US20040171478A1 - Process for recovering homogenous metal hydrate catalysts - Google Patents

Process for recovering homogenous metal hydrate catalysts Download PDF

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US20040171478A1
US20040171478A1 US10/479,070 US47907004A US2004171478A1 US 20040171478 A1 US20040171478 A1 US 20040171478A1 US 47907004 A US47907004 A US 47907004A US 2004171478 A1 US2004171478 A1 US 2004171478A1
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reactor
catalyst
absorbent
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Simon Crabtree
Robert Wild
Simon Jackson
James Banister
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Johnson Matthey Davy Technologies Ltd
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Assigned to DAVY PROCESS TECHNOLOGY LIMITED reassignment DAVY PROCESS TECHNOLOGY LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CRABTREE, SIMON PETER, JACKSON, SIMON WAYNE, WILD, ROBERT, BANISTER, JAMES ANDREW
Publication of US20040171478A1 publication Critical patent/US20040171478A1/en
Priority to US13/295,855 priority Critical patent/US9035080B2/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/121—Metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4069—Regeneration or reactivation of catalysts containing metals involving extraction with coordinating ionic liquids or supercritical fluids, e.g. CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4092—Regeneration or reactivation of catalysts containing metals involving a stripping step, with stripping gas or solvent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/74—Regeneration or reactivation of catalysts, in general utilising ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Definitions

  • the present invention relates to a process for recovering transition metal catalysts. More particularly it relates to a process for recovering Group VIII noble metal catalysts in active form. Most particularly it relates to a process for recovering rhodium catalysts in active form.
  • Group VIII noble metal complexes are commonly used as homogeneous catalysts in a variety of organic reactions.
  • the rhodium complexes are particularly useful in hydroformylation reactions in which an olefin is reacted with hydrogen and carbon monoxide in the presence of the catalyst to yield an aldehyde.
  • Complexes of rhodium with organophosphorous ligands such as triphenylphosphine and triphenylphosphite are particularly attractive catalysts as they favour the formation of the desired aldehyde products.
  • the selectivity for the desired aldehyde may be in the region of 90% or more when the appropriate phosphorous ligand is present.
  • the deactivated catalyst may have been thermally deactivated i.e. clustered and/or chemically deactivated i.e. poisoned or inhibited.
  • the catalyst solution includes such a high concentration of non-volatile material that it is of no further practical use.
  • metal e.g. rhodium clusters, having phosphido bridges may be formed, for example, by the loss of one or more phenyl groups from the aryl phosphine molecule.
  • the chemical deactivation may be poisoning such as sulphur compounds, chloride, cyanide and the like.
  • the chemical deactivation may also be inhibition of the catalyst.
  • Inhibitors that may be found in, for example, propylene and butylene hydroformylation include acetylenes and acroleins.
  • reactor stream we mean any stream which is obtained from any point in a process and which will contain Group VIII noble metal catalyst.
  • the Group VIII noble metals have conventionally been removed from the organic solutions by a variety of means before being shipped off-site for regeneration. This means that if the operation of the plant is not to be shut down for a prolonged period, the operator must purchase more of the very expensive catalyst to operate the plant than he actually requires at any one time.
  • a variety of means of recovering the Group VIII noble metals from solution has been suggested including precipitation followed by extraction or filtration and extraction from the organic mixtures using, for example, amine solutions, acetic acid, or organophosphines.
  • the organic solution of a deactivated solubilized catalyst may be treated to improve the extractability of the metal. Examples of this may be found in U.S. Pat. No. 4,929,767 and U.S. Pat. No. 5,237,106 which are incorporated herein by reference.
  • Ion-exchange methods have also been suggested, for example in U.S. Pat. No. 3,755,393 which describes passing a hydroformylation mixture through a basic ion-exchange resin to recover rhodium.
  • a similar process is described in U.S. Pat. No. 4,388,279 in which Group VIII metals are recovered from organic solution using either a solid absorbent such as calcium sulfate, an anionic ion-exchange resin or molecular sieves.
  • the impurities which may include aryl phosphine oxide, alkyl phosphine oxide, mixed phosphine oxide and high molecular weight organic compounds, are removed from the resin by washing with, for example, an organic solvent.
  • the effluent from this wash is removed as a waste stream.
  • the active catalyst remains bound to the resin during this washing process.
  • the resin is then treated with a catalyst removal solvent such as isopropanol/HCl to produce a stream containing “active” rhodium catalyst for eventual recycling to the hydroformylation reactor.
  • a catalyst removal solvent such as isopropanol/HCl
  • the catalyst has not been deactivated by thermal or chemical means and is therefore referred to as “active” it is not in a form in which it will actually act as a catalyst in the reactor.
  • the catalyst before the catalyst can be recycled it must first be removed from the resin using a strong acid reagent and then converted to the hydridocarbonyl by treatment with hydrogen and carbon monoxide in the presence of an acid scavenger and a ligand to make it a truly active catalyst.
  • the inactive rhodium catalyst i.e. the clustered catalyst, which passed through the ion-exchange resin without being absorbed and which is contained in the purified recycle stream may be reactivated by conventional technology such as by wiped film evaporation followed by oxidation and subsequent reduction before being returned to the reactor.
  • this inactive catalyst is not treated by the ion-exchange resin.
  • U.S. Pat. No. 5,773,665 does suggest that the thermally deactivated catalyst may be regenerated before return to the reactor, the overall plant is expensive to construct and operate because of the number of separation and treatment steps, some of which occur in the presence of corrosive acid media, required to achieve full recycle.
  • a further drawback associated with the presence of acid media is the further complexity and costs associated with the consumption of base required to neutralise the acid and dispose of the acid salts.
  • a process has now been developed which enables the catalytic metal, whether catalytically inactive or active, to be separated from the stream from the reactor by a suitable absorbent, such as an ion-exchange resin, and then removed from the absorbent in a form which is suitable for return to the reactor. Whilst the process is particularly effective at allowing rhodium catalysts from a hydroformylation reactor to be recovered and regenerated for return to the reactor it is also suitable for regenerating other Group VIII catalysts for use in other reactors.
  • a suitable absorbent such as an ion-exchange resin
  • the metal hydride catalyst removed from the acidic absorbent is recovered in an active state and can be recycled to the reactor.
  • the fluid stripping medium may comprise hydrogen and a process compatible solvent in a single fluid phase, which may be a supercritical phase.
  • the fluid stripping medium comprises hydrogen and a process compatible solvent in a two phase system.
  • the process compatible solvent may be a solvent or reactant of the reaction.
  • the ratio of the gas phase to the liquid phase may be any suitable value.
  • One suitable example would be one volume of gas to ten volumes of liquid.
  • the ratio of dissolved hydrogen to solvent present may be any suitable value and may be similar to that used for the two phase system.
  • An important parameter is that an appropriate amount of hydrogen is present.
  • the solvent is a liquid which is contacted with a gas phase including hydrogen until it is partially or totally saturated with dissolved gases.
  • the liquid may then be separated from the gas phase prior to being passed over the metal containing absorbent as a single phase.
  • the saturated solution may be increased in pressure before being passed over the absorbent as the stripping medium.
  • Supercritical propane or carbon dioxide may be used as process compatible solvent.
  • a supercritical mixture including hydrogen, an optional co-solvent, and ligand may be used as the stripping fluid.
  • the metal hydride catalyst is preferably a platinum, palladium, iridium or rhodium hydride catalyst. Most preferably it is a rhodium hydride catalyst such as, for example HRh(CO)(PPh 3 ) 3 , further details of which can be found in, for example, page 792 of “Advanced Inorganic Chemistry” (Third Edition) by F. Albert Cotton and Geoffrey Wilkinson, published by Interscience Publishers. The process is also suitable for use with other rhodium catalysts, for example those described in U.S. Pat. No. 4,482,749 which is incorporated herein by reference.
  • the reactor stream may be any stream which is obtained from any point in a process and which will contain metal hydride catalyst in solution.
  • catalyst may be removed from the reactor in product stream or in other streams including purge streams. These streams may be treated in accordance with the present invention to recover this valuable catalyst in a form which is suitable for return the reactor.
  • the reactor stream may be passed directly for treatment in accordance with the process of the present invention or may first undergo any suitable pretreatment. Where the reactor stream is a product stream, the reaction product may be present during the recovery process of the present invention or may be removed before the stream is contacted with the absorbent.
  • the present invention is particularly suitable for removing the metal catalyst from reactor streams containing molecules having a high molecular weight and hence low volatility and which are therefore difficult to separate from the catalyst by conventional means.
  • each stream from the reactor, following suitable pre-treatment, such as to remove product may be combined for treatment through a single catalyst recovery plant.
  • each stream may be treated separately or streams with similar compositions may be treated together.
  • the invention is particularly suitable for use with streams removed from a hydroformylation reactor, and most particularly those streams which comprise catalyst and high molecular weight organic compounds known as “heavies”, (i.e. high boiling byproducts).
  • heavies include organic condensation products and will include cyclic trimers and higher cyclic moieties and linear and branched polymeric moieties which could also be present in the feed to the reactor.
  • These compositions typically have low volatility and can be difficult to separate from the catalyst by conventional techniques.
  • the present invention will enable the metal catalyst to be separated from essentially non-volatile components of the stream which can then be removed, with optionally subsequent treatment in accordance with conventional means.
  • the acidic absorbent is an acidic ion exchange resin.
  • the resin may be a styrene divinylbenzene copolymer containing sulphonic acid groups or carboxylic acid groups.
  • the resin may have a siloxane-containing backbone and an acidic functional group attached to the backbone.
  • the acidic functional group is preferably selected from the group consisting of aromatic carboxylic acids, aliphatic carboxylic acids, aromatic sulphonic acids and aliphatic sulphonic acids, with the sulphonic acids being particularly preferred.
  • the resin is used in the protonated form.
  • the sulphonic acid groups are the active groups, they are in the form —SO 3 H and in the presence of phosphines they are at least partially in the form —SO 3 ( ⁇ ) [HPR 3 ] (+) .
  • Neutralized sulphonic acid resins, in which some or all of the protons have been exchanged by a cation may also be suitable but are not preferred.
  • Particularly preferred resins include AmberlystTM 15 and AmberlystTM DPT-1, with AmberlystTM DPT-1 being most preferred.
  • AmberlystTM 15 is available from Rohm and Haas (U.K.) Limited of Lennig House, 2 Mason's Avenue, Croydon CR9 3NB, England and AmberlystTM DPT-1 ion exchange resin is available from Kvaerner Process Technology Limited of The Technology Centre, Princeton Drive, Thornaby, Stockton-on-Tees TS17 6PY, England.
  • the absorbent may be pre-treated prior to use.
  • the absorbent may be washed, for example, with methanol to remove water and may also be sieved prior to being contacted with the reactor stream.
  • the ion-exchange resin or other suitable absorbent will allow the absorption of the metal hydride species onto its surface by a protonation and subsequent elimination of hydrogen by the reaction of Scheme 1. This hydrogen elimination is a reversible reaction and thus the metal species remains as a labile species and can be desorbed by the hydrogen in the fluid stripping medium.
  • M is a Group VIII metal
  • each X is a liganding group which may be the same or different and n is an integer of from 2 to 5.
  • the contact of the reactor stream with the solid acid absorbed resin may be carried out at any suitable temperature. Temperatures of from 0° C. to about 120° C. may be used with those of from about 20° C. to about 100° C. being preferred. A temperature in the region of from about 65° C. to about 95° C. is particularly preferred as the higher temperature will facilitate the removal of the metal from solution and its loading onto the absorbent. The temperatures and pressures will generally be selected such that any solids formation such as crystallisation of ligand or ligand oxide is avoided.
  • a catalyst depleted solution will remain and may be removed from the system.
  • the further treatment of this solution will depend on the content of the stream.
  • the reaction stream treated in accordance with the present invention is a stream containing the heavies from a hydroformylation reaction
  • the catalyst depleted solution will preferably be removed.
  • the catalyst depleted solution may be passed through a conventional catalyst collection system to trap the inactive catalytic metal and any trace amounts of the catalyst remaining.
  • the stream to be treated may be concentrated before being contacted with the acidic absorbent.
  • the concentration will preferably occur by removal of volatilisable material.
  • the reactor stream or the concentrated stream may require dilution with a solvent compatible with the absorbent before it is contacted with the absorbent. Any suitable solvent may be used. Normally, the solvent will be miscible with the reactor stream or concentrated stream. Suitable solvents include xylene and toluene.
  • the stream to be treated includes inactive catalyst this may be exposed to the absorbent but may not react therewith and if no reaction occurs will be removed with the non-volatile components.
  • the inactive catalyst may be deactivated by the formation of clusters, these may be broken before the stream is contacted with the absorbent such that they can be absorbed by the absorbent and treated with the stripping medium. By this means this inactive catalyst may be regenerated such that it may be returned to the reactor and take part in the reaction.
  • the stream is preferably passed through an oxidiser where air is passed through the solution to break down the clusters before being brought into contact with the absorbent.
  • an oxidiser where air is passed through the solution to break down the clusters before being brought into contact with the absorbent.
  • the air will break down the rhodium clusters by oxidation of the phosphido bridges.
  • the oxidiser may also at least partially oxidise any trivalent phosphorous compounds which may be present to the pentavalent form (i.e. conversion from phosphites to phosphates).
  • the oxidation step in addition to breaking up the clusters, may additionally change the oxidation state of the metal in that it will be converted to a simple cationic form.
  • the metal is rhodium, Rh 2+ and Rh 3+ will be formed.
  • reaction stream may be treated in accordance with one or more of the organic reagents described in U.S. Pat. No. 4,929,767 and U.S. Pat. No. 5,237,106 which are incorporated herein by reference.
  • the process may additionally include, treating the catalyst such that it is in a suitable state for absorption.
  • the catalyst is rhodium for use in hydroformylation
  • the catalyst preferably is subjected to hydrocarbonylation where it is treated with an organophosphorous ligand such as triphenylphosphine, carbon monoxide and hydrogen to reform the catalyst in the form HRh(CO)(PPh 3 ) 3 .
  • the absorbent may be washed to further remove impurities.
  • the absorbent may also serve to remove some impurities.
  • the catalyst of the reaction is a Group VIII noble metal catalyst
  • iron, nickel and/or chromium may additionally be present. These will generally also be absorbed by the absorbent but will not be retrieved by the stripping medium of the present invention. Thus the stream recycled to the reactor will be free of these impurities.
  • the partial pressure of the gaseous phase of the stripping media, or of the hydrogen component of the supercritical phase or the fluid phase, for removing the absorbed metal may be of any suitable value. Partial pressures of about 200 kPa or higher may be particularly advantageous. The upper limit on the partial pressure will be dictated by the equipment rating.
  • the stripping media fluid preferably additionally includes carbon monoxide.
  • the presence of carbon monoxide has been found to offer improved results. This is particularly appropriate where the metal catalyst complex includes CO as a ligand.
  • the fluid of the stripping media preferably includes a liquid phase which comprises liquids which are compatible with the reactants, other compounds and products in the reactor, such that the product stream containing the metal hydride catalyst may be returned to the reactor without further processing.
  • the fluid is preferably also compatible with product recovery operations.
  • the fluid of the stripping media will comprise liquids which are required to be present in the reactor such as ligands and raw materials.
  • the liquid phase will comprise triphenylphosphine.
  • the reaction is hydroformylation, the liquid phase may comprise olefin and/or triphenylphosphine.
  • the fluid includes material that is used in the catalyst recovery process but which is inert to the reaction process, for example, the hydroformylation process.
  • the material is preferably recoverable and recyclable from the reaction process to the metal recovery section of the plant.
  • suitable material is toluene which may be used as a solvent or diluent in the metal recovery process.
  • the absorbent is preferably a resin bed in a column through which the reactor stream flows. Once the resin bed has been loaded with the metal, the stripping medium is then preferably passed through the resin bed and into the reactor.
  • the reactor stream may be contacted with the absorbent in a stirred vessel. In this arrangement, the contact will be a repeated batch process.
  • the stripping process will preferably simultaneously regenerate the absorbent bed for further subsequent absorption of metal from a fresh stream. However, it may be advisable to wash the resin at least periodically to remove any impurities, ligand and the like which may build up over several passes of reactor stream.
  • the stripping may be carried out at similar temperatures as those used for the loading. However, lower temperatures favour the metal being desorbed and going into solution. Suitable temperatures include from about 20° C. to about 70° C. This is particularly the case where higher partial pressures of hydrogen are used.
  • the plant may include at least two beds of absorbent operated in parallel.
  • the reactor stream will be passed through a first bed of absorbent such that the metal is substantially removed from the stream.
  • the stream will be switched to flow through the second bed. Whilst the second bed is being similarly loaded, the stripping medium will be applied to the first bed such that the metal is desorbed.
  • the procedure will then be reversed such that the first bed is being loaded while the second bed is being desorbed.
  • the process is effectively continuous.
  • the present invention provides a process the plant for which is cost-effective to construct and to operate and which enables the catalyst to be recovered from reactor streams and returned to the reactor.
  • a further advantage of the present invention is that where reactants, ligands and the like are used for the stripping medium and these are passed via the absorbent where stripping occurs, to the reactor, not only are no additional substances, or only inert substances, introduced into the reactor, there are no costs associated with the stripping medium.
  • the recovery of the catalyst in accordance with the present invention may also enable poisoned and/or inhibited catalyst to be reactivated. Without wishing to be bound by any theory, it is believed that the metal is attracted to the absorbent and the poison/inhibitor is removed in the catalyst depleted stream.
  • the process of the invention is particularly suitable for use in hydroformylation of optionally substituted C 3 to C 20 olefinically unsaturated hydrocarbons.
  • FIGURE 1 is a schematic diagram of a process in accordance with the present invention.
  • Hydroformylation will occur in a hydroformylation zone containing a charge of a liquid reaction medium having in solution therein the complex rhodium hydroformylation catalyst comprising rhodium, carbon monoxide and triphenylphosphine.
  • the olefin is supplied to the hydroformylation zone which is maintained at temperature and pressure conditions which are conducive to hydroformylation of the olefin. Carbon monoxide and hydrogen will then be supplied such that reaction occurs.
  • the aldehyde product will be removed from the reaction zone.
  • the reaction zone will be purged of non-volatile condensation components in a “heavies” removal stream. Either of these streams may be the subject of the rhodium recovery process of the present invention. However, for ease of understanding, the further discussions will be made with regard to the “heavies” removal stream.
  • This stream 1 will be passed to an evaporator, such as a wiped film evaporator 2 to separate any remaining volatile components. Volatile components of the stream will be removed in line 3 and may be subjected to further treatment including condensation and separation. Triphenylphosphine may also be removed in line 3 .
  • the stream including the rhodium leaves the oxidiser in line 8 and is then pumped to a hydrocarbonylation zone 9 .
  • the catalyst containing stream is mixed with triphenylphosphine added in line 10 and is contacted with hydrogen and carbon monoxide which is added in line 11 .
  • the triphenylphosphine added via line 10 may be recycled triphenylphosphine recovered from line 3 .
  • the carbonylated catalyst is then removed in line 12 and is passed into the first absorber column 13 ′ which is packed with ion-exchange resin AmberlystTM DPT-1.
  • the resin bed will be at a temperature in the region of about 85° C. to aid the rate of absorption of the rhodium by the ion-exchange resin.
  • the rhodium As the stream passes through the absorbent bed, the rhodium is absorbed onto the resin and the non-volatile heavies and impurities are removed in stream 14 ′ for optional further processing. Due to the value of the rhodium, the stream may be passed through a conventional rhodium recovery system to collect any catalyst which may pass through the resin bed, which may be inactive catalyst, for off-site regeneration.
  • the rhodium loaded in column 13 ′ is then stripped from the resin using a stripping medium which is passed through the column. Where the stripping medium contains a mixture of organic liquids, these will be combined in mixer 15 .
  • the liquid phase is preferably a combination of process compatible solvents and/or olefin added in line 16 and triphenylphosphine added in line 17 .
  • the olefin may be fresh olefin which will be passed through the resin bed before being added to the reactor.
  • the olefin may be recycled olefin, isomerised olefin and paraffin recovered from streams removed from the hydroformylation reactor.
  • the process compatible solvents may be fresh solvents or recycled solvents recovered from streams removed from the hydroformylation reactor or the downstream product recovery systems.
  • the triphenylphosphine may be fresh triphenylphosphine or it may be recycled, for example from stream 3 of volatile compounds removed from the wiped film evaporator 2 .
  • This combined liquid phase for the stripping medium is removed from the mixer 15 in line 18 where it is combined with hydrogen and carbon monoxide of the gaseous phase which is added in line 19 .
  • the stripping medium will be passed through column 13 ′ which is held at ambient or higher temperature.
  • the solution was purged with 1:1 hydrogen/carbon monoxide at atmospheric pressure, heated to 85° C. and pressurised with hydrogen to 85° C. and pressurised with hydrogen to 1000 psig. The autoclave was then allowed to cool. The triphenylphosphine solution was removed from the resin and found to contain 160 ppm rhodium.
  • the solution was purged with 1:1 hydrogen/carbon monoxide at atmospheric pressure, heated to 85° C. and pressurised with hydrogen to 85° C. and pressurised with hydrogen to 1000 psig.
  • the autoclave was then allowed to cool.
  • the triphenylphosphine solution was removed from the resin and found to contain 150 ppm rhodium. This solution was then made up to 100 ml using further octene, toluene and triphenylphosphine, replaced in the cleaned reactor and pressurised with 1:1 hydrogen/carbon monoxide at 85° C. and 85 psig. From the rate of gas uptake it was determined that the activity of the solution was 98% of the activity that would be expected from an uninhibited solution.

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US8575061B2 (en) 2010-11-11 2013-11-05 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8575062B2 (en) 2010-11-11 2013-11-05 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8586500B2 (en) 2010-11-11 2013-11-19 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8658558B2 (en) 2010-11-11 2014-02-25 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8703641B2 (en) 2010-11-11 2014-04-22 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US9168519B2 (en) 2010-11-11 2015-10-27 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US9199224B2 (en) 2012-09-05 2015-12-01 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalysts and method for making thereof
US11292752B2 (en) 2017-11-15 2022-04-05 Mitsubishi Chemical Corporation Method for producing aldehyde and method for producing alcohol

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EP2075070A1 (en) * 2007-12-13 2009-07-01 BP Chemicals Limited Catalyst recovery process
DE102008057857B4 (de) 2008-11-18 2014-09-11 Oxea Gmbh Verfahren zur Rückgewinnung von Rhodium aus Rhodiumkomplexverbindungen enthaltenden wässrigen Lösungen
US20220143590A1 (en) 2019-06-27 2022-05-12 Dow Technology Investments Llc Process to prepare solution from hydroformylation process for precious metal recovery

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US9776181B2 (en) 2010-11-11 2017-10-03 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8575062B2 (en) 2010-11-11 2013-11-05 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8586500B2 (en) 2010-11-11 2013-11-19 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8658558B2 (en) 2010-11-11 2014-02-25 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8703641B2 (en) 2010-11-11 2014-04-22 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US9168519B2 (en) 2010-11-11 2015-10-27 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8575061B2 (en) 2010-11-11 2013-11-05 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US9199224B2 (en) 2012-09-05 2015-12-01 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalysts and method for making thereof
US9266098B2 (en) 2012-09-05 2016-02-23 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalysts and method for making thereof
US9327274B2 (en) 2012-09-05 2016-05-03 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US9327275B2 (en) 2012-09-05 2016-05-03 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalysts and method for making thereof
US9504993B2 (en) 2012-09-05 2016-11-29 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalysts and method for making thereof
US9205413B2 (en) 2012-09-05 2015-12-08 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalysts and method for making thereof
US11292752B2 (en) 2017-11-15 2022-04-05 Mitsubishi Chemical Corporation Method for producing aldehyde and method for producing alcohol

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