US10132789B2 - Apparatus and method for detecting gas - Google Patents

Apparatus and method for detecting gas Download PDF

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Publication number
US10132789B2
US10132789B2 US15/032,085 US201415032085A US10132789B2 US 10132789 B2 US10132789 B2 US 10132789B2 US 201415032085 A US201415032085 A US 201415032085A US 10132789 B2 US10132789 B2 US 10132789B2
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Prior art keywords
conduit
carrier gas
pump
membrane
gas
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US20160266085A1 (en
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Sebastian Hollunder
Martin Kubiczek
Juergen SCHUEBEL
Karsten Viereck
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Maschinenfabrik Reinhausen GmbH
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Maschinenfabrik Reinhausen GmbH
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Assigned to MASCHINENFABRIK REINHAUSEN GMBH reassignment MASCHINENFABRIK REINHAUSEN GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HOLLUNDER, Sebastian, VIERECK, KARSTEN, KUBICZEK, Martin, SCHUEBEL, JUERGEN
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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/26—Oils; Viscous liquids; Paints; Inks
    • G01N33/28—Oils, i.e. hydrocarbon liquids
    • G01N33/2835—Specific substances contained in the oils or fuels
    • G01N33/2841—Gas in oils, e.g. hydrogen in insulating oils
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00—Investigating or analyzing materials by the use of thermal means
    • G01N25/14—Investigating or analyzing materials by the use of thermal means by using distillation, extraction, sublimation, condensation, freezing, or crystallisation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F27/00—Details of transformers or inductances, in general
    • H01F27/08—Cooling; Ventilating
    • H01F27/10—Liquid cooling
    • H01F27/12—Oil cooling

Definitions

  • the invention relates to an apparatus and to a method for detecting gas in a high-voltage apparatus filled with an insulating medium, particularly high-voltage transformers.
  • WO 2011/120113 [U.S. Pat. No. 8,442,775] describes a system and a method for monitoring gases in power transformers cooled by oil.
  • the system consists of a rod and a main housing.
  • the rod has two conduits running in the interior and is positioned in the oil of the power transformer.
  • the conduits are connected together by two oil chambers and a pump so that the oil is sucked from the power transformer via a conduit to the first oil chamber and can be subsequently introduced by the second oil chamber through the other conduit back into the power transformer.
  • the pump is in that case provided in a conduit section between the oil chambers.
  • An additional region with a temperature detector and a moisture sensor is present in front of the pump.
  • the two oil chambers have a wall consisting of a semipermeable material. Gases present in the oil of the power transformer can migrate through this wall into the interior of the main housing. An additional gas sensor detects the gases that collect in the main housing of the system.
  • two valves each with a respective filter are provided at the housing. One of the valves is used for sucking air from the environment by a pump. The air is expelled from the interior of the main housing through the second valve. The system is controlled by a control.
  • This known system is of very complicated construction.
  • the multiplicity of individual parts used means that the system is not only expensive, but also maintenance-intensive.
  • the valves for the air exchange wear particularly quickly and thus form a weak point in the system.
  • the flatly constructed membrane can rupture particularly quickly in the case of a sudden pressure rise and especially at the time of evaluation of the carrier gas.
  • U.S. Pat. No. 6,526,805 describes an apparatus for continuous analysis and measurement of the content of gas components in an insulating liquid substantially on a real-time basis.
  • This apparatus comprises a gas extraction unit for separation of the gases from the liquid, an infrared gas analyzer for determining the concentration of the individual gas components, a gas pump for circulating the gases to the gas extraction unit in a closed loop and a calibrating device for the infrared gas analyzer.
  • the gas extraction unit comprises a gas-permeable polymer membrane and a gas chamber with a gas flow inlet and a gas flow outlet.
  • the infrared gas analyzer comprises an infrared source, a gas cell with a gas inlet and gas outlet and a quad-detector with extremely narrow-band optical infrared filters.
  • the calibrating device comprises a valve device for flushing out the gas components with air and for resetting the infrared source to zero.
  • the valve device comprises a first three-way valve that is seated between the gas pump and the gas extraction unit, and a second three-way valve that is seated between the gas cell and the gas pump.
  • U.S. Pat. No. 8,075,675 describes an apparatus for extraction of gas from a liquid.
  • This apparatus comprises a housing, a separating membrane in the housing, a porous membrane support, an oil pump, a gas pump, a gas distributor and an analyzing instrument.
  • the housing defines a fluid path and a gas path that is isolated from the fluid path, and has an inlet to the fluid path, an outlet from the fluid path, an inlet to the gas path and an outlet from the gas path.
  • the separating membrane separates the fluid path from the gas path and comprises a fluorosilicone element that is impermeable to the liquid and permeable to the gas.
  • the separating membrane has a first side facing the fluid path and a second side facing the gas path.
  • the separating membrane forms a flattened disk that is thicker at the edge and thinner in the center.
  • the membrane support faces toward the first side of the separating membrane.
  • the fluid path contains the first side of the separating membrane.
  • the oil pump conveys the liquid through the fluid path.
  • the gas pump conveys a carrier gas and the gas that is released from the liquid, through the gas path.
  • the analyzing instrument is connected with the gas path by the gas distributer.
  • the gas distributor is described in detail in U.S. Pat. No. 6,391,096 and comprises seven control valves.
  • the object of the invention is to provide an apparatus for detecting gas molecules in a high-voltage apparatus filled with insulating medium, which apparatus is constructed to be economic, maintenance friendly and wear-free, and to indicate a method for detecting gases in a high-voltage apparatus filled with liquids, which method ensures reliable operation of the apparatus.
  • the invention proposes an apparatus for detecting gas in a high-voltage apparatus filled with an insulating medium, comprising:
  • At least one gas sensor for detecting a gas
  • a membrane consisting of at least one semipermeable material and that is at least partly surrounded by the insulating medium and at least partly exposed to a flow of the carrier gas;
  • the proposed apparatus is particularly wear-free and thus maintenance-friendly.
  • a further advantage resides in the fact that not the insulating medium, but the carrier gas is circulated. It is thereby possible to introduce fresh carrier gas into the apparatus prior to the enrichment and detection and to discharge it from the apparatus after the detection.
  • the high-voltage apparatus can be constructed in desired mode and manner according to requirements, for example as a high-voltage transformer, a power transformer, an on-load tap changer, a power switch, a capacitor lead-through or other oil-filled electrical equipment.
  • the insulating medium can be constructed in desired mode and manner according to requirements, for example as insulating oil or ester fluid.
  • the gas to be detected can be formed in any desired mode and manner according to requirements and for example contain at least one hydrocarbon compound and/or other gas molecules and/or other gas atoms.
  • the semipermeable membrane can be constructed in any desired mode and manner according to requirements and can consist for example at least partly of Teflon.
  • the pumps can be constructed in any desired mode and manner according to requirements, for example as diaphragm pumps.
  • the inlet has a first conduit.
  • a filter is preferably seated in the conduit.
  • the membrane has an at least partly tubular and/or at least partly hose-like construction.
  • the membrane has an at least partly spiral and/or at least partly meandering and/or at least partly helical configuration.
  • the outlet has a second conduit.
  • the second pump is preferably provided in the second conduit, but it can also be provided in the first conduit.
  • thermoelement and/or at least one temperature sensor is or are provided in the measuring chamber.
  • thermoelement the temperature sensor and the thermoelement are connected with a controller
  • thermoelement is controlled on the basis of the measurements of the temperature sensor.
  • the measuring chamber is provided between the first conduit and the membrane.
  • thermoelement is constructed as a Peltier element.
  • the measuring chamber in the interior is lined with an inert material, platinum or gold.
  • the second pump if the second pump is seated in the first conduit then it has an aspect ratio that is greater than the second conduit and/or greater than 100, 200, 500, 1000, 2000, 5000 or 10,000 and/or it has a flow resistance that is greater than that of the second conduit and/or that corresponds with that of a conduit with a constant inner diameter and an aspect ratio greater than 100, 200, 500, 1000, 2000, 5000 or 10,000;
  • the second pump if the second pump is seated in the second conduit then it has an aspect ratio that is greater than the first conduit and/or greater than 100, 200, 500, 1000, 2000, 5000 or 10,000 and/or it has a flow resistance that is greater than that of the first conduit and/or that corresponds with that of a conduit with a constant inner diameter and an aspect ratio greater than 100, 200, 500, 1000, 2000, 5000 or 10,000.
  • the aspect ratio of a conduit is in that case the ratio of its length to its inner diameter.
  • Each conduit can be constructed in any desired mode and manner according to requirements and have for example a constant internal diameter over its length.
  • at least one throttle or nozzle can be seated in a conduit with a smaller aspect ratio and is preferably dimensioned in such a way that the flow resistance of this conduit corresponds with a conduit with one of the indicated larger aspect ratios.
  • the first conduit opens between the first pump and the membrane into a first connecting conduit that connects an outlet of the measuring chamber with an inlet of the membrane, or opens between the first pump and the measuring chamber into a second connecting conduit, that connects an outlet of the membrane with an inlet of the measuring chamber.
  • the invention proposes a method for detecting gas in a high-voltage apparatus filled with an insulating medium, preferably by means one of the apparatuses proposed in accordance with the first aspect, wherein
  • the carrier gas in a second step after the first step the carrier gas is conveyed by a first pump out of the measuring chamber, through a membrane and into the measuring chamber and in that case gas, that has accumulated in the carrier gas flowing against the membrane, is detected in the measuring chamber;
  • the membrane consists at least of at least one semipermeable material and is surrounded at least partly by the insulating medium.
  • the carrier gas is sucked through a first conduit, conveyed through the measuring chamber and the membrane and purged through a second conduit.
  • the amount and/or kind of gas in the measuring chamber is or are determined before and/or after the carrier gas was conveyed out.
  • the amount and/or kind of the gas in the measuring chamber is or are determined before and/or after the carrier was conveyed.
  • One of the proposed methods can be carried out for example by any of the proposed apparatuses.
  • each of the proposed apparatuses is constructed in such a way and/or serves the purpose and/or is suitable for the purpose that it carries out and/or can carry out one of the proposed methods.
  • FIG. 1 shows a first embodiment of an apparatus for detecting gas
  • FIG. 2 shows a second embodiment of the apparatus
  • FIG. 3 shows a third embodiment of the apparatus
  • FIG. 4 shows a fourth embodiment of the apparatus
  • FIG. 5 shows a method for detection of gas.
  • FIG. 1 A first embodiment of an system 1 for detection of gas molecules, ions or gases 4 in a high-voltage apparatus 3 filled with a liquid or an insulating medium 2 , is schematically illustrated in FIG. 1 .
  • the high-voltage apparatus 3 can be a high-voltage transformer, a power transformer, an on-load tap changer, a power switch or a capacitor lead-through.
  • the system 1 comprises a membrane or capillary 13 consisting of at least one semipermeable material and of tubular or hose-like construction.
  • the tubular membrane 13 can be shaped as desired, for example as a spiral and/or a helix and/or as a meander. By virtue of this advantageous form of the membrane 13 it is suitable for particularly high pressures.
  • the membrane 13 is disposed in the high-voltage apparatus 3 or at least in a part of the high-voltage apparatus accessible to the insulating medium 2 .
  • the membrane 13 can thus be in a Buchholz relay, a conduit of the cooling system, etc.
  • the membrane 13 is connected at one end forming its inlet by a first connecting conduit 19 with the outlet of a measuring chamber 11 and at another end forming forms its outlet by a second connecting conduit 20 with the inlet of the measuring chamber 11 .
  • the measuring chamber 11 comprises a thermoelement 14 that is for example a Peltier element that controls the temperature inside the measuring chamber 11 .
  • a gas sensor 12 and a temperature sensor 18 are provided in the measuring chamber 11 .
  • the measuring chamber 11 is lined or coated internally with an inert material such as for example gold.
  • This coating offers the advantage that the gases 4 do not deposit or condense in the interior and are non-reproducibly absorbed, in that case being able to enter into at least one polar physical bond and thus be absent in the overall gas balance, and false values by comparison with a laboratory analysis would be measured.
  • the measuring chamber 11 is connected with an intake 5 by a first conduit 7 that opens into the second connecting conduit 20 .
  • a filter 15 is provided upstream of the inlet 5 .
  • the first conduit 7 has a particularly high ratio between the length and flow cross-section.
  • the measuring chamber 11 is additionally connected with a first pump 9 that is seated in the second connecting conduit 20 between the membrane 13 and the first conduit 7 .
  • This conveys the carrier gas 16 through the connecting conduits 19 , 20 , the measuring chamber 11 and the membrane 13 , so that a circuit arises and the carrier gas 16 is enriched with the gases 4 from the insulating medium 2 .
  • the first pump 9 blocks flow.
  • the system 1 additionally comprises a second pump 10 that on one side is connected with an outlet 6 by a second conduit 8 that opens into the second connecting conduit 20 between the membrane 13 and the first pump 9 , and on the other side with the inlet 5 by the first conduit 7 , the measuring chamber 11 and the membrane 13 .
  • the second pump 10 takes over the function of a closed valve.
  • the first pump 9 the second pump 10 is always switched off.
  • the first pump 9 is switched off.
  • the carrier gas 16 is enriched with the gases 4 that migrate through the semipermeable membrane 13 and thus release from the insulating medium 2 , until the quantity of gases 4 to be taken up by the carrier gas 16 no longer significantly increases.
  • thermoelement 14 is carried out on the basis of the measurements of the temperature sensor 18 .
  • FIG. 2 A second embodiment of the system 1 is schematically illustrated in FIG. 2 .
  • This embodiment is similar to the first embodiment so that in the following primarily the differences are explained in more detail.
  • the second pump 10 is seated, not as in the first embodiment in the second conduit 8 , but in the first conduit 7 and is consequently connected on one side with the inlet 5 and on the other side by the measuring chamber 11 , the membrane 13 and the second conduit 8 with the outlet 6 .
  • the second conduit 8 has a particularly high aspect ratio between the intrinsic length and the cross-section.
  • FIG. 3 A third embodiment of the system 1 is schematically illustrated in FIG. 3 , this embodiment is similar to the first embodiment, so that primarily the differences are explained in more detail in the following.
  • the first pump 9 is seated not in the second connecting conduit 20 as in the case of the first embodiment, but in the first connecting conduit 19 .
  • the first conduit 7 opens between the first pump 9 and the membrane 13 and the second conduit 8 opens between the measuring chamber 11 and the first pump 9 into the first connecting conduit 19 .
  • the second pump 10 consequently inducts the carrier gas by the inlet 5 and conveys it through the filter 15 , the first conduit 7 , the downstream part of the first connecting conduit 19 , the membrane 13 , the second connecting conduit 20 , the measuring chamber 11 and the upstream part of the first connecting conduit 19 to the outlet 6 . Consequently, for the enrichment the first pump 9 circulates the carrier gas through the downstream part of the first connecting conduit 19 , the membrane 13 , the second connecting conduit 20 , the measuring chamber 11 and the upstream part of the first connecting conduit 19 .
  • FIG. 4 A fourth embodiment of the system 1 is schematically illustrated in FIG. 4 .
  • This embodiment is similar to the third embodiment, so that primarily the differences are explained in more detail in the following.
  • the second pump 10 is seated not in the second conduit 8 as in the case of the third embodiment, but in the first conduit 7 and consequently is connected on one side with the inlet 5 and on the other side by the membrane 13 , the measuring chamber 11 and the second conduit 8 with the outlet 6 .
  • the second conduit 9 has a particularly high aspect ratio between the intrinsic length and the cross-section.
  • FIG. 5 A flow chart for a preferred embodiment of a method for detection of gases 4 in a high-voltage apparatus 3 filled with a liquid 2 is illustrated in FIG. 5 , and the method is executed by the system 1 constructed in accordance with the first, second, third or fourth embodiment.
  • Step 100 Initially the system 1 is flushed. During operation of the second pump 10 , the first pump 9 is switched off and thus blocks flow. The carrier gas 16 is drawn in through the inlet 5 then through the filter 15 into the first conduit 7 .
  • the carrier gas 16 then passes through the measuring chamber 11 and the membrane 13 until it reaches the outlet 6 through the second pump 10 and the second conduit 8 .
  • the carrier gas 16 passes from the inlet 5 through the filter 15 , the second pump 10 , the first conduit 7 , the membrane 13 , and the measuring chamber 11 , to arrive at the upstream end of the second connecting conduit 20 whence it reaches the outlet 6 through the second conduit 8 .
  • the carrier gas 16 traverses the membrane 13 and the measuring chamber 11 whence it reaches the outlet 6 through the second pump 10 and the second conduit 8 .
  • the carrier gas 16 then passes from the inlet 5 via the filter 15 , the second pump 10 , the first conduit 7 , and the membrane 13 to the upstream part of the first connecting conduit 19 and then through the measuring chamber 11 until it reaches the outlet 6 via the second conduit 8 .
  • Step 101 After a predetermined time or in dependence on the measurements of the gas sensor 12 in the measuring chamber 11 the flushing is concluded and the second pump 10 switched off.
  • the parameters determined in the measuring chamber 11 at the cycle's end serve as a starting point or zero point for the further measurements.
  • Step 102 In the enrichment phase the first pump 9 is switched on, as a result of which the carrier gas 16 is recirculated through the system 1 .
  • the second pump 10 remains switched off and now blocks flow.
  • the carrier gas 16 is moved in a closed circuit through the measuring chamber 11 and the membrane 13 . Since the pressure inside the high-voltage apparatus 3 is greater than the pressure in the system 1 , gases 4 pass from the insulating medium 2 through the membrane 13 permeable by gas molecules in one direction into the system 1 . Enrichment of the carrier gas 16 thus takes place.
  • the duration of the enrichment can be determined either by a fixedly preset time or by the measurements of the gas sensor 19 in the measuring chamber 11 .
  • Step 103 After the enrichment phase, the amount and kind of gases 4 in the measuring chamber 11 are determined by the gas sensor 12 . The system 1 is flushed after determination of the gases 4 .
  • the described method can be carried out either continuously or, however, a few times per day.
  • a discontinuous operation of the system 1 can lead to an increase in the service life of the gas sensor 12 used in the measuring chamber 11 .

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Applications Claiming Priority (4)

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DE102013112823 2013-11-20
DE102013112823.8 2013-11-20
DE102013112823.8A DE102013112823B3 (de) 2013-11-20 2013-11-20 Vorrichtung und Verfahren zur Detektion von Gas
PCT/EP2014/074745 WO2015074990A1 (de) 2013-11-20 2014-11-17 Vorrichtung und verfahren zur detektion von gas

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US10132789B2 true US10132789B2 (en) 2018-11-20

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US (1) US10132789B2 (de)
EP (1) EP3071964B1 (de)
JP (1) JP6648018B2 (de)
KR (1) KR102294346B1 (de)
CN (1) CN105849553B (de)
CA (1) CA2930125C (de)
DE (1) DE102013112823B3 (de)
ES (1) ES2791599T3 (de)
MX (1) MX2016006463A (de)
PT (1) PT3071964T (de)
WO (1) WO2015074990A1 (de)

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US11137382B2 (en) 2018-06-15 2021-10-05 Morgan Schaffer Ltd. Apparatus and method for performing gas analysis using optical absorption spectroscopy, such as infrared (IR) and/or UV, and use thereof in apparatus and method for performing dissolved gas analysis (DGA) on a piece of electrical equipment
US11280724B2 (en) 2019-10-08 2022-03-22 Morgan Schaffer Ltd. Apparatus and method for performing calibration of a dissolved gas analysis system using optical absorption spectroscopy and use thereof in an apparatus and method for performing dissolved gas analysis (DGA) on a piece of electrical equipment

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JP5859159B1 (ja) * 2015-06-18 2016-02-10 株式会社ピュアロンジャパン 水素ガス濃度の連続測定方法及びそれに用いる水素ガス濃度測定装置
US10585036B2 (en) 2017-03-13 2020-03-10 Abb Schweiz Ag Dissolved gas analysis devices, systems, and methods
US10586649B2 (en) 2017-03-13 2020-03-10 Abb Schweiz Ag Dissolved gas analysis devices, systems, and methods
CN110770568B (zh) * 2017-03-13 2023-04-04 Abb 瑞士股份有限公司 溶解气体分析装置、系统及方法
JP2019128325A (ja) * 2018-01-26 2019-08-01 日本特殊陶業株式会社 ガスセンサ
DE102018121647A1 (de) * 2018-09-05 2020-03-05 Maschinenfabrik Reinhausen Gmbh Analyse eines in einem isoliermedium eines hochspannungsgeräts gelösten gases
DE102020101132A1 (de) * 2020-01-20 2021-07-22 Maschinenfabrik Reinhausen Gmbh Vorrichtung und Verfahren zur Detektion von Gas
CN113789546B (zh) * 2021-10-14 2024-03-26 中国华能集团清洁能源技术研究院有限公司 一种隔膜完整性测试系统及使用方法
CN116559384A (zh) * 2023-07-10 2023-08-08 华能澜沧江水电股份有限公司 水库环境气体监测装置和水库环境气体监测方法

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CA2930125A1 (en) 2015-05-28
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DE102013112823B3 (de) 2015-03-26

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