US20080138603A1 - Method of Applying an Anti-Freeze Film to a Transparent Substrate - Google Patents

Method of Applying an Anti-Freeze Film to a Transparent Substrate Download PDF

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Publication number
US20080138603A1
US20080138603A1 US11/815,049 US81504906A US2008138603A1 US 20080138603 A1 US20080138603 A1 US 20080138603A1 US 81504906 A US81504906 A US 81504906A US 2008138603 A1 US2008138603 A1 US 2008138603A1
Authority
US
United States
Prior art keywords
substrate
film
temperature
flexible film
frost
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/815,049
Other languages
English (en)
Inventor
Helene Grussaute-Nghiem
Marie-Isabelle Watchi
Yves Demars
Gilles Lonchampt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Original Assignee
Saint Gobain Glass France SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS filed Critical Saint Gobain Glass France SAS
Assigned to SAINT-GOBAIN GLASS FRANCE reassignment SAINT-GOBAIN GLASS FRANCE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DEMARS, YVES, GRUSSAUTE-NGHIEM, HELENE, LONCHAMPT, GILLES, WATCHI, MARIE-ISABELLE
Publication of US20080138603A1 publication Critical patent/US20080138603A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/0047—Preventing air-inclusions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10321—Laminated safety glass or glazing containing liquid layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0038—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving application of liquid to the layers prior to lamination, e.g. wet laminating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/48—Preparation of the surfaces
    • B29C2063/483—Preparation of the surfaces by applying a liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
    • B29C63/02—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/406—Bright, glossy, shiny surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2405/00—Adhesive articles, e.g. adhesive tapes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0007—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality
    • B32B37/003—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving treatment or provisions in order to avoid deformation or air inclusion, e.g. to improve surface quality to avoid air inclusion
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/30—Aspects of methods for coating glass not covered above
    • C03C2218/355—Temporary coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249994—Composite having a component wherein a constituent is liquid or is contained within preformed walls [e.g., impregnant-filled, previously void containing component, etc.]
    • Y10T428/249995—Constituent is in liquid form

Definitions

  • the present invention relates to substrates that are occasionally or permanently at temperatures below 0° C., especially transparent substrates.
  • anti-frost allowing the transparency to be protected, hydrophobic, hydrophilic, anti-soiling/self-cleaning (photocatalytic), reflecting light or thermal radiation, at least partly coloured, electrically conducting/heating, semiconductive, antistatic, electroluminescent, etc.
  • the process for forming the coating is adapted in order to guarantee the desired adhesion and mechanical strength and, in particular, a scratchability that is as low as possible or a self-healing ability of the scratches in the coating, when the substrate is transparent.
  • the coating is regenerated when necessary.
  • one or more functions may be provided by an adhesive film, having the advantage of being easy to replace with an identical film or a film having different functions.
  • one process may consist in interposing a sufficient amount of a liquid, especially water as a mixture with a surfactant, in order to make it possible to expel all the bubbles by applying a pressure to the film, for example from its central portion to its periphery, using a scraper.
  • the object of the invention is therefore to make available a process for assembling a flexible film to a substrate guaranteeing a perfect interside between the two and, especially, the absence of trapped air bubbles and frost formation.
  • one subject of the invention is a process for adhering a flexible film to a substrate, comprising the interposition between film and substrate of a sufficient amount of a liquid, so that no bubbles are trapped between film and substrate after the film has been applied to the substrate using a scraper, characterized in that the liquid does not freeze at a substrate temperature that is occasionally or permanently below 0° C., especially of at most ⁇ 5° C. and in particular of at most ⁇ 10° C., and also of at least ⁇ 25° C.
  • the substrate is cleared of any particles that are bonded thereto, cleaned and dried, prior to the interposition of a sufficient amount of a liquid between film and substrate.
  • the side of the flexible film to be adhered to the substrate is wetted with said sufficient amount of a liquid.
  • All suitable techniques for depositing liquid such as flow coating, spray coating or equivalent, may be used. It is not on the other hand excluded to wet the side of the substrate onto which the film is to be adhered with said sufficient amount of a liquid, nor to wet both said sides of the film and said side of the substrate.
  • the side of the flexible film to be adhered to the substrate comprises an adhesive layer optionally equipped with a protective film to be removed before adhesion to the substrate.
  • an adhesive may be incorporated into the liquid interposed between film and substrate.
  • the adhesives may be chosen from:
  • Ethanol and isopropanol are especially used as alcohols.
  • the hydrophilic polymers, copolymers, prepolymers or oligomers that make up the interposed liquid are especially based on polyvinylpyrrolidone of the poly(n-vinyl-2-pyrrolidone) or poly(1-vinylpyrrolidone) type, polyvinylpyridine of the poly(n-vinyl-2-pyridine) type, of the poly(n-vinyl-3-pyridine) type or of the poly(n-vinyl-4-pyridine) type, polyacrylate of the poly(2-hydroxyethyl acrylate) type, polyacrylamide of the poly(N′,N-hydroxyacrylamide) type, polyvinyl acetate, polyacrylonitrile, polyvinyl alcohol, polyacrolein, polyethylene glycol, polypropylene glycol and polyoxyethylene.
  • the copolymers are based on at least one of the monomers forming these polymers.
  • a lipophilic part Y which may be a linear, branched or unsaturated aliphatic chain or an aromatic or alkyl aromatic chain, and an ionic or nonionic hydrophilic head.
  • Another subject of the invention is formed by a mutually adhered substrate and flexible film obtained with interposition of a sufficient amount of a liquid in the absence of any trapped bubbles, characterized by the persistent absence of frost in the event of moving the substrate and film into an atmosphere where their temperature will be below 0° C., respectively of at most ⁇ 5° C. and ⁇ 10° C., from an atmosphere having a temperature at least equal to 0, preferably between 10 and 35, especially 15 and 30 and in particular 23 and 27° C. and residual humidity of at least 25%.
  • the substrate and flexible film form a transparent assembly.
  • the substrate is made of glass or a plastic such as polycarbonate, polypropylene, polymethyl methacrylate, ethylene/vinyl acetate copolymer, polyethylene terephthalate, polybutylene terephthalate, polyurethane, polyvinyl butyral, cycloolefinic copolymer such as ethylene/norbornene or ethylene/cyclopentadiene, polycarbonate/polyester copolymer, ionomer resin such as ethylene/(meth)acrylic acid copolymer neutralized by a polyamine, and similar, alone or as blends.
  • a plastic such as polycarbonate, polypropylene, polymethyl methacrylate, ethylene/vinyl acetate copolymer, polyethylene terephthalate, polybutylene terephthalate, polyurethane, polyvinyl butyral, cycloolefinic copolymer such as ethylene/n
  • the term “physical interaction” is understood here to mean a hydrogen bond, a polar interaction of the Van der Waals type or a hydrophobic interaction able to produce a mechanical reinforcement comparable to crosslinking.
  • the anti-frost function may be incorporated into the film itself or into a coating formed on the support for the film.
  • Another subject of the invention is glazing comprising a substrate and flexible film as described previously, and also optionally other transparent sheets to which they are connected via intermediate adhesive layer(s) or gas-filled cavity or cavities.
  • Said flexible film advantageously forms an outer side of this thus functionalized glazing.
  • the glazing especially consists of monolithic, laminated, multiple, insulating, vaccuum glazing.
  • Such a multiple insulating glazing has for example two or three sheets of monolithic or laminated glass separated in pairs by a gasfilled cavity.
  • the advantage therein may be the thermal insulation of a refrigerated cabinet with respect to the outside atmosphere (of a shop, etc.).
  • a vacuum glazing comprising at least two sheets of monolithic or laminated glass separated by a vacuum or a gas-filled cavity at reduced pressure. These two sheets may be combined with a third from which they are separated by a gas-filled cavity that may or may not be at reduced pressure.
  • Such structures may comprise one or more low-emissivity layers that reflect the heat radiated by the outside of the refrigerated cabinet.
  • the thermal conductivity of its barrier that is to say all the elements by which the various constituent sheets of monolithic or laminated glass are kept together and spaced in pairs, is at most 1.46 W/m.K.
  • the invention is indeed particularly benefited from for products subjected, at least occasionally, to temperatures below 0° C., and has an increased advantage for outside applications in harsh climatic conditions.
  • the polycarbonate film was coated, on the side opposite that of the adhesive layer, with an adsorbent anti-frost layer forming a three-dimensional polymer network based on polyvinylpyrrolidone and on polyurethane.
  • the thickness of the anti-frost layer was equal to 14.5 ⁇ m.
  • Tests were carried out on doors installed on refrigerated sales cabinets within which a temperature of ⁇ 25.5° C. was maintained. The temperature measured on the inner side of the door was ⁇ 22° C. The cabinets were placed in an atmosphere at a temperature of 25° C. and 60% residual humidity.
  • the door of the cabinet was opened 10 min before fitting the film in order to avoid the formation of frost on the glass.
  • the inner side of the door was wetted using a sprayer filled with a washing composition (soapy water).
  • the glass was scraped with a scraper in order to remove all the particles that were stuck to it, then with a rubber squeegee to wipe off the water. There should no longer have been any frost on the door. If necessary, the edges could be wiped with a rag.
  • the protective film was removed from the adhesive of the polycarbonate film and the liquid indicated in the table below was sprayed onto the adhesive.
  • the adhesive side of the film was applied to the glass.
  • the other side of the film was wetted by spraying with the same liquid as on the adhesive, so that the rubber squeegee slid easily over the film.
  • the film was cut so as to leave a gap of a few mm between the door posts and the film in order to promote the expulsion of the liquid.
  • Triton X 100% isopropanol No No No No 12% PEG 200 in water Yes Yes Yes No 50% PEG 200 in water No No No PEG 200 No No No No The percentages are indicated by weight.
  • Mir is a detergent composition sold by Henkel.
  • Triton X is a mixture of polyethoxylated octylphenols (nonionic surfactant) sold by Union Carbide.
  • PEG 200 is a polyethylene glycol sold by Merck (Art. 807483).
  • This table illustrates the possibility of reducing the formation of frost until it is prevented from forming, and thus obtaining a permanent absence of frost.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Combustion & Propulsion (AREA)
  • Laminated Bodies (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Adhesives Or Adhesive Processes (AREA)
US11/815,049 2005-01-31 2006-01-30 Method of Applying an Anti-Freeze Film to a Transparent Substrate Abandoned US20080138603A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0550271A FR2881422B1 (fr) 2005-01-31 2005-01-31 Pose de film antigivre sur substrat transparent
FR0550271 2005-01-31
PCT/FR2006/050073 WO2006079763A2 (fr) 2005-01-31 2006-01-30 Pose de film antigivre sur substrat transparent

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2006/050073 A-371-Of-International WO2006079763A2 (fr) 2005-01-31 2006-01-30 Pose de film antigivre sur substrat transparent

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/690,967 Division US8057615B2 (en) 2005-01-31 2010-01-21 Method of applying an anti-freeze film to a transparent substrate

Publications (1)

Publication Number Publication Date
US20080138603A1 true US20080138603A1 (en) 2008-06-12

Family

ID=35840147

Family Applications (2)

Application Number Title Priority Date Filing Date
US11/815,049 Abandoned US20080138603A1 (en) 2005-01-31 2006-01-30 Method of Applying an Anti-Freeze Film to a Transparent Substrate
US12/690,967 Expired - Fee Related US8057615B2 (en) 2005-01-31 2010-01-21 Method of applying an anti-freeze film to a transparent substrate

Family Applications After (1)

Application Number Title Priority Date Filing Date
US12/690,967 Expired - Fee Related US8057615B2 (en) 2005-01-31 2010-01-21 Method of applying an anti-freeze film to a transparent substrate

Country Status (10)

Country Link
US (2) US20080138603A1 (fr)
EP (1) EP1843895A2 (fr)
JP (1) JP5160900B2 (fr)
KR (3) KR101364233B1 (fr)
CN (1) CN101111369A (fr)
BR (1) BRPI0607050A2 (fr)
CA (1) CA2595977C (fr)
FR (1) FR2881422B1 (fr)
MX (1) MX2007008994A (fr)
WO (1) WO2006079763A2 (fr)

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NL1036681C2 (nl) * 2009-03-09 2010-09-13 Zeffex Ventures B V Zelfklevende, optisch transparante anti-condens film.
WO2015102623A1 (fr) * 2013-12-31 2015-07-09 Entrotech, Inc. Procédé pour l'application de film polymère et ensembles associés
US10315399B2 (en) 2013-12-31 2019-06-11 Entrotech, Inc. Methods for application of polymeric film and related assemblies

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FR2910117A1 (fr) * 2006-12-18 2008-06-20 Saint Gobain Procede de detection de dysfonctionnement d'une porte d'enceinte refrigeree
GB2500368A (en) 2012-02-22 2013-09-25 C G I Internat Ltd Fire resistant glazing unit with hydrogel interlayer
EP2953792B1 (fr) * 2013-02-05 2019-03-20 3M Innovative Properties Company Article graphique
FR3027596A1 (fr) * 2014-10-24 2016-04-29 Saint Gobain Substrat transparent monolithique anti-condensation
WO2017042697A1 (fr) 2015-09-07 2017-03-16 Sabic Global Technologies B.V. Éléments aérodynamiques de vitrages plastiques de hayons arrière
EP3347184B1 (fr) 2015-09-07 2022-08-03 SABIC Global Technologies B.V. Moulage d'un vitrage en matière plastique de hayons
CN108025625B (zh) 2015-09-07 2021-06-29 沙特基础工业全球技术公司 背门的塑料玻璃表面
US10690314B2 (en) 2015-09-07 2020-06-23 Sabic Global Technologies B.V. Lighting systems of tailgates with plastic glazing
JP6732912B2 (ja) 2015-11-23 2020-07-29 サビック グローバル テクノロジーズ ビー．ブイ． プラスチックグレージングを有するウィンドウ用の点灯システム
US11116333B2 (en) 2019-05-07 2021-09-14 Carrier Corporation Refrigerated display cabinet including microchannel heat exchangers
US11559147B2 (en) 2019-05-07 2023-01-24 Carrier Corporation Refrigerated display cabinet utilizing a radial cross flow fan
US11675111B2 (en) 2020-07-17 2023-06-13 Ford Global Technologies, Llc Vehicle sensor assembly
CN112430900A (zh) * 2020-11-26 2021-03-02 吉林大学 一种防霜透光的静电纺丝薄膜及其制备方法和应用

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US6627319B2 (en) * 1998-12-21 2003-09-30 Saint-Gobain Glass France Glazing with a functional, especially hydrophobic, mesoporous coating
US7003920B1 (en) * 1999-05-25 2006-02-28 Saint-Gobain Glass France Transparent glazing and use thereof in a chilling chamber door comprising in particular a glazing under vacuum

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KR101364041B1 (ko) 2014-02-26
CA2595977A1 (fr) 2006-08-03
FR2881422B1 (fr) 2007-03-16
KR101364233B1 (ko) 2014-02-14
US20100116416A1 (en) 2010-05-13
KR101362793B1 (ko) 2014-02-21
US8057615B2 (en) 2011-11-15
MX2007008994A (es) 2007-09-18
EP1843895A2 (fr) 2007-10-17
BRPI0607050A2 (pt) 2009-12-01
JP5160900B2 (ja) 2013-03-13
WO2006079763A2 (fr) 2006-08-03
WO2006079763A3 (fr) 2006-10-19
JP2008528329A (ja) 2008-07-31
KR20120140259A (ko) 2012-12-28
CN101111369A (zh) 2008-01-23
KR20120128170A (ko) 2012-11-26

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