US20030223946A1 - Durable fiber treatment composition - Google Patents

Durable fiber treatment composition Download PDF

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Publication number
US20030223946A1
US20030223946A1 US10/409,313 US40931303A US2003223946A1 US 20030223946 A1 US20030223946 A1 US 20030223946A1 US 40931303 A US40931303 A US 40931303A US 2003223946 A1 US2003223946 A1 US 2003223946A1
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United States
Prior art keywords
treatment composition
composition according
fiber treatment
hair
silicone
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US10/409,313
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English (en)
Inventor
Robert Glenn
Simon Godfrey
Anthony McMeekin
Coralie Claude Boumard
Neil Dring
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Procter and Gamble Co
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Procter and Gamble Co
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Assigned to PROCTER & GAMBLE COMPANY, THE reassignment PROCTER & GAMBLE COMPANY, THE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GLENN, ROBERT WAYNE, MCMEEKIN, ANTHONY, BOURNARD, CORALIE CLAUDE MONIQUE, DRING, NELL CHARLES, GODFREY, SIMON PAUL
Publication of US20030223946A1 publication Critical patent/US20030223946A1/en
Priority to US12/267,096 priority Critical patent/US7785576B2/en
Abandoned legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/415Aminophenols
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/08Preparations for bleaching the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/10Preparations for permanently dyeing the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

Definitions

  • the present invention relates to topical compositions for treating natural and synthetic fibrous substrates.
  • the topical compositions comprise mixtures of functionalized silicones having defined physico-chemical properties with a durability additive.
  • the durability additive is capable of modifying the functionalized silicones to render them more durable on polar fibrous substrates than previously known silicone based conditioners, especially where the substrate is hair that has been previously damaged through chemical treatments, such as occurs during permanent dyeing, bleaching and permanent waving.
  • Oxidative dyeing otherwise known as permanent colouring leads to irreversible physico-chemical changes to the hair.
  • two components are mixed together prior to application to the hair.
  • These components usually comprise an oxidising agent, such as hydrogen peroxide, and a dyeing material, such as oxidative dye precursors and couplers (buffered at a high pH, typically around 10).
  • an oxidising agent such as hydrogen peroxide
  • a dyeing material such as oxidative dye precursors and couplers (buffered at a high pH, typically around 10).
  • the mixture is left for a period of time suitable to allow the required colour transformation to occur, after which the hair becomes more hydrophilic versus non-coloured hair due to irreversible chemical changes.
  • this change in hair hydrophilicity appears to be due, among other things, to the oxidation of the keratin-keratin cysteine amino acids within the hair creating more hydrophilic cysteic acid amino acid residues and the hydrolysis of the hair's natural hydrophobic, protective layer denoted as the F-Layer, a covalently attached lipid to the outer epicuticular envelope, 18-methyleicosanoic acid.
  • This colouring process is usually repeated regularly by consumers in order to maintain their desired hair colour and colour intensity and also to ensure that new hair growth has the same colour as the older hair.
  • the hair changes polarity from a relatively hydrophobic surface near the scalp where it could be experiencing its first colour, to a progressively more polar substrate at the hair tips, which may have been subjected to multiple colouring treatments.
  • a discussion of oxidation dyeing of hair can be found in “The Science of Hair Care” by Charles Zviak, Marcel Dekker, New York, 1986. These irreversible physicochemical changes can manifest themselves as increased roughness, brittleness and dryness leading to less manageable hair.
  • the invention will ideally provide a hair treatment composition comprising a conditioning agent that is durable, i.e. does not wash off so rapidly that the conditioning benefit is lost to the consumer, especially on chemically damaged hair, such as occurs during permanent dyeing, bleaching and permanent waving.
  • a fiber treatment composition which comprises a mixture of
  • a functionalized silicone polymer having an interfacial tension (IFT) of less than or equal to 15 mN/m (15 dyne/cm) and a hydrophilicity index (HI) of less than 100; and
  • IFT interfacial tension
  • HI hydrophilicity index
  • G′ is the storage modulus
  • G′′ and G′ are established by means of the dynamic rheological properties, which, in turn, are measured by an oscillation sweep on a rheometer, as described hereinbelow. More information on the measurement of dynamic rheological properties can be found in “Rheological Properties of Cosmetics and Toiletries” by Dennis Laba, Cosmetic Science and Technology Series, Volume 13, Marcel Dekker, Inc., ISBN 0-8247-9090-1.
  • the functionalized silicone polymers according to the invention are capable of depositing durably on hair in all states of damage.
  • durability additive includes materials which improve the durability of the functionalized silicone, as measured by the Silicone Durability Index Value, as defined hereinbelow.
  • a durability additive is a material which, when mixed with a functionalized silicone, gives a mixture which is more durable than the functionalized silicone alone.
  • a material Y is “miscible” in a material Z if Y and Z may be mixed to generate a homogenous mixture that does not phase separate at standard conditions of temperature and pressure within 3 weeks following termination of mixing.
  • HLB value is known to the skilled person working in this technical area—see for example Römpp Chemie Lexikon, Thieme Varlag, Stuttgart, 9 th Edition, 1995 under “HLB-Wert”.
  • hydrophility region we are interested in includes the region of IFT less than 1 mN/m.
  • the present inventors were forced to adopt an alternative method for this region—the so-called hydrophilicity index (HI) as also defined hereinbelow.
  • HI hydrophilicity index
  • the functionalized silicone fluids of the present invention have an IFT of less than or equal to 15 mN/m and an HI of less than 100, preferably an IFT of less than 12 mN/m and an HI of less than or equal to 99.5, more preferably an IFT of less than 8 mN/m and an HI of less than or equal to 98, more preferably still an IFT of less than 1 mN/m and an HI of less than 99.5, yet more preferably an HI in the range from 87 to 98.
  • an IFT of 1 mN/m (1 dyne/cm) corresponds to an HI of approximately 85.
  • the lower the IFT value the higher the corresponding HI value and vice versa.
  • (tan ⁇ ) ⁇ 1 is greater than zero, preferably from 0.001 to less than or equal to 0.1. Above this upper limit, the tactile feel performance is reduced, with the mixture of functionalized silicone/additive becoming sticky and tacky to the touch, reducing acceptance by consumers. More preferably, (tan ⁇ ) 1 is from 0.01 to less than or equal to 0.075.
  • the ratio of the weight of functionalized silicone to durability additive is in the range from 5:1 to 1000:1, preferably from 10:1 to 1000:1 and more preferably from about 20:1 to about 1000:1.
  • Fiber treatment compositions according to an embodiment of the invention may comprise from 0.1 to 20%, preferably from 0.50 to 15%, more preferably from 0.50 to 10% and more preferably still from 0.5 to 7.5% by weight of the mixture of functionalized silicone fluid and durability additive.
  • Functionalized silicones which may be incorporated into compositions according to the invention include organomodified silicones of the pendant or graft type wherein polar functional substituents are incorporated within or onto monovalent organic groups, A 1 , A 2 , A 3 and A 4 used hereinafter, as follows:
  • organomodified silicones of the block copolymer type wherein these polar functional substituents are incorporated within or onto bivalent organic groups A 1 , A 2 , A 3 and A 4 used hereinafter.
  • Me is methyl, m is greater than or equal to 1, n is about 50 to 2000, p is about 0 to 50, q is about 0 to 50, r is about 0 to 50, s is about 0 to 50, wherein p+q+r+s is greater than or equal to 1, B 1 is H, OH, an alkyl or an alkoxy group.
  • Organic groups A 1 , A 2 , A 3 and A 4 may be straight, branched or mono- or polycyclic aliphatic, mono or polyunsaturated alkyl, aryl, heteroalkyl, heteroaliphatic or heteroolefinic moiety comprising 3 to 150 carbon atoms together with 0-50 heteroatoms, especially O, N, S, P and can incorporate one or more polar substituents selected from electron withdrawing, electron neutral, or electron donating groups with Hammett sigma para values between ⁇ 1.0 and +1.5 which can be non-ionic, zwitterionic, cationic or anionic comprising, for example, groups ⁇ 1 , ⁇ 2 , ⁇ 3 , and ⁇ 4 as defined below; S-linked groups including S ⁇ 1 , SCN, SO 2 ⁇ 1 , SO 3 ⁇ 1 , SS ⁇ 1 1 , SO ⁇ 1 , SO 2 N ⁇ 1 ⁇ 2 , SN ⁇ 1 ⁇ 2 , S(N ⁇ 1 ) ⁇ 2
  • ⁇ 1 , ⁇ 2 , ⁇ 3 , and ⁇ 4 may be straight, branched or mono or polycyclic aliphatic, mono or polyunsaturated alkyl, aryl, heteroalkyl, heteroaliphatic or heteroolefinic moiety comprising 3 to 150 carbon atoms together with 0-50 heteroatoms, especially O, N, S, P.
  • X is F, Cl, Br, or I.
  • H is hydrogen, O is oxygen, N is nitrogen, C is carbon, S is sulfur, Cl is chlorine, Br is bromine, I is iodine, F is fluorine.
  • Preferred polar functional substituents for inclusion within the functionalized silicone contain at least one class of oxygen containing polar functional substituent, such that the oxygen content (% oxygen) within the summation of the one or more polar functional substituents (not including the oxygen in the PDMS backbone) is from 1% to 17%, preferably from 2% to 15%, and more preferably from 3% to 13% of the weight of the functionalized silicone.
  • the hydrophilic functional silicone components of the present invention should have a silicone content (% silicone) of from 45 to 95%, preferably from 50 to 90%, and more preferably from 55 to 85% of the weight of the functionalized silicone.
  • the functionalized silicone polymer comprises polyoxyalkylene substituents.
  • the polyoxyalkylene content (% polyether) should be from 5 to 55%, preferably from 10 to 50%, and more preferably from 15 to 45%.
  • the sum of % silicone and % polyether does not total 100%, other constituents, such as amine and amide making up the balance.
  • the silicone content is defined above and the polyether content (% polyether) is defined as the molecular weight of each polyether pendant or block multiplied by the average number of pendants or blocks and divided by the average molecular weight of the whole polymer.
  • the pendant or block polyether comprises of both ethylene oxide (EO) and propylene oxide (PO) units
  • this % polyether comprises the summation of % EO and % PO. If the pendant or block polyether is comprised of either only EO or only PO units, this % polyether is equivalent to the % EO or % PO, respectively.
  • the functionalized silicone is according to the following formula (1):
  • the pendant organomodified silicones comprising amino and polyoxyalkylene groups of the average formula (1) can be prepared by methods known to those skilled in the art, via steps including known polymerisation reactions (e.g. equilibration or polycondensation) and known methods of introducing organic substitution to the silicone backbone (e.g. hydrosililation).
  • organosiloxane resins are believed to create a 3-dimensional network within the functionalized silicone fluid giving rise to vicoelasticity thereby improving the adhesive properties of the fluid and hence the durability on a fibrous substrate.
  • the organosiloxane resin is insoluble in water.
  • the mixture of the functionalized silicone and the organosiloxane resin may be dispersed therewithin in the form of emulsified droplets.
  • Organosiloxane resins which my be included in the durability additive according to the invention comprise combinations of R 3 SiO 1/2 “M” units, R 2 SiO “D” units, RsiO 3/2 “T” units, SiO 2 “Q” units in ratios to each other that satisfy the relationship R n SiO (4-n)/2 where n is a value between 1.0 and 1.50 and R is a methyl group. Silanol or alkoxy functionalities may also be present in the resin structure.
  • the organosiloxane resins comprise repeating monofunctional R 3 SiO 1/2 “M” units and the quadrafunctional SiO 2 “Q” units, otherwise known as “MQ” resins.
  • MQ monofunctional SiO 1/2
  • the ratio of the “M” to “Q” functional units is advantageously from 0.7 and the value of n is 1.2.
  • Organosiloxane resins such as these are commercially available as SR1000 available from GE Bayer Silicones and Wacker 803 from Wacker Silicones.
  • the organosiloxane resins according to the invention are solid at about 25° C. and have a molecular weight range of from 1,000 to 10,000 grams/mole.
  • Silicone Z is an aminosilicone with an average of 110 D units and two terminal aminopropyl functional groups
  • the fiber treatment composition according to the invention is advantageously a hair treatment composition.
  • the composition may additionally comprise a hair bleaching component and/or a hair dyeing component.
  • a hair treatment kit comprising:
  • a hair treatment composition as defined hereinabove comprised within component (a) and/or within component (b) and/or provided as a separate component.
  • the fiber treatment composition according to the present invention may include a cosmetically acceptable vehicle to act as a diluent, dispersant, or carrier for the silicone oil in the composition, so as to facilitate the distribution of the silicone oil when the composition is applied.
  • vehicle may be an aqueous emulsion, water, liquid or solid emollients, solvents, humectants, propellants, thickeners and powders.
  • the fiber treatment compositions according to the present invention may be in the form an emulsion with water as a primary component, although aqueous organic solvents, may also be included.
  • the emulsion may be a water-in-oil emulsion, an oil-in-water emulsion, a water-in-oil-in-water multiple emulsion, or an oil-in-water-in-oil multiple emulsion, but is preferably an oil-in-water emulsion (a silicone-in-water emulsion).
  • the aqueous continuous phase of the emulsion treatment compositions of the present invention may further comprise an emulsifier to facilitate the formation of the emulsion.
  • Emulsifiers for use in the aqueous continuous phase of the present emulsion treatment compositions may include an anionic surfactant, cationic surfactant, amphoteric surfactant, water-soluble polymeric surfactant, water-soluble silicone-containing surfactant, nonionic surfactant having an HLB of greater than about 10, or a surfactant system capable of forming stabilizing liquid crystals around the silicone droplets.
  • the nonionic surfactant preferably has an HLB of at least 12, and more preferably, an HLB value of at least about 15. Surfactants belonging to these classes are listed in McCutcheon's Emulsifiers and Detergents, North American and International Editions , MC Publishing Co., Glen Rock N.J., pages 235-246 (1993).
  • the emulsifier for the aqueous phase does not gel the aqueous phase.
  • the emulsifier may, however, be capable of forming a stabilizing layer of lamellar liquid crystals around silicone droplets. This barrier film prevents coalescence between emulsion droplets.
  • the surfactant system may be a single surfactant or a blend of surfactants. In some cases, a particular surfactant cannot form a liquid crystal structure alone, but can participate in the formation of liquid crystals in the presence of a second surfactant. Such a surfactant system forms a layer of lamellar liquid crystals around the silicone to provide a barrier between the silicone and the aqueous phase.
  • Exemplary classes of surfactants capable of participating in the formation of a liquid crystal structure around the silicone droplets include, but are not limited to specific cationic surfactants, anionic surfactants, nonionic surfactants, quaternary ammonium surfactants and lipid surfactants.
  • Nonionic surfactants are fatty alcohols or fatty acids, or derivatives thereof, or a mixture of any of these, having a chain length of from about 14 to about 20 carbon atoms. These materials may be predominantly linear or may be branched. Some examples include myristyl alcohol, myristic acid, cetyl alcohol, palmitic acid, cestearyl alcohol, stearyl alcohol, stearic acid, oleic acid, oleyl alcohol, arachidyl alcohol, arachidic acid, and mixtures thereof.
  • Non-ionic surfactants include condensation products of aliphatic (C 16 to C 22 ) primary or secondary linear or branched chain alcohols or phenols with alkylene oxides, usually ethylene oxide, and generally having from 1 to 30 ethylene oxide groups.
  • Some examples include, but are not limited to, ceteth-1, ceteth-2, ceteth-3, ceteth-4, ceteth-5, ceteth-6, ceteth-10, ceteth-12, ceteth-14, ceteth-15, ceteth-16, ceteth-20, ceteth-24, ceteth-25, ceteth-30, ceteareth-2, ceteareth-3, ceteareth-4, ceteareth-5, ceteareth-6, ceteareth-7, ceteareth-8, ceteareth-9, ceteareth-10, ceteareth-11, ceteareth-12, ceteareth-13, ceteareth-14, ceteareth-15, ceteareth-16, ceteareth-17, ceteareth-18, ceteareth-20, ceteareth-22, ceteareth-23, ceteareth-24, ceteareth-25, ceteareth-27, ceteareth-28, ceteareth-29, ceteareth-30, steareth-2, steare
  • Specific cationic surfactants include quaternary ammonium halides, e.g., alkyltrimethylammonium halides in which the alkyl group has from about 12 to 22 carbon atoms, for example dodecyltrimethyl-ammonium chloride, hexadecyltrimethylammonium chloride, cetyltrimethylammonium chloride, behenyltrimethylammonium chloride, benzyltrimethylammonium chloride, octyldimethylbenzyl-ammonium chloride, decetyldimethylbenzylammonium chloride, stearyldimethylbenzylammonium chloride, distearyldimethylammonium chloride, didodecyldimethylammonium chloride, dioctadecyldimethylammonium chloride, tallow trimethylammonium chloride, cocotrimethyl-ammonium chloride, cetylpyridinium chloride and their other quatern
  • Preferred cationic surfactants are cetyltrimethylammonium chloride (CTAC) and cetyltrimethylammonium bromide (CTAB 99% from Fluka, CTAC 50% (Arquad 16-50, Akzo).
  • CTAC cetyltrimethylammonium chloride
  • CTAB cetyltrimethylammonium bromide
  • cationic surfactants are used at 2-10% with CTAC and CTAB being the preferred cationic surfactants.
  • Specific anionic surfactants are di-alkyl sulfonates, di-alkyl ether sulfonates, di-alkylaryl sulfonates, di-alkanoyl isethionates, di-alkyl succinates, di-alkyl sulfosuccinates, di-N-alkoyl sarcosinates, di-alkyl phosphates, di-alkyl ether phosphates, di-alkyl ether carboxylates, and di-alpha-olefin sulfonates, especially their sodium, magnesium, ammonium and mono-, di- and triethanolamine salts.
  • the alkyl and acyl groups generally contain from 12 to 20 carbon atoms and may be unsaturated.
  • the stabilizing liquid crystals may also be formed from lipid surfactants including either phospholipids, i.e., based on glycerol and sphingosine, or glycolipid, i.e. based on sphingosine.
  • Phospholipids are preferred with phosphatidyl choline (lecithin) being the preferred phospholipid.
  • phosphatidyl choline lecithin
  • alcohol moieties which comprise the phosphoglycerides serine, choline and ethanolamine are particularly preferred, and of the fatty chains, those having a chain length of C 14 to C 24 are preferred.
  • the fatty acid chains may be branched or unbranched, saturated or unsaturated, and palmitic, myristic, oleic, stearic, arachidonic, linolenic, linoleic and arachidic acids are particularly preferred.
  • Preferred surfactants for the formation of liquid crystals in the aqueous continuous phase are of the nonionic type and include C 16-22 fatty alcohols, and C 16-22 fatty alcohol ethoxylates with 1 to 30 ethylene oxide groups.
  • Specific examples include cetearyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, oleyl alcohol, ceteareth ethoxylates with between 10 and 30 ethylene oxide groups, ceteth ethoxylates with between 10 to 30 ethylene oxide groups, steareth ethoxylates with between 10 and 30 ethoxylates, and combinations thereof.
  • C 16-22 fatty alcohols are used in combination with C 16-22 fatty alchol ethoxylates at a ratio of between 10:1 to 0.5:1, more preferably between 6:1 and 1:1, and most preferably between 5:1 and 1.5:1.
  • the aqueous continuous phase should ideally comprise the emulsifier in an amount sufficient to stabilize the silicone.
  • the aqueous continuous phase comprises the emulsifier in an amount of from about 0.1% to about 15%, and more preferably from about 0.1% to about 10%, based on the weight of the aqueous continuous phase.
  • composition according to the present application finds particular utility in hair coloring compositions especially oxidative hair colorants wherein the hair is subjected to a particularly aggressive environment.
  • a preferred hair coloring agent for use herein is an oxidative hair coloring agent.
  • concentration of each oxidative hair coloring agent in the compositions according to the present invention may be from about 0.0001% to about 5% by weight.
  • oxidative hair coloring agent can be used in the compositions herein.
  • oxidative hair coloring agents comprise at least two components, which are collectively referred to as dye forming intermediates (or precursors).
  • Dye forming intermediates can react in the presence of a suitable oxidant to form a colored molecule.
  • the dye forming intermediates used in oxidative hair colorants include: aromatic diamines, aminophenols, various heterocycles, phenols, napthols and their various derivatives. These dye forming intermediates can be broadly classified as; primary intermediates and secondary intermediates.
  • Primary intermediates which are also known as oxidative dye precursors, are chemical compounds which become activated upon oxidation and can then react with each other and/or with couplers to form colored dye complexes.
  • the secondary intermediates also known as color modifiers or couplers, are generally colorless molecules which can form colors in the presence of activated precursors/primary intermediates, and are used with other intermediates to generate specific color effects or to stabilise the color.
  • Primary intermediates suitable for use in the compositions and processes herein include: aromatic diamines, polyhydric phenols, amino phenols and derivatives of these aromatic compounds (e.g., N-substituted derivatives of the amines, and ethers of the phenols). Such primary intermediates are generally colorless molecules prior to oxidation.
  • the process by which color is generated from these primary intermediates and secondary coupler compounds generally includes a stepwise sequence whereby the primary intermediate can become activated (by oxidation), and then enjoins with a coupler to give a dimeric, conjugated colored species, which in turn can enjoin with another ‘activated’ primary intermediate to produce a trimeric conjugated colored molecule.
  • oxidative dye primary intermediates include those materials which, on oxidation, form oligomers or polymers having extended conjugated systems of electrons in their molecular structure. Because of the new electronic structure, the resultant oligomers and polymers exhibit a shift in their electronic spectra to the visible range and appear colored.
  • oxidative primary intermediates capable of forming colored polymers include materials such as aniline, which has a single functional group and which, on oxidation, forms a series of conjugated imines and quinoid dimers, trimers, etc. ranging in color from green to black.
  • Oxidative dyes known in the art can be used in the compositions according to the present invention.
  • a representative list of primary intermediates and secondary couplers suitable for use herein is found in Sagarin, “Cosmetic Science and Technology”,“Interscience, Special Ed. Vol. 2 pages 308 to 310.
  • the primary intermediates can be used alone or in combination with other primary intermediates, and one or more can be used in combination with one or more couplers.
  • the choice of primary intermediates and couplers will be determined by the color, shade and intensity of coloration which is desired.
  • the hair coloring compositions of the present invention may, in addition to or instead of an oxidative hair coloring agent, include non-oxidative and other dye materials.
  • Optional non-oxidative and other dyes suitable for use in the hair coloring compositions and processes according to the present invention include both semi-permanent, temporary and other dyes.
  • Non-oxidative dyes as defined herein include the so-called ‘direct action dyes’, metallic dyes, metal chelate dyes, fiber reactive dyes and other synthetic and natural dyes.
  • Various types of non-oxidative dyes are detailed in: ‘Chemical and Physical Behaviour of Human Hair’ 3rd Ed. by Clarence Robbins (pp250-259); ‘The Chemistry and Manufacture of Cosmetics’. Volume IV. 2nd Ed. Maison G.
  • a preferred oxidising agent for use herein is an inorganic peroxygen oxidising agent.
  • the inorganic peroxygen oxidising agent should be safe and effective for use in the present compositions.
  • the inorganic peroxygen oxidising agents suitable for use herein will be soluble in the compositions according to the present invention when in liquid form or in the form intended to be used.
  • inorganic peroxygen oxidising agents suitable for use herein will be water-soluble.
  • Water soluble oxidising agents as defined herein means agents which have a solubility to the extent of about 10 g in 1000 ml of deionised water at 25° C. (“Chemistry” C. E. Mortimer. 5th Edn. p277).
  • the inorganic peroxygen oxidising agents useful herein are generally inorganic peroxygen materials capable of yielding peroxide in an aqueous solution.
  • Inorganic peroxygen oxidising agents are well known in the art and include hydrogen peroxide, inorganic alkali metal peroxides such as sodium periodate, sodium perbromate and sodium peroxide, and inorganic perhydrate salt oxidising compounds, such as the alkali metal salts of perborates, percarbonates, perphosphates, persilicates, persulphates and the like. These inorganic perhydrate salts may be incorporated as monohydrates, tetrahydrates etc. Mixtures of two or more of such inorganic peroxygen oxidising agents can be used if desired. While alkali metal bromates and iodates are suitable for use herein the bromates are preferred. Highly preferred for use in the compositions according to the present invention is hydrogen peroxide.
  • compositions herein may instead or in addition to the inorganic peroxygen oxidising agent(s), comprise one or more preformed organic peroxyacid oxidising agents.
  • Suitable organic peroxyacid oxidising agents for use in the coloring compositions according to the present invention have the general formula:
  • R is selected from saturated or unsaturated, substituted or unsubstituted, straight or branched chain, alkyl, aryl or alkaryl groups with from 1 to 14 carbon atoms.
  • the organic peroxyacid oxidising agents should be safe and effective for use in the compositions herein.
  • the preformed organic peroxyacid oxidising agents suitable for use herein will be soluble in the compositions used according to the present invention when in liquid form and in the form intended to be used.
  • organic peroxyacid oxidising agents suitable for use herein will be water-soluble.
  • Water-soluble preformed organic peroxyacid oxidising agents as defined herein means agents which have a solubility to the extent of about log in 1000 ml of deionised water at 25° C. (“Chemistry” C. E. Mortimer. 5th Edn. p277).
  • compositions herein may optionally contain a transition metal containing catalyst for the inorganic peroxygen oxidising agents and the optional preformed peroxy acid oxidising agent(s).
  • Suitable catalysts for use herein are disclosed in WO98/27945.
  • compositions herein may contain as an optional component a heavy metal ion sequestrant.
  • heavy metal ion sequestrant it is meant herein components which act to sequester (chelate or scavenge) heavy metal ions. These components may also have calcium and magnesium chelation capacity, but preferably they show selectivity to binding heavy metal ions such as iron, manganese and copper.
  • sequestering agents are valuable in hair coloring compositions as herein described for the delivery of controlled oxidising action as well as for the provision of good storage stability of the hair coloring products.
  • Heavy metal ion sequestrants may be present at a level of from about 0.005% to about 20%, preferably from about 0.01% to about 10%, more preferably from about 0.05% to about 2% by weight of the compositions.
  • Suitable sequestering agents are disclosed in WO98/27945.
  • the treatment compositions according to an embodiment of the invention may be provided at a pH from about 3 to 11, preferably from 4 to 10.5.
  • compositions do not only find application in the treatment of fibers, such as hair, but may also be applied to other substrates, such as human skin, nails and various animal body parts, such as horns, hooves and feathers.
  • hydrophilicity indexes were measured via turbidimetry on an LP2000 Turbidity Meter from Hanna Instruments, Bedfordshire, United Kingdom.
  • a 100 ml beaker is thoroughly cleaned, including prior rinsing with hexane then ethanol, and then dried:
  • Steps 1-5 are repeated 3 times, the turbidity values being averaged to give the average turbidity reading for the functionalized silicone.
  • hydrophilicity index for the functionalized silicone is then computed as follows:
  • Hydrophilicity Index 100 ⁇ ((Average turbidity)/400) ⁇ 100
  • An AR 500 rotational rheometer (TA Instruments Ltd., Leatherhead, Surrey KT22 7UQ, UK) is used to determine the viscosity of the functionalized silicone fluids used herein. The determination is performed at 30° C., with the 4 cm 2° steel cone measuring system set with a 49 ⁇ m (micron) gap and is performed via the programmed application of a shear stress of 0.5 to 590 Pa over a 2 minute time period. These data are used to create a shear rate vs. shear stress curve for the material. This flow curve can then be modelled in order to provide a material's viscosity. These results were fitted with the following well-accepted Newtonian model:
  • Durability is only assessed on a polar, chemically damaged hair substrate. Hair is supplied by Hugo Royer International Limited (10 Lakeside Business Park, Sandhurst, Berkshire, GU47 9DN, England) and is a blended, Eastern European, mid-brown human hair. Prior to use, the hair is assessed and qualified for low cuticular damage ( ⁇ 20%) and misalignment ( ⁇ 5%), based on at least 200 hair strands per batch. Any damage on a hair strand counts as one point damaged, and then the total is calculated as a percentage. This hair is made into 4′′ (10 cm), 2 g round tied switches (where the length and weight of hair corresponds to the hair below the tie).
  • Carrier base for dye base Ingredients Wt/Wt % 1. Acetic acid pre-mix Deionized water 46.49 Acetic acid (50%) (12) 3.91 2. Emulsion base Deionized water 29.78 Cetyl alcohol (1) 2.24 Stearyl alcohol (2) 2.24 Ceteareth-25 (3) 1.50 Phenoxyethanol (4) 0.11 Sodium benzoate (5) 0.09 Tetrasodium EDTA (87%) (6) 0.04 Ammonium hydroxide (13) 13.60
  • the first stage is to make the emulsion base; this is prepared by adding to a vessel deionized water and commencing agitation, and then heating to 82° C. Then tetrasodium EDTA and sodium benzoate are added and dissolved, followed by addition of ceteareth25, cetyl alcohol and stearyl alcohol. During the addition process the temperature is maintained above 80° C., finally phenoxyethanol is added, the mixture is then homogenized for 30 min. The emulsion structure is obtained by cooling whilst still high shear mixing the product down below 50° C. The emulsion base is then left to thicken for 60 min.
  • the chelants are added to the deionised water with mixing to form the chelant premix. This is then added with stirring to the pre-made emulsion base. Adding the peroxide mix water followed by hydrogen peroxide to the emulsion base/chelant premix and stirring until homogeneous makes the completed peroxide base.
  • the bleached hair switches are then washed in a sink fitted with a shower attachment set with a flow rate of 6 ⁇ 1 L min ⁇ 1 and a temperature of 37 ⁇ 2° C. Switches are initially wetted under the shower attachment for 30 s. The hair is then removed from the water flow and 0.2 g of shampoo (Pantene Pro-V Clarifying Shampoo) is applied down each switch, and then lathered for 30 s by hand before rinsing for 60 s under the shower. The hair is again removed from the shower, and has a further 0.2 g of shampoo applied, and lathered for 30 s before finally rinsing under the shower for 60 s.
  • shampoo Purified Pro-V Clarifying Shampoo
  • Hair switches are then dried using a hot air drier (Babyliss Lightweight Professional model 1015 (1400 W) for 3 min.
  • This washing protocol comprising two shampoo applications and one drying step is defined as a single wash cycle.
  • This washing method is then repeated again through another complete wash cycle.
  • the dry hair switches are then bleached again according to the method outlined above and subsequently washed again through two complete wash cycles.
  • This hair is hereinafter defined as “damaged” hair and is hereafter used a hydrophilic hair substrate.
  • the functionalised silicone under investigation for durability is prepared for assessment using the following method.
  • the functionalised silicone polymer is pre-mixed with the durability additive until homogeneous.
  • a matrix comprising 36 wt. % of the “emulsion base”, described hereinbefore for use in the preparation of the damaged hair substrate, obtained primarily through dilution with water, but also optionally comprising hydrogen peroxide and ammonium hydroxide, is used.
  • 1.75% of the silicone/additive under investigation is thoroughly dispersed using conventional techniques. A sufficient amount of product is applied to four chemically damaged hair switches for a sufficient time to provide an initial deposition above 100 ppm.
  • the hair is then rinsed to remove the matrix (in a sink fitted with a shower attachment set with a flow rate of 6 ⁇ 1 L min ⁇ 1 and a temperature of 37 ⁇ 2° C.) with finger agitation.
  • the switches are dried using a hot air drier (Babyliss Lightweight Professional model 1015 (1400 W) for 3 min.
  • switches When the switches are dry they are split into two groups both comprising equal numbers of damaged hair switches. The first are used to measure the initial deposition. The second set is washed to assess the silicone durability. The hair switches are washed in a sink fitted with a shower attachment set with a flow rate of 6 ⁇ 1 L min ⁇ 1 and a temperature of 37 ⁇ 2° C. Switches are initially wetted under the shower attachment for 30 s. The hair is removed from the water flow and 0.2 g of shampoo (“Pantene Classic Clean Shampoo”) is applied along each switch, and then lathered for 30 s by hand before rinsing for 60 s under the shower.
  • shampoo Purge Clean Shampoo
  • the switch then has a further 0.2 g of shampoo application, and is lathered for 30 s before finally rinsing under the shower for 60 s. Hair switches are then dried using a hot air drier (Babyliss Lightweight Professional model 1015 (1400 W) for 3 min. This protocol comprising two shampoo applications and one drying step is defined as one complete wash cycle. This washing protocol is then repeated again through another eleven complete cycles (to make twelve wash cycles in total). These switches are then measured for silicone deposition to assess the durability performance.
  • a hot air drier Bobyliss Lightweight Professional model 1015 (1400 W)
  • the drift in the analytical signal is regularly monitored and evaluated.
  • the preferred approach employed is to use a known standard that does not need to be prepared each time the drift is assessed.
  • An Ausmon sample is an appropriate monitor sample for many applications, including silicon determinations.
  • a drift correction with the Ausmon sample for silicon is performed at the beginning of each day samples are analyzed. The calculated drift is below 3% between sets of analysis.
  • m 1 and b 1 are calculated from a calibration curve constructed from measurements of the XRF signal as a function of the amount of silicone deposited on hair subsequently assayed using atomic absorption on the extracted silicone.
  • Dep(initial) equals the XRF deposition value obtained on hair after silicone deposition with no washing cycles
  • Dep(12 cycles) equals the XRF deposition value obtained on hair after silicone deposition and subsequent 12 wash cycles.
  • the AR 500 rotational Rheometer (TA Instruments) is used to determine the G′ and G′′ of the functional silicone fluids used herein. The determination is performed at 25° C., with the 6 cm acryllic parrellel plate measuring system set with a 100 micron gap and is performed via the programmed application of a oscillatory stress of 2 Pa over a oscillation frquency range of 1 to 40 Hz. This data is used to determine the ratio of G′ to G′′. A minimum of 30 data points is recorded over a linear frequency ramp. These data is used to determine the mean ratio of G′ to G′′ between 20 and 40 Hz.
  • Peroxide base #1 #2 #3 #4 Ingredients Wt % Wt % Wt % Wt % Emulsion base: Deionized water 29.17 29.17 29.17 29.17 Cetyl alcohol (1) 2.20 2.20 2.20 Stearyl alcohol (2) 2.20 2.20 2.20 Ceteareth-25 (3) 1.47 1.47 1 .47 1.47 Phenoxyethanol (4) 0.11 0.11 0.11 0.11 Sodium benzoate (5) 0.09 0.09 0.09 0.09 Tetrasodium EDTA (87%) (6) 0.04 0.04 0.04 0.04 0.04 Deionized water 35.00 35.00 35.00 35.00 Pentasodium pentetate (40%) (7) 0.24 0.24 0.24 0.24 Hydroxyethane diphosphonic acid 0.16 0.16 0.16 0.16 (60%) (8) Phosphoric acid (75%) (9) 0.08 0.08 0.08 0.08 Sodium stannate (95%) (10) 0.04 0.04 0.04 0.04 Hydrogen peroxide (35%) (11) 16.80 16.80 16.80
  • Carrier base for dye base #1 #2 #3 #4 Ingredients Wt % Wt % Wt % Wt % Wt % Deionized water 46.49 46.49 46.49 46.49 Acetic acid (50%) (12) 3.91 3.91 3.91 3.91 Emulsion base (see ingredients 36.00 36.00 36.00 36.00 above) Ammonium hydroxide (13) 13.60 13.60 13.60 13.60 13.60
  • the emulsion base is prepared by adding to a vessel the deionized water and commencing agitation with heating to 82° C. Then the preservatives (tetrasodium EDTA, sodium benzoate) are added and dissolved. This is followed by addition of ceteareth 25, cetyl alcohol and stearyl alcohol while keeping the temperature above 80° C. Then phenoxytol is added. The mixture is then fully blended hot through a recirculation line and homogenized. The emulsion structure is obtained by cooling the product down below 50° C. and shearing while cooling. The product is left to thicken for 60 min.
  • preservatives tetrasodium EDTA, sodium benzoate
  • the chelant premix is prepared by adding the chelants to water and mixing them together in a vessel. Then this solution is added to the emulsion base. The completed peroxide base is made by adding water to the previous mixture followed by the hydrogen peroxide while stirring.
  • the carrier base is prepared by adding water to a vessel and commencing agitation, followed by the addition of acetic acid. Then emulsion base (see emulsion base preparation described above) is added. When fully homogenized, ammonium hydroxide is added to the mixture.
  • the peroxide base and the dye base are mixed together at a 1:1 ratio and applied to dry hair.
  • the conditioner composition is prepared by adding to a vessel the deionized water and the emulsion base (see emulsion base preparation described above) while stirring. When homogenized citric acid is added to the mixture until the pH of the emusltion is between 5 and 6.
  • the functionalized silicones premix is prepared by pre-mixing together the functionalised silicone fluid and the organosiloxane resin with agitation. The functionalised silicone premix is then added to the main mix and stirred until the desired particle size is obtained.

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US20050132506A1 (en) * 2003-12-18 2005-06-23 The Procter & Gamble Company Enhancing the colour perception of artificially coloured hair
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US10045931B2 (en) 2015-02-17 2018-08-14 Noxell Corporation Composition for forming a film on keratin fibres
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ES2560852T3 (es) 2016-02-23
WO2003090510A3 (fr) 2004-12-09
CN100391435C (zh) 2008-06-04
WO2003090508A3 (fr) 2004-12-09
EP1358864A2 (fr) 2003-11-05
US20030211953A1 (en) 2003-11-13
MXPA04010079A (es) 2004-12-13
CN1649562A (zh) 2005-08-03
EP1356800B1 (fr) 2015-11-11
EP1358864A3 (fr) 2004-01-07
US7785576B2 (en) 2010-08-31
EP1356800A3 (fr) 2004-01-21
GB0209485D0 (en) 2002-06-05
WO2003090510A2 (fr) 2003-11-06
BRPI0309513A8 (pt) 2016-09-13
WO2003090508A2 (fr) 2003-11-06
JP2005527595A (ja) 2005-09-15
AU2003234147A1 (en) 2003-11-10
MXPA04010041A (es) 2004-12-13
EP1356800A2 (fr) 2003-10-29
AU2003223694A1 (en) 2003-11-10
JP2005524691A (ja) 2005-08-18
CA2483443C (fr) 2011-09-20
CA2483443A1 (fr) 2003-11-06
US20090068135A1 (en) 2009-03-12
CN1694681A (zh) 2005-11-09
BRPI0309513A2 (pt) 2016-08-09
AU2003223694A8 (en) 2003-11-10

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