TWI830274B - 合成纖維用處理劑及合成纖維 - Google Patents
合成纖維用處理劑及合成纖維 Download PDFInfo
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- TWI830274B TWI830274B TW111125045A TW111125045A TWI830274B TW I830274 B TWI830274 B TW I830274B TW 111125045 A TW111125045 A TW 111125045A TW 111125045 A TW111125045 A TW 111125045A TW I830274 B TWI830274 B TW I830274B
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- Taiwan
- Prior art keywords
- treatment agent
- compound
- synthetic fibers
- mass
- moles
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
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Abstract
本發明課題在於提供:可輕易清洗紡絲步驟時所產生的焦油、能獲得耐起毛性優異之良好紡絲性,且染色性良好、作成為補強線時能獲得良好橡膠接著性的合成纖維用處理劑,以及附著有該合成纖維用處理劑的合成纖維。
本發明的合成纖維用處理劑係含有:平滑劑(A)、離子界面活性劑(B)及非離子界面活性劑(C)的合成纖維用處理劑;其中,上述平滑劑(A)係含有含下述分支酯化合物(A1-1)的酯化合物(A1);上述離子界面活性劑(B)係含有下述羧酸化合物(B1);相對於合成纖維用處理劑的非揮發份,含有上述酯化合物(A1) 15質量%以上,且從二亞磷酸及其鹽中選擇之至少1者的含量係0~0.15質量%之範圍;
分支酯化合物(A1-1):分子中具有分支之鏈狀結構的酯化合物;
羧酸化合物(B1):從分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇之至少1者。
Description
本發明係關於合成纖維用處理劑及合成纖維。詳言之,係關於在合成纖維的製絲步驟中能發揮良好的步驟順暢性與焦油清洗性,且在後加工步驟中具有良好染色性與橡膠接著性的合成纖維用處理劑,以及經附著該合成纖維用處理劑的合成纖維。
近年,在合成纖維的紡絲步驟與加工步驟中,隨著高速化進展,而容易發生起毛、斷紗情形。所以,作為抑制該等情況的合成纖維用處理劑,已提案有:含有在多元醇中加成了聚氧伸烷基之聚醚者(例如專利文獻1、2)、含有具特異結構之有機鋅化合物者(例如、專利文獻3)等。但是,該等習知合成纖維用處理劑中存在有合成纖維用處理劑對纖維間的滲透性不足、在紡絲時與加工時無法充分抑制發生起毛與斷絲的問題。
再者,因為合成纖維用處理劑將曝露於高溫之導絲羅拉的熱中,因而隨長時間操作亦導致在導絲羅拉上成為焦油,絲通過焦油上則導致絲品質降低,更會引發斷絲情形,除了成為生產性降低的原因之外,尚有了清洗囤積的焦油,必需暫時停止生產,而有因清洗焦油所耗時間導致生產性降低的問題。
另一方面,所獲得之合成纖維大多被利用為產業資材,尤其通用為輪胎類、帶類、軟管類等橡膠製品的補強材。該等橡膠製品係藉由對合成纖維製之撚絲以接著劑施行了處理的補強線進行補強,該補強線係為了提升橡膠製品的耐久性,而被要求對橡膠具有充分接著性。為了滿足此項要求,已提案有使用合成纖維用處理劑,含有在多元醇及/或多元羧酸中加成了聚氧伸烷基之化合物者(例如專利文獻4)等。但是,該等習知之對已附著合成纖維用處理劑的合成纖維利用接著劑施行處理過的補強線,仍有橡膠接著性不足的問題。
[先前技術文獻]
[專利文獻]
[專利文獻1]日本專利特開2003-306869號公報
[專利文獻2]日本專利特開2000-273766號公報
[專利文獻3]日本專利特開2013-007141號公報
[專利文獻4]日本專利特開2004-019088號公報
(發明所欲解決之問題)
本發明課題在於提供:可輕易清洗紡絲步驟時所產生的焦油、能獲得耐起毛性優異之良好紡絲性,且染色性良好、作為補強線時能獲得良好之橡膠接著性的合成纖維用處理劑,以及附著有該合成纖維用處理劑的合成纖維。
(解決問題之技術手段)
本案發明人為了解決上述課題經深入鑽研,結果發現,為了提升在紡絲步驟中所產生之焦油的清洗性,獲得耐起毛性優異的良好紡絲性,且能兼顧良好之染色性與橡膠接著性等後加工性,具有特定化學結構的羧酸化合物具有頗大貢獻,遂解決上述課題。
本發明具體主旨係如下事項。
1.一種合成纖維用處理劑,係含有:平滑劑(A)、離子界面活性劑(B)及非離子界面活性劑(C)的合成纖維用處理劑;其中,
上述平滑劑(A)係含有含下述分支酯化合物(A1-1)的酯化合物(A1);
上述離子界面活性劑(B)係含有下述羧酸化合物(B1);
相對於合成纖維用處理劑的非揮發份,含有上述酯化合物(A1) 15質量%以上,且從二亞磷酸及其鹽中選擇之至少1者的含量係0~0.15質量%之範圍;
分支酯化合物(A1-1):分子中具有分支之鏈狀結構的酯化合物;
羧酸化合物(B1):從分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇之至少1者。
2.如1.所記載的合成纖維用處理劑,其中,相對於上述處理劑的非揮發份,含有上述羧酸化合物(B1) 0.01~4質量%。
3.如1.或2.所記載的合成纖維用處理劑,其中,上述分支酯化合物(A1-1)係含有:具有分支之鏈狀結構且碳數3~10之三~六元脂肪族醇、與碳數8~20之一元脂肪酸的完全酯化合物。
4.如1.~3.中任一項所記載的合成纖維用處理劑,其中,上述非離子界面活性劑(C)係更進一步含有從下述脂肪酸衍生物(C1)、及下述醇衍生物(C2)中選擇之至少1者;
脂肪酸衍生物(C1):碳數8~20之一元脂肪酸、與以碳數2~4之環氧烷為構成單元且質量平均分子量200~1000之(聚)烷二醇的酯化合物,以及對碳數8~20之一元脂肪酸每1莫耳依合計1~20莫耳之比例加成了碳數2~4之環氧烷的化合物;
醇衍生物(C2):對碳數8~15之一元脂肪族醇每1莫耳依合計1~50莫耳之比例加成了碳數2~4之環氧烷的化合物。
5.如1.~4.中任一項所記載的合成纖維用處理劑,其中,上述非離子界面活性劑(C)係更進一步含有下述醯胺衍生物(C3);
醯胺衍生物(C3):從下述化合物中選擇之至少1者,即,碳數8~20之一元脂肪酸與二乙醇胺的醯胺化合物、及對碳數8~20之一元脂肪酸與二乙醇胺的醯胺化合物每1莫耳依合計1~10莫耳之比例加成了碳數2~4之環氧烷的化合物。
6.如1.~5.中任一項所記載的合成纖維用處理劑,其中,上述非離子界面活性劑(C)係更進一步含有下述胺衍生物(C4);
胺衍生物(C4):從下述化合物中選擇之至少1者,即,對碳數8~20之一級脂肪族胺每1莫耳,依合計1~20莫耳之比例加成了碳數2~4之環氧烷的化合物。
7.如1.~6.中任一項所記載的合成纖維用處理劑,其中,若將上述平滑劑(A)、上述離子界面活性劑(B)及上述非離子界面活性劑(C)的含有比例之合計設為100質量份,係含有上述平滑劑(A) 15~70質量份、上述離子界面活性劑(B) 0.01~15質量份、及上述非離子界面活性劑(C) 20~80質量份。
8.一種合成纖維,係附著有1.~7.中任一項所記載的合成纖維用處理劑。
(對照先前技術之功效)
本發明的合成纖維用處理劑、附著有該合成纖維用處理劑的合成纖維,在近年進展為高速化的合成纖維之紡絲步驟、加工步驟等製絲步驟中,能發揮良好的步驟順暢性。特別係藉由降低合成纖維絲線的起毛,可發揮良好的步驟順暢性,能獲得優異紡絲性。
再者,在紡絲步驟中所產生焦油的清洗容易,進而可減輕與羅拉間之摩擦阻力。
此外,附著有本發明合成纖維用處理劑的合成纖維,在後加工步驟中可發揮良好的染色性與橡膠接著性。此項效能尤其在安全帶用途、輪胎簾布用途等的後加工步驟相當有效。詳言之,當安全帶等需要染色的情況可提升染色性,當作為使用於輪胎等橡膠製品的補強線時,可發揮提升橡膠接著性的效果,例如可獲得能適用屬於產業用帶之一、傳遞動力的傳動帶(V皮帶)等之補強線。
本發明係關於含有:平滑劑(A),係含有酯化合物(A1),該酯化合物(A1)係含有分子中具分支之鏈狀結構之酯化合物的分支酯化合物(A1-1);離子界面活性劑(B),係含有羧酸化合物(B1),該羧酸化合物(B1)係從分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇至少1者;以及非離子界面活性劑(C);且從二亞磷酸及其鹽中選擇至少1者的含量為0~0.15質量%範圍之合成纖維用處理劑,以及經附著該合成纖維用處理劑的合成纖維。
以下,針對本發明進行詳細說明。
<平滑劑(A)>
本發明的合成纖維用處理劑係含有平滑劑(A)作為必要成分,該平滑劑(A)係以酯化合物(A1)作為必要成分,該酯化合物(A1)係含有屬於分子中具有分支的鏈狀結構的酯化合物的分支酯化合物(A1-1),且相對於本發明合成纖維用處理劑的非揮發份係含有15質量%以上,較佳係含有25質量%以上、更佳係含有35質量%以上;分支酯化合物(A1-1)相對於本發明合成纖維用處理劑的非揮發份,較佳係含有15質量%以上、更佳係含有20質量%以上、特佳係含有30質量%以上。
本發明合成纖維用處理劑的非揮發份係指在培養皿(外徑5cm、高15mm、厚0.6mm)中秤量合成纖維用處理劑1g,以105℃施行2小時熱處理後的殘餘。
上述分支酯化合物(A1-1)係可舉例如:菜籽油、三羥甲基丙烷三油酸酯、甘油三油酸酯、棕櫚油、椰子油、麻油、新戊四醇四辛酸酯等分子中具有分支之鏈狀結構、且源自多元醇的完全酯化合物;三羥甲基丙烷二油酸酯、三羥甲基丙烷單油酸酯等分子中具有分支之鏈狀結構、且源自多元醇的部分酯化合物;硬脂酸異十三烷酯、油酸異十三烷酯、棕櫚酸異辛酯等單酯;己二酸二(異硬脂酯)、癸二酸二(異辛酯)等二酯;硫基二丙酸二(異硬脂酯)、硫基二丙酸二(異鯨蠟酯)等分支含硫酯等之分子中具有分支之鏈狀結構且源自一元醇的酯化合物等。單酯較佳係化學結構的總碳數24~32。若總碳數達24以上,便可抑制紡絲步驟時的發煙,又,若總碳數在32以下便可兼顧平滑性與安定性。多元酯較佳係化學結構的總碳數24~70。若總碳數達24以上,便可抑制紡絲步驟時的發煙,又,若總碳數在70以下,便可兼顧平滑性與安定性。
其中,分支酯化合物(A1-1)較佳係含有:具有分支之鏈狀結構且碳數3~10之三~六元脂肪族醇、與碳數8~20之一元脂肪酸的完全酯化合物。
再者,分支酯化合物(A1-1)較佳係具有分支之鏈狀結構且碳數3~6之三或四元脂肪族醇、與碳數8~20之一元脂肪酸的完全酯化合物,具體係可舉例如與甘油、三羥甲基丙烷、新戊四醇的完全酯化合物等。
分支酯化合物(A1-1)以外的酯化合物(A1)係可舉例如:油酸十二烷酯、棕櫚酸十二烷酯等單酯;己二酸二辛酯、癸二酸二辛酯等二酯等具有直鏈結構且源自一元醇的酯化合物;丁二醇二油酸酯等具有直鏈結構且源自二元醇的完全酯化合物等。
另外,本發明的酯化合物(A1)並未含有化學結構中含(聚)氧伸烷基的酯化合物。
本發明的合成纖維用處理劑係在不致妨礙本發明效果之範圍內,除了含有上述分支酯化合物(A1-1)的酯化合物(A1)之外,亦可併用合成纖維用處理劑所採用的公知平滑劑。公知平滑劑的具體例係可舉例如:芳香族系烴、石蠟系烴、萘系烴、礦物油等。作為稀釋劑所通用的低黏度烴(<2mm
2/s、40℃)並未涵括於公知平滑劑中。
<離子界面活性劑(B)>
本發明合成纖維用處理劑係含有離子界面活性劑(B)作為必要成分,該離子界面活性劑(B)係含有羧酸化合物(B1),而該羧酸化合物(B1)係從分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇至少1者。其中,羧酸化合物(B1)較佳係從分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇至少1者,更佳係分子中具有碳數10~20之醯基,特佳係分子中具有碳數12~18之醯基。進而最佳係分子中具有碳數8~18之醯基的N-甲基甘胺酸衍生物。
具體係可舉例如:N-甲基甘胺酸、N-苄基-N-甲基甘胺酸、N,N-二甲基甘胺酸、N-甲基-N-乙基甘胺酸、N-甲基-N-椰子油脂甘胺酸、N-甲基-N-月桂醯基甘胺酸、N-甲基-N-癸醯基甘胺酸、N-甲基-N-油醯基甘胺酸、N-甲基-N-椰子油脂丙胺酸、N-甲基-N-月桂醯基丙胺酸、N-甲基-N-肉豆蔻醯基丙胺酸,其中,較佳係可舉例如:N-甲基-N-椰子油脂甘胺酸、N-甲基-N-月桂醯基甘胺酸、N-甲基-N-癸醯基甘胺酸、N-甲基-N-油醯基甘胺酸、N-甲基-N-椰子油脂丙胺酸、N-甲基-N-月桂醯基丙胺酸。
(B1)可為未中和者、亦可為經中和的鹽。可將未中和物在合成纖維用處理劑中施行中和,亦可經中和處理後才提供給合成纖維用處理劑。相對離子係可舉例如:鉀鹽、鈉鹽等鹼金屬鹽;銨鹽;(聚)氧伸烷基烷胺、三乙醇胺等烷醇胺鹽;鏻鹽等。其中,較佳為鹼金屬鹽或烷醇胺鹽。
本發明的合成纖維用處理劑中,從上述分子中具碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇至少1者的羧酸化合物(B1),係相對於合成纖維用處理劑的非揮發份,含有0.01~4質量%、更佳係含有0.05~3質量%、特佳係含有0.1~2質量%。
本發明的合成纖維用處理劑係在不致妨礙本發明效果之範圍內,除了從上述分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇至少1者的羧酸化合物(B1)之外,亦可併用合成纖維用處理劑所採用的公知離子界面活性劑。具體的離子界面活性劑係可舉例如:陰離子界面活性劑、陽離子界面活性劑、兩性界面活性劑。
陰離子界面活性劑的具體例係可舉例如:(1)月桂基磺酸鹽、肉荳蔻基磺酸鹽、鯨蠟基磺酸鹽、油基磺酸鹽、硬脂基磺酸鹽、十四烷基磺酸鹽、α-烯烴磺酸鹽、十二烷基苯磺酸鹽、二級烷基磺酸鹽等脂肪族磺酸鹽或芳香族磺酸鹽;(2)月桂基硫酸酯鹽、油基硫酸酯鹽、硫酸硬脂酯鹽等脂肪族醇的硫酸酯鹽;(3)聚氧乙烯月桂醚硫酸酯鹽、聚氧伸烷基(聚氧乙烯、聚氧丙烯)月桂醚硫酸酯鹽、聚氧乙烯油醚硫酸酯鹽等對脂肪族醇中加成了從環氧乙烷(EO)與環氧丙烷(PO)中選擇至少一種環氧烷的硫酸酯鹽;(4)篦麻油脂肪酸硫酸酯鹽、麻油脂肪酸硫酸酯鹽、松脂油脂肪酸硫酸酯鹽、大豆油脂肪酸硫酸酯鹽、菜籽油脂肪酸硫酸酯鹽、棕櫚油脂肪酸硫酸酯鹽、豬油脂肪酸硫酸酯鹽、鯨油脂肪酸硫酸酯鹽等脂肪酸的硫酸酯鹽;(5)篦麻油的硫酸酯鹽、麻油的硫酸酯鹽、松脂油的硫酸酯鹽、大豆油的硫酸酯鹽、菜籽油的硫酸酯鹽、棕櫚油的硫酸酯鹽、豬油的硫酸酯鹽、鯨油的硫酸酯鹽等油脂的硫酸酯鹽;(6)月桂酸鹽、油酸鹽、硬脂酸鹽、十二碳烯琥珀酸鹽等脂肪酸鹽;(7)二辛基磺琥珀酸鹽等脂肪族醇的磺琥珀酸酯鹽;(8)月桂基磷酸酯鹽、磷酸異鯨蠟酯鹽、磷酸油酯鹽、聚氧乙烯油醚的磷酸酯鹽等磷酸酯鹽等。陰離子界面活性劑係可為未中和、亦可為經中和的鹽。陰離子界面活性劑的相對離子係可舉例如:鉀鹽、鈉鹽等鹼金屬鹽;銨鹽、三乙醇胺等烷醇胺鹽等等。
陽離子界面活性劑的具體例,係可舉例如:氯化月桂基三甲銨、氯化鯨蠟基三甲銨、氯化硬脂基三甲銨、氯化廿二烷基三甲銨、氯化二癸基二甲銨等。
兩性界面活性劑的具體例係可舉例如:甜菜型兩性界面活性劑等。
<非離子界面活性劑(C)>
本發明的合成纖維用處理劑係含有非離子界面活性劑(C)作為必要成分。本發明中,在化學結構中含有(聚)氧伸烷基的酯化合物係涵括於非離子界面活性劑(C)中。其中,較佳係含有從脂肪酸衍生物(C1)與醇衍生物(C2)中選擇至少1種;該脂肪酸衍生物(C1)係碳數8~20之一元脂肪酸、與以碳數2~4之環氧烷為構成單元且質量平均分子量200~1000之(聚)烷二醇的酯化合物,以及對碳數8~20之一元脂肪酸每1莫耳依合計1~20莫耳之比例加成了碳數2~4之環氧烷的化合物;該醇衍生物(C2)係對碳數8~15之一元脂肪族醇每1莫耳,依合計1~50莫耳之比例加成了碳數2~4之環氧烷的化合物。
本發明的合成纖維用處理劑中,非離子界面活性劑(C)較佳係更進一步含有醯胺衍生物(C3);該醯胺衍生物(C3)係從下述化合物中選擇之至少1者:碳數8~20之一元脂肪酸與二乙醇胺的醯胺化合物,及對碳數8~20之一元脂肪酸與二乙醇胺的醯胺化合物每1莫耳依合計1~10莫耳之比例加成了碳數2~4之環氧烷的化合物。
本發明的合成纖維用處理劑中,非離子界面活性劑(C)較佳係更進一步含有胺衍生物(C4);該胺衍生物(C4)係從下述化合物中選擇之至少1者:對碳數8~20之一級脂肪族胺每1莫耳,依合計1~20莫耳之比例加成了碳數2~4之環氧烷的化合物。
另外,本發明的非離子界面活性劑(C)係並不包括公知非離子界面活性劑中屬於本發明之酯化合物(A1)者。
<脂肪酸衍生物(C1)>
本發明的脂肪酸衍生物(C1)係碳數8~20之一元脂肪酸、與以碳數2~4之環氧烷為構成單元且質量平均分子量200~1000的(聚)烷二醇之酯化合物,以及碳數8~20之一元脂肪酸每1莫耳依合計1~20莫耳之比例加成了碳數2~4之環氧烷的化合物。
上述脂肪酸衍生物(C1)中,碳數8~20之一元脂肪酸中,較佳係碳數10~20之一元脂肪酸、更佳係碳數12~18之一元脂肪酸。一元脂肪酸係可為飽和脂肪酸、亦可為不飽和脂肪酸,具體係可舉例如:辛酸(碳數:8)、癸酸(碳數:10)、月桂酸(碳數:12)、肉荳蔻酸(碳數:14)、肉豆蔻油酸(myristoleic acid)(碳數:14)、棕櫚酸(碳數:16)、棕櫚油酸(碳數:16)、硬脂酸(碳數:18)、油酸(碳數:18)、亞麻油酸(碳數:18)、次亞麻油酸(碳數:18)、花生酸(碳數:20)等。
上述脂肪酸衍生物(C1)中,以碳數2~4之環氧烷為構成單元的(聚)烷二醇,較佳係以環氧乙烷為構成單元的聚乙二醇,且質量平均分子量較佳係400~800。
本發明的脂肪酸衍生物(C1)具體係可舉例如:對月桂酸1莫耳加成了5莫耳EO者、對月桂酸1莫耳加成了10莫耳EO者、對棕櫚酸1莫耳加成了5莫耳EO者、對棕櫚酸1莫耳加成了10莫耳EO者、對硬脂酸1莫耳加成了5莫耳EO者、對異硬脂酸1莫耳加成了10莫耳EO者、對油酸1莫耳加成了10莫耳EO者、對油酸1莫耳加成了5莫耳PO與5莫耳EO者、對聚乙二醇(平均分子量200)1莫耳經利用2莫耳油酸施行了酯化者、對聚乙二醇(平均分子量400)1莫耳經利用2莫耳油酸施行了酯化者、對聚乙二醇(平均分子量200)1莫耳經利用2莫耳椰子油脂肪酸施行了酯化者、對聚乙二醇(平均分子量600)1莫耳經利用2莫耳油酸施行了酯化者、對聚乙二醇(平均分子量400)1莫耳經利用2莫耳月桂酸施行了酯化者、對聚乙二醇(平均分子量600)1莫耳經利用1.5莫耳棕櫚油脂肪酸施行了酯化者。其中,較佳係對油酸1莫耳加成了10莫耳EO者、對聚乙二醇(平均分子量600)1莫耳經利用2莫耳油酸施行了酯化者、對聚乙二醇(平均分子量400)1莫耳經利用2莫耳月桂酸施行了酯化者、對聚乙二醇(平均分子量600)1莫耳經利用1.5莫耳棕櫚油脂肪酸施行了酯化者。
本發明中,化合物名稱末端標有EO與PO者,分別係指環氧乙烷及環氧丙烷的加成物,在其後面標註的數字係表示平均加成莫耳數。
本發明的質量平均分子量與平均分子量係表示進行凝膠滲透色層分析且標準物質設為聚乙二醇時的質量平均分子量。
<醇衍生物(C2)>
本發明的醇衍生物(C2)係對碳數8~15之一元脂肪族醇每1莫耳,依合計1~50莫耳之比例加成了碳數2~4之環氧烷的化合物。
上述醇衍生物(C2)中,碳數8~15之一元脂肪族醇中,較佳係碳數9~14之一元脂肪族醇、更佳係碳數10~13之一元脂肪族醇。脂肪族醇係可為直鏈結構、亦可為分支結構,但從合成纖維用處理劑的安定性觀點,較佳係具有分支結構者。又,脂肪族醇係可為飽和醇、亦可為不飽和醇,較佳係飽和醇。脂肪族醇係可舉例如:辛醇、異辛醇、壬醇、異壬醇、癸醇、異癸醇、十一醇、異十一醇、十二醇、異十二醇、十三醇、異十三醇、十四醇、異十四醇、十五烷基醇、異十五醇。醇衍生物(C2)係可舉例如:環氧乙烷加成物、環氧丙烷加成物、環氧丁烷加成物、環氧乙烷與環氧丙烷的無規加成物、環氧乙烷與環氧丁烷的嵌段加成物、環氧乙烷與環氧丙烷的嵌段加成物等。其中,較佳係化學結構中含有氧伸丙基的醇衍生物。
本發明的醇衍生物(C2),具體係可舉例如:對2-乙基己醇1莫耳無規加成了4莫耳EO與8莫耳PO者、對辛醇1莫耳無規加成了5莫耳EO與5莫耳PO者、在對癸醇1莫耳無規加成了5莫耳PO者中再加成了5莫耳EO者、對異十二醇加成了5莫耳EO者、對異十三醇無規加成了10莫耳EO與10莫耳PO者、在對異十三醇1莫耳加成了10莫耳PO者中再加成了10莫耳EO者、對十四醇加成了10莫耳EO者等。其中,較佳係對異十二醇1莫耳無規加成了10莫耳EO與10莫耳PO者、在對異十三醇1莫耳加成了10莫耳PO者中再加成了10莫耳EO者、對2-乙基己醇1莫耳無規加成了4莫耳EO與8莫耳PO者。
<醯胺衍生物(C3)>
本發明的醯胺衍生物(C3)係從下述化合物中選擇之至少1者:碳數8~20之一元脂肪酸與二乙醇胺的醯胺化合物,以及對碳數8~20之一元脂肪酸與二乙醇胺的醯胺化合物每1莫耳依合計1~10莫耳之比例加成了碳數2~4之環氧烷的化合物。
上述醯胺衍生物(C3)的碳數8~20之一元脂肪酸中,較佳係碳數10~20之一元脂肪酸、更佳係碳數12~18之一元脂肪酸。一元脂肪酸係可為飽和脂肪酸、亦可為不飽和脂肪酸,可舉例與脂肪酸衍生物(C1)所使用者相同物。碳數2~4之環氧烷中,較佳係環氧乙烷,且加成數較佳係2~8莫耳。
本發明醯胺衍生物(C3)所包含的化合物,具體係可舉例如:月桂酸二乙醇醯胺、肉荳蔻酸二乙醇醯胺、棕櫚酸二乙醇醯胺、硬脂酸二乙醇醯胺、油酸二乙醇醯胺、椰油脂肪酸二乙醇醯胺、棕櫚仁油脂肪酸二乙醇醯胺、菜籽油脂肪酸二乙醇醯胺、對月桂酸二乙醇醯胺1莫耳加成了3莫耳EO者、對油酸二乙醇醯胺1莫耳加成了3莫耳EO者、對椰油脂肪酸二乙醇醯胺1莫耳加成了5莫耳EO者。
<胺衍生物(C4)>
本發明的胺衍生物(C4)係從下述化合物中選擇之至少1者:對碳數8~20之一級脂肪族胺每1莫耳,依合計1~20莫耳之比例加成了碳數2~4之環氧烷的化合物。
上述胺衍生物(C4)中,碳數8~20之一級脂肪族胺中,較佳係碳數10~18之一級脂肪族胺、更佳係碳數12~18之一級脂肪族胺。一級脂肪族胺的烷基部分係可為飽和結構、亦可為不飽和結構。可舉例如:辛胺、癸胺、月桂胺、肉荳蔻胺、肉豆蔻醯基胺、棕櫚胺、棕櫚油基胺、硬脂胺、油胺,亦可舉例如屬於該等混合物的椰油胺(coconut amine)等。碳數2~4之環氧烷中較佳係環氧乙烷。胺衍生物係亦可為具有1個(聚)氧伸烷基的二級胺化合物、或具有2個(聚)氧伸烷基的三級胺化合物,該(聚)氧伸烷基係由在具1個烴基的一級胺上加成碳數2~4之環氧烷而形成者。
本發明的胺衍生物(C4)所含化合物,具體係可舉例如:對月桂胺1莫耳加成了3莫耳EO者、對肉荳蔻胺1莫耳加成了5莫耳EO者、對棕櫚胺1莫耳加成了8莫耳EO者、對硬脂胺1莫耳加成了10莫耳EO者、對油胺1莫耳加成了15莫耳EO者、對硬脂胺與棕櫚胺的混合物1莫耳加成了10莫耳EO者、對椰油胺1莫耳加成了5莫耳EO者。
本發明的合成纖維用處理劑係在不致妨礙本發明效果之範圍內,除了上述脂肪酸衍生物(C1)、醇衍生物(C2)、醯胺衍生物(C3)、及胺衍生物(C4)之外,亦可併用合成纖維用處理劑所採用的公知非離子界面活性劑。具體例係可舉例如:未與(C1)~(C4)重複範圍的脂肪酸衍生物、醇衍生物、醯胺衍生物、胺衍生物;對羧酸與多元醇的酯化合物加成了環氧烷之醚・酯化合物;對芳香族醇加成了環氧烷的化合物;烷氧基聚烷二醇與脂肪酸的酯;多元醇與脂肪酸的直鏈結構部分酯化合物;山梨糖醇酐等具有碳數3~6之環狀結構的多元醇、與脂肪酸之部分酯化合物等;亦可併用例如:硬化篦麻油的環氧烷加成物、壬基酚的環氧烷加成物、聚氧乙烯甲醚油酸酯、甘油單油酸酯、山梨糖醇酐單油酸酯、山梨糖醇酐三油酸酯、山梨糖醇酐單硬脂酸酯、山梨糖醇酐三硬脂酸酯等。
本發明的合成纖維用處理劑係含有平滑劑、離子界面活性劑及非離子界面活性劑,從二亞磷酸及其鹽中選擇至少1者的含量,相對於合成纖維用處理劑的非揮發份係設為0~0.15質量%範圍。上限值較佳係0.1質量%以下,更佳係0.05質量%以下。
形成鹽的相對離子係可舉例如:鈉、鉀、鈣、鎂、銅、鎳、鐵、胺化合物等。
二亞磷酸及其鹽係有混入於合成纖維用處理劑之製造時所使用之觸媒或抗著色劑中的可能性,該等最好利用公知精製方法從合成纖維用處理劑中除去。二亞磷酸及其鹽係使焦油清洗性惡化,且導致所製造之合成纖維的起毛數增加之物質,但本發明的合成纖維用處理劑中,若二亞磷酸及其鹽的含量在0.15質量%以下範圍內,則不致特別妨礙本發明效果。
<摻合比率>
本發明的合成纖維用處理劑中,若將必要成分的平滑劑(A)、離子界面活性劑(B)及非離子界面活性劑(C)之含有比例合計設為100質量份,則平滑劑(A)係含有15~70質量份、較佳係25~70質量份、更佳係35~65質量份,離子界面活性劑(B)係含有0.01~15質量份、較佳係0.1~12質量份、更佳係0.5~10質量份,非離子界面活性劑(C)係含有20~80質量份、較佳係25~75質量份、更佳係30~70質量份。
<其他成分>
本發明的合成纖維用處理劑係可併用其他成分,例如:消泡劑、抗氧化劑、防腐劑、防鏽劑等。其他成分的併用量係可規定於不致損及本發明效果的範圍內。
<合成纖維>
本發明的合成纖維係附著有本發明合成纖維用處理劑的合成纖維。使本發明合成纖維用處理劑附著的合成纖維並無特別的限制,可舉例如:聚對苯二甲酸乙二酯、聚對苯二甲酸丙二酯、聚乳酸酯等聚酯系纖維;尼龍6、尼龍66等聚醯胺系纖維;聚乙烯、聚丙烯等聚烯烴系纖維等。該等之中,較佳係使用聚酯系纖維、聚醯胺系纖維。使本發明合成纖維用處理劑附著的合成纖維係可依延伸絲或半延伸絲之形式獲得。其中,本發明的合成纖維用處理劑較適合用於延伸絲製造。
使本發明合成纖維用處理劑(未包含溶劑)附著於合成纖維上的比例,並無特別的限制,較佳係使本發明合成纖維用處理劑相對於合成纖維成為0.1~3質量%的比例附著。
再者,使本發明合成纖維用處理劑附著的步驟係可舉例如:紡絲步驟、延伸步驟、同時執行紡絲與延伸的步驟。又,使本發明合成纖維用處理劑附著的方法係可適當採用公知方法,可舉例如:羅拉供油法、使用計量泵的導件供油法、浸漬供油法、噴霧供油法等。使本發明合成纖維用處理劑附著於合成纖維時,處理劑的形態係可舉例如使用稀釋劑的有機溶劑溶液、水性液、單劑等。此時所使用的稀釋劑係可舉例如:水、低黏度烴(<2mm
2/s、40℃)、有機溶劑(丙酮、氯仿、甲醇、異丙醇等)、以及該等的混合物,從經濟性、附著性的觀點,較佳係水或低黏度烴。
[實施例]
以下,列舉實施例針對本發明進行說明,惟,本發明的技術範圍並不僅侷限於該等。另外,以下的實施例及比較例中,「份」係指質量份,「%」係指質量%。
<合成纖維用處理劑之調製>
•實施例1
將下述者依比例進行均勻混合而調製得實施例1的處理劑:作為平滑劑(A),屬於分支酯化合物(A1-1)之菜籽油(A1-1-1)40%及硫基二丙酸二(異硬脂酯)(A1-1-3)4%;作為離子界面活性劑(B),屬於羧酸化合物(B1)之N-甲基-N-月桂醯基甘胺酸/鈉鹽(B1-2)1%、屬於其他離子界面活性劑之二級烷烴磺酸鈉鹽(碳數:11~14)(B2-1)1%;作為非離子界面活性劑(C),屬於脂肪酸衍生物(C1)之對油酸1莫耳加成了10莫耳EO者(C1-1)10%,屬於醇衍生物(C2)之對異十二醇1莫耳無規加成了10莫耳EO與10莫耳PO者(C2-1)10%,屬於醯胺衍生物(C3)之對油酸二乙醇醯胺1莫耳加成了3莫耳EO者(C3-1)3%,屬於胺衍生物(C4)之對油胺、硬脂胺及棕櫚胺的混合物1莫耳加成了10莫耳EO者(C4-1)2%,屬於其他非離子界面活性劑之對硬化篦麻油1莫耳加成了10莫耳EO者(C5-1)10%、對篦麻油1莫耳加成了20莫耳EO者再經利用2莫耳油酸施行了酯化的化合物(C5-5)10%、山梨糖醇酐單油酸酯(C5-7)8%;以及作為其他成分,聚醚改質聚矽氧(X-1)0.3%、乙二醇(X-3)0.7%。
・實施例16
將下述者依比例進行均勻混合而調製得實施例16的處理劑:作為平滑劑(A),屬於分支酯化合物(A1-1)之三羥甲基丙烷三油酸酯(A1-1-2)25%;作為離子界面活性劑(B),屬於羧酸化合物(B1)之N-甲基-N-月桂醯基甘胺酸/鈉鹽(B1-2)1.4%,屬於其他離子界面活性劑之二辛基磺琥珀酸鈉鹽(B2-2)1%及油醇-環氧乙烷5莫耳加成物的磷酸酯(B2-5)0.6%;作為非離子界面活性劑(C),屬於脂肪酸衍生物(C1)之對聚乙二醇(平均分子量600)1莫耳利用棕櫚油脂肪酸1.5莫耳施行了酯化者(C1-4)10%,屬於醇衍生物(C2)之對異十二醇1莫耳無規加成了10莫耳EO與10莫耳PO者(C2-1)10%,以及對異十三醇1莫耳加成了10莫耳PO者再加成10莫耳EO者(C2-2)20%,屬於醯胺衍生物(C3)之油酸二乙醇醯胺(C3-3)1%,屬於胺衍生物(C4)之對油胺、硬脂胺及棕櫚胺的混合物1莫耳加成了10莫耳EO者(C4-1)1%,屬於其他非離子界面活性劑之對硬化篦麻油1莫耳加成了20莫耳EO者再經利用油酸3莫耳施行了酯化的化合物(C5-2)14.99%、及山梨糖醇酐單油酸酯(C5-7)15%、二亞磷酸(市售試劑、50質量%水溶液)以純份計0.01%。
・實施例2~15、17~33及比較例1~8
實施例2~15、17~33及比較例1~8的合成纖維用處理劑係依下述表1、2所示配方,依照與上述實施例1、16之調製方法同樣地進行調製。
[表1]
區分 | 平滑劑(A) | 離子界面活性劑(B) | 非離子界面活性劑(C) | 二亞磷酸 | 其他成分 | ||||||||||||||||||
酯化合物(A1) | 其他平滑劑 | 羧酸化合物(B1) | 其他離子界面活性劑 | 脂肪酸衍生物(C1) | 醇衍生物(C2) | 醯胺衍生物(C3) | 胺衍生物(C4) | 其他非離子界面活性劑 | |||||||||||||||
分岐酯化合物(A1-1) | 其他酯化合物 | ||||||||||||||||||||||
種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 比率 (質量%) | 種類 | 比率 (質量%) | |
實施例1 | A1-1-1 | 40 | - | - | - | - | B1-2 | 1 | B2-1 | 1 | C1-1 | 10 | C2-1 | 10 | C3-1 | 3 | C4-1 | 2 | C5-1 | 10 | - | X-1 | 0.3 |
A1-1-3 | 4 | C5-5 | 10 | X-3 | 0.7 | ||||||||||||||||||
C5-7 | 8 | ||||||||||||||||||||||
實施例2 | A1-1-2 | 30 | - | - | - | - | B1-1 | 0.5 | B2-2 | 0.5 | C1-1 | 5 | - | - | C3-2 | 1 | C4-2 | 3 | C5-2 | 10 | - | X-2 | 0.5 |
A1-1-4 | 10 | B2-7 | 0.5 | C1-2 | 9 | C5-5 | 10 | ||||||||||||||||
A1-1-5 | 20 | ||||||||||||||||||||||
實施例3 | A1-1-2 | 25 | - | - | - | - | B1-2 | 1.4 | B2-2 | 1 | C1-4 | 10 | C2-1 | 10 | C3-3 | 1 | C4-1 | 1 | C5-2 | 15 | - | - | - |
B2-5 | 0.6 | C2-2 | 20 | C5-7 | 15 | ||||||||||||||||||
實施例4 | A1-1-2 | 20 | A1-2-2 | 10 | - | - | B1-3 | 3.8 | - | - | - | - | C2-2 | 10 | C3-1 | 5 | C4-2 | 2 | C5-4 | 5 | - | X-5 | 0.2 |
A1-1-6 | 20 | C5-5 | 14 | ||||||||||||||||||||
C5-7 | 5 | ||||||||||||||||||||||
C5-8 | 5 | ||||||||||||||||||||||
實施例5 | A1-1-1 | 20 | - | - | - | - | B1-4 | 2.5 | B2-4 | 0.2 | C1-2 | 17 | C2-2 | 5 | C3-2 | 1 | C4-1 | 2.5 | C5-1 | 10 | - | X-4 | 0.3 |
A1-1-2 | 25 | B2-7 | 1.2 | C5-2 | 10 | X-7 | 0.3 | ||||||||||||||||
C5-3 | 5 | ||||||||||||||||||||||
實施例6 | A1-1-1 | 15 | - | - | - | - | B1-5 | 0.8 | B2-4 | 0.1 | C1-1 | 13 | C2-2 | 15 | C3-3 | 2 | C4-1 | 1 | C5-9 | 3 | - | X-6 | 0.1 |
A1-1-2 | 30 | C1-2 | 10 | ||||||||||||||||||||
C1-3 | 10 | ||||||||||||||||||||||
實施例7 | A1-1-1 | 35 | - | - | - | - | B1-3 | 1 | - | - | C1-1 | 10 | C2-3 | 15 | C3-2 | 2 | C4-2 | 1 | C5-7 | 5 | - | X-7 | 1 |
A1-1-2 | 15 | C1-2 | 15 | ||||||||||||||||||||
實施例8 | A1-1-1 | 10 | A1-2-3 | 20 | - | - | B1-1 | 2 | B2-3 | 1 | C1-2 | 10 | C2-1 | 5 | C3-1 | 1 | C4-2 | 5 | C5-3 | 3 | - | X-1 | 1 |
A1-1-2 | 20 | B2-6 | 2 | C5-6 | 15 | ||||||||||||||||||
A1-1-3 | 5 | ||||||||||||||||||||||
實施例9 | A1-1-1 | 10 | - | - | - | - | B1-2 | 0.7 | B2-4 | 0.2 | C1-1 | 15 | C2-1 | 10 | C3-3 | 1 | C4-1 | 1 | - | - | - | X-2 | 0.5 |
A1-1-2 | 30 | B2-7 | 1 | C1-2 | 20 | C2-2 | 10 | X-4 | 0.5 | ||||||||||||||
B2-8 | 0.1 | ||||||||||||||||||||||
實施例10 | A1-1-1 | 10 | - | - | - | - | B1-3 | 2.5 | B2-2 | 0.5 | C1-1 | 5 | C2-2 | 5 | C3-1 | 0.5 | C4-1 | 1 | C5-3 | 5 | - | X-4 | 1.5 |
A1-1-2 | 40 | B2-7 | 1 | C5-4 | 10 | ||||||||||||||||||
A1-1-3 | 10 | C5-5 | 5 | ||||||||||||||||||||
C5-6 | 3 | ||||||||||||||||||||||
實施例11 | A1-1-2 | 35 | - | - | - | - | B1-4 | 1.3 | B2-2 | 0.5 | C1-3 | 4 | C2-1 | 10 | C3-2 | 1 | C4-2 | 1 | C5-2 | 5 | - | X-1 | 0.2 |
A1-1-5 | 20 | B2-3 | 0.5 | C2-3 | 20 | X-3 | 1 | ||||||||||||||||
B2-7 | 0.5 | ||||||||||||||||||||||
實施例12 | A1-1-1 | 10 | - | - | A2-1 | 10 | B1-5 | 1 | - | - | C1-1 | 15 | C2-2 | 5 | C3-3 | 2 | C4-2 | 1 | C5-7 | 5 | - | - | - |
A1-1-2 | 35 | C5-9 | 15 | ||||||||||||||||||||
A1-1-9 | 1 | ||||||||||||||||||||||
實施例13 | A1-1-1 | 5 | - | - | - | - | B1-2 | 0.5 | B2-2 | 0.5 | C1-2 | 5 | C2-2 | 5 | C3-1 | 0.5 | C4-1 | 1.5 | C5-2 | 7 | - | X-1 | 0.5 |
A1-1-2 | 45 | B2-4 | 0.5 | C5-3 | 5 | X-2 | 0.5 | ||||||||||||||||
A1-1-4 | 5 | B2-6 | 0.5 | C5-4 | 15 | X-6 | 1 | ||||||||||||||||
C5-9 | 2 | ||||||||||||||||||||||
實施例14 | A1-1-2 | 55 | - | - | - | - | B1-3 | 1 | - | - | C1-1 | 5 | - | - | C3-3 | 1 | C4-2 | 1 | C5-3 | 5 | - | X-5 | 2 |
A1-1-3 | 3 | C5-4 | 10 | ||||||||||||||||||||
A1-1-5 | 5 | C5-5 | 10 | ||||||||||||||||||||
A1-1-9 | 2 | ||||||||||||||||||||||
實施例15 | A1-1-2 | 50 | - | - | - | - | B1-4 | 2 | B2-1 | 0.3 | C1-1 | 6 | C2-1 | 4 | C3-2 | 1 | C4-2 | 2 | C5-3 | 5 | - | X-3 | 1 |
A1-1-3 | 3 | B2-3 | 0.6 | C5-5 | 20 | ||||||||||||||||||
A1-1-9 | 3 | B2-7 | 2 | ||||||||||||||||||||
B2-8 | 0.1 | ||||||||||||||||||||||
實施例16 | A1-1-2 | 25 | - | - | - | - | B1-2 | 1.4 | B2-2 | 1 | C1-4 | 10 | C2-1 | 10 | C3-3 | 1 | C4-1 | 1 | C5-2 | 14.99 | 0.01 | - | - |
B2-5 | 0.6 | C2-2 | 20 | C5-7 | 15 | ||||||||||||||||||
實施例17 | A1-1-2 | 25 | - | - | - | - | B1-2 | 1.4 | B2-2 | 1 | C1-4 | 10 | C2-1 | 10 | C3-3 | 1 | C4-1 | 1 | C5-2 | 14.98 | 0.02 | - | - |
B2-5 | 0.6 | C2-2 | 20 | C5-7 | 15 | ||||||||||||||||||
實施例18 | A1-1-2 | 50 | - | - | - | - | B1-1 | 0.5 | B2-3 | 0.5 | - | - | - | - | C3-3 | 2 | C4-1 | 1 | C5-1 | 10 | - | X-3 | 0.5 |
A1-1-3 | 3 | B2-6 | 0.5 | C5-2 | 10 | ||||||||||||||||||
A1-1-5 | 10 | C5-5 | 2 | ||||||||||||||||||||
C5-9 | 10 | ||||||||||||||||||||||
實施例19 | A1-1-1 | 30 | A1-2-1 | 15 | - | - | B1-5 | 2 | B2-1 | 2 | C1-1 | 5 | C2-2 | 5 | C3-2 | 1 | C4-2 | 1 | C5-3 | 5 | - | X-1 | 1 |
A1-1-7 | 15 | B2-7 | 3 | C1-2 | 10 | C5-7 | 3 | ||||||||||||||||
C5-8 | 2 | ||||||||||||||||||||||
實施例20 | A1-1-1 | 20 | - | - | - | - | B1-6 | 1.5 | - | - | C1-1 | 10 | - | - | C3-1 | 2 | C4-2 | 3 | C5-1 | 10 | - | X-2 | 0.5 |
A1-1-2 | 30 | C5-2 | 10 | ||||||||||||||||||||
A1-1-3 | 10 | C5-7 | 3 | ||||||||||||||||||||
實施例21 | A1-1-1 | 20 | - | - | - | - | B1-5 | 5 | B2-1 | 2 | C1-1 | 10 | C2-1 | 5 | C3-3 | 1 | C4-1 | 2 | C5-1 | 5 | - | X-2 | 0.95 |
A1-1-2 | 30 | B2-2 | 0.3 | C5-2 | 10 | X-3 | 1 | ||||||||||||||||
A1-1-3 | 3 | B2-4 | 0.05 | C5-7 | 4 | X-5 | 0.7 | ||||||||||||||||
實施例22 | A1-1-6 | 30 | A1-2-1 | 15 | - | - | B1-2 | 1 | B2-1 | 2 | C1-2 | 10 | C2-2 | 5 | C3-2 | 1 | C4-2 | 2 | C5-2 | 5 | - | X-4 | 2 |
A1-1-7 | 15 | B2-4 | 1 | C2-3 | 5 | C5-7 | 2 | ||||||||||||||||
B2-5 | 2 | C5-8 | 2 | ||||||||||||||||||||
實施例23 | A1-1-6 | 15 | A1-2-2 | 10 | - | - | B1-5 | 4 | B2-4 | 2 | C1-1 | 10 | C2-1 | 5 | C3-1 | 1 | C4-2 | 4 | C5-2 | 5 | - | - | - |
A1-1-8 | 30 | B2-7 | 5 | C2-3 | 7 | C5-7 | 2 | ||||||||||||||||
實施例24 | A1-1-7 | 30 | - | - | - | - | B1-4 | 0.2 | B2-1 | 1 | C1-2 | 20 | C2-1 | 12 | C3-1 | 2 | C4-1 | 2 | C5-1 | 10 | - | X-1 | 1 |
B2-2 | 0.8 | C2-3 | 10 | C5-9 | 10 | ||||||||||||||||||
B2-6 | 1 | ||||||||||||||||||||||
實施例25 | A1-1-7 | 10 | A1-2-1 | 10 | A2-1 | 20 | B1-4 | 0.2 | B2-1 | 1.4 | C1-3 | 10 | C2-2 | 16 | C3-1 | 2 | C4-1 | 2 | C5-1 | 10 | - | X-6 | 1 |
B2-4 | 0.4 | C2-3 | 16 | ||||||||||||||||||||
B2-5 | 1 | ||||||||||||||||||||||
實施例26 | A1-1-2 | 20 | A1-2-2 | 10 | - | - | B1-3 | 3.8 | - | - | - | - | C2-4 | 10 | C3-1 | 5 | C4-2 | 2 | C5-4 | 5 | - | X-5 | 0.2 |
A1-1-6 | 20 | C5-5 | 14 | ||||||||||||||||||||
C5-7 | 5 | ||||||||||||||||||||||
C5-8 | 5 | ||||||||||||||||||||||
實施例27 | A1-1-2 | 20 | A1-2-2 | 10 | - | - | B1-3 | 3.8 | - | - | - | - | C2-5 | 10 | C3-1 | 5 | C4-2 | 2 | C5-4 | 5 | - | X-5 | 0.2 |
A1-1-6 | 20 | C5-5 | 14 | ||||||||||||||||||||
C5-7 | 5 | ||||||||||||||||||||||
C5-8 | 5 | ||||||||||||||||||||||
實施例28 | A1-1-1 | 20 | - | - | - | - | B1-5 | 5 | B2-1 | 2 | C1-1 | 10 | C2-1 | 5 | C3-3 | 1 | C4-1 | 2 | C5-1 | 5 | 0.08 | X-2 | 0.95 |
A1-1-2 | 30 | B2-2 | 0.3 | C5-2 | 9.92 | X-3 | 1 | ||||||||||||||||
A1-1-3 | 3 | B2-4 | 0.05 | C5-7 | 4 | X-5 | 0.7 | ||||||||||||||||
實施例29 | A1-1-1 | 10 | - | - | - | - | B1-5 | 1 | - | - | C1-1 | 15 | C2-1 | 7 | C3-3 | 2 | - | - | C5-9 | 5 | - | - | - |
A1-1-2 | 30 | C1-2 | 20 | C2-2 | 8 | ||||||||||||||||||
A1-1-9 | 2 | ||||||||||||||||||||||
實施例30 | A1-1-1 | 10 | - | - | - | - | B1-3 | 2.5 | B2-2 | 0.5 | C1-1 | 5 | C2-2 | 5 | C3-1 | 0.5 | C4-1 | 1 | C5-3 | 5 | 0.14 | X-4 | 1.5 |
A1-1-2 | 40 | B2-7 | 1 | C5-4 | 9.86 | ||||||||||||||||||
A1-1-3 | 10 | C5-5 | 5 | ||||||||||||||||||||
C5-6 | 3 | ||||||||||||||||||||||
實施例31 | A1-1-1 | 20 | - | - | - | - | B1-1 | 1.5 | - | - | C1-2 | 12 | C2-1 | 10 | - | - | - | - | C5-2 | 10 | - | X-2 | 0.5 |
A1-1-2 | 40 | C5-7 | 4 | ||||||||||||||||||||
A1-1-4 | 2 | ||||||||||||||||||||||
實施例32 | A1-1-1 | 15 | - | - | - | - | B1-3 | 1 | B2-1 | 2 | C1-3 | 10 | - | - | - | - | - | - | C5-1 | 10 | - | X-8 | 0.5 |
A1-1-2 | 25 | B2-6 | 1.5 | C5-2 | 20 | ||||||||||||||||||
A1-1-5 | 10 | C5-3 | 5 | ||||||||||||||||||||
實施例33 | A1-1-6 | 30 | A1-2-2 | 18 | - | - | B1-5 | 2.5 | B2-3 | 1.5 | - | - | C2-3 | 10 | - | - | - | - | C5-1 | 5 | - | X-6 | 1.5 |
B2-4 | 0.5 | C5-4 | 10 | ||||||||||||||||||||
B2-7 | 1 | C5-5 | 10 | ||||||||||||||||||||
C5-8 | 10 |
[表2]
區分 | 平滑劑(A) | 離子界面活性劑(B) | 非離子界面活性劑(C) | 二亞磷酸 | 其他成分 | |||||||||||||||||||||||||||
酯化合物(A1) | 其他平滑劑 | 羧酸化合物(B1) | 其他離子界面活性劑 | 脂肪酸衍生物(C1) | 醇衍生物(C2) | 醯胺衍生物(C3) | 胺衍生物(C4) | 其他非離子界面活性劑 | ||||||||||||||||||||||||
分岐酯化合物(A1-1) | 其他酯化合物 | |||||||||||||||||||||||||||||||
種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 種類 | 比率 (質量%) | 比率 (質量%) | 種類 | 比率 (質量%) | ||||||||||
比較例1 | A1-1-1 | 90 | - | - | - | - | B1-2 | 10 | - | - | - | - | - | - | - | - | - | - | - | - | - | - | - | |||||||||
比較例2 | - | - | - | - | - | - | B1-5 | 0.5 | B2-4 | 0.5 | C1-1 | 13 | C2-1 | 40 | - | - | - | - | C5-1 | 5 | - | X-1 | 0.5 | |||||||||
B2-6 | 0.5 | C2-2 | 40 | |||||||||||||||||||||||||||||
比較例3 | A1-1-8 | 10 | - | - | A2-1 | 25 | B1-4 | 5 | B2-8 | 5 | C1-1 | 20 | C2-1 | 15 | - | - | - | - | C5-4 | 15 | - | X-8 | 5 | |||||||||
比較例4 | - | - | - | - | A2-1 | 25 | - | - | B2-5 | 2 | C1-1 | 17 | C2-1 | 15 | C3-1 | 3 | - | - | - | - | - | X-1 | 1 | |||||||||
B2-6 | 2 | C1-2 | 35 | |||||||||||||||||||||||||||||
比較例5 | - | - | A1-2-2 | 40 | - | - | B1-4 | 3 | B2-6 | 3 | C1-1 | 8 | C2-1 | 40 | - | - | - | - | C5-6 | 5 | - | X-1 | 1 | |||||||||
比較例6 | A1-1-2 | 25 | - | - | - | - | - | - | B2-2 | 1 | C1-4 | 10 | C2-1 | 10 | C3-3 | 1 | C4-1 | 1 | C5-2 | 15 | - | - | - | |||||||||
B2-5 | 2 | C2-2 | 20 | C5-7 | 15 | |||||||||||||||||||||||||||
比較例7 | A1-1-2 | 25 | - | - | - | - | B1-2 | 1.4 | B2-2 | 1 | C1-4 | 10 | C2-1 | 10 | C3-3 | 1 | C4-1 | 1 | C5-2 | 14.65 | 0.35 | - | - | |||||||||
B2-5 | 0.6 | C2-2 | 20 | C5-7 | 15 | |||||||||||||||||||||||||||
比較例8 | A1-1-8 | 57 | - | - | - | - | B1-5 | 2 | B2-2 | 1 | C1-4 | 5 | C2-1 | 5 | C3-3 | 9 | - | - | C5-1 | 9.5 | 0.5 | - | - | |||||||||
B2-4 | 6 | C5-7 | 5 | |||||||||||||||||||||||||||||
表1、2中的比率(%)係將合成纖維用處理劑全體設為100質量%時,依質量比率(%)表示各成分摻合比例的數值。
表1、2中的各代號係表示下述成分。
<平滑劑(A)>
・分支酯化合物(A1-1)
A1-1-1:菜籽油
A1-1-2:三羥甲基丙烷三油酸酯
A1-1-3:硫基二丙酸二(異硬脂酯)
A1-1-4:硫基二丙酸二(異鯨蠟酯)
A1-1-5:己二酸二(異硬脂酯)
A1-1-6:硬脂酸異十三烷酯
A1-1-7:油酸異十三烷酯
A1-1-8:棕櫚酸異辛酯
A1-1-9:三羥甲基丙烷二油酸酯
・其他酯化合物(A1-2)
A1-2-1:油酸十二烷酯
A1-2-2:棕櫚酸十二烷酯
A1-2-3:丁二醇二油酸酯
・其他平滑劑
A2-1:礦物油(30mm
2/s、40℃)
<離子界面活性劑(B)>
・羧酸化合物(B1)
B1-1:N-甲基-N-椰子油脂甘胺酸/鈉鹽
B1-2:N-甲基-N-月桂醯基甘胺酸/鈉鹽
B1-3:N-甲基-N-月桂醯基甘胺酸
B1-4:N-甲基-N-癸醯基甘胺酸/鈉鹽
B1-5:N-甲基-N-油醯基甘胺酸/鉀鹽
B1-6:N-甲基-N-椰子油脂丙胺酸/鉀鹽
・其他離子界面活性劑
B2-1:二級烷烴磺酸鈉鹽(碳數:11~14)
B2-2:二辛基磺琥珀酸鈉鹽
B2-3:α-烯烴磺酸鈉鹽
B2-4:油酸鉀鹽
B2-5:油醇-環氧乙烷5莫耳加成物的磷酸酯
B2-6:磷酸異鯨蠟酯
B2-7:磷酸油酯
B2-8:次亞麻油酸
<非離子界面活性劑(C)>
・脂肪酸衍生物(C1)
C1-1:對油酸1莫耳加成了10莫耳EO者
C1-2:對聚乙二醇(平均分子量600)1莫耳利用油酸2莫耳施行了酯化者
C1-3:對聚乙二醇(平均分子量400)1莫耳利用月桂酸2莫耳施行了酯化者
C1-4:對聚乙二醇(平均分子量600)1莫耳利用棕櫚油脂肪酸1.5莫耳施行了酯化者
・醇衍生物(C2)
C2-1:對異十二醇1莫耳無規加成了10莫耳EO與10莫耳PO者
C2-2:對異十三醇1莫耳加成了10莫耳PO者,再加成了10莫耳EO者
C2-3:對2-乙基己醇1莫耳無規加成了4莫耳EO與8莫耳PO者
C2-4:對油醇1莫耳加成了10莫耳EO者
C2-5:對丁醇1莫耳無規加成了10莫耳EO與10莫耳PO者
・醯胺衍生物(C3)
C3-1:對油酸二乙醇醯胺1莫耳加成了3莫耳EO者
C3-2:對椰油肪酸二乙醇醯胺1莫耳加成了5莫耳EO者
C3-3:油酸二乙醇醯胺
・胺衍生物(C4)
C4-1:對油胺、硬脂胺及棕櫚胺的混合物1莫耳加成了10莫耳EO者
C4-2:對椰油胺1莫耳加成了5莫耳EO者
・其他非離子界面活性劑
C5-1:對硬化篦麻油1莫耳加成了10莫耳EO者
C5-2:對硬化篦麻油1莫耳加成了20莫耳EO者,並利用油酸3莫耳施行了酯化的化合物
C5-3:對硬化篦麻油1莫耳加成了25莫耳EO者,並利用己二酸施行交聯,再利用硬脂酸施行了末端酯化的化合物(平均分子量:5000)
C5-4:對篦麻油1莫耳加成了20莫耳EO者
C5-5:對篦麻油1莫耳加成了20莫耳EO者,並利用油酸2莫耳施行了酯化的化合物
C5-6:對壬基酚1莫耳加成了7莫耳EO者
C5-7:山梨糖醇酐單油酸酯
C5-8:山梨糖醇酐三油酸酯
C5-9:聚氧乙烯(9莫耳)甲醚油酸酯
<其他成分>
X-1:聚醚改質聚矽氧
X-2:1,3,5-三(4-第三丁基-3-羥基-2,6-二甲基苄基)異三聚氰酸
X-3:乙二醇
X-4:二乙二醇
X-5:聚乙二醇(平均分子量:300)
X-6:甘油
X-7:檸檬酸三乙醇胺鹽
X-8:油基咪唑啉
<合成纖維用處理劑對合成纖維的附著與橡膠接著評價試驗>
將依上述「合成纖維用處理劑之調製」所調製的合成纖維用處理劑,利用稀釋劑均勻稀釋,形成15%溶液(實施例1~21、實施例26~33、比較例1~8的稀釋劑係有機溶劑,實施例22~25的稀釋劑係水)。將該溶液利用上油羅拉供油法,依非揮發份計附著量成為1.0質量%的方式,附著於1670分特克斯、288細絲、固有黏度0.93的無供油聚對苯二甲酸乙二酯纖維上,而製造合成纖維。
使用所製作之2支合成纖維,依下撚40次/10cm、上撚40次/10cm的撚數施行撚絞,形成撚紗線。將該撚紗線浸漬於作為第1接著劑之由環氧化合物(Denacol EX512:Nagase ChemteX公司製)、與封端型異氰酸酯(阻斷ELASTRON BN-27:第一工業製藥公司製)依固形份比成為5:5方式所摻合的接著劑中,然後依245℃施行熱處理。更進一步將撚紗線浸漬於作為第2接著劑之由間苯二酚(resorcinol:Kishida化學公司製)、福馬林(甲醛液37%:Kishida化學公司製)、以及乳膠(Nipol2518FS:日本ZEON公司製)依固形份比成為1.5:0.5:8方式所摻合的溶液(RFL溶液)中,然後依245℃施行熱處理。
將藉由依照以上順序所製作接著劑施行處理過的補強線,根據JIS-L1017(化學纖維輪胎簾布測試方法)所記載的T測試(A法)測定接著力,並依下述基準施行評價。結果整理如下述表3、4所示。
[接著性之評價基準]
◎◎:接著力達16.0kg以上的情況
◎〇:接著力達15.7kg以上、且未滿16.0kg的情況
〇〇:接著力達15.4kg以上、且未滿15.7kg的情況
〇:接著力達15.0kg以上、且未滿15.4kg的情況
×:接著力未滿15.0kg的情況
<染色性評價試驗>
在將聚對苯二甲酸乙二酯碎片依常法施行乾燥後,使用擠壓機施行熔融紡絲,再從紡嘴吐出,於經冷卻固化後的游走絲線上,依照使用計量泵的導件供油法,附著將依上述「合成纖維用處理劑之調製」所調製之合成纖維用處理劑利用稀釋劑均勻稀釋的20%稀釋溶液(實施例1~21、實施例26~33、比較例1~8的稀釋劑係低黏度礦物油,實施例22~25的稀釋劑係水)。依合成纖維用處理劑的附著量成為0.6質量%(未包含水與低黏度礦物油)的方式供油。然後,利用導件進行集束,經由245℃的延伸羅拉、弛緩羅拉,依總延伸倍率成為5.5倍的方式施行延伸,獲得1670分特克斯、144細絲的延伸絲。使用由該紡絲步驟所獲得纖維360支設為經絲,且緯絲係使用560分特克斯-96細絲的聚酯絲,依緯絲密度21支/吋製作出寬51mm安全帶用原布,未精練而浸漬於以下染液(對水1L添加Dianix Red S-4G:3.4g、Dianix Yellow S-6G:3.3g、Dianix S-2G:3.3g的溶液)中,連續於220℃發色槽施行2分鐘處理而進行染色。此時從安全帶每2000m的染色缺點數,依照以下基準施行染色性評價。結果整理如表3、4所示。
[染色性評價基準]
◎:染色缺點數0~3
○:染色缺點數4~10
×:染色缺點數11以上
<焦油清洗性評價試驗>
將在上述「合成纖維用處理劑對合成纖維的附著與橡膠接著評價試驗」中,依合成纖維用處理劑附著量以非揮發份計成為1.0質量%的方式賦予了處理劑的纖維,依初期張力1.5kg、絲速度0.5m/分接觸於表面溫度250℃的梨面鉻針,並遊走12小時,使焦油附著於梨面鉻針上。接著,針對梨面鉻針上附著的焦油,使用經含潤依5%NaOH方式調製之甘油溶液的綿棒,於180℃下擦拭,測定直到焦油消失為止的次數。焦油清洗性係依如下基準施行評價。結果整理如表3、4所示。
[焦油清洗性評價基準]
◎:未滿50次
○:50次以上、且未滿200次
×:200次以上
<起毛評價試驗>
對上述「染色性評價試驗」中,依處理劑附著量以非揮發份計成為0.6質量%的方式賦予了合成纖維用處理劑的纖維,且依300m/min游走的纖維,依初期張力2kg接觸表面溫度150℃的梨面鉻針。使用起毛計數裝置(東麗工程公司製),測定經鉻針摩擦後的游走絲每10分鐘的起毛數,依以下基準施行評價。結果整理如表3、4所示。
[起毛評價基準]
◎◎(特優):所測得起毛數未滿2個
◎〇(優):所測得起毛數達2個以上、且未滿4個
〇〇(佳):所測得起毛數達4個以上、且未滿6個
〇(普通):所測得起毛數達6個以上、且未滿8個
×(不佳):所測得起毛數達8個以上
[表3]
區分 | 評價 | 區分 | 評價 | 區分 | 評價 | |||||||||
接著 | 染色 | 焦油清洗 | 起毛 | 接著 | 染色 | 焦油清洗 | 起毛 | 接著 | 染色 | 焦油清洗 | 起毛 | |||
實施例1 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例12 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例23 | ◎◎ | ◎ | ◎ | ◎〇 |
實施例2 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例13 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例24 | ◎◎ | ◎ | ◎ | ◎〇 |
實施例3 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例14 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例25 | ◎◎ | ◎ | ◎ | ◎〇 |
實施例4 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例15 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例26 | ◎◎ | ◎ | ◎ | ◎〇 |
實施例5 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例16 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例27 | ◎◎ | ◎ | ◎ | ◎〇 |
實施例6 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例17 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例28 | ◎◎ | ◎ | 〇 | ◎〇 |
實施例7 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例18 | ◎◎ | ◎ | ◎ | ◎〇 | 實施例29 | ◎〇 | ◎ | 〇 | ◎〇 |
實施例8 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例19 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例30 | ◎〇 | ◎ | 〇 | 〇〇 |
實施例9 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例20 | ◎◎ | ◎ | ◎ | ◎〇 | 實施例31 | 〇〇 | 〇 | 〇 | ◎〇 |
實施例10 | ◎◎ | ◎ | ◎ | ◎◎ | 實施例21 | ◎◎ | ◎ | 〇 | ◎◎ | 實施例32 | 〇〇 | 〇 | 〇 | ◎〇 |
實施例11 | ◎◎ | ◎ | ◎ | ◎◎ | 實施傅22 | ◎◎ | ◎ | ◎ | ◎〇 | 實施例33 | 〇〇 | 〇 | 〇 | 〇〇 |
[表4]
區分 | 評價 | |||
接著 | 染色 | 焦油清洗 | 起毛 | |
比較例1 | 〇 | × | × | 〇 |
比較例2 | × | 〇 | 〇 | × |
比較例3 | 〇 | 〇 | × | × |
比較例4 | × | × | × | × |
比較例5 | × | 〇 | × | 〇 |
比較例6 | × | 〇 | × | × |
比較例7 | 〇 | 〇 | × | × |
比較例8 | 〇 | 〇 | × | × |
由表3、4的結果得知,本發明的合成纖維用處理劑(實施例1~33),係含有:平滑劑(A),其含有酯化合物(A1),該酯化合物(A1)係含有分子中具有分支之鏈狀結構的分支酯化合物(A1-1);離子界面活性劑(B),其含有羧酸化合物(B1),該羧酸化合物(B1)係從分子中具碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇至少1者;及非離子界面活性劑(C);藉由相對於合成纖維用處理劑的非揮發份,含有上述酯化合物(A1)達15質量%以上,便可獲得耐起毛性優異的良好紡絲性、與優異的焦油清洗性,且可得到良好染色性與橡膠接著性。
再者,含有二亞磷酸0.01質量%、0.02質量%、0.08質量%的實施例16、17、28,在橡膠接著性、染色性、焦油清洗性及耐起毛性方面,相較於除了未含有二亞磷酸之外其餘均為相同組成的實施例3、21之下,確認到同樣可發揮優異效果。
再者,含有二亞磷酸0.14質量%的實施例30,相較於除了未含有二亞磷酸之外其餘均為相同組成的實施例10之下,確認到同樣可獲得優異的染色性與橡膠接著性,且焦油清洗性與耐起毛性良好,實用上無問題。
相對於此,不同於本發明組成的合成纖維用處理劑(比較例1~8),詳言之,未含非離子界面活性劑(C)的比較例1、未含平滑劑(A)的比較例2、未含分支酯化合物(A1-1)的比較例5、未含酯化合物(A1)的比較例4、雖含有本發明分支酯化合物(A1-1)但含量卻少於本發明的比較例3,以及未含有本發明從分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇至少1種羧酸化合物(B1)的比較例6,可得知橡膠接著性、染色性、焦油清洗性及耐起毛性均劣化。
特別確認到相較於本發明合成纖維用處理劑具體例的實施例3之下,比較例6係除了未含有本發明從分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇至少1種羧酸化合物(B1)之外,其餘組成均大致相同,但橡膠接著性、焦油清洗性、耐起毛性卻出現大幅劣化。
再者,含有二亞磷酸0.35質量%的比較例7,相較於除了未含有二亞磷酸之外其餘均為相同組成的實施例3之下,得知其橡膠接著性、染色性、焦油清洗性及耐起毛性較差,尤其在焦油清洗性與耐起毛性方面,在實際使用時有使用困難之情形。含有二亞磷酸0.50質量%的比較例8,亦同樣地得知在焦油清洗性與耐起毛性方面,在實際使用時有使用困難之情形。
二亞磷酸及其鹽係有混入於合成纖維用處理劑製造時所使用觸媒、抗著色劑中的可能性,導致焦油清洗性惡化,且屬於造成所製造之合成纖維之起毛數增加的物質,但由上述評價結果得知,若二亞磷酸及其鹽的含量在0.15質量%以下的範圍,可獲得耐起毛性優異的良好紡絲性、焦油清洗性優異、且良好染色性與橡膠接著性,不致妨礙本發明效果。
(產業上之可利用性)
本發明的合成纖維用處理劑、附著有該合成纖維用處理劑的合成纖維,係藉由減少合成纖維絲線的起毛,可發揮良好的步驟順暢性,可獲得優異紡絲性,能使紡絲步驟中所產生焦油的清洗容易,更可減小與羅拉間之摩擦阻力。
此外,附著有本發明合成纖維用處理劑的合成纖維,在後加工步驟中可發揮良好的染色性與橡膠接著性,因而尤其在安全帶用途、輪胎簾布用途等方面,的後加工步驟中非常有用。
Claims (8)
- 一種合成纖維用處理劑,係含有:平滑劑(A)、離子界面活性劑(B)及非離子界面活性劑(C)的合成纖維用處理劑;其中,上述平滑劑(A)係含有含下述分支酯化合物(A1-1)的酯化合物(A1);上述離子界面活性劑(B)係含有下述羧酸化合物(B1);上述非離子界面活性劑(C)含有從下述醇衍生物(C2)中選擇之至少1者;相對於合成纖維用處理劑的非揮發份,含有上述酯化合物(A1)15質量%以上,且從二亞磷酸及其鹽中選擇之至少1者的含量係0~0.15質量%之範圍;分支酯化合物(A1-1):分子中具有分支之鏈狀結構的酯化合物;羧酸化合物(B1):從分子中具有碳數8~20之醯基的N-甲基甘胺酸衍生物、及分子中具有碳數8~20之醯基的N-甲基丙胺酸衍生物中選擇之至少1者;醇衍生物(C2):對碳數8~15之具有分支結構的一元脂肪族醇每1莫耳依合計1~50莫耳之比例加成了碳數2~4之環氧烷的化合物。
- 如請求項1之合成纖維用處理劑,其中,相對於上述處理劑的非揮發份,含有上述羧酸化合物(B1)0.01~4質量%。
- 如請求項1或2之合成纖維用處理劑,其中,上述分支酯化合物(A1-1)係含有:具有分支之鏈狀結構且碳數3~10之三~六元脂肪族醇、與碳數8~20之一元脂肪酸的完全酯化合物。
- 如請求項1或2之合成纖維用處理劑,其中,上述非離子界面活性劑(C)係更進一步含有從下述脂肪酸衍生物(C1)中選擇之至少1者;脂肪酸衍生物(C1):碳數8~20之一元脂肪酸、與以碳數2~4之環氧烷為構成單元且質量平均分子量200~1000之(聚)烷二醇的酯化合物,以及對碳數8~20之一元脂肪酸每1莫耳依合計1~20莫耳之比例加成了碳數2~4之環氧烷的化合物。
- 如請求項1或2之合成纖維用處理劑,其中,上述非離子界面活性劑(C)係更進一步含有下述醯胺衍生物(C3);醯胺衍生物(C3):從下述化合物中選擇之至少1者,即,碳數8~20之一元脂肪酸與二乙醇胺的醯胺化合物、及對碳數8~20之一元脂肪酸與二乙醇胺的醯胺化合物每1莫耳依合計1~10莫耳之比例加成了碳數2~4之環氧烷的化合物。
- 如請求項1或2之合成纖維用處理劑,其中,上述非離子界面活性劑(C)係更進一步含有下述胺衍生物(C4);胺衍生物(C4):從下述化合物中選擇之至少1者,即,對碳數8~20之一級脂肪族胺每1莫耳,依合計1~20莫耳之比例加成了碳數2~4之環氧烷的化合物。
- 如請求項1或2之合成纖維用處理劑,其中,若將上述平滑劑(A)、上述離子界面活性劑(B)及上述非離子界面活性劑(C)的含有比例之合計設為100質量份,係含有上述平滑劑(A)15~70質量份、上述 離子界面活性劑(B)0.01~15質量份、及上述非離子界面活性劑(C)20~80質量份。
- 一種合成纖維,係附著有請求項1至7中任一項之合成纖維用處理劑。
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