TWI815596B - Additive thin circuit board manufacturing method - Google Patents
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- TWI815596B TWI815596B TW111129850A TW111129850A TWI815596B TW I815596 B TWI815596 B TW I815596B TW 111129850 A TW111129850 A TW 111129850A TW 111129850 A TW111129850 A TW 111129850A TW I815596 B TWI815596 B TW I815596B
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 25
- 239000000654 additive Substances 0.000 title claims abstract description 20
- 230000000996 additive effect Effects 0.000 title claims abstract description 20
- 239000002184 metal Substances 0.000 claims abstract description 101
- 229910052751 metal Inorganic materials 0.000 claims abstract description 101
- 238000000034 method Methods 0.000 claims abstract description 48
- 238000009713 electroplating Methods 0.000 claims abstract description 26
- 238000001312 dry etching Methods 0.000 claims abstract description 10
- 238000001039 wet etching Methods 0.000 claims abstract description 9
- 239000000758 substrate Substances 0.000 claims description 39
- 239000011888 foil Substances 0.000 claims description 17
- 238000010329 laser etching Methods 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 238000005553 drilling Methods 0.000 claims description 2
- 230000000149 penetrating effect Effects 0.000 claims description 2
- 229920002120 photoresistant polymer Polymers 0.000 abstract description 21
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000005530 etching Methods 0.000 description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007769 metal material Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000000206 photolithography Methods 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004590 computer program Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
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Abstract
本發明的加成法細線路電路板製造方法包含以下步驟:準備一線路基 板,其第一表面上具有一第一金屬層,並在第一金屬層上設置一阻劑層,接著進行乾式蝕刻程序,在第一金屬層上的阻劑層中形成貫穿阻劑層的一圖案化槽道,使得第一金屬層的表面露出於圖案化槽道中,並進行一電鍍程序,在圖案化槽道中的第一金屬層表面設置一第一線路層,最後在移除阻劑層後,進行濕式蝕刻程序,移除未被第一線路層覆蓋的部份的第一金屬層。本發明用阻劑層及乾式蝕刻取代光阻層及曝光顯影製程,從而避免細線路的線路圖案品質不佳的問題,確保細線路形成的品質。 The additive thin circuit circuit board manufacturing method of the present invention includes the following steps: preparing a circuit base The board has a first metal layer on its first surface, and a resist layer is provided on the first metal layer, and then a dry etching process is performed to form a through-resist layer in the resist layer on the first metal layer. A patterned channel, so that the surface of the first metal layer is exposed in the patterned channel, and an electroplating process is performed to set a first circuit layer on the surface of the first metal layer in the patterned channel, and finally remove the resist After the first circuit layer is formed, a wet etching process is performed to remove the portion of the first metal layer that is not covered by the first circuit layer. The invention uses a resist layer and dry etching to replace the photoresist layer and the exposure and development process, thereby avoiding the problem of poor circuit pattern quality of thin circuits and ensuring the quality of fine circuit formation.
Description
一種電路板製造方法,尤指一種加成法細線路電路板製造方法。 A circuit board manufacturing method, especially an additive method for manufacturing thin circuit circuit boards.
現有的加成法電路板線路製造方法中,主要係以微影配合電鍍及蝕刻的製程在線路基板上形成所設計的線路圖案。微影蝕刻的步驟主要係先在線路基板上的種子層上設置一光阻層,在該光阻層上方設置一圖案化遮罩後進行曝光、顯影以形成圖案化光阻層,然後對該線路基板進行電鍍,以在圖案化光阻層的槽道中形成線路結構。最後在移除該圖案化光阻層後,進行蝕刻移除多餘的種子層,完成該線路基板上的線路圖形。 In the existing additive circuit board circuit manufacturing method, the designed circuit pattern is mainly formed on the circuit substrate by photolithography combined with electroplating and etching processes. The steps of photolithography etching mainly include first setting a photoresist layer on the seed layer on the circuit substrate, setting a patterned mask above the photoresist layer, and then exposing and developing it to form a patterned photoresist layer. The circuit substrate is electroplated to form circuit structures in the channels of the patterned photoresist layer. Finally, after removing the patterned photoresist layer, etching is performed to remove excess seed layer to complete the circuit pattern on the circuit substrate.
在通過圖案化遮罩進行曝光以形成圖案化光阻層的步驟中,該圖案化遮罩上預先形成有貫穿圖案化遮罩且對應所需線路圖案的槽道。當放置在光阻層上進行曝光時,光線只能由槽道中通過以照射在光阻層,使得照射到光線的光阻層產生化學反應,最後再以溶液移除有產生化學反應(或未產生化學反應)的光阻層,產生對應所需線路結構的圖案化光阻層。 In the step of exposing through the patterned mask to form a patterned photoresist layer, a channel that penetrates the patterned mask and corresponds to the required circuit pattern is preformed on the patterned mask. When placed on the photoresist layer for exposure, light can only pass through the channel to illuminate the photoresist layer, causing a chemical reaction in the photoresist layer that is exposed to the light. Finally, it is removed with a solution to produce a chemical reaction (or not The photoresist layer produces a chemical reaction) to produce a patterned photoresist layer corresponding to the desired circuit structure.
然而,針對近年線路板微小化的需求,線路圖形設計的線徑寬度及間距寬度越來越小且窄,所對應的圖案化光阻層上的線路圖案的線徑寬度及間距寬度也必須越來越小且窄。然而,根據現有光阻層材料特性,曝光程序中有解析度的限制,因此具有線徑及間距寬度的極限值,當線距或間距過小時,可能會有曝光不完全,以及圖案化光阻層中線路圖案之結構過細而容易崩 落,導致圖案化光阻層中的線路圖案不完整之風險。如此一來,在下一步驟的電鍍程序中,亦無法正確地形成的線路結構。 However, in response to the demand for miniaturization of circuit boards in recent years, the line diameter width and spacing width of circuit pattern designs are getting smaller and narrower, and the corresponding line diameter width and spacing width of circuit patterns on the patterned photoresist layer must also be narrower. Getting smaller and narrower. However, according to the material characteristics of the existing photoresist layer, there are resolution limitations in the exposure process, so there are limits to the line diameter and spacing width. When the line spacing or spacing is too small, there may be incomplete exposure and patterned photoresist. The structure of the circuit pattern in the layer is too thin and easy to collapse falling, resulting in the risk of incomplete circuit patterns in the patterned photoresist layer. As a result, the circuit structure cannot be formed correctly in the next step of the electroplating process.
也就是說,光阻層及曝光顯影製程之技術限制了線路板線路微小化及精密化的發展,故現有技術的線路板製造方法勢必須進一步改善。 In other words, the technology of the photoresist layer and the exposure and development process limits the development of circuit board circuit miniaturization and precision, so the existing circuit board manufacturing methods must be further improved.
有鑑於現有的加成法電路板製造技術中光阻層在形成細線路製程時容易產生結構不穩固或崩落導致線路圖案不完整,本發明提供一種加成法細線路電路板製造方法,包含以下步驟:準備一線路基板,該線路基板的一第一表面上具有一第一金屬層;在該第一金屬層上設置一阻劑層;進行一乾式蝕刻程序,在該第一金屬層上的阻劑層中形成一圖案化槽道,該圖案化槽道貫穿該阻劑層,使得該第一金屬層的表面露出於該圖案化槽道中;進行一電鍍程序,在該圖案化槽道中的第一金屬層表面設置一第一線路層;移除該阻劑層;以及進行一濕式蝕刻程序,移除未被該第一線路層覆蓋的部份的第一金屬層。 In view of the fact that in the existing additive circuit board manufacturing technology, the photoresist layer is prone to structural instability or collapse during the fine circuit formation process, resulting in incomplete circuit patterns. The present invention provides an additive fine circuit circuit board manufacturing method, which includes the following Steps: prepare a circuit substrate with a first metal layer on a first surface of the circuit substrate; set a resist layer on the first metal layer; perform a dry etching process, and add a resist layer on the first metal layer. A patterned channel is formed in the resist layer, and the patterned channel penetrates the resist layer, so that the surface of the first metal layer is exposed in the patterned channel; an electroplating process is performed, and the patterned channel in the patterned channel is A first circuit layer is provided on the surface of the first metal layer; the resist layer is removed; and a wet etching process is performed to remove the portion of the first metal layer that is not covered by the first circuit layer.
在本發明中,在第一金屬層上設置阻劑層後,利用乾式蝕刻程序在阻劑層中形成鏤空的圖案化槽道,以用於在電鍍程序中在第一金屬層上形成具有線路結構的第一線路層。相較以曝光顯影程序產生具有線路圖案的圖案化光阻層必須仰賴曝光解析度,且顯影程序的化學反應中有較多變因可能導致圖案化光阻層的結構不夠穩定,本發明採用乾式蝕刻(如雷射蝕刻)具有更高的指定蝕刻路徑的精密度,而且阻劑層中非蝕刻範圍內的阻劑層材料不易受影響 而能保持結構穩定,從而能夠在阻劑層中形成符合細線路規格所要求的20μm甚至以下的線路寬度及間距的圖案化槽道,解決以曝光顯影程序形成圖案化光阻層在線路圖案細密時容易剝落導致線路圖案不完整之問題。 In the present invention, after a resist layer is provided on the first metal layer, a dry etching process is used to form hollow patterned channels in the resist layer for forming circuits on the first metal layer during the electroplating process. The first line layer of the structure. Compared with using an exposure and development process to produce a patterned photoresist layer with circuit patterns, which must rely on exposure resolution, and there are many variables in the chemical reaction of the development process that may cause the structure of the patterned photoresist layer to be unstable. The present invention adopts a dry process. Etching (such as laser etching) has higher precision in specifying the etching path, and the resist layer material in the non-etching range of the resist layer is not easily affected It can maintain structural stability, thereby forming patterned channels in the resist layer that meet the line width and spacing of 20 μm or less required by fine line specifications, and solve the problem of fine line patterns in the patterned photoresist layer formed by the exposure and development process. It is easy to peel off, resulting in incomplete circuit patterns.
10:線路基板 10: Circuit substrate
11:第一表面 11: First surface
12:第二表面 12: Second surface
100:通孔 100:Through hole
101:內壁 101:Inner wall
20:第一金屬層 20: First metal layer
201:部分的第一金屬層表面 201: Part of the first metal layer surface
21:金屬箔層 21:Metal foil layer
30:阻劑層 30: Resistor layer
300:圖案化槽道 300:Patterned Channel
40:第一線路層 40: First line layer
41:阻劑薄膜 41: Resistor film
50:第二金屬層 50: Second metal layer
51:金屬箔層 51:Metal foil layer
501:部分的第二金屬層表面 501: Part of the second metal layer surface
60:電鍍層 60:Electroplating layer
70:第二線路層 70: Second line layer
71:阻劑薄膜 71: Resistor film
80:線路導通層 80: Line conduction layer
圖1A至1H係本發明加成法細線路電路板製造法的製造流程剖面示意圖。 1A to 1H are schematic cross-sectional views of the manufacturing process of the additive thin circuit board manufacturing method of the present invention.
圖2A至2J係本發明加成法細線路電路板製造法的製造流程剖面示意圖。 2A to 2J are schematic cross-sectional views of the manufacturing process of the additive thin circuit circuit board manufacturing method of the present invention.
請參閱圖1A至1F所示,本發明的加成法細線路電路板製造法主要包含以下步驟。 Referring to FIGS. 1A to 1F , the additive thin circuit circuit board manufacturing method of the present invention mainly includes the following steps.
如圖1A所示,準備一線路基板10,該線路基板10的一第一表面11上具有一第一金屬層20。
As shown in FIG. 1A , a
如圖1B所示,在該第一金屬層20上設置一阻劑層30。較佳的,該阻劑層30例如是一油墨層,更佳是一抗電鍍油墨層。
As shown in FIG. 1B , a
如圖1C所示,進行一乾式蝕刻程序,在該第一金屬層20上的阻劑層30中形成一圖案化槽道300,該圖案化槽道300貫穿該阻劑層30,使得部分的第一金屬層表面201露出於該圖案化槽道300中。
As shown in FIG. 1C , a dry etching process is performed to form a patterned
如圖1D所示,進行一電鍍程序,在該圖案化槽道300中的部分的第一金屬層表面201設置一第一線路層40。
As shown in FIG. 1D , an electroplating process is performed, and a
如圖1E所示,在該第一線路層40上設置一阻劑薄膜41,該阻劑薄膜41例如是利用電鍍、化學鍍程序設置的一金屬阻劑薄膜41。較佳的,該阻劑薄膜41與該第一線路層40、第一金屬層20為不相同之金屬材料。舉例而言,該第一線路層40、第一金屬層20為銅金屬,該阻劑薄膜41為錫、鎳...等金屬或其合金,惟本發明不限於此。由於在溼式蝕刻程序中,係將線路基板10連同其
上的第一金屬層20、第一線路層40浸入蝕刻溶液中,該蝕刻溶液係侵蝕特定種類金屬,例如做為第一金屬層20、第一線路層40的銅金屬。由於該阻劑薄膜41與該第一線路層40、第一金屬層20為不同之金屬材料,不受蝕刻溶液侵蝕,故能夠保護該第一線路層40之表面不受侵蝕,確保第一線路層40表面及邊角形狀之完整。
As shown in FIG. 1E , a
如圖1F所示,移除該阻劑層30,留下該第一線路層40及其上的阻劑薄膜41。
As shown in FIG. 1F , the resist
如圖1G所示,進行一濕式蝕刻程序,移除未被該第一線路層40覆蓋的部份的第一金屬層20,完成該第一線路層40的設置。
As shown in FIG. 1G , a wet etching process is performed to remove the portion of the
最後,如圖1H所示,移除該阻劑薄膜41。
Finally, as shown in FIG. 1H , the resist
較佳的,該乾式蝕刻程序是一通過電腦程序控制的指定深度的雷射蝕刻程序。通過電腦控制,除了指定雷射蝕刻的深度之外,同時可指定雷射蝕刻所形成之圖案化槽道300的圖形,也就是第一線路層40的線路結構之圖形。在本發明中,較佳的,該雷射蝕刻的指定深度為該阻劑層30之厚度,也就是確保露出部分的第一金屬層表面201,以供下一步驟的電鍍程序進行即可。較佳的,該雷射蝕刻程序例如為使用紫外光雷射、綠光雷射、奈秒雷射或飛秒雷射技術。
Preferably, the dry etching process is a laser etching process with a specified depth controlled by a computer program. Through computer control, in addition to specifying the depth of laser etching, the pattern of the patterned
在本發明的一第一實施例中,本發明的加成法細線路電路板製造方法亦可應用在雙面線路電路板之製造流程。請參閱圖2A至2C所示,在本實施例中,該線路基板10還具有與該第一表面11相對的一第二表面12,該第二表面12上具有一第二金屬層50,且在前述準備該線路基板10的步驟中,還進一步包含以下子步驟。
In a first embodiment of the present invention, the additive thin circuit board manufacturing method of the present invention can also be applied to the manufacturing process of double-sided circuit boards. Please refer to FIGS. 2A to 2C . In this embodiment, the
如圖2A所示,提供該線路基板10,該線路基板10的該第一表面11上設置有一金屬箔層21,且該第二表面12設置有另一金屬箔層51。該等金屬
箔層21、51例如為預先設置於該線路基板10的第一表面11及第二表面12上的銅箔層,厚度較佳為3~5μm。
As shown in FIG. 2A , the
如圖2B所示,進行鑽孔程序,形成貫穿該線路基板10及該二金屬箔層21、51的至少一通孔100。
As shown in FIG. 2B , a drilling process is performed to form at least one through
如圖2C所示,進行鍍金屬程序,在該線路基板10的第一表面11的金屬箔層21及第二表面12的金屬箔層51上及該至少一通孔100的一內壁101上形成一電鍍層60。在本實施例中,該第一表面11上的金屬箔層21及電鍍層60之結合可視為前述第一實施例的該第一金屬層20,該第一表面11上的電鍍層60表面為該第一金屬層20的表面,而該第二表面12上的金屬箔層51及電鍍層60之結合可視為前述的該第二金屬層50,該第二表面12上的電鍍層60表面為該第二金屬層50的表面。該電鍍層60的厚度較佳為3~5μm。較佳的,該等金屬箔層21、51及該電鍍層60為相同的金屬材料,例如銅。
As shown in FIG. 2C , a metal plating process is performed to form a
圖2A至圖2C中所示的步驟係完成雙面電路板的線路基板10中通孔100的設置。接下來請參閱圖2D至2G,將進一步完成該線路基板10的第一表面11上的第一線路層40及第二表面12上的第二線路層70。
The steps shown in FIGS. 2A to 2C complete the arrangement of the through
如圖2D所示,在設置阻劑層30時,同時在第一金屬層20表面、第二金屬層50的表面上及該至少一通孔100中的內壁101上設置該阻劑層30。
As shown in FIG. 2D , when the resist
如圖2E所示,進行該乾式蝕刻程序,在第一金屬層20、第二金屬層50表面的阻劑層30上形成該圖案化槽道300。該等圖案化槽道300分別貫穿第一金屬層20、第二金屬層50上的阻劑層30,並使得部分的第一金屬層20表面201、部分的第二金屬層50表面501露出於圖案化槽道300中,並且移除該至少一通孔100中的阻劑層30,使得通孔100中的電鍍層60表面露出。
As shown in FIG. 2E , the dry etching process is performed to form the patterned
如圖2F所示,進行該電鍍程序,在部分的第一金屬層20表面201上的阻劑層30的圖案化槽道300中設置第一線路層40,在部分的第二金屬層50
表面501上的阻劑層30的圖案化槽道300中設置第二線路層70,以及在該至少一通孔100中的電鍍層60上形成一線路導通層80。
As shown in FIG. 2F , the electroplating process is performed, and the
如圖2G所示,在該第一線路層40上覆蓋該阻劑薄膜41,且在該第二線路層70上設置另一阻劑薄膜71。
As shown in FIG. 2G , the resist
如圖2H所示,移除其餘的阻劑層30,露出未被該第一線路層40、第二線路層70或線路導通層80覆蓋的第一金屬層20、第二金屬層50表面。
As shown in FIG. 2H , the remaining resist
如圖2I所示,進行一溼式蝕刻程序,移除未被該第一線路層40覆蓋的部份的第一金屬層20、未被第二線路層70覆蓋的部分的第二金屬層50。當完成濕式蝕刻程序後,該第一線路層40通過該至少一通孔100的內壁101的電鍍層60及線路導通層80電性連接該第二線路層70,完成該線路基板10的第一表面11、第二表面12上的第一線路層40及第二線路層70。該等阻劑薄膜41、71與該第一線路層40、第一金屬層20、該第二線路層70、第二金屬層50為不同之金屬材料,不受蝕刻溶液侵蝕,故能夠保護該第一線路層40、第二線路層70之表面不受侵蝕,確保第一線路層40、第二線路層70表面及邊角形狀之完整。
As shown in FIG. 2I , a wet etching process is performed to remove the portion of the
最後,如圖2J所示,移除該等阻劑薄膜41、71。
Finally, as shown in FIG. 2J , the resist
較佳的,該線路基板10例如為硬式線路基板、軟式線路基板或軟硬複合線路基板。此外,該線路基板10亦可為已包含複合線路結構的多層線路板,包含複數已壓合的介電層、線路層等。
Preferably, the
以上所述僅是本發明的實施例而已,並非對本發明做任何形式上的限制,雖然本發明已以實施例揭露如上,然而並非用以限定本發明,任何熟悉本專業的技術人員,在不脫離本發明技術方案的範圍內,當可利用上述揭示的技術內容做出些許更動或修飾為等同變化的等效實施例,但凡是未脫離本發明技術方案的內容,依據本發明的技術實質對以上實施例所作的任何簡單修改、等同變化與修飾,均仍屬於本發明技術方案的範圍內。 The above descriptions are only embodiments of the present invention, and do not limit the present invention in any form. Although the present invention has been disclosed in the embodiments above, they are not used to limit the present invention. Any skilled person familiar with the art will not Without departing from the scope of the technical solution of the present invention, the technical content disclosed above can be used to make some changes or modifications to equivalent embodiments with equivalent changes. Any simple modifications, equivalent changes and modifications made to the above embodiments still fall within the scope of the technical solution of the present invention.
10:線路基板 10: Circuit substrate
11:第一表面 11: First surface
20:第一金屬層 20: First metal layer
201:部分的第一金屬層表面 201: Part of the first metal layer surface
30:阻劑層 30: Resistor layer
300:圖案化槽道 300:Patterned Channel
Claims (10)
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TW201043105A (en) * | 2010-07-30 | 2010-12-01 | Speedy Circuits Co Ltd | Production method of printed circuit board with high-precision wiring lines |
TW201826899A (en) * | 2017-01-03 | 2018-07-16 | 台虹科技股份有限公司 | Manufacturing method of flexible circuit board |
US20200084888A1 (en) * | 2018-09-12 | 2020-03-12 | Lg Innotek Co., Ltd. | Flexible circuit board, chip package including the same, and electronic device including the chip package |
US20220225500A1 (en) * | 2019-05-15 | 2022-07-14 | Sumitomo Electric Industries, Ltd. | Printed circuit board |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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TW201043105A (en) * | 2010-07-30 | 2010-12-01 | Speedy Circuits Co Ltd | Production method of printed circuit board with high-precision wiring lines |
TW201826899A (en) * | 2017-01-03 | 2018-07-16 | 台虹科技股份有限公司 | Manufacturing method of flexible circuit board |
US20200084888A1 (en) * | 2018-09-12 | 2020-03-12 | Lg Innotek Co., Ltd. | Flexible circuit board, chip package including the same, and electronic device including the chip package |
US20220225500A1 (en) * | 2019-05-15 | 2022-07-14 | Sumitomo Electric Industries, Ltd. | Printed circuit board |
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