US20090294080A1 - Glossy paper - Google Patents
Glossy paper Download PDFInfo
- Publication number
- US20090294080A1 US20090294080A1 US11/721,528 US72152805A US2009294080A1 US 20090294080 A1 US20090294080 A1 US 20090294080A1 US 72152805 A US72152805 A US 72152805A US 2009294080 A1 US2009294080 A1 US 2009294080A1
- Authority
- US
- United States
- Prior art keywords
- paper
- glossy
- scintillating
- microplatelets
- microbeads
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/24—Addition to the formed paper during paper manufacture
Definitions
- the invention relates to the field of glossy or scintillating papers that can be used for producing magazines, brochures, publicity documents, art papers or printing and writing papers.
- Glossy papers are generally obtained by means of an operation of calendering or supercalendering papers coated with an essentially inorganic coating, said calendering operation enabling the surface to be thoroughly smoothed.
- Gloss is obtained on the coated calendered paper by uniform reflection of light on the extremely smooth and uniform surface.
- the method does not make it possible in any way to obtain a textured or embossed paper since the method consists of leveling the surface completely.
- Such embossed papers correspond, non-exclusively, to papers of printing or writing categories, for texts and covers and art papers, for which a special paper texture is often sought.
- Paper texture should be understood to mean papers having watermarks, special lookthroughs, laid lines and various markings such as those produced with grained felts or marking presses etc.
- Another means to enable glossy papers to be produced and more particularly papers with embossing consists of coating with a gloss varnish during a converting operation, off the paper machine. Gloss is obtained by depositing large quantities of a glossy polymer.
- a method similar to that of varnishing can be carried out on a coating machine with a formula close to that of a varnish.
- Another technique consists of laminating the finished paper with a polymer film.
- the object of the invention is therefore to resolve these main difficulties, that is to say to produce a glossy or scintillating paper in an economical manner without a calendering or varnishing operation on all paper machines, with or without an integrated coating machine, and with all achievable bases, in particular colored or textured ones.
- the glossy or scintillating paper according to the invention has a roughness greater that 30 ml/min measured in accordance with ISO 8791-2 standard and is produced entirely on a paper machine and is characterized in that it includes reflecting microplatelets or microbeads with a size less than 300 ⁇ m incorporating at least one optically transparent material in their structure.
- the advantages of the paper according to the invention are economical, since it is possible to produce a glossy or scintillating paper without forming calendering, coating or conversion, and the same time technical, since glossy papers such as those proposed make it possible to obtain special optical effects and in particular remarkable gloss on textured or colored papers with integral retention of the mechanical properties of the paper, in particular as concerns rigidity and burst strength.
- optical yield of the paper according to the invention is variable according to the ambient illumination at the moment of observation.
- illumination is high, in the sense of light reaching the paper, treatment leads to a uniform gloss effect, whereas when illumination is low individual scintillating points are perceptible on the surface of said paper.
- the glossy or scintillated paper retains all its physical mechanical properties as well as its appearance and feel properties, which is a determining factor in the case of textured papers for which a relief effect is required and for which an agreeable feel is often required, and this is particularly the case for papers incorporating cotton linters in their fibrous composition.
- Coating compositions followed by calendering or varnishing bring about a loss of these appearance properties that are particularly appreciated for art papers and most papers used in printing and writing.
- coated papers should be understood to mean any papers having at their surface a coating containing at least one polymeric binder and possibly mineral or organic fillers, the operation being carried out on or off the paper machine by means of a coating device enabling the deposited layer to be kept on the surface of the paper, that is to say the layer does not penetrate more than 20% and generally less than 10% into the paper thickness.
- An uncoated paper should be understood to mean a base paper having no surface treatment or impregnation or coating by means of various devices, preferably rollers, which cause the treatment composition to penetrate into all the thickness of the sheet or at least 30% of said thickness.
- a varnished paper is a paper on which a glossy transparent layer is deposited, penetrating very little into the paper, that is to say less than 20% of its thickness, generally consisting substantially of a glossy polymer without additional fillers and with a dry matter deposit at least equal to 2 g/m 2 and preferably more than 5 g/m 2 .
- the varnishing operation is carried out off the paper machine on specific equipment, a varnishing machine, or by means of a coating apparatus.
- the gloss or scintillation of the paper within the meaning of the invention is defined by the visual effect produced on observing the paper at a variable angle between 20° and 80°.
- the optical effect produced is situated between a scintillating effect, such as that produced by snow in the sun, that is to say randomly distributed bright points reflecting light, and a gloss effect without individual scintillating points.
- optical effects obtained in the invention are not only variable according to the angle of observation of the treated paper but also according to the ambient illumination, and the visual effect changes according to whether the lighting is low, when under these conditions individual scintillating points are more particularly visible, or high, and under these conditions the gloss effect is uniform and very intense. These effects are very different from those obtained with calendered coated or varnished papers which never exhibit a scintillating appearance and of which the gloss is relatively independent of the illuminating conditions.
- the roughness of the paper is usually measured by means of various apparatuses such as “Bekk”, “Bendtsen” or “Sheffield” apparatuses, said roughness measurement being standardized, and reference is made here more particularly to ISO 8791-2 standard making it possible to express the roughness of the paper in ml/min with the “Bendtsen” apparatus.
- Papers according to the invention have a roughness of at least 30 ml/min and preferably more than 100 ml/min, which in the traditional classification of papers corresponds to untreated or slightly calendered papers but in no way to traditional glossy papers of which the roughness values measured by Bendtsen are situated at values less than 30 ml/min and more generally less than 10 ml/min.
- Textured papers for which the treatment has special interest have roughnesses greater than 300 ml/min and generally above 1000 ml/min when texturing is employed by means of marking felts or engraved presses.
- the treatment composition according to the invention is applicable on all types of papers, in particular textured or colored papers, by means of a device positioned inside the paper machine, preferably a size press, a device with multiple rollers known under the names “gate roll” or “Massey”, an impregnator, a device with rollers depositing pre-metered amounts for the coating formulation such as that called for example a “blade metering size press” (“BMSP”), or any other device comprising at least one roller in contact with the paper.
- BMSP blade metering size press
- Traditional coating devices positioned inside the paper machine can be used, such as for example trailing blade or bar coaters.
- the treatment composition according to the invention employs reflecting particles in the form of platelets or microbeads incorporating in their structure at least one optically transparent material, generally a component classified in the general family of glasses, for example a borosilicate.
- the size of the particles is less than 300 ⁇ m and preferably between 50 and 250 ⁇ m, so that the reflecting effect is optimal.
- the reflecting effect of platelets or beads is created by the association of an optically transparent material and a material reflecting light. Production of these particles in the form of platelets or beads is known and is carried out in particular by Merck who have developed technologies enabling particles to be obtained with different materials in successive layers.
- the roughness of the finished paper is greater than 100 ml/min in accordance with ISO 8791-2 standard and the reflecting microplatelets or microbeads are incorporated at a rate of at least 0.05%, preferably at least 0.15% by dry weight based on the finished paper.
- the treatment composition according to the invention comprises at least one category of particles in the form of microplatelets or microbeads incorporating at least one optically transparent material in their structure, and at least one binder enabling said particles to be fixed in the paper and on its surface.
- Reflecting microplatelets with a size between 20 and 200 ⁇ m, which are entirely suitable, are marketed by Merck under the name Miraval® and under the reference 5411 Magic White.
- the binder can conventionally be a starch, a polyvinyl alcohol, a latex or any other polymer that can be used in a known manner in papermaking.
- the quantity and nature of said binder is chosen according to the coating means employed and factors related to the subsequent use of the paper such as for example the printing means employed.
- At least one binder is used that brings about gloss and is optically transparent so as not to cause a deterioration in the effect obtained with the particles incorporated.
- binders that can reinforce the gloss of reflecting particles are for example, and in a non-limiting manner, polymers chosen from the family of polyvinyl alcohols, acrylic latices and polyvinylpyrrolidones.
- the glossy or scintillating paper that has reflecting microplatelets or microbeads at a rate of at least 0.05% and preferably at least 0.15% dry weight based on the paper also contains a polymeric binder at a rate of at least 0.1% and preferably more than 1% dry weight based on the paper weight.
- the level of binder inside the treatment composition should be sufficiently high, and it has been found particularly advantageous to add at least the same quantity of binder, by dry weight incorporated, as the reflecting particles, and preferably at least twice more.
- the invention also relates to the method for obtaining a glossy or scintillating paper with a roughness greater than 30 ml/min measured in accordance with ISO 8791-2 standard, produced on a paper machine in a single step, and characterized by the following successive steps:
- the method is characterized by the fact that the substrate paper can be colored, textured, watermarked, laid, marked with felts or engraved presses or any other device known to give embossing or non-uniformity to the paper by any method inside the paper machine, before the treatment formulation is applied to its surface.
- the method for obtaining a glossy or scintillating paper is also characterized in that the reflecting microplatelets or microbeads are incorporated in the paper at the same time as the polymeric binder in a treatment composition applied by means of a coating device comprising at least one roller, in the conventional manner of a size press.
- the method is particularly well suited to obtaining glossy or scintillating colored papers without a calendering or coating operation.
- a treatment composition containing reflecting microplatelets incorporating at least one optically transparent material in their structure was applied with a size press onto 150 g/m 2 paper textured by means of marker felts.
- the treatment composition consisted of a solution comprising by weight based on the total weight of the formulation: 2% of a high-viscosity polyvinyl alcohol, Mowiol® 28-99 marketed by Seppic and 0.5% Miraval® 5411 Magic White from Merck.
- the pick-up of the preceding solution at the size press was 35% by weight based on the paper, which represented a weight of microplatelets incorporated in the paper of 0.175% and a weight of polymeric binder of 0.7%. Said binder was in a quantity four times greater than the quantity of reflecting microplatelets in the composition.
- the gloss effect obtained varied according to the illuminating conditions. When the paper was observed in sunlight or close to a lamp, the gloss effect was uniform and very intense. When the paper was observed in a place with low illumination, essentially scintillating points were observed.
- the glossy white paper obtained in this way had a roughness measured in accordance with ISO 8791-2 standard, of 1500 ml/min.
- the mechanical properties of the paper were identical to those of a glossy untreated paper.
- a glossy laid paper was obtained by producing a colored 100 g/m 2 paper laid on the paper machine table and body-colored in a conventional way.
- the colored and textured sheet was coated on the size press with a composition comprising by weight, based on the total weight of the formulation: 1% of a high-viscosity polyvinyl alcohol, Mowiol® 28-99 marketed by Seppic, 5% by dry weight of a styrene butadiene latex DL 955 marketed by Dow Chemical and 2% of Miraval® 5411 Magic White from Merck.
- a composition comprising by weight, based on the total weight of the formulation: 1% of a high-viscosity polyvinyl alcohol, Mowiol® 28-99 marketed by Seppic, 5% by dry weight of a styrene butadiene latex DL 955 marketed by Dow Chemical and 2% of Miraval® 5411 Magic White from Merck.
- the treatment composition penetrated through the entire thickness of the paper and a pick-up of 40% was found.
- the polymeric binder represented by polyvinyl alcohol and latex was incorporated at a rate of three times the quantity of reflecting microplatelets and at a rate of 2.4% based on the paper weight.
- the finished paper still retained its original color and texture before treatment, roughness was measured at 1000 ml/min, and the gloss of the paper was very strong under high illumination producing a particular optical yield but with conventional properties of feel and relief produced by laid lines.
- the preceding solution was applied by means of a size press on the base paper at the rate of at least 30 liters of treatment composition for 100 kg of paper, which took account of the fact that this paper represented approximately 30% of the treated thickness and a quantity of hydrophilic binder of 1.8% based on the paper weight.
- the reflecting microplatelets were incorporated at a rate of 0.9% in dry product based on the finished paper.
- the paper coated in this way was dried on a drying unit and the finished product was reeled without calendering so as to preserve the texture formed by the engraved presses.
- the product possessed the texture of paper for watercolor with a high gloss and a high ability to be printed by inkjet.
- Such a paper could be used for the reproduction of works of art on inkjet printers with wide formats or as a base for the printing of photos in office printers.
- the equivalent does not exist on the market of such a paper that is at the same time textured, glossy and suitable for inkjet printing, even produced by a different technique.
- the fibers used to produce a paper can be cellulosic and/or cotton linters, all or in part, in association or not with synthetic fibers or other natural fibers. All additives traditionally used in papermaking such as additional fillers (talc, kaolin, calcium carbonate etc), binding agents, retention agents, coloring agents, optical brighteners, etc. can be employed without departing from the scope of the invention.
- the texture of the product can be strong or non-existent, the paper can be watermarked or not, it can be with a high or low grammage without departing from the scope of the invention which is to provide a glossy effect to uncalendered and unvarnished papers, while preserving their usual appearance properties, in particular roughness and feel.
- one of the advantages of the invention is that it is possible to produce a paper that is treated differently on its two sides, directly in the papermaking process, and finally to obtain in this way a paper having two different glosses on its two faces, which represents a considerable commercial advantage.
- a paper can be produced marked with a marker felt on one face and a smooth surface on the opposite face, or in a more sophisticated manner, two different textures on the two faces by combining various marker felts and/or associated engraved presses with an identical treatment on the two faces at the size press.
Landscapes
- Paper (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0413319A FR2879225B1 (fr) | 2004-12-15 | 2004-12-15 | Papier brillant |
FR0413319 | 2004-12-15 | ||
PCT/FR2005/003011 WO2006064101A1 (fr) | 2004-12-15 | 2005-12-01 | Papier brillant |
Publications (1)
Publication Number | Publication Date |
---|---|
US20090294080A1 true US20090294080A1 (en) | 2009-12-03 |
Family
ID=34952592
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/721,528 Abandoned US20090294080A1 (en) | 2004-12-15 | 2005-12-01 | Glossy paper |
Country Status (6)
Country | Link |
---|---|
US (1) | US20090294080A1 (fr) |
EP (1) | EP1825055B1 (fr) |
ES (1) | ES2440475T3 (fr) |
FR (1) | FR2879225B1 (fr) |
WO (1) | WO2006064101A1 (fr) |
ZA (1) | ZA200705697B (fr) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8668965B2 (en) | 2010-10-22 | 2014-03-11 | Hewlett-Packard Development Company, L.P. | Printed article with metallic appearance |
US8715812B2 (en) | 2011-09-30 | 2014-05-06 | Hewlett-Packard Development Company, L.P. | Metallic luster printed medium and method of preparing same |
JP2016014213A (ja) * | 2014-06-11 | 2016-01-28 | 特種東海製紙株式会社 | 印刷用紙 |
US9382436B2 (en) * | 2011-05-05 | 2016-07-05 | Teknologian Tutkimuskeskus Vtt | Method for surface modification of a body |
US20170134509A1 (en) * | 2014-08-08 | 2017-05-11 | Nikon Corporation | Information processing apparatus and information processing method |
Citations (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3485658A (en) * | 1965-07-22 | 1969-12-23 | Du Pont | Plural monolayer coated article and process of making |
US3583876A (en) * | 1965-04-02 | 1971-06-08 | Mo Och Domsjoe Ab | Coating composition |
US3873390A (en) * | 1972-09-27 | 1975-03-25 | Richard K Cornell | Phosphorescent, fluorescent and reflective coated sheets or films and compositions and method for making the same |
US4317849A (en) * | 1979-11-06 | 1982-03-02 | Mitsubishi Paper Mills, Ltd. | Process for producing high-gloss coated paper |
US5118533A (en) * | 1988-09-14 | 1992-06-02 | Kanazaki Paper Mfg. Co., Ltd. | Method of manufacturing coated paper |
US5125996A (en) * | 1990-08-27 | 1992-06-30 | Eastman Kodak Company | Three dimensional imaging paper |
US5372878A (en) * | 1992-06-23 | 1994-12-13 | Yamasa Momi Kikaku Co., Ltd. | Slackened or creased fibrous sheet |
US6197155B1 (en) * | 1997-10-11 | 2001-03-06 | Haindl Papier Gmbh | Coated web printing paper with cold-set suitability |
US20020027587A1 (en) * | 2000-09-01 | 2002-03-07 | Toyoaki Sugaya | Inkjet recording apparatus and inkjet recording method |
US20030035917A1 (en) * | 1999-06-11 | 2003-02-20 | Sydney Hyman | Image making medium |
US6565770B1 (en) * | 2000-11-17 | 2003-05-20 | Flex Products, Inc. | Color-shifting pigments and foils with luminescent coatings |
US20040149406A1 (en) * | 2001-06-25 | 2004-08-05 | Kirsi Nissinen | Method of producing a coated fibrous web |
US20040173329A1 (en) * | 2001-04-24 | 2004-09-09 | Petri Silenius | Coated fibrous web and process for the production thereof |
US20050208303A1 (en) * | 2002-03-14 | 2005-09-22 | Nittetsu Mining Co., Ltd. | Coated powder, coating composition, and coated article |
US20050260428A1 (en) * | 2004-05-24 | 2005-11-24 | Song Jay C | Gloss coated multifunctional printing paper |
US6977025B2 (en) * | 1996-08-01 | 2005-12-20 | Loctite (R&D) Limited | Method of forming a monolayer of particles having at least two different sizes, and products formed thereby |
US20060102304A1 (en) * | 2002-05-03 | 2006-05-18 | Christopher Nutbeem | Paper coating pigments |
US20060251819A1 (en) * | 2002-12-25 | 2006-11-09 | Yoshiaki Zama Et Al | Copolymer latex for non-contact coating, composition containing the same, coated paper and process for producing the same |
US20080060774A1 (en) * | 2006-09-12 | 2008-03-13 | Zuraw Paul J | Paperboard containing microplatelet cellulose particles |
US20090155498A1 (en) * | 2007-12-17 | 2009-06-18 | The Pilot Ink Co., Ltd. | Color-change laminate |
US20100047300A1 (en) * | 2007-04-05 | 2010-02-25 | Kaupp Guenter | Pearlescent pigments containing cosmetic compositions |
US20100116169A1 (en) * | 2007-04-05 | 2010-05-13 | Kaupp Guenter | Effect pigments comprising a glass flake substrate |
US20110088595A1 (en) * | 2008-04-23 | 2011-04-21 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Pigment preparations |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR694861A (fr) * | 1930-05-02 | 1930-12-09 | Procédé de fabrication de feuilles à effets nacrés | |
GB752374A (en) * | 1954-03-26 | 1956-07-11 | Walter Roberts | Improvements in or relating to transfers |
FR1474425A (fr) * | 1965-04-02 | 1967-03-24 | Mo Och Domsjoe Ab | Composition d'enduisage |
FR2192153A1 (en) * | 1972-07-11 | 1974-02-08 | Rhone Poulenc Sa | Coating compsn for paper and card - giving good brightness, and suitable for printing |
FR2791368B1 (fr) * | 1999-03-26 | 2001-06-01 | Arjo Wiggins Sa | Feuille avec un toucher "peau" imprimable a des cadences elevees et son procede de fabrication et emballage la comportant |
-
2004
- 2004-12-15 FR FR0413319A patent/FR2879225B1/fr not_active Expired - Fee Related
-
2005
- 2005-12-01 ZA ZA200705697A patent/ZA200705697B/xx unknown
- 2005-12-01 WO PCT/FR2005/003011 patent/WO2006064101A1/fr active Application Filing
- 2005-12-01 EP EP05824442.7A patent/EP1825055B1/fr not_active Not-in-force
- 2005-12-01 US US11/721,528 patent/US20090294080A1/en not_active Abandoned
- 2005-12-01 ES ES05824442.7T patent/ES2440475T3/es active Active
Patent Citations (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3583876A (en) * | 1965-04-02 | 1971-06-08 | Mo Och Domsjoe Ab | Coating composition |
US3485658A (en) * | 1965-07-22 | 1969-12-23 | Du Pont | Plural monolayer coated article and process of making |
US3873390A (en) * | 1972-09-27 | 1975-03-25 | Richard K Cornell | Phosphorescent, fluorescent and reflective coated sheets or films and compositions and method for making the same |
US4317849A (en) * | 1979-11-06 | 1982-03-02 | Mitsubishi Paper Mills, Ltd. | Process for producing high-gloss coated paper |
US5118533A (en) * | 1988-09-14 | 1992-06-02 | Kanazaki Paper Mfg. Co., Ltd. | Method of manufacturing coated paper |
US5125996A (en) * | 1990-08-27 | 1992-06-30 | Eastman Kodak Company | Three dimensional imaging paper |
US5372878A (en) * | 1992-06-23 | 1994-12-13 | Yamasa Momi Kikaku Co., Ltd. | Slackened or creased fibrous sheet |
US6977025B2 (en) * | 1996-08-01 | 2005-12-20 | Loctite (R&D) Limited | Method of forming a monolayer of particles having at least two different sizes, and products formed thereby |
US6197155B1 (en) * | 1997-10-11 | 2001-03-06 | Haindl Papier Gmbh | Coated web printing paper with cold-set suitability |
US20030035917A1 (en) * | 1999-06-11 | 2003-02-20 | Sydney Hyman | Image making medium |
US20020027587A1 (en) * | 2000-09-01 | 2002-03-07 | Toyoaki Sugaya | Inkjet recording apparatus and inkjet recording method |
US6565770B1 (en) * | 2000-11-17 | 2003-05-20 | Flex Products, Inc. | Color-shifting pigments and foils with luminescent coatings |
US20040173329A1 (en) * | 2001-04-24 | 2004-09-09 | Petri Silenius | Coated fibrous web and process for the production thereof |
US20040149406A1 (en) * | 2001-06-25 | 2004-08-05 | Kirsi Nissinen | Method of producing a coated fibrous web |
US20050208303A1 (en) * | 2002-03-14 | 2005-09-22 | Nittetsu Mining Co., Ltd. | Coated powder, coating composition, and coated article |
US20060102304A1 (en) * | 2002-05-03 | 2006-05-18 | Christopher Nutbeem | Paper coating pigments |
US20060251819A1 (en) * | 2002-12-25 | 2006-11-09 | Yoshiaki Zama Et Al | Copolymer latex for non-contact coating, composition containing the same, coated paper and process for producing the same |
US20050260428A1 (en) * | 2004-05-24 | 2005-11-24 | Song Jay C | Gloss coated multifunctional printing paper |
US20080060774A1 (en) * | 2006-09-12 | 2008-03-13 | Zuraw Paul J | Paperboard containing microplatelet cellulose particles |
US20100047300A1 (en) * | 2007-04-05 | 2010-02-25 | Kaupp Guenter | Pearlescent pigments containing cosmetic compositions |
US20100116169A1 (en) * | 2007-04-05 | 2010-05-13 | Kaupp Guenter | Effect pigments comprising a glass flake substrate |
US20090155498A1 (en) * | 2007-12-17 | 2009-06-18 | The Pilot Ink Co., Ltd. | Color-change laminate |
US20110088595A1 (en) * | 2008-04-23 | 2011-04-21 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Pigment preparations |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8668965B2 (en) | 2010-10-22 | 2014-03-11 | Hewlett-Packard Development Company, L.P. | Printed article with metallic appearance |
US9382436B2 (en) * | 2011-05-05 | 2016-07-05 | Teknologian Tutkimuskeskus Vtt | Method for surface modification of a body |
US8715812B2 (en) | 2011-09-30 | 2014-05-06 | Hewlett-Packard Development Company, L.P. | Metallic luster printed medium and method of preparing same |
JP2016014213A (ja) * | 2014-06-11 | 2016-01-28 | 特種東海製紙株式会社 | 印刷用紙 |
US20170134509A1 (en) * | 2014-08-08 | 2017-05-11 | Nikon Corporation | Information processing apparatus and information processing method |
Also Published As
Publication number | Publication date |
---|---|
EP1825055B1 (fr) | 2013-10-23 |
ES2440475T3 (es) | 2014-01-29 |
FR2879225B1 (fr) | 2007-02-16 |
FR2879225A1 (fr) | 2006-06-16 |
WO2006064101A1 (fr) | 2006-06-22 |
EP1825055A1 (fr) | 2007-08-29 |
ZA200705697B (en) | 2009-01-28 |
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