US12540931B2 - Gas analyzer - Google Patents

Gas analyzer

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Publication number
US12540931B2
US12540931B2 US18/288,086 US202218288086A US12540931B2 US 12540931 B2 US12540931 B2 US 12540931B2 US 202218288086 A US202218288086 A US 202218288086A US 12540931 B2 US12540931 B2 US 12540931B2
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Prior art keywords
flow path
drain
liquid container
drain flow
terminal end
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US18/288,086
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English (en)
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US20240210369A1 (en
Inventor
Atsuko SENDA
Toshihisa Itabashi
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Shimadzu Corp
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Shimadzu Corp
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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/2247—Sampling from a flowing stream of gas
    • G01N1/2258—Sampling from a flowing stream of gas in a stack or chimney
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/42—Low-temperature sample treatment, e.g. cryofixation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26—Drying gases or vapours
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N2001/2282—Devices for withdrawing samples in the gaseous state with cooling means

Definitions

  • the present invention relates to a gas analyzer including a drain pot.
  • the exhaust gas generated in the facilities described above generally contains water vapor, and if such exhaust gas is introduced into the analyzer as it is, accurate measurement cannot be performed. Therefore, a cooler which cools an analysis target gas is provided in the gas flow path connecting a sampling point of the exhaust gas and the analyzer. When the exhaust gas is cooled in the cooler, water vapor is liquefied in the cooler, and the water vapor is removed from the analysis target gas.
  • the liquefied water (drain water) is introduced into a drain pot through a drain flow path (drain pipe) (for example, Patent Literature 1).
  • the drain pot is provided to prevent outside air from flowing into the gas flow path through the drain flow path and being mixed with the analysis target gas.
  • a sealed drain pot is a closed container provided with a drain port having an on-off valve, and a terminal end of the drain flow path extending from the cooler is inserted into the container.
  • the container In a normal sealed drain pot, the container is closed by closing the on-off valve, which prevents outside air from flowing into the gas flow path. Since the amount of liquid in the drain pot increases as the drain water flows in from the cooler, an operator of the facility periodically stops an operation of the gas analyzer and then opens the on-off valve of the drain port to discharge the stored drain water to the outside of the drain pot.
  • An overflow drain pot is a container having a side wall provided with a drain port which is always open to the atmosphere, and a terminal end of the drain flow path extending from the cooler is disposed below the drain port.
  • water is always stored up to the drain port (that is, above the terminal end of the drain flow path), thus preventing outside air from flowing into the gas flow path through the drain flow path and the cooler (water sealing).
  • the drain water pours out from the drain port to the outside of the drain pot, and the height of the liquid level is maintained at the height of the drain port (that is, above the terminal end of the drain flow path).
  • the overflow drain pot is superior to the sealed drain pot in that it is not necessary to perform an operation of discharging drain water to the outside of the drain pot and thus time and effort for such management can be reduced, but has the following problems.
  • the analysis target gas enters the drain flow path from the gas flow path, while the liquid in the drain pot enters the drain flow path from the terminal end of the drain flow path.
  • the height of the liquid level in the drain flow path is the position where the pressure of the analysis target gas and the water pressure of the drain water entering the drain flow path from the drain pot are balanced.
  • the gauge pressure (pressure obtained by subtracting the atmospheric pressure from the absolute pressure) of the analysis target gas is x
  • the height of the liquid level in the drain pot) and the height of the terminal end of the drain flow path to be x max / ⁇ g or more in order to maintain the water-sealed state.
  • ⁇ H should be preferably about 980 mm or more (p is calculated as the density of water).
  • the dimension of the drain pot would be very large depending on the expected gauge pressure of the analysis target gas.
  • An object of the present invention is to provide a gas analyzer including an overflow drain pot which is capable of reducing management time and effort and can be small in size.
  • Using the conventional drain pot having only one container for storing drain water in order to water-seal the analysis target gas having the maximum gauge pressure of ( ⁇ H1+ ⁇ H2) ⁇ g similarly to the present invention requires setting a difference ⁇ H between the height of the discharge port provided in the container and the height of the terminal end of the drain flow path to ( ⁇ H1+ ⁇ H2) or more, and thus the height of the entire drain pot must be higher than ( ⁇ H1+ ⁇ H2).
  • FIG. 2 is an exploded view of the drain pot in the gas analyzer of the present embodiment.
  • FIG. 3 is a schematic configuration diagram illustrating a modification of the drain pot in the gas analyzer according to the present invention.
  • FIG. 4 is a schematic configuration diagram illustrating another modification of the drain pot in the gas analyzer according to the present invention.
  • FIG. 5 A is a diagram for explaining an operation of the drain pot in the gas analyzer of the present embodiment, and is a diagram illustrating a state where the gauge pressure of an analysis target gas is positive.
  • FIG. 5 B is a diagram for explaining an operation of the drain pot in the gas analyzer of the present embodiment, and is a diagram illustrating a state where the pressure of the analysis target gas is higher than that illustrated in FIG. 5 A .
  • FIG. 5 C is a diagram for explaining an operation of the drain pot in the gas analyzer of the present embodiment, and is a diagram illustrating a state where the pressure of the analysis target gas is higher than that illustrated in FIG. 5 B .
  • FIG. 6 is a diagram for explaining an operation of the drain pot in the gas analyzer of the present embodiment, and is a diagram illustrating an example of a state where the gauge pressure of the analysis target gas is negative.
  • FIG. 7 is a schematic configuration diagram illustrating a modification of the drain pot in the gas analyzer of the present embodiment.
  • FIG. 8 is a schematic configuration diagram illustrating another modification of the drain pot in the gas analyzer of the present embodiment.
  • Embodiments of a gas analyzer according to the present invention will be described with reference to FIGS. 1 to 9 .
  • the gas analyzer 10 includes a gas intake port 11 and a gas analysis unit 12 , which are connected by an analysis target gas flow path 13 .
  • a gas analysis unit 12 for example, a non-dispersive infrared (NDIR) spectrometer is used.
  • an analysis target gas pump 15 is connected to the analysis target gas flow path 13 .
  • the gas analyzer 10 includes a cooling unit (cooler) 14 in the analysis target gas flow path 13 from the gas intake port 11 to the gas analysis unit 12 .
  • the analysis target gas is cooled to a predetermined temperature by the cooling unit 14 and then introduced into the gas analysis unit 12 .
  • one cooling unit 14 is provided in the present embodiment, an analysis target gas may be cooled in stages by arranging a plurality of cooling units.
  • the drain pot 20 includes a first liquid container 211 , a second liquid container 212 , and a third liquid container 213 .
  • the first liquid container 211 has a first lid 241
  • the second liquid container 212 has a second lid 242
  • the third liquid container 213 has a third lid 243 . Any one or more (including all three) of the first lid 241 , the second lid 242 , and the third lid 243 may be omitted.
  • a terminal end 2201 of the first drain flow path 221 is disposed inside the first liquid container 211 .
  • the first liquid container 211 has a communication port 231 above the terminal end 2201 of the first drain flow path 221 .
  • a first connection pipe 251 extending outward the first liquid container 211 is connected to the communication port 231 .
  • a combination of the communication port 231 and the first connection pipe 251 can be regarded as a communication port in the present invention.
  • a second drain flow path 222 is provided to extend outward and downward from (the first connection pipe 251 of) the communication port of the first liquid container 211 .
  • a terminal end 2202 of the second drain flow path 222 is disposed inside the second liquid container 212 .
  • the second liquid container 212 has a first discharge port 232 above the terminal end 2201 of the first drain flow path 221 and the terminal end 2202 of the second drain flow path 222 , and below the communication port 231 .
  • a second connection pipe 252 extending outward the second liquid container 212 is connected to the first discharge port 232 .
  • a combination of the first discharge port 232 and the second connection pipe 252 can be regarded as a discharge port in the present invention.
  • a third drain flow path 223 is provided to extend outward and downward from (the second connection pipe 252 of) the discharge port of the second liquid container 212 .
  • a terminal end 2203 of the third drain flow path 223 is disposed inside the third liquid container 213 .
  • the third liquid container 213 has a second discharge port 233 above the terminal end 2202 of the second drain flow path 222 and the terminal end 2203 of the third drain flow path 223 , and below the first discharge port 232 .
  • a third connection pipe 253 extending outward the third liquid container 213 is connected to the second discharge port 233 , and a discharge pipe 29 extending downward is connected to the third connection pipe 253 .
  • FIG. 2 illustrates an exploded view of the drain pot 20 .
  • the first liquid container 211 , the second liquid container 212 , and the third liquid container 213 can be separated from each other.
  • a first connection pipe insertion port 262 is provided on a side surface of the second liquid container 212 , and the first liquid container 211 and the second liquid container 212 are integrated by inserting the first connection pipe 251 into the first connection pipe insertion port 262 . After the first connection pipe 251 is inserted into the first connection pipe insertion port 262 , the second drain flow path 222 is connected to the first connection pipe 251 , and then the second lid 242 is attached.
  • a second connection pipe insertion port 263 is provided on a side surface of the third liquid container 213 , and the second liquid container 212 and the third liquid container 213 are integrated by inserting the second connection pipe 252 into the second connection pipe insertion port 263 .
  • the third drain flow path 223 is connected to the second connection pipe 252 , and then the third lid 243 is attached.
  • the number of liquid containers included in the drain pot 20 is determined depending on the maximum pressure of the analysis target gas generated from the exhaust gas generation facility 90 .
  • a plurality of container sets having the same configuration as described above are prepared in advance, and only a necessary number of the prepared container sets may be used depending on the actual maximum pressure of the analysis target gas.
  • more liquid containers than necessary are not connected, so that a space occupied by drain pot 20 can be suppressed.
  • the drain pot 20 can be flexibly set depending on the maximum pressure of the analysis target gas without causing waste.
  • the operation of the gas analyzer of the present embodiment is similar to the operation of the conventional gas analyzer except for the operation of the drain pot 20 .
  • the operation of drain pot 20 will be described below.
  • water is stored to the heights of the communication port 231 , the first discharge port 232 , and the second discharge port 233 in advance.
  • Drain water generated by cooling the analysis target gas in the cooling unit 14 flows into the first liquid container 211 through the first drain flow path 221 .
  • the water in the first liquid container 211 overflows, and flows into the second liquid container 212 from the communication port 231 through the second drain flow path 222 .
  • the water in the second liquid container 212 overflows, and flows into the third liquid container 213 from the first discharge port 232 through the third drain flow path 223 .
  • the water in third liquid container 213 overflows, and is discharged from the second discharge port 233 to the outside of the drain pot 20 through the discharge pipe 29 .
  • the water discharged is recovered, and treatment such as removal of components of the analysis target gas (exhaust gas) contained in the water is performed.
  • the height of the liquid level of the drain water in the first drain flow path 221 is the same as the height of the liquid level in the first liquid container 211 (that is, the height of the communication port 231 ), but when the gauge pressure P G of the analysis target gas is positive (absolute pressure is higher than the atmospheric pressure), the height of the liquid level is pressed below the height of the liquid level in the first liquid container 211 .
  • a gauge pressure P G of the analysis target gas is ⁇ h1 ⁇ g (where, ⁇ is a density of the drain water and g is a gravitational acceleration)
  • a difference in height between the liquid level in the first liquid container 211 and the liquid level in the first drain flow path 221 is ⁇ h1 ( FIG. 5 A ).
  • ⁇ h1 ⁇ H1 a difference in height between the communication port 231 and the terminal end 2201 of the first drain flow path 221 is ⁇ H1
  • ⁇ h1 ⁇ H1 is satisfied.
  • the gauge pressure P G of the analysis target gas becomes higher than ⁇ H1 ⁇ g, the liquid level in the first drain flow path 221 is pressed down to the terminal end 2201 of the first drain flow path 221 .
  • the analysis target gas flows into the second drain flow path 222 through the communication port 231 , and the height of the liquid level in the second drain flow path 222 is pressed below the height of the liquid level in the second liquid container 212 (that is, the height of the first discharge port 232 ).
  • the gauge pressure P G of the analysis target gas is ( ⁇ H1+ ⁇ h2) ⁇ g, a difference in height between the liquid level in the second liquid container 212 and the liquid level in the second drain flow path 222 is ⁇ h2 ( FIG. 5 B ).
  • 8h2 ⁇ H2 is satisfied.
  • the gauge pressure P G of the analysis target gas becomes higher than ( ⁇ H1+ ⁇ H2) ⁇ g, the liquid level in the second drain flow path 222 is pressed down to the terminal end 2202 of the second drain flow path 222 .
  • the analysis target gas flows into the third drain flow path 223 through the first discharge port 232 , and the height of the liquid level in the third drain flow path 223 is pressed below the height of the liquid level in the third liquid container 213 (that is, the height of the second discharge port 233 ).
  • the gauge pressure P G of the analysis target gas is ( ⁇ H1+ ⁇ H2+8h3) ⁇ g, a difference in height between the liquid level in the third liquid container 213 and the liquid level in the third drain flow path 223 is ⁇ h3 ( FIG. 5 C ).
  • a difference in height between the second discharge port 233 and the terminal end 2203 of the third drain flow path 223 is ⁇ H3, 8h3 ⁇ ⁇ H3 is satisfied.
  • the gauge pressure P G of the analysis target gas When the gauge pressure P G of the analysis target gas further increases and the liquid level in the third drain flow path 223 is pressed down to the terminal end 2203 of the third drain flow path 223 , the gauge pressure P G at this time is ( ⁇ H1+ ⁇ H2+ ⁇ H3) ⁇ g, which is the maximum gauge pressure P Gmax that can be water-sealed by the drain pot 20 having the three liquid containers illustrated in FIGS. 1 and 5 A to 5 C .
  • a difference in height between the discharge port of the liquid container and the end of the drain flow path needs to be set to be ( ⁇ H1+ ⁇ H2+ ⁇ H3).
  • a difference in height between the communication port 231 which is a discharge port having the highest position and the terminal end 2203 of the third drain flow path 223 which is a terminal end of the drain flow path having the lowest position is ( ⁇ H1+ ⁇ H2+ ⁇ H3 ⁇ m1 ⁇ m2).
  • ⁇ m1 is a difference in height between the first discharge port 232 and the terminal end 2201 of the first drain flow path 221
  • ⁇ m2 is a difference in height between the second discharge port 233 and the terminal end 2202 of the second drain flow path 222 .
  • ⁇ m1 and ⁇ m2 are subtracted from ( ⁇ H1+ ⁇ H2+ ⁇ H3) because the first discharge port 232 is disposed above the terminal end 2201 of the first drain flow path 221 and the second discharge port 233 is disposed above the terminal end 2202 of the second drain flow path 222 .
  • the height of the entire drain pot 20 in the present embodiment can be made smaller than that of a drain pot having only one liquid container.
  • a size of the cross-sectional area of the drain pot does not affect the pressure of the analysis target gas that can be water-sealed. Therefore, even in the case of using a plurality of liquid containers as in the present embodiment, reducing the cross-sectional area of each liquid container allows a space occupied by the drain pot in the lateral direction to be equal to or smaller than the conventional space.
  • the drain pot 20 can be small in size as compared with the conventional one.
  • the maximum gauge pressure P Gmax is ( ⁇ H1+ ⁇ H2+ ⁇ H3+ ⁇ H4) ⁇ g (where, ⁇ H4 is a difference in height between a third discharge port 234 and a terminal end 2204 of the fourth drain flow path 224 ), and the maximum gauge pressure is higher than that in the drain pot 20 having the three liquid containers illustrated in FIGS. 1 and 5 A to 5 C .
  • the maximum gauge pressure can be further increased.
  • the maximum gauge pressure P Gmax is ( ⁇ H1+ ⁇ H2) ⁇ g, which is lower than a maximum gauge pressure in the drain pot 20 illustrated in FIGS. 1 and 5 A to 5 C , but the height of the entire drain pot can be suppressed as compared with the drain pot 20 .
  • the gauge pressure P G of the analysis target gas is positive, that is, the absolute pressure of the analysis target gas exceeds the atmospheric pressure has been described so far, however, as illustrated in FIG. 6 , even when the gauge pressure P G of the analysis target gas is negative, that is, the absolute pressure of the analysis target gas is less than the atmospheric pressure, water sealing can be achieved by the drain pot 20 .
  • the liquid levels of the first drain flow path 221 and the second drain flow path 222 are the same as the liquid levels of the first liquid container 211 and the second liquid container 212 , respectively, and the liquid level of the third drain flow path 223 is higher than the liquid level of the third liquid container 213 .
  • the liquid level of the third drain flow path 223 reaches the liquid level of the second liquid container 212 , and the liquid level of the second drain flow path 222 becomes higher than the liquid level of the second liquid container 212 .
  • the gauge pressure P G further decreases, the liquid level of the second drain flow path 222 reaches the liquid level of the first liquid container 211 , and the liquid level of the first drain flow path 221 becomes higher than the liquid level of the first liquid container 211 ( FIG. 6 ).
  • the present invention is not limited to the above embodiments, and various variations are possible.
  • a part of the second drain flow path 222 may be disposed outside the second liquid container 212 as long as even the terminal end 2202 of the second drain flow path 222 is disposed inside the second liquid container 212 .
  • a part of the third drain flow path 223 may be disposed outside the third liquid container 213 .
  • one lid (the first lid 241 to the third lid 243 ) is provided for each container (the first liquid container 211 to the third liquid container 213 ), but as illustrated in FIG. 7 , a common lid 24 may be provided for a plurality of liquid containers.
  • the discharge pipe 29 is connected to the third connection pipe 253 extending outward from the side surface of the third liquid container 213 , but instead, a discharge pipe 291 extending upward through the bottom surface of the third liquid container 213 may be used.
  • a discharge pipe 291 extending upward through the bottom surface of the third liquid container 213 may be used.
  • the plurality of containers (the first liquid container 211 to the third liquid container 213 ) that can be separated from each other are used, but instead, as illustrated in FIG. 9 , a space in one liquid container may be divided into a plurality of partial spaces 2111 , 2112 , and 2113 by partitions 2101 and 2102 , and the plurality of partial spaces 2111 to 2113 may be used as the first liquid container, the second liquid container, and so on in the present invention.
  • a gas analyzer includes: a gas flow path through which an analysis target gas flows; and a drain pot provided in the gas flow path and disposed upstream of an analysis unit configured to analyze the analysis target gas, the drain pot into which liquid generated by cooling the analysis target gas in the gas flow path is introduced,
  • a gas analyzer according to clause 3 is the gas analyzer according to clause 2, wherein

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Immunology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Drying Of Gases (AREA)
US18/288,086 2021-04-26 2022-01-28 Gas analyzer Active 2042-12-08 US12540931B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2021074001 2021-04-26
JP2021-074001 2021-04-26
PCT/JP2022/003388 WO2022230269A1 (ja) 2021-04-26 2022-01-28 ガス分析装置

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US20240210369A1 US20240210369A1 (en) 2024-06-27
US12540931B2 true US12540931B2 (en) 2026-02-03

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US (1) US12540931B2 (https=)
EP (1) EP4332545A4 (https=)
JP (1) JP7497778B2 (https=)
CN (1) CN117083513A (https=)
WO (1) WO2022230269A1 (https=)

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JPH0678855U (ja) * 1993-04-15 1994-11-04 株式会社堀場製作所 ガス分析計のサンプリング装置
KR100361667B1 (ko) * 2000-10-31 2002-11-22 유니셈 주식회사 폐가스 처리 장치
JP2005195327A (ja) 2003-12-26 2005-07-21 Shimadzu Corp ガス分析計の試料前処理装置
US20080073206A1 (en) * 2006-09-27 2008-03-27 Fujifilm Corporation Liquid circulating apparatus, and measurement apparatus
JP2014145625A (ja) 2013-01-28 2014-08-14 Mitsubishi Heavy Ind Ltd ガスサンプリングプローブ
CN110156190A (zh) * 2018-04-16 2019-08-23 协建（江苏）智能装备有限公司 一种自动增压净水器及水质取样检测装置
CN111287715A (zh) * 2020-03-30 2020-06-16 中国华能集团清洁能源技术研究院有限公司 一种实验模拟二氧化碳置换驱替油气的系统
JP2021015028A (ja) * 2019-07-11 2021-02-12 株式会社島津製作所 ガス分析装置

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JPH0744994Y2 (ja) * 1988-09-03 1995-10-11 株式会社堀場製作所 サンプリング装置
JP2007183137A (ja) * 2006-01-05 2007-07-19 Mitsubishi Electric Corp トリチウムモニタ
CN103852576B (zh) * 2012-12-03 2017-11-28 科宝智慧医疗科技（上海）有限公司 用于液体分析的容器
CN205749050U (zh) * 2016-07-07 2016-11-30 塔里木大学 分析化学实验用气体采样装置

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Publication number Priority date Publication date Assignee Title
JPH0678855U (ja) * 1993-04-15 1994-11-04 株式会社堀場製作所 ガス分析計のサンプリング装置
KR100361667B1 (ko) * 2000-10-31 2002-11-22 유니셈 주식회사 폐가스 처리 장치
JP2005195327A (ja) 2003-12-26 2005-07-21 Shimadzu Corp ガス分析計の試料前処理装置
US20080073206A1 (en) * 2006-09-27 2008-03-27 Fujifilm Corporation Liquid circulating apparatus, and measurement apparatus
JP2014145625A (ja) 2013-01-28 2014-08-14 Mitsubishi Heavy Ind Ltd ガスサンプリングプローブ
CN110156190A (zh) * 2018-04-16 2019-08-23 协建（江苏）智能装备有限公司 一种自动增压净水器及水质取样检测装置
JP2021015028A (ja) * 2019-07-11 2021-02-12 株式会社島津製作所 ガス分析装置
CN111287715A (zh) * 2020-03-30 2020-06-16 中国华能集团清洁能源技术研究院有限公司 一种实验模拟二氧化碳置换驱替油气的系统

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* Cited by examiner, † Cited by third party
Title
Extended European Application No. issued Jul. 18, 2024 in European Application No. 22795192.8.
International Search Report for PCT/JP2022/003388 dated Mar. 8, 2022 (PCT/ISA/210).
Written Opinion for PCT/JP2022/003388 dated Mar. 8, 2022 (PCT/ISA/237).
Extended European Application No. issued Jul. 18, 2024 in European Application No. 22795192.8.
International Search Report for PCT/JP2022/003388 dated Mar. 8, 2022 (PCT/ISA/210).
Written Opinion for PCT/JP2022/003388 dated Mar. 8, 2022 (PCT/ISA/237).

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CN117083513A (zh) 2023-11-17
US20240210369A1 (en) 2024-06-27
EP4332545A1 (en) 2024-03-06
JPWO2022230269A1 (https=) 2022-11-03
WO2022230269A1 (ja) 2022-11-03
EP4332545A4 (en) 2024-08-21
JP7497778B2 (ja) 2024-06-11

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