat multifoliar cross section and cellulose-based fibers in combination and that when processed into a spun yarn or a woven or knitted fabric, it has high water absorbability and quick drying properties and has high anti-transparent properties without blending with high content of titanium fibers.
  • a spun yarn including 20 to 80% by mass of a polyester-based fiber having a flat multifoliar cross section and 20 to 80% by mass of a cellulose-based fiber, wherein a cross-sectional shape of the polyester-based fiber having a flat multifoliar cross section is a flat shape having 6 or more convex parts on a circumference thereof, and when a maximum length of a cross section of the polyester-based fiber having a flat multifoliar cross section is taken as A, a maximum width of the cross section of the polyester-based fiber having a flat multifoliar cross section is taken as B, a length of a line connecting vertexes of convex parts which are adjacent to each other in a maximum concave-convex part is taken as C, and a length of a perpendicular line drawn from the line connecting the vertexes of the convex parts adjacent to each other in the maximum concave-convex part to a bottom point of a concave part is taken as D, a flat ratio defined by
  • Modified shape ratio( C/D ) 1.0 to 5.0 (2).
  • the modified shape ratio is 2.0 to 5.0.
  • a single filament fineness of the polyester-based fiber having a flat multifoliar cross section is 2.0 dtex or less.
  • the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
  • the above-mentioned spun yarn can be suitably used for a woven or knitted fabric for clothing uses, for example, for inner shirts and sports shirts.
  • FIG. 1 is a cross-sectional view for illustrating an example of a cross-sectional shape of a polyester-based fiber having a flat multifoliar cross section included in the spun yarn which has a plurality (8) of convex parts on a circumference of a fiber cross section.
  • A The maximum length of a cross section of a polyester-based fiber having a flat multifoliar cross section
  • D The length of a perpendicular line drawn down from the line connecting the vertexes of the convex parts which are adjacent to each other in the maximum concave-convex part to a bottom point of a concave part
  • the spun yarn is obtained by blending 20 to 80% by mass of polyester-based fibers having a flat multifoliar cross section and 20 to 80% by mass of cellulose-based fibers.
  • the cellulose-based fibers are selected from at least one kind of cellulose-based fibers of natural fibers such as hemp, cotton and silk, regenerated fibers such as viscose rayon, cupra and solvent-spun cellulose, and semisynthetic fibers such as acetate.
  • the regenerated fibers such as viscose rayon and solvent-spun cellulose are preferably used from the viewpoints of handleability, general versatility and functionality.
  • the arbitrary cross-sectional shape is preferably a flat shape having concaves and convexes on a circumference thereof. Water absorbability is increased by having the concaves and convexes on the circumference and, further, liquid is uniformly diffused by a capillary action so that there is an effect of having quick drying properties to easily keep dry feeling and refreshing cool feeling.
  • the number of the above-mentioned convex parts on the circumference is preferably 6 to 14, and more preferably 8 to 12.
  • the number of the convex parts present on the circumference of the cross-sectional shape is less than 6, spaces are decreased, thereby causing poor water absorbability, liquid retainability and diffusibility. Further, the irregular reflectance of light is decreased, thereby causing deteriorated anti-transparent properties. Furthermore, at the time of touching the skin, contact points decrease, thereby providing rough touch feeling.
  • the number of the convex parts exceeds 14, the cellulose-based fibers have low rigidity as compared to the polyester-based fibers and are easily worn away, resulting in a decrease in yarn strength.
  • the shape of the convex parts is preferably a rounded shape from the viewpoint of texture.
  • the single filament fineness of the cellulose-based fibers is preferably 1.0 to 5.0 dtex.
  • the single filament fineness is more preferably 1.2 to 2.2 dtex.
  • the single filament fineness is less than 1.0 dtex, the fibers tend to be easily wound around a cylinder of a card, thereby causing a significant reduction in process passability in some cases. As a result, a defect of the spun yarn tends to easily occur.
  • touch feeling at the time of touching human skin is hard, which shows an undesirable tendency in use in terms of soft touch feeling.
  • the spaces among the fibers become excessively large by an increase in single filament fineness so that water absorbability tends to be significantly deteriorated.
  • the fiber length of the cellulose-based fibers is preferably 30 to 64 mm, from the viewpoints of high entanglement with other constituent fibers such as the polyester-based fibers to be blended and being able to improve card process passability.
  • the fiber length is more preferably 35 to 51 mm.
  • Examples of commercially available products of the cellulose-based fibers include rayon (trade name “COLONA”) manufactured by Daiwabo Rayon Co., Ltd., and the like.
  • the content of the above-mentioned cellulose-based fibers is 20 to 80% by mass.
  • the mixing ratio (content) of the cellulose-based fibers is less than 20% by mass, water absorbability for impregnating liquid becomes weak. Diffusibility is therefore deteriorated, and dry feeling and refreshing cool feeling of the spun yarn are reduced. Further, soft touch feeling peculiar to the cellulose-based fibers is also impaired so that texture feeling during the use becomes inferior.
  • the mixing ratio of the cellulose-based fibers exceeds 80% by mass, water absorbability becomes excessively strong, and liquid impregnated is held in the fibers. Accordingly, the liquid cannot be quickly evaporated. That is, quick drying properties become poor.
  • a polyester constituting the polyester-based fibers means a high molecular weight polymer formed by a condensation reaction of terephthalic acid with ethylene glycol, trimethylene glycol, butylene glycol or the like, a condensate of sebacic acid, adipic acid, trimellitic acid, isophthalic acid, p-hydroxybenzoic acid or the like with polyethylene glycol or the like, a polyester polymer containing another polyester, and the like.
  • the polyester-based fibers having a flat multifoliar cross section are polyester-based fibers in which the cross-sectional shape thereof is a flat shape having 6 or more convex parts.
  • the number of the convex parts present on a circumference of the cross-sectional shape is less than 6, spaces formed among fibers adjacent to one another are decreased, thereby causing poor water absorbability, liquid retainability and diffusibility. Further, the irregular reflectance of light is decreased, thereby causing deteriorated anti-transparent properties.
  • the modified shape ratio tends to be extremely decreased from the feature of a production method of the polyester-based fibers, and the spaces formed among the fibers adjacent to one another are decreased, thereby causing poor water absorbability, liquid retainability and diffusibility, similarly as described above.
  • the flat cross-sectional shape makes it possible to form spaces among fibers, which improves water absorbability, liquid retainability and diffusibility. Further, the irregular reflectance of light is increased, thereby improving anti-transparent properties. Furthermore, falling properties per single fiber are improved so that soft touch feeling can be obtained.
  • FIG. 1 shows an example of a cross-sectional shape of a single fiber of the polyester-based fiber having a flat multifoliar cross section.
  • the cross-sectional shape of the polyester-based fiber having a flat multifoliar cross section included in the spun yarn which has a plurality (8) of convex parts on the circumference of the fiber cross section is shown as an example.
  • A is the maximum length of the cross section of the above-mentioned polyester-based fiber having a flat multifoliar cross section.
  • B is the maximum width of the cross section of the polyester-based fiber having a flat multifoliar cross section, and means the length of a line of the maximum width connecting vertexes of convex parts vertically crossing the above-mentioned maximum length A.
  • C means the length of a line connecting vertexes of convex parts which are adjacent to each other in a maximum concave-convex part.
  • D means the length of a perpendicular line drawn from the line connecting the vertexes of the convex parts which are adjacent to each other in the maximum concave-convex part to a bottom point of a concave part.
  • E means the longest length except for the maximum width B among lines between vertexes of both convex parts opposing to each other using the maximum length A as an axis of symmetry.
  • the polyester-based fibers in which the cross-sectional shape thereof is a flat shape having 6 or more convex parts are used.
  • the number of convex parts is preferably 7 to 13 and more preferably 8 to 12.
  • the shape of the convex part is preferably a rounded shape from the viewpoint of texture.
  • the flat ratio (A/B) is 2.0 to 3.0.
  • the flat ratio (A/B) is less than 2.0, falling properties of fibers are deteriorated, thereby failing to obtain soft touch feeling.
  • the flat ratio (A/B) exceeds 3.0, stiffness feeling is decreased, and permanent set in fatigue is liable to be caused. Further, fiber-forming properties are deteriorated, or the modified shape ratio is deteriorated.
  • the flat ratio (A/B) is more preferably 2.0 to 2.7, and still more preferably 2.0 to 2.5.
  • the modified shape ratio (C/D) represents the size of a concave part between the adjacent convex parts in the above-mentioned flat multifoliar shape.
  • the larger value thereof indicates the smaller concave part, and the smaller value thereof indicates the larger concave part.
  • the modified shape ratio (C/D) is large, the concave part becomes shallow, and the spaces formed among the fibers are also decreased. Accordingly, water absorbability and diffusibility tend to be deteriorated. Furthermore, the irregular reflectance of light is also decreased, and anti-transparent properties tend to be deteriorated. Accordingly, the modified shape ratio (C/D) is 5.0 or less.
  • the modified shape ratio (C/D) is 1.0 or more.
  • the modified shape ratio (C/D) is 1.0 to 5.0 from the above viewpoint.
  • the modified shape ratio (C/D) is more preferably 1.0 to 4.0 in terms of water absorbability and diffusibility, and still more preferably 2.0 to 4.0 from the viewpoint of the balance between flat shape keeping properties, water absorbability and diffusibility.
  • the convex part ratio indicates the length ratio of the maximum width B and the longest length E except for the maximum width B of lines between vertexes of both convex parts using the maximum length A as an axis of symmetry in the above-mentioned flat multifoliar shape.
  • This has a meaning as an index to measure the degree of distortion of an approximately elliptic shape obtained when lines connecting vertexes of the respective convex parts of the maximum width B, E and the maximum length A are drawn.
  • the convex part ratio is preferably 0.6 or more.
  • the convex part ratio is excessively large, many concave parts are completely blocked when the concaves and convexes of the fibers are fitted to each other. The spaces are therefore decreased and water absorbability and diffusibility are deteriorated.
  • the convex part ratio (E/B) is preferably 0.9 or less.
  • the convex part ratio (E/B) is preferably 0.6 to 0.9 from the above-mentioned viewpoint.
  • the convex part ratio (EB) is preferably 0.6 to 0.8, and more preferably 0.7 to 0.8.
  • the content of the polyester-based fibers having a flat multifoliar cross section in the spun yarn is 20 to 80% by mass.
  • the mixing rate (content) of the polyester-based fibers having a flat multifoliar cross section is less than 20% by mass, hydrophobicity of the spun yarn is decreased. Accordingly, water absorbed tends to become difficult to be evaporated, quick drying properties are poor, and texture feeling is also deteriorated.
  • the mixing ratio (content) of the polyester-based fibers having a flat multifoliar cross section exceeds 80% by mass, the capillary phenomenon effect becomes weak and liquid diffusibility is deteriorated, thereby impairing dry feeling and refreshing cool feeling at the time of touching the skin. From the above, as a preferred balance, the content of the polyester-based fibers having a flat multifoliar cross section in the spun yarn is 30 to 70% by mass, and more preferably 40 to 60% by mass.
  • the single filament fineness of the polyester-based fibers having a flat multifoliar cross section is preferably 2.0 dtex or less.
  • the single filament fineness is more preferably 1.0 to 2.0 dtex, and still more preferably 1.2 to 1.8 dtex.
  • rigidity peculiar to the polyester-based fiber is increased so that irritation of texture feeling becomes strong, and soft touch feeling is also impaired in some cases.
  • the spaces formed among the fibers are excessively increased so that the capillary phenomenon effect becomes weak and liquid diffusibility is deteriorated, thereby tending to impair dry feeling and refreshing cool feeling at the time of touching the skin.
  • the single filament fineness is less than 1.0 dtex, process passability in a carding process is deteriorated and productivity tends to be reduced.
  • the polyester-based fibers having a flat multifoliar cross section can be allowed to contain inorganic particles for the purpose of improving anti-transparent properties and softness.
  • the content of the inorganic particles is preferably 0.2 to 2.5% by mass, more preferably 0.2 to 2.2% by mass, and still more preferably 0.3 to 2.0% by mass.
  • the content of the inorganic particles is less than 0.2% by mass, friction with the cellulose-based fibers is increased, and the soft touch feeling tends to be impaired and, further, the irregular reflection of light becomes insufficient, and the anti-transparent performance tends to be deteriorated.
  • the content of the inorganic particles exceeds 2.5% by mass, process passability in spinning is deteriorated, and the guide wear tends to occur and, further, the modified shape ratio of the polyester-based fibers having a flat multifoliar cross section tends to be decreased during melt spinning thereof. Furthermore, a matte effect acts strongly so that whiteness is inferior, and color developability tends to be lost.
  • the fiber length of the polyester-based fibers having a flat multifoliar cross section is preferably 30 to 64 mm, and more preferably 35 to 51 mm, from the viewpoint of process passability in spinning.
  • the spun yarn and a production method thereof will be described below.
  • the twist coefficient of the spun yarn is preferably 3.0 to 4.5.
  • the twist coefficient is less than 3.0, sufficient yarn strength tends to be not obtained, and yarn breakage during spinning or a reduction in strength when it is formed into the woven or knitted fabric tends to be brought about.
  • the twist coefficient exceeds 4.5, a kink caused by untwisting tends to occur, and when it is formed into the woven or knitted fabric, it tends to have coarse feeling.
  • the spun yarn can be produced by an ordinary spinning method using the polyester-based fibers having a flat multifoliar cross section and the cellulose-based fibers, and can be produced using a ring spinning frame (including bundling and eddy-current types), an air spinning frame or the like.
  • the count of the spun yarn is preferably 30 to 53, and more preferably 40.
  • the woven or knitted fabric including the spun yarn may be a woven or knitted fabric using 100% of the spun yarn. However, preferably, at least 40% by mass of the spun yarn is contained. When the ratio of the spun yarn is less than 40% by mass, there is a tendency that the water absorbability effect due to the combination of the polyester-based fibers having a flat multifoliar cross section and the cellulose-based fibers is less likely to be obtained. Further, in the woven or knitted fabric, it is possible to use the spun yarn within a range of less than 60% by mass, and to mixedly weave or knit other spun yarn, filaments or the like, in addition to the spun yarn.
  • the spun yarn and the woven or knitted fabric using the same have water absorbability, quick drying properties and anti-transparent properties and soft touch feeling so that they can be suitably used as inner shirts, pants, sports shirts, white coats, sweaters, national costumes and the like.
  • Evaluation was performed in accordance with JIS L1907 (2010 edition, Byreck method). Evaluation contents were as follows. “ ⁇ ” and “ ⁇ ” were judged as passed.
  • a test specimen allowed to stand for 24 hours under an atmosphere of a room temperature of 25° C. and a humidity of 40% RH is cut out into a 10-cm square, and the mass (A) thereof is measured.
  • the test specimen is immersed in ion-exchanged water for 30 seconds, and thereafter taken out of the liquid by pinching one corner of the test specimen with tweezers.
  • the test specimen taken out is allowed to stand for 1 hour similarly under an atmosphere of a room temperature of 25° C. and a humidity of 40% RH, followed by naturally drying, and the mass (B) thereof is measured.
  • the residual water content (C) is calculated by the following formula:
  • Evaluation contents were as follows. “ ⁇ ” and “ ⁇ ” were judged as passed.
  • Anti-transparent degree(%) 100 ⁇ ( Lfw ⁇ Lfb )/( Lw ⁇ Lb ) ⁇ 100
  • Lw L value of the standard white board in a state where there was no sample cloth
  • Lb L value of the standard black board in a state where there was no sample cloth
  • Lfb L value at the time when the sample cloth was placed on the standard black board
  • Evaluation contents were as follows. “ ⁇ ” and “ ⁇ ” were judged as passed.
  • test specimen was cut out into a 10-cm square, and the test specimen cut out was grasped by five subjects, and point evaluation was performed according to the following criteria. Thereafter, the average points were calculated, and “ ⁇ ” and “ ⁇ ” were judged as passed.
  • polyester-based fibers having a flat multifoliar cross section having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 80% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5.
  • polyester-based fibers having a flat multifoliar cross section having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 50% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5.
  • polyester-based fibers having a flat multifoliar cross section having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 20% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5.
  • polyester-based fibers having a flat multifoliar cross section having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.1% by mass, a flat ratio of 2.0, a modified shape ratio of 2.5 and a convex part ratio of 0.7 and having a cross-sectional shape with 8 convex parts and 20% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5.
  • polyester-based fibers having a flat multifoliar cross section having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 15% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5.
  • polyester-based fibers having a flat multifoliar cross section having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 85% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5.
  • polyester-based fibers having a trifoliar (Y-shaped) cross section (fiber length: 51 mm) having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 1.0, a modified shape ratio of 6.7 and a convex part ratio of 0.9 and having a cross-sectional shape with 3 convex parts and 20% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5.
  • polyester-based fibers fiber length: 51 mm
  • fiber length: 51 mm 80% by mass of polyester-based fibers having a rounded cross-sectional shape having a single filament fineness of 1.7 dtex and a titanium oxide content of 0.3% by mass and 20% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5.
  • a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom.
  • the fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.

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Abstract

A spun yarn includes 20 to 80% by mass of a polyester-based fiber having a flat multifoliar cross section and 20 to 80% by mass of a cellulose-based fiber. A cross-sectional shape of the polyester-based fiber having a flat multifoliar cross section is a flat shape having 6 or more convex parts on a circumference thereof. The polyester-based fiber having a flat multifoliar cross section has the specific flat ratio and specific modified shape ratio.

Description

    TECHNICAL FIELD
  • This disclosure relates to a spun yarn having good water absorbability, quick drying properties and anti-transparent properties and soft touch feeling and, particularly, to a spun yarn which makes it possible to obtain a woven or knitted fabric suitable for clothing uses, for example, uses for inner shirts, pants, sports shirts and the like and a woven or knitted fabric using the same.
  • BACKGROUND
  • For clothing uses such as uses for inner shirts, pants and sports shirts, studies have been conventionally made on water absorption-quick drying, soft touch feeling, anti-transparency and the like using polyester materials, and spun yarns and woven or knitted fabrics using polyester fibers having a modified shape cross section have been proposed.
  • For example, a spun yarn obtained by controlling the mixing ratio of 3 or 4 kinds of polyester-based short fibers having modified shape cross sections to 15 to 20% by weight or more has been proposed (see JP 9-59838 A). However, in that proposal, there was a problem that water absorbability and soft touch feeling were not sufficient, because the spun yarn was composed of only synthetic fibers.
  • Further, a blended yarn including polyester short fibers having a modified shape cross section having 3 or more projections in a cross-sectional shape thereof and a modified shape ratio of 1.8 or more, natural fibers and cellulose-based fibers has been proposed (see JP 2008-133584 A). However, in that proposal, although the blended yarn including the polyester fibers having a modified shape cross section, the natural fibers and the cellulose-based fibers were used, there was a problem that water absorbability and soft touch feeling were not sufficient yet.
  • Furthermore, a spun yarn in which soft touch feeling is obtained by using blended cotton yarn with polyester-based fibers having modified shape cross section of multifoliar cross-sectional shape or polygonal shape and cellulose-based fibers, and anti-transparent properties are improved by further blending with high content of titanium fibers has been proposed (see JP 2012-188792 A). However, also in that proposal, there was a problem that water absorbability and soft touch feeling were not always sufficient and that anti-transparent properties were also insufficient, as with the proposal in JP 2008-133584 A.
  • It could therefore be helpful to provide a spun yarn having soft touch feeling which could not be realized by the above-mentioned conventional techniques in use of polyester-based fibers and further also having functions of high water absorbability, quick drying properties and anti-transparent properties which could not be realized only by natural fibers and cellulose-based fibers.
  • Further, it could be helpful to provide a woven or knitted fabric particularly suitable for clothing uses, for example, uses for inner shirts, pants, sports shirts, white coats, sweaters, national costumes and the like.
  • SUMMARY
  • We focused our attention on spaces among fibers. It has been presumed that water absorbability and soft touch feeling are not sufficient, because the spaces are less formed among the single fibers in the polyester fibers having a modified cross section in JP 2008-133584 A. Further, it has been considered that the same applies in JP 2012-188792 A and further that irregular reflection of light caused by fiber surface shape is not sufficient also in anti-transparent properties. Furthermore, it has been presumed that not only unilaterally high water absorbability, but also compatibility with quick drying properties is important.
  • We found that soft touch feeling is realized by using polyester-based fibers having a specific flat multifoliar cross section and cellulose-based fibers in combination, and that when processed into a spun yarn or a woven or knitted fabric, it has high water absorbability and quick drying properties and has high anti-transparent properties without blending with high content of titanium fibers.
  • We thus provide a spun yarn including 20 to 80% by mass of a polyester-based fiber having a flat multifoliar cross section and 20 to 80% by mass of a cellulose-based fiber, wherein a cross-sectional shape of the polyester-based fiber having a flat multifoliar cross section is a flat shape having 6 or more convex parts on a circumference thereof, and when a maximum length of a cross section of the polyester-based fiber having a flat multifoliar cross section is taken as A, a maximum width of the cross section of the polyester-based fiber having a flat multifoliar cross section is taken as B, a length of a line connecting vertexes of convex parts which are adjacent to each other in a maximum concave-convex part is taken as C, and a length of a perpendicular line drawn from the line connecting the vertexes of the convex parts adjacent to each other in the maximum concave-convex part to a bottom point of a concave part is taken as D, a flat ratio defined by formula (1) and a modified shape ratio defined by formula (2) are satisfied:

  • Flat ratio(A/B)=2.0 to 3.0   (1)

  • Modified shape ratio(C/D)=1.0 to 5.0   (2).
  • According to preferable aspects of the spun yarn, the modified shape ratio is 2.0 to 5.0.
  • According to preferable aspects of the spun yarn, when the longest length except for the maximum width B of the cross section among lines between vertexes of both convex parts opposing to each other using the maximum length A as an axis of symmetry is taken as E, a convex part ratio defined by formula (3) is satisfied:

  • Convex part ratio(E/B)=0.6 to 0.9   (3).
  • According to preferable aspects of the spun yarn, a single filament fineness of the polyester-based fiber having a flat multifoliar cross section is 2.0 dtex or less.
  • According to preferable aspects of the spun yarn, the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
  • The above-mentioned spun yarn can be suitably used for a woven or knitted fabric for clothing uses, for example, for inner shirts and sports shirts.
  • It becomes possible to have spaces of variable size among fibers by having a flat shape and having concaves and convexes on an outer periphery portion thereof, and further by not equalizing the heights of the concaves and convexes on the outer periphery portion and, thus, a spun yarn having excellent water absorbability and quick drying properties and soft touch feeling, and a woven or knitted fabric using the same can be obtained. Further, a spun yarn and woven or knitted fabric also having high anti-transparent performance are obtained.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a cross-sectional view for illustrating an example of a cross-sectional shape of a polyester-based fiber having a flat multifoliar cross section included in the spun yarn which has a plurality (8) of convex parts on a circumference of a fiber cross section.
  • DESCRIPTION OF REFERENCE NUMERALS AND SIGNS
  • A: The maximum length of a cross section of a polyester-based fiber having a flat multifoliar cross section
  • B: The maximum width of the cross section of the polyester-based fiber having a flat multifoliar cross section
  • C: The length of a line connecting vertexes of convex parts which are adjacent to each other in a maximum concave-convex part
  • D: The length of a perpendicular line drawn down from the line connecting the vertexes of the convex parts which are adjacent to each other in the maximum concave-convex part to a bottom point of a concave part
  • E: The longest length except for the maximum width B among lines between vertexes of both convex parts opposing to each other using the maximum length A as an axis of symmetry
  • DETAILED DESCRIPTION
  • Our spun yarns will be described in detail below.
  • The spun yarn is obtained by blending 20 to 80% by mass of polyester-based fibers having a flat multifoliar cross section and 20 to 80% by mass of cellulose-based fibers.
  • The cellulose-based fibers are selected from at least one kind of cellulose-based fibers of natural fibers such as hemp, cotton and silk, regenerated fibers such as viscose rayon, cupra and solvent-spun cellulose, and semisynthetic fibers such as acetate. Of these, the regenerated fibers such as viscose rayon and solvent-spun cellulose are preferably used from the viewpoints of handleability, general versatility and functionality.
  • The arbitrary cross-sectional shape is preferably a flat shape having concaves and convexes on a circumference thereof. Water absorbability is increased by having the concaves and convexes on the circumference and, further, liquid is uniformly diffused by a capillary action so that there is an effect of having quick drying properties to easily keep dry feeling and refreshing cool feeling.
  • The number of the above-mentioned convex parts on the circumference is preferably 6 to 14, and more preferably 8 to 12. When the number of the convex parts present on the circumference of the cross-sectional shape is less than 6, spaces are decreased, thereby causing poor water absorbability, liquid retainability and diffusibility. Further, the irregular reflectance of light is decreased, thereby causing deteriorated anti-transparent properties. Furthermore, at the time of touching the skin, contact points decrease, thereby providing rough touch feeling. In addition, when the number of the convex parts exceeds 14, the cellulose-based fibers have low rigidity as compared to the polyester-based fibers and are easily worn away, resulting in a decrease in yarn strength. Further, liquid impregnated is held in the fibers because of their excessively high water absorbability so that the liquid cannot be quickly evaporated, resulting in poor quick drying properties. Furthermore, the shape of the convex parts is preferably a rounded shape from the viewpoint of texture.
  • Further, the single filament fineness of the cellulose-based fibers is preferably 1.0 to 5.0 dtex. The single filament fineness is more preferably 1.2 to 2.2 dtex. When the single filament fineness is less than 1.0 dtex, the fibers tend to be easily wound around a cylinder of a card, thereby causing a significant reduction in process passability in some cases. As a result, a defect of the spun yarn tends to easily occur. Furthermore, when the single filament fineness exceeds 5.0 dtex, touch feeling at the time of touching human skin is hard, which shows an undesirable tendency in use in terms of soft touch feeling. In addition, the spaces among the fibers become excessively large by an increase in single filament fineness so that water absorbability tends to be significantly deteriorated.
  • The fiber length of the cellulose-based fibers is preferably 30 to 64 mm, from the viewpoints of high entanglement with other constituent fibers such as the polyester-based fibers to be blended and being able to improve card process passability. The fiber length is more preferably 35 to 51 mm. Examples of commercially available products of the cellulose-based fibers include rayon (trade name “COLONA”) manufactured by Daiwabo Rayon Co., Ltd., and the like.
  • The content of the above-mentioned cellulose-based fibers is 20 to 80% by mass. When the mixing ratio (content) of the cellulose-based fibers is less than 20% by mass, water absorbability for impregnating liquid becomes weak. Diffusibility is therefore deteriorated, and dry feeling and refreshing cool feeling of the spun yarn are reduced. Further, soft touch feeling peculiar to the cellulose-based fibers is also impaired so that texture feeling during the use becomes inferior. Furthermore, when the mixing ratio of the cellulose-based fibers exceeds 80% by mass, water absorbability becomes excessively strong, and liquid impregnated is held in the fibers. Accordingly, the liquid cannot be quickly evaporated. That is, quick drying properties become poor.
  • A polyester constituting the polyester-based fibers means a high molecular weight polymer formed by a condensation reaction of terephthalic acid with ethylene glycol, trimethylene glycol, butylene glycol or the like, a condensate of sebacic acid, adipic acid, trimellitic acid, isophthalic acid, p-hydroxybenzoic acid or the like with polyethylene glycol or the like, a polyester polymer containing another polyester, and the like.
  • The polyester-based fibers having a flat multifoliar cross section are polyester-based fibers in which the cross-sectional shape thereof is a flat shape having 6 or more convex parts. When the number of the convex parts present on a circumference of the cross-sectional shape is less than 6, spaces formed among fibers adjacent to one another are decreased, thereby causing poor water absorbability, liquid retainability and diffusibility. Further, the irregular reflectance of light is decreased, thereby causing deteriorated anti-transparent properties. When the number of the convex parts exceeds 12, the modified shape ratio tends to be extremely decreased from the feature of a production method of the polyester-based fibers, and the spaces formed among the fibers adjacent to one another are decreased, thereby causing poor water absorbability, liquid retainability and diffusibility, similarly as described above. The flat cross-sectional shape makes it possible to form spaces among fibers, which improves water absorbability, liquid retainability and diffusibility. Further, the irregular reflectance of light is increased, thereby improving anti-transparent properties. Furthermore, falling properties per single fiber are improved so that soft touch feeling can be obtained.
  • FIG. 1 shows an example of a cross-sectional shape of a single fiber of the polyester-based fiber having a flat multifoliar cross section. In FIG. 1, the cross-sectional shape of the polyester-based fiber having a flat multifoliar cross section included in the spun yarn which has a plurality (8) of convex parts on the circumference of the fiber cross section is shown as an example.
  • In FIG. 1, A is the maximum length of the cross section of the above-mentioned polyester-based fiber having a flat multifoliar cross section. B is the maximum width of the cross section of the polyester-based fiber having a flat multifoliar cross section, and means the length of a line of the maximum width connecting vertexes of convex parts vertically crossing the above-mentioned maximum length A. Further, C means the length of a line connecting vertexes of convex parts which are adjacent to each other in a maximum concave-convex part. Then, D means the length of a perpendicular line drawn from the line connecting the vertexes of the convex parts which are adjacent to each other in the maximum concave-convex part to a bottom point of a concave part. E means the longest length except for the maximum width B among lines between vertexes of both convex parts opposing to each other using the maximum length A as an axis of symmetry.
  • The polyester-based fibers in which the cross-sectional shape thereof is a flat shape having 6 or more convex parts are used. The number of convex parts is preferably 7 to 13 and more preferably 8 to 12. Further, the shape of the convex part is preferably a rounded shape from the viewpoint of texture.
  • It is important that the flat cross-sectional shape in the single fiber cross section satisfies the flat ratio defined by formula (1) and the modified shape ratio defined by formula (2). Further, preferably, the convex part ratio defined by formula (3) is satisfied:

  • Flat ratio(A/B)=2.0 to 3.0   (1)

  • Modified shape ratio(C/D)=1.0 to 5.0   (2)

  • Convex part ratio(E/B)=0.6 to 0.9   (3).
  • The flat ratio (A/B) is 2.0 to 3.0. When the flat ratio (A/B) is less than 2.0, falling properties of fibers are deteriorated, thereby failing to obtain soft touch feeling. On the other hand, the flat ratio (A/B) exceeds 3.0, stiffness feeling is decreased, and permanent set in fatigue is liable to be caused. Further, fiber-forming properties are deteriorated, or the modified shape ratio is deteriorated. The flat ratio (A/B) is more preferably 2.0 to 2.7, and still more preferably 2.0 to 2.5.
  • Further, the modified shape ratio (C/D) represents the size of a concave part between the adjacent convex parts in the above-mentioned flat multifoliar shape. The larger value thereof indicates the smaller concave part, and the smaller value thereof indicates the larger concave part. When the modified shape ratio (C/D) is large, the concave part becomes shallow, and the spaces formed among the fibers are also decreased. Accordingly, water absorbability and diffusibility tend to be deteriorated. Furthermore, the irregular reflectance of light is also decreased, and anti-transparent properties tend to be deteriorated. Accordingly, the modified shape ratio (C/D) is 5.0 or less.
  • On the other hand, when the modified shape ratio (C/D) is excessively small, the concave part in the fiber cross section is easily bent, resulting in a failure to keep the flat shape. Further, the fibers are easily damaged by friction so that there is a possibility that the skin might be hurt when rubbed therewith. From these facts, the modified shape ratio (C/D) is 1.0 or more. The modified shape ratio (C/D) is 1.0 to 5.0 from the above viewpoint. Further, the modified shape ratio (C/D) is more preferably 1.0 to 4.0 in terms of water absorbability and diffusibility, and still more preferably 2.0 to 4.0 from the viewpoint of the balance between flat shape keeping properties, water absorbability and diffusibility.
  • Further, the convex part ratio (E/B) indicates the length ratio of the maximum width B and the longest length E except for the maximum width B of lines between vertexes of both convex parts using the maximum length A as an axis of symmetry in the above-mentioned flat multifoliar shape. This has a meaning as an index to measure the degree of distortion of an approximately elliptic shape obtained when lines connecting vertexes of the respective convex parts of the maximum width B, E and the maximum length A are drawn. When the convex part ratio is excessively small, the depth of the concave part is decreased, and the cross-sectional shape thereof becomes a shape closely approximate to a flat cross shape. For this reason, a capillary phenomenon effect is decreased, and water absorbability and diffusibility are deteriorated. Further, at the time of touching the skin, the number of touching convex parts decreases because of the shape approximate to the flat cross shape, and texture feeling and softness are deteriorated. Accordingly, the convex part ratio is preferably 0.6 or more. On the other hand, when the convex part ratio is excessively large, many concave parts are completely blocked when the concaves and convexes of the fibers are fitted to each other. The spaces are therefore decreased and water absorbability and diffusibility are deteriorated. Further, at the time of touching the skin, the number of touching convex parts decreases because of the shape approximate to the flat hexagonal shape, and texture feeling and softness are deteriorated. From these facts, the convex part ratio (E/B) is preferably 0.9 or less. The convex part ratio (E/B) is preferably 0.6 to 0.9 from the above-mentioned viewpoint. Further, from the viewpoint of a balance thereof, the convex part ratio (EB) is preferably 0.6 to 0.8, and more preferably 0.7 to 0.8.
  • The content of the polyester-based fibers having a flat multifoliar cross section in the spun yarn is 20 to 80% by mass. When the mixing rate (content) of the polyester-based fibers having a flat multifoliar cross section is less than 20% by mass, hydrophobicity of the spun yarn is decreased. Accordingly, water absorbed tends to become difficult to be evaporated, quick drying properties are poor, and texture feeling is also deteriorated. Further, when the mixing ratio (content) of the polyester-based fibers having a flat multifoliar cross section exceeds 80% by mass, the capillary phenomenon effect becomes weak and liquid diffusibility is deteriorated, thereby impairing dry feeling and refreshing cool feeling at the time of touching the skin. From the above, as a preferred balance, the content of the polyester-based fibers having a flat multifoliar cross section in the spun yarn is 30 to 70% by mass, and more preferably 40 to 60% by mass.
  • The single filament fineness of the polyester-based fibers having a flat multifoliar cross section is preferably 2.0 dtex or less. The single filament fineness is more preferably 1.0 to 2.0 dtex, and still more preferably 1.2 to 1.8 dtex. When the single filament fineness exceeds 2.0 dtex, rigidity peculiar to the polyester-based fiber is increased so that irritation of texture feeling becomes strong, and soft touch feeling is also impaired in some cases. Further, the spaces formed among the fibers are excessively increased so that the capillary phenomenon effect becomes weak and liquid diffusibility is deteriorated, thereby tending to impair dry feeling and refreshing cool feeling at the time of touching the skin. Furthermore, when the single filament fineness is less than 1.0 dtex, process passability in a carding process is deteriorated and productivity tends to be reduced.
  • The polyester-based fibers having a flat multifoliar cross section can be allowed to contain inorganic particles for the purpose of improving anti-transparent properties and softness.
  • The content of the inorganic particles is preferably 0.2 to 2.5% by mass, more preferably 0.2 to 2.2% by mass, and still more preferably 0.3 to 2.0% by mass. When the content of the inorganic particles is less than 0.2% by mass, friction with the cellulose-based fibers is increased, and the soft touch feeling tends to be impaired and, further, the irregular reflection of light becomes insufficient, and the anti-transparent performance tends to be deteriorated. On the other hand, when the content of the inorganic particles exceeds 2.5% by mass, process passability in spinning is deteriorated, and the guide wear tends to occur and, further, the modified shape ratio of the polyester-based fibers having a flat multifoliar cross section tends to be decreased during melt spinning thereof. Furthermore, a matte effect acts strongly so that whiteness is inferior, and color developability tends to be lost.
  • Further, the fiber length of the polyester-based fibers having a flat multifoliar cross section is preferably 30 to 64 mm, and more preferably 35 to 51 mm, from the viewpoint of process passability in spinning.
  • The spun yarn and a production method thereof will be described below.
  • The twist coefficient of the spun yarn is preferably 3.0 to 4.5. When the twist coefficient is less than 3.0, sufficient yarn strength tends to be not obtained, and yarn breakage during spinning or a reduction in strength when it is formed into the woven or knitted fabric tends to be brought about. Further, when the twist coefficient exceeds 4.5, a kink caused by untwisting tends to occur, and when it is formed into the woven or knitted fabric, it tends to have coarse feeling.
  • The spun yarn can be produced by an ordinary spinning method using the polyester-based fibers having a flat multifoliar cross section and the cellulose-based fibers, and can be produced using a ring spinning frame (including bundling and eddy-current types), an air spinning frame or the like.
  • Further, with regard to a blending method, it is possible to blend two kinds of the polyester-based fibers having a flat multifoliar cross section and the cellulose-based fibers, and also possible to blend with other fibers within the blending ratio range. For inner materials or shirt materials, the count of the spun yarn is preferably 30 to 53, and more preferably 40.
  • The woven or knitted fabric including the spun yarn may be a woven or knitted fabric using 100% of the spun yarn. However, preferably, at least 40% by mass of the spun yarn is contained. When the ratio of the spun yarn is less than 40% by mass, there is a tendency that the water absorbability effect due to the combination of the polyester-based fibers having a flat multifoliar cross section and the cellulose-based fibers is less likely to be obtained. Further, in the woven or knitted fabric, it is possible to use the spun yarn within a range of less than 60% by mass, and to mixedly weave or knit other spun yarn, filaments or the like, in addition to the spun yarn.
  • The spun yarn and the woven or knitted fabric using the same have water absorbability, quick drying properties and anti-transparent properties and soft touch feeling so that they can be suitably used as inner shirts, pants, sports shirts, white coats, sweaters, national costumes and the like.
  • EXAMPLES
  • The spun yarn will be described in detail below with reference to examples. However, this disclosure should not be construed as being limited to only the examples. Respective physical property values in the examples were measured by the following methods.
  • Water Absorbability Evaluation
  • Evaluation was performed in accordance with JIS L1907 (2010 edition, Byreck method). Evaluation contents were as follows. “⊙” and “◯” were judged as passed.
  • ⊙: 80 mm or more
  • ◯: 70 to 79 mm
  • Δ: 50 to 69 mm
  • ×: 49 mm or less
  • Quick Drying Property Evaluation
  • A test specimen allowed to stand for 24 hours under an atmosphere of a room temperature of 25° C. and a humidity of 40% RH is cut out into a 10-cm square, and the mass (A) thereof is measured. The test specimen is immersed in ion-exchanged water for 30 seconds, and thereafter taken out of the liquid by pinching one corner of the test specimen with tweezers. The test specimen taken out is allowed to stand for 1 hour similarly under an atmosphere of a room temperature of 25° C. and a humidity of 40% RH, followed by naturally drying, and the mass (B) thereof is measured. The residual water content (C) is calculated by the following formula:

  • C(%)=(B−A)/100
  • Evaluation contents were as follows. “⊙” and “◯” were judged as passed.
  • ⊙: 30% or less
  • ◯: 31 to 40%
  • Δ: 41 to 50%
  • ×: 51% or more
  • Anti-Transparent Property
  • Using a spectrophotometer (Minolta M-3600d), respective L values (reflectances) were measured using a standard white board and a standard black board as backgrounds of a sample cloth, and the anti-transparent degree (%) was determined by the following formula:

  • Anti-transparent degree(%)=100−(Lfw−Lfb)/(Lw−Lb)×100
  • Lw: L value of the standard white board in a state where there was no sample cloth
  • Lb: L value of the standard black board in a state where there was no sample cloth
  • Lfw: L value when the sample cloth was placed on the standard white board
  • Lfb: L value at the time when the sample cloth was placed on the standard black board
  • Evaluation contents were as follows. “⊙” and “◯” were judged as passed.
  • ⊙: 70% or more
  • ◯: 60 to 69%
  • Δ: 50 to 59%
  • ×: 49% or less
  • Soft Touch Feeling
  • A test specimen was cut out into a 10-cm square, and the test specimen cut out was grasped by five subjects, and point evaluation was performed according to the following criteria. Thereafter, the average points were calculated, and “⊙” and “◯” were judged as passed.
  • 3 points: Touch feeling was soft.
  • 2 points: Touch feeling was somewhat hard.
  • 1 point: Touch feeling was hard.
  • ⊙: 2.8 points or more
  • ◯: 2.4 to 2.7 points
  • Δ: 1.9 to 2.3 points
  • ×: 1.8 points or less
  • Example 1
  • 20% by mass of polyester-based fibers having a flat multifoliar cross section (fiber length: 51 mm) having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 80% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5. Using the spun yarn as warps and wefts, a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom. The fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.
  • Example 2
  • 50% by mass of polyester-based fibers having a flat multifoliar cross section (fiber length: 51 mm) having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 50% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5. Using the spun yarn as warps and wefts, a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom. The fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.
  • Example 3
  • 80% by mass of polyester-based fibers having a flat multifoliar cross section (fiber length: 51 mm) having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 20% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5. Using the spun yarn as warps and wefts, a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom. The fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.
  • Example 4
  • 80% by mass of polyester-based fibers having a flat multifoliar cross section (fiber length: 51 mm) having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.1% by mass, a flat ratio of 2.0, a modified shape ratio of 2.5 and a convex part ratio of 0.7 and having a cross-sectional shape with 8 convex parts and 20% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5. Using the spun yarn as warps and wefts, a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom. The fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.
  • Comparative Example 1
  • 85% by mass of polyester-based fibers having a flat multifoliar cross section (fiber length: 51 mm) having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 15% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5. Using the spun yarn as warps and wefts, a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom. The fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.
  • Comparative Example 2
  • 15% by mass of polyester-based fibers having a flat multifoliar cross section (fiber length: 51 mm) having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 2.1, a modified shape ratio of 2.7 and a convex part ratio of 0.8 and having a cross-sectional shape with 8 convex parts and 85% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5. Using the spun yarn as warps and wefts, a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom. The fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.
  • Comparative Example 3
  • 80% by mass of polyester-based fibers having a trifoliar (Y-shaped) cross section (fiber length: 51 mm) having a single filament fineness of 1.7 dtex, a titanium oxide content of 0.3% by mass, a flat ratio of 1.0, a modified shape ratio of 6.7 and a convex part ratio of 0.9 and having a cross-sectional shape with 3 convex parts and 20% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5. Using the spun yarn as warps and wefts, a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom. The fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.
  • Comparative Example 4
  • 80% by mass of polyester-based fibers (fiber length: 51 mm) having a rounded cross-sectional shape having a single filament fineness of 1.7 dtex and a titanium oxide content of 0.3% by mass and 20% by mass of rayon fibers (fiber length: 51 mm) having a single filament fineness of 1.7 dtex were blended to obtain a spun yarn having an English cotton count of 40 s, setting the twist coefficient K to 3.5. Using the spun yarn as warps and wefts, a plain woven fabric having a warp density of 110 ends/2.54 cm and a weft density of 76 picks/2.54 cm was obtained using an air jet loom. The fiber constitution of the spun yarn is shown in Table 1, and the evaluation results are shown in Table 2.
  • TABLE 1
    Comparative Comparative Comparative Comparative
    Fibers Used Example 1 Example 2 Example 3 Example 4 Example 1 Example 2 Example 3 Example 4
    Polyester having octafoliar flat 20 50 80 80 85 15
    cross section (mass %)
    Polyester having trifoliar (Y) 80
    cross section (mass %)
    Polyester having rounded cross 80
    section (mass %)
    Rayon (mass %) 80 50 20 20 15 85 20 20
    Titanium oxide content 0.3 0.3 0.3 0.1 0.3 0.3 0.3 0.3
    (mass %)
  • TABLE 2
    Comparative Comparative Comparative Comparative
    Example 1 Example 2 Example 3 Example 4 Example 1 Example 2 Example 3 Example 4
    Water Absorbability Δ X
    Quick Drying Property X Δ
    Anti-Transparent Property Δ Δ X
    Soft Touch Feeling Δ X X

Claims (21)

1.-6. (canceled)
7. A spun yarn comprising 20 to 80% by mass of a polyester-based fiber having a flat multifoliar cross section and 20 to 80% by mass of a cellulose-based fiber, wherein a cross-sectional shape of the polyester-based fiber having a flat multifoliar cross section is a flat shape having 6 or more convex parts on a circumference thereof, and when a maximum length of a cross section of the polyester-based fiber having a flat multifoliar cross section is taken as A, a maximum width of the cross section of the polyester-based fiber having a flat multifoliar cross section is taken as B, a length of a line connecting vertexes of convex parts adjacent to each other in a maximum concave-convex part is taken as C, and a length of a perpendicular line drawn from the line connecting the vertexes of the convex parts adjacent to each other in the maximum concave-convex part to a bottom point of a concave part is taken as D, a flat ratio defined by formula (1) and a modified shape ratio defined by formula (2) are satisfied:

Flat ratio(A/B)=2.0 to 3.0   (1)

Modified shape ratio(C/D)=1.0 to 5.0   (2).
8. The spun yarn according to claim 7, wherein the modified shape ratio is 2.0 to 5.0.
9. The spun yarn according to claim 7, wherein, when a longest length except for the maximum width B of the cross section among lines between vertexes of both convex parts opposed to each other using the maximum length A as an axis of symmetry is taken as E, a convex part ratio defined by formula (3) is satisfied:

Convex part ratio(E/B)=0.6 to 0.9   (3).
10. The spun yarn according to claim 7, wherein a single filament fineness of the polyester-based fiber having a flat multifoliar cross section is 2.0 dtex or less.
11. The spun yarn according to claim 7, wherein the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
12. A woven or knitted fabric comprising the spun yarn according to claim 7.
13. The spun yarn according to claim 8, wherein, when a longest length except for the maximum width B of the cross section among lines between vertexes of both convex parts opposed to each other using the maximum length A as an axis of symmetry is taken as E, a convex part ratio defined by formula (3) is satisfied:

Convex part ratio(E/B)=0.6 to 0.9   (3).
14. The spun yarn according to claim 8, wherein a single filament fineness of the polyester-based fiber having a flat multifoliar cross section is 2.0 dtex or less.
15. The spun yarn according to claim 9, wherein a single filament fineness of the polyester-based fiber having a flat multifoliar cross section is 2.0 dtex or less.
16. The spun yarn according to claim 13, wherein a single filament fineness of the polyester-based fiber having a flat multifoliar cross section is 2.0 dtex or less.
17. The spun yarn according to claim 8, wherein the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
18. The spun yarn according to claim 9, wherein the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
19. The spun yarn according to claim 10, wherein the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
20. The spun yarn according to claim 13, wherein the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
21. The spun yarn according to claim 14, wherein the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
22. The spun yarn according to claim 15, wherein the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
23. The spun yarn according to claim 16, wherein the polyester-based fiber having a flat multifoliar cross section contains an inorganic particle, and a content thereof is 0.2 to 2.5% by mass.
24. A woven or knitted fabric comprising the spun yarn according to claim 8.
25. A woven or knitted fabric comprising the spun yarn according to claim 9.
26. A woven or knitted fabric comprising the spun yarn according to claim 10.
US14/779,587 2013-03-27 2014-02-27 Spun yarn and woven or knitted fabric Abandoned US20160076173A1 (en)

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