TWI738642B - 熱塑性樹脂薄膜層合體、及含有熱塑性樹脂薄膜層合體之成形品 - Google Patents

熱塑性樹脂薄膜層合體、及含有熱塑性樹脂薄膜層合體之成形品 Download PDF

Info

Publication number
TWI738642B
TWI738642B TW105109227A TW105109227A TWI738642B TW I738642 B TWI738642 B TW I738642B TW 105109227 A TW105109227 A TW 105109227A TW 105109227 A TW105109227 A TW 105109227A TW I738642 B TWI738642 B TW I738642B
Authority
TW
Taiwan
Prior art keywords
thermoplastic resin
resin film
molded product
welding
film
Prior art date
Application number
TW105109227A
Other languages
English (en)
Other versions
TW201702075A (zh
Inventor
黒川晴彦
Original Assignee
日商三菱瓦斯化學股份有限公司
日商Ｍｇｃ菲爾須特股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日商三菱瓦斯化學股份有限公司, 日商Ｍｇｃ菲爾須特股份有限公司 filed Critical 日商三菱瓦斯化學股份有限公司
Publication of TW201702075A publication Critical patent/TW201702075A/zh
Application granted granted Critical
Publication of TWI738642B publication Critical patent/TWI738642B/zh

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53—Joining single elements to tubular articles, hollow articles or bars
    • B29C66/534—Joining single elements to open ends of tubular or hollow articles or to the ends of bars
    • B29C66/5346—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/06—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions for securing layers together; for attaching the product to another member, e.g. to a support, or to another product, e.g. groove/tongue, interlocking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/08—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using ultrasonic vibrations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112—Single lapped joints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/114—Single butt joints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1222—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a lapped joint-segment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12—Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1224—Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a butt joint-segment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/20—Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines
    • B29C66/24—Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines said joint lines being closed or non-straight
    • B29C66/242—Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines said joint lines being closed or non-straight said joint lines being closed, i.e. forming closed contours
    • B29C66/2424—Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines said joint lines being closed or non-straight said joint lines being closed, i.e. forming closed contours being a closed polygonal chain
    • B29C66/24243—Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines said joint lines being closed or non-straight said joint lines being closed, i.e. forming closed contours being a closed polygonal chain forming a quadrilateral
    • B29C66/24244—Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines said joint lines being closed or non-straight said joint lines being closed, i.e. forming closed contours being a closed polygonal chain forming a quadrilateral forming a rectangle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/01—General aspects dealing with the joint area or with the area to be joined
    • B29C66/05—Particular design of joint configurations
    • B29C66/302—Particular design of joint configurations the area to be joined comprising melt initiators
    • B29C66/3022—Particular design of joint configurations the area to be joined comprising melt initiators said melt initiators being integral with at least one of the parts to be joined
    • B29C66/30223—Particular design of joint configurations the area to be joined comprising melt initiators said melt initiators being integral with at least one of the parts to be joined said melt initiators being rib-like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53—Joining single elements to tubular articles, hollow articles or bars
    • B29C66/534—Joining single elements to open ends of tubular or hollow articles or to the ends of bars
    • B29C66/5346—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat
    • B29C66/53461—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat joining substantially flat covers and/or substantially flat bottoms to open ends of container bodies
    • B29C66/53462—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat joining substantially flat covers and/or substantially flat bottoms to open ends of container bodies joining substantially flat covers and substantially flat bottoms to open ends of container bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/731—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
    • B29C66/7311—Thermal properties
    • B29C66/73115—Melting point
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/731—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
    • B29C66/7311—Thermal properties
    • B29C66/73115—Melting point
    • B29C66/73116—Melting point of different melting point, i.e. the melting point of one of the parts to be joined being different from the melting point of the other part
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/731—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
    • B29C66/7311—Thermal properties
    • B29C66/73117—Tg, i.e. glass transition temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/731—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the intensive physical properties of the material of the parts to be joined
    • B29C66/7311—Thermal properties
    • B29C66/73117—Tg, i.e. glass transition temperature
    • B29C66/73118—Tg, i.e. glass transition temperature of different glass transition temperature, i.e. the glass transition temperature of one of the parts to be joined being different from the glass transition temperature of the other part
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/735—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the extensive physical properties of the parts to be joined
    • B29C66/7352—Thickness, e.g. very thin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7392—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
    • B29C66/73921—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/80—General aspects of machine operations or constructions and parts thereof
    • B29C66/82—Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps
    • B29C66/824—Actuating mechanisms
    • B29C66/8242—Pneumatic or hydraulic drives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/80—General aspects of machine operations or constructions and parts thereof
    • B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/832—Reciprocating joining or pressing tools
    • B29C66/8322—Joining or pressing tools reciprocating along one axis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/90—Measuring or controlling the joining process
    • B29C66/92—Measuring or controlling the joining process by measuring or controlling the pressure, the force, the mechanical power or the displacement of the joining tools
    • B29C66/929—Measuring or controlling the joining process by measuring or controlling the pressure, the force, the mechanical power or the displacement of the joining tools characterized by specific pressure, force, mechanical power or displacement values or ranges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00—General aspects of processes or apparatus for joining preformed parts
    • B29C66/90—Measuring or controlling the joining process
    • B29C66/94—Measuring or controlling the joining process by measuring or controlling the time
    • B29C66/949—Measuring or controlling the joining process by measuring or controlling the time characterised by specific time values or ranges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • B29K2105/0026—Flame proofing or flame retarding agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0088—Blends of polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/25—Solid
    • B29K2105/253—Preform
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2667/00—Use of polyesters or derivatives thereof for preformed parts, e.g. for inserts
    • B29K2667/006—PBT, i.e. polybutylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2669/00—Use of PC, i.e. polycarbonates or derivatives thereof for preformed parts, e.g. for inserts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2022/00—Hollow articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof
    • B29L2031/3481—Housings or casings incorporating or embedding electric or electronic elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/712—Containers; Packaging elements or accessories, Packages
    • B29L2031/7146—Battery-cases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2398/00—Unspecified macromolecular compounds
    • B32B2398/20—Thermoplastics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/40—Closed containers
    • B32B2439/62—Boxes, cartons, cases

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Laminated Bodies (AREA)

Abstract

藉由熱塑性樹脂薄膜與熱塑性樹脂成形品之超音波熔接，而提供高的熔接強度及熔接痕較少之具有優異外觀之熱塑性樹脂薄膜層合體。
藉由將厚度0.4mm以下之熱塑性樹脂薄膜(A)與具有熔接擋邊(margin)(C)之厚度0.5mm以上之熱塑性樹脂成形品(B)之前述熔接擋邊(C)進行超音波熔接而得的熱塑性樹脂層合體，且該熔接擋邊(C)之高度為該熱塑性樹脂薄膜(A)之厚度之72~130%的熱塑性樹脂薄膜層合體，可解決上述課題。

Description

熱塑性樹脂薄膜層合體、及含有熱塑性樹脂薄膜層合體之成形品
本發明有關使薄壁之熱可塑性樹脂薄膜與熱塑性樹脂成形品進行超音波熔接而得之樹脂層合體等。
近年來，關於電氣電子機器之構件，由於進展為製品之小型化與零件之薄壁化，故要求進一步之高設計性。其中內建小型充電池之電池堆用之框體，基於高容量化之目的已進展至塑膠成形品之薄壁化。日後亦因構件之薄壁化進展，一般認為電池堆用框體之厚度為0.4mm以下之部分成為佔成形品表面積中之40%以上。
作為獲得此種薄壁成形品之方法迄今所採用者，舉例為通常之射出成形法、及專利文獻1中記載之使用預先將薄壁薄膜設置於模具內進行射出成形之模內(in mold)薄膜之射出成形法等。然而通常之射出成形法中，樹脂難以對薄壁部填充，而有製品成為填充不足(short shot)之問題，且以高射出壓力填充時有成形品之薄壁部翹曲之問題。又，專利文獻1中記載之利用模內薄膜之射出 成形法，於具有開口部之成形品時，因成形品與薄膜之接觸部與非接觸部之熱收縮差，會使被覆開口部之薄膜撓曲之問題。
又此外，雖有經由接著劑或兩面膠帶貼合薄膜與射出成形品之方法等，但藉由任一方法，由於局部之接著部之厚度增加而無法獲得外觀良好者。
作為成形品等之其他接合方法，舉例有專利文獻2、3中記載之利用成形品間之摩擦之超音波熔接方法。然而，關於利用超音波熔接方法之樹脂間之接合，一般係以使厚壁之射出成形品彼此之接合為主流，以薄膜與厚壁之某射出成形品進行熔接試驗時，會有容易因薄膜接觸成形品時之熔接痕而產生外觀不良之問題。
[先前技術文獻]
[專利文獻]
專利文獻1：日本特開2013-129077號公報
專利文獻2：日本專利第4558374
專利文獻3：日本特開62-54757號公報
本發明之課題在於藉由熱塑性樹脂薄膜與熱塑性樹脂成形品之超音波熔接，而提供高的熔接強度及熔 接痕較少之具有優異外觀之熱塑性樹脂薄膜層合體。
本發明人等為解決上述課題而重複檢討之結果，而著眼於熱塑性樹脂薄膜與熱塑性樹脂成形品之熱變形溫度之差、及設置於熱塑性樹脂成形品表面之熔接擋邊(導能角(energy director))之高度，而可能過去為困難之薄膜熔接品之良好外觀與熔接強度之兼具。
亦即，本發明係關於以下所示之使熱塑性樹脂薄膜與熱塑性樹脂成形品進行超音波熔接而得之熱塑性樹脂薄膜層合體者，以下為主旨。
[1]一種熱塑性樹脂薄膜層合體，其係將厚度0.4mm以下之熱塑性樹脂薄膜(A)與具有熔接擋邊(C)之厚度0.5mm以上之熱塑性樹脂成形品(B)之前述熔接擋邊(C)進行超音波熔接而得的熱塑性樹脂層合體，該熔接擋邊(C)之高度為該熱塑性樹脂薄膜(A)之厚度之72~130%，熱塑性樹脂薄膜(A)與熱塑性樹脂成形品(B)之熱變形溫度之差為20℃以下。
[2]如[1]記載之熱塑性樹脂薄膜層合體，其中熱塑性樹脂薄膜(A)與熱塑性樹脂成形品(B)為以同種的樹脂材料形成。
[3]如[1]或[2]記載之熱塑性樹脂薄膜層合體，其中熱塑性樹脂薄膜(A)之厚度為0.2mm~0.3mm。
[4]如[1]~[3]中任一項記載之熱塑性樹脂薄膜層合 體，其中熱塑性樹脂成形品(B)具有至少一個3cm2以上之開口部，熱塑性樹脂薄膜(A)覆蓋前述開口部之至少一部分。
[5]一種成形品，其係含有如[1]~[4]中任一項記載之熱塑性樹脂薄膜層合體。
將熱塑性樹脂薄膜與熱塑性樹脂成形品進行超音波熔接之本發明之熱塑性樹脂薄膜層合體具有優異之熔接強度及良好外觀。因此，本發明之熱塑性樹脂薄膜層合體可較好地使用作為例如電氣電子OA機器用框體、電池堆框體、透明窗/窗框一體成形品。
10‧‧‧熱塑性樹脂薄膜
10T‧‧‧熱塑性樹脂薄膜厚度
20‧‧‧熱塑性樹脂成形品
20H‧‧‧開口部
20S‧‧‧熔接面
24‧‧‧熔接擋邊
24H‧‧‧熔接擋邊高度
圖1為熱塑性樹脂薄膜與熱塑性樹脂成形品之簡略剖面圖。
圖2為顯示熱塑性樹脂薄膜被覆熱塑性樹脂成形品之開口部之狀態之平面圖(圖2(A))、沿圖2(A)之II-II線切斷而顯示熱塑性樹脂成形品之側面形狀之剖面圖(圖2(B))。
圖3為與圖2不同之熱塑性樹脂成形品之平面圖。
圖4係放大顯示圖3中之熱塑性樹脂成形品之區域I及II之平面圖。
以下詳細說明本發明。又，本發明不限於以下之實施形態，在具有發明效果之範圍內可實施任意變更。
[熱塑性樹脂薄膜(A)、熱塑性樹脂成形品(B)及熱塑性樹脂成形品之熔接擋邊(導能角)(C)之組成]
本發明之樹脂組成物中所含之熱塑性樹脂並未特別限制，可自過去作為成形材料使用者中任意選擇使用。舉例為例如苯乙烯系樹脂、聚苯醚系樹脂、聚烯烴系樹脂、聚氯乙烯系樹脂、聚醯胺系樹脂、聚酯系樹脂、聚碳酸酯系樹脂及丙烯酸系樹脂等。
作為苯乙烯系樹脂舉例為例如苯乙烯、α-甲基苯乙烯等之均聚物或該等之共聚物，或該等與共聚合之不飽和單體之共聚物等。具體舉例為一般用聚苯乙烯(GPPS)、耐衝擊性聚苯乙烯(HIPS)、耐熱性聚苯乙烯(例如α-甲基苯乙烯聚合物或共聚物等)、丙烯腈．丁二烯．苯乙烯共聚物(ABS)、丙烯腈．丁二烯．苯乙烯．α-甲基苯乙烯共聚物(α-甲基苯乙烯系耐熱ABS)、丙烯腈．丁二烯．苯乙烯．苯基馬來醯亞胺共聚物(苯基馬來醯亞胺系耐熱ABS)、丙烯腈-苯乙烯共聚物(AS)、丙烯腈-氯化聚苯乙烯．苯乙烯系共聚物(ACS)、丙烯腈．乙烯丙烯橡膠．苯乙烯共聚物(AES)、丙烯酸橡膠．丙烯腈．苯乙烯共聚物(AAS)或間規(syndiotactic)聚苯乙烯(SPS)等。且苯乙烯 系樹脂亦可為聚合物摻合者。
作為聚苯醚系樹脂(PPE)舉例為例如聚(2,6-二甲基-1,4-伸苯基)醚、聚(2-甲基-6-乙基-1,4-伸苯基)醚等之均聚物，亦可使用該等以苯乙烯系樹脂改質者。
作為聚烯烴系樹脂代表性舉例為乙烯、丙烯、丁烯-1、3-甲基丁烯-1、3-甲基戊烯-1、4-甲基戊烯-1等之α-烯烴之均聚物或該等之共聚物，或該等與其他可共聚合不飽和單體之共聚物等。作為代表例可舉例高密度聚乙烯、中密度聚乙烯、低密度聚乙烯、直鏈狀低密度聚乙烯、超高分子量聚乙烯、乙烯．乙酸乙烯酯共聚物、乙烯．丙烯酸乙酯共聚物、苯乙烯．辛烯-1共聚物等之茂金屬系乙烯．α-烯烴共聚物等之聚乙烯類、無規聚丙烯、間規聚丙烯、等歸聚丙烯或丙烯．乙烯嵌段共聚物或無規共聚物等聚丙烯類、聚甲基戊烯-1等。
作為聚氯乙烯系樹脂舉例為例如氯乙烯均聚物或氯乙烯與可共聚合之不飽和單體之共聚物。具體舉例為氯乙烯．丙烯酸酯共聚物、聚乙烯．甲基丙烯酸酯共聚物、氯乙烯．乙烯共聚物、氯乙烯．丙烯共聚物、氯乙烯．乙酸乙烯酯共聚物、氯乙烯．偏氯乙烯共聚物等。又，亦可使用將該等聚氯乙烯系樹脂氯化而提高氯含量者。
作為聚醯亞胺系樹脂(PA)可舉例例如6-耐綸(聚醯胺6)或12-耐綸等為代表之環狀脂肪族內醯胺開環聚合者、6,6-耐綸、6,10-耐綸、6,12-耐綸等之脂肪族二胺與 脂肪族二羧酸進行聚縮合者，或視情況使芳香族二胺、芳香族二羧酸共聚縮合者等。
作為聚酯系樹脂舉例為例如芳香族二羧酸與乙二醇、丙二醇、丁二醇等之烷二醇聚縮合者。作為具體例，舉例為聚對苯二甲酸乙二酯(PET)、聚對苯二甲酸丙二酯(PPT)、聚對苯二甲酸丁二酯(PBT)等。
作為聚碳酸酯系樹脂舉例為例如4,4’-二羥基二芳基烷烴系聚碳酸酯等。作為具體例可舉例為雙酚A系聚碳酸酯(PC)、改質雙酚系聚碳酸酯、該等之共聚物等。
作為丙烯酸系樹脂舉例為例如甲基丙烯酸酯、丙烯酸酯均聚物或該等之共聚物、或該等與其他可共聚合之不飽和單體之共聚物等。作為甲基丙烯酸酯、丙烯酸酯單體，舉例為甲基丙烯酸或丙烯酸之甲酯、乙酯、正丙酯、異丙酯、丁酯之各種酯體等。代表性舉例為聚甲基丙烯酸甲酯(PMMA)。
[熱塑性樹脂薄膜(A)]
本發明中，熱塑性樹脂薄膜(A)之厚度為0.4mm以下。此意指熱塑性樹脂薄膜中，厚度為0.4mm以下之區域的表面積佔薄膜全體表面積之70%以上者。熱塑性樹脂薄膜(A)之厚度大於0.4mm時，通常射出成形之成形變容易。且由於具有充分厚度故未觀察到因導能角之押入所致之外觀不良，因此無法充分得到本發明效果。熱塑性樹脂薄膜(A)之較佳厚度為自0.01mm至0.4mm以下，更好為 自0.1mm至0.4mm，最好為自0.2mm至0.3mm。熱塑性樹脂薄膜(A)之厚度若小於0.01mm，則由於薄膜過薄，故無法獲得超音波熔接後之良好外觀，且作為框體使用時，可能產生內部零件之保護不充分之問題。又，本發明之熱塑性樹脂薄膜(A)可使用自利用T模嘴之熔融擠出法、溶劑澆鑄法、吹塑成形法製造之薄膜。
[熱塑性樹脂成形品(B)]
本發明中，熱塑性樹脂成形品(B)厚度之平均為0.5mm以上。熱塑性樹脂成形品(B)之成形方法舉例為射出成形品、加壓成形品、吹塑成形品、擠出成形品、真空成形品、壓空成形品等，但基於生產性之觀點較好使用射出成形品。
本發明之熱塑性樹脂薄膜層合體中，熱塑性樹脂成形品(B)不限於平板狀，亦可為三次元形狀。作為特別有效之形狀，熱塑性樹脂成形品(B)為具有3cm2以上之開口部之三次元成形品，例如框體，且該開口部以熱塑性樹脂薄膜(A)覆蓋之構成於本發明中可較好地使用。藉由以熱塑性樹脂薄膜(A)覆蓋熱塑性樹脂成形品(B)之開口部，可使構件輕量化例如可使框體的成形品(B)之內部中之零件高填充化。
[熱塑性樹脂成形品之熔接擋邊(導能角)(C)]
熔接擋邊(導能角)(C)係為了接合熱塑性樹脂薄膜(A) 與熱塑性樹脂成形品(B)而設置於熱塑性樹脂成形品(B)之熔接面。作為接合方法係使用超音波熔接。超音波熔接中，將超音波能集中於設置於熱塑性樹脂成形品(B)之熔接擋邊(導能角)，藉由熱塑性樹脂成形品(B)之熔接擋邊(導能角)(C)與熱塑性樹脂薄膜(A)之摩擦產生之發熱，使熔融之熔接擋邊(導能角)與熱塑性樹脂薄膜(A)接合。
導能角係朝向所接合之熱塑性樹脂薄膜(A)側亦即上側之凸形狀，較好薄膜厚度之剖面形狀為三角形。關於該剖面之三角形，係使用頂點角度為40度至120度之導能角，較好頂點角度為50~70度，最好為60度。亦即，特佳剖面形狀為正三角形。如此，若熔接擋邊(導能角)(C)之剖面形狀為三角形，特別是正三角形，則超音波熔接時，超音波能量可集中於上端部亦即三角形頂點，且可確保熱塑性樹脂成形品(B)側亦即三角形底邊側之熔接擋邊之區域。基於此等觀點，熔接擋邊(導能角)(C)之剖面形狀應避免四角形，較好亦避免圓形。熔接擋邊(導能角)(C)之形狀可藉由射出成形或熱加壓成形後以模具轉印之方法、成形品之機械切削、印刷等之加工而賦予。
又，熔接擋邊(C)較好於熱塑性樹脂成形品(B)之熔接面以連續行狀(線狀)配置。尤其熔接擋邊(C)較好於熱塑性樹脂成形品(B)之熔接面設為一行。係因為熱塑性樹脂成形品(B)之熔接面之熔接擋邊(C)設置複數行例如平行之複數行時，超音波能量分散至複數行。
熔接擋邊((C)導能角)之高度亦即如圖1所示 般，自熱塑性樹脂成形品(B)20之熔接面20S至例如剖面為三角形之熔接擋邊24之頂點之長度24H，較好為熱塑性樹脂薄膜(A)10之厚度10T之72%~130%。亦即，熱塑性樹脂薄膜(A)之厚度設為A(mm)、熔接擋邊(C)之高度設為C(mm)時，C(mm)/A(mm)×100(%)之值較好為72%~130%，(1-C(mm)/A(mm))×100(%)之值較好為-28%~30%。
又較好，熔接擋邊24之高度24H為熱塑性樹脂薄膜(A)10之厚度10T之75~125%，更好為80~120%，特佳為85~115%。熔接擋邊(導能角)之高度24H超過上限時，雖獲得熔接強度但可能產生易因導能角之押入引起外觀不良之問題。且熔接擋邊(導能角)之高度24H未達下限時，雖獲得良好外觀之層合體，但可能產生熔接強度降低之問題。
如圖1所示，以熱塑性樹脂薄膜10與熱塑性樹脂成形品20相互對向之狀態，藉由如箭頭所示之熔接之超音波熔接，形成熱塑性樹脂薄膜10與熱塑性樹脂成形品20之層合體。如此獲得之層合體之熱塑性樹脂薄膜10與熱塑性樹脂成形品20之間，熔接擋邊24因超音波熔接而熔化成為與熱塑性樹脂薄膜10熔融混合之接合部。因此，所製造之層合體之熱塑性樹脂薄膜10與熱塑性樹脂成形品20之接合區域，於該等構件之表面均實質平滑，不會產生外觀上之問題。
[熱塑性樹脂薄膜(A)、熱塑性樹脂成形品(B)之熱變形溫度]
本發明之熱塑性樹脂薄膜(A)、熱塑性樹脂成形品(B)之熱變形溫度，於該等樹脂為非晶性樹脂時設為玻璃轉移溫度，該等樹脂為結晶性樹脂時設為熔點。熱變形溫度可藉由DSC(示差熱掃描熱量分析計)測定。非相溶系之聚合物合金材時，設為基質樹脂之熱變形溫度。
熱塑性樹脂薄膜(A)與熱塑性樹脂成形品(B)之組合較好使用熱變形溫度之差為20℃以下者。更好熱變形溫度之差為15℃以下，特佳為10℃以下。其中較好使用熱塑性樹脂薄膜(A)與熱塑性樹脂成形品(B)樹脂之種類為相溶性高者，或反應性高者。特別是熱塑性樹脂薄膜(A)與熱塑性樹脂成形品(B)較好由同種樹脂材料形成。此處所謂同種材料意指段落[0013]以下所示之樹脂之系統為相同者，更具體而言為具有同種化學鍵之熱塑性樹脂材料。因此，若為具有同種分子構造之樹脂材料，則可為分子量不同者，亦可為共聚合種類、共聚合組成比、添加劑之調配量不同者，定義為本發明中之同種樹脂材料。
熱塑性樹脂薄膜(A)與熱塑性樹脂成形品(B)之熱變形溫度之差超過20℃時，於外觀優先時，樹脂熔接強度不充分，於其熔接強度優先時由於需要更高的超音波能量，故可能產生所得熱塑性樹脂薄膜層合體(成形品)之外觀劣化之問題。
[熱塑性樹脂薄膜層合體之製造方法]
本發明之熱塑性樹脂薄膜層合體之製造方法中，使用超音波熔接。亦即，熱塑性樹脂薄膜層合體係藉由使上述之熱塑性樹脂薄膜(A)與上述之熱塑性樹脂成形品(B)之熔接擋邊(C)進行超音波熔接而製造。例如於熱塑性樹脂成形品(B)之開口部周圍設置熔接擋邊(C)，以覆蓋開口部之方式使熱塑性樹脂薄膜(A)接合，獲得熱塑性樹脂薄膜層合體。
如以上，藉由將熱塑性樹脂薄膜(A)之厚度調整為特定範圍內之值，進而於熱塑性樹脂成形品(B)之熔接表面設置特定高度之熔接擋邊(C)之製法，可獲得熔接強度及外觀良好之層合體，進而藉由抑制熱塑性樹脂薄膜(A)與熱塑性樹脂成形品(B)之熱變形溫度之差，可確實兼具高的熔接強度與良好外觀。
本發明所用之熱塑性樹脂組成物只要不顯著損及期望之諸物性，則亦可根據需要含有上述者以外之成分。作為其他成分舉例為例如磷酸酯、亞磷酸酯為代表之熱安定劑，以受阻酚化合物為代表之抗氧化劑，以苯并三唑系化合物為代表之紫外線吸收劑、防霧劑、抗黏連劑、流動性改良劑、衝擊強度改良劑、滑動性改質劑、可塑劑、分散劑、抗菌劑、難燃劑、玻璃纖維、碳纖維等之各種樹脂添加劑等。該等樹脂添加劑可含有1種，亦可以任意組合及比例含有2種以上。
圖2所示之本發明之一實施形態中，對於具 有開口部20H之熱塑性樹脂成形品20，以熱塑性樹脂薄膜10覆蓋開口部20H之方式，可形成抑制熱塑性樹脂薄膜10與熱塑性樹脂成形品20之層合體。該情況下，熱塑性樹脂薄膜10之熔接面10S與熱塑性樹脂成形品20之熔接面20S(參考圖1)接觸之區域，亦即圖2之交界面30S中，熱塑性樹脂薄膜10與熱塑性樹脂成形品20藉由超音波熔接而熔接。
如此製造之框體的層合體40中，與由厚度大於熱塑性樹脂薄膜10之熱塑性樹脂成形品20之壁構件20W全面形成之情況相比，可確保更廣的內部空間40A，例如收容電子等之內部零件之空間增加。
[實施例]
以下，顯示實施例對本發明更具體說明。惟，本發明不限定於以下之實施例者，在不脫離本發明主旨之範圍內，可任意實施變更。
<熱變形溫度之測定>
熱塑性樹脂之熱變形溫度(Tg)係以示差掃描熱量分析計SEIKO電子工業(股)製之SSC-5200(DSC)測定。測定中，在氮氣氛圍下以20℃/min升溫至使樹脂成分熔融之溫度(260℃)，急冷至-30℃後，再度以10℃/min升溫(第二輪)。自所得DSC曲線利用起點法求出玻璃轉移溫度及熔點。
<熔接強度>
作為超音波熔接強度之評價，係以手指自成形品側押入薄膜層合體之熔接後之成形品之成形品開孔部。
特別良好：於熔接部未見到破壞。
良好：一部分熔接部見到破壞。
不良：熔接之薄膜剝離。
<外觀評價>
目視進行薄膜層合體之超音波熔接後之成形品層合體之外觀評價。目視觀察係對薄膜側進行。薄膜表面幾乎無因熔接擋邊(導能角)之押入導致之表面損傷之特別優異狀態設為特別良好，表面損傷較少之良好狀態設為良好，表面傷痕稍明顯者設為稍不良。表面損傷大外觀劣化之狀態設為不良。
<撓曲性評價>
如圖3所示，使具有2個開口部之圖1及圖2所示之成形品以薄膜層合體熔接於形狀不同之平板狀成形品後，以目視確認成形品層合之撓曲程度。幾乎無撓曲之狀態設為良好，撓曲較大之狀態設為不良。
[使用材料]
<熱塑性樹脂>
聚碳酸酯樹脂以表1之調配實施混合化，聚對苯二甲酸丁二酯係使用市售品。
(a-1)三菱工程塑膠(股)製「UPILON(註冊商標)S-3000F」，雙酚A型芳香族聚碳酸酯樹脂，熱變形溫度(玻璃轉移溫度)145℃
(a-2)三菱工程塑膠(股)製「NOVADURAN(註冊商標)5020」，聚對苯二甲酸丁二酯樹脂，熱變形溫度(熔點)224℃
(a-3)三菱工程塑膠(股)製「NOVADURAN(註冊商標)5510S」，聚對苯二甲酸丁二酯樹脂，熱變形溫度(熔點)219℃
<難燃劑>
(b-1)大八化學工業(股)製「PX-200」，芳香族縮合磷酸酯系難燃劑，1,3-伸苯基雙(二-2,6-二甲苯磷酸酯)
[實施例1~10、比較例1~4]
<樹脂顆粒之製造>
聚碳酸酯樹脂組成物之混合化時，使用具備1個排放口之日本製鋼所公司製雙軸擠出機TEX30α(C18 block)。接著，以螺桿轉數200rpm、噴出量20kg/小時、滾筒溫度270℃之條件，混練各成分，將擠出為線股狀之熔融樹脂於水槽中急冷，使用切粒機顆粒化，獲得聚碳酸酯樹脂組成物之混合物。
<熱塑性樹脂薄膜(A)>
使用由滾筒直徑32mm、螺桿之L/D=35之雙軸擠出機所成之T模嘴熔融擠出機，以噴出量20kg/h、螺桿旋轉數200rpm成形寬度400mm之薄片。汽缸．模頭溫度之設定，於聚碳酸酯係於260℃進行，於聚對苯二甲酸丁二酯係於235℃進行。使用薄膜表面係一者為鏡面，另一者轉印有表面粗糙度Ra=1.5μm之墊子形狀者。使用薄膜厚度示於表1者。超音波熔接試驗所用之薄膜大小為了覆蓋圖3所示之熱塑性樹脂成形品(B)而使用切成150mm×40mm者。
<熱塑性樹脂成形品(B)>
以射出成形成形表1所記載之組成品之150mm×100mm×1.2mm厚平板之樹脂板。藉由切削加工所得射出成形品，製造圖3所示之尺寸、及具有圖1概略所示之形狀之熔接擋邊(ED，導能角)(C)24之熱塑性樹脂成形品(B)20。又，圖3及4中與符號中不同之數值表示各構件之尺寸(mm)。該等數值為各構件尺寸之一例，各構件之尺寸並非限定者。
<具備層合體之樹脂成形品>
上述熱塑性樹脂成形品(B)20與熱塑性樹脂薄膜(A)10成為一體而製作熔接擋邊一體型熱塑性樹脂成形品。熔接 擋邊(ED，導能角)(C)之高度設為表1所示之0.1~0.4mm之值。而且使用具有圖3所示形狀之熱塑性樹脂成形品(B)20，以熱塑性樹脂薄膜完全覆蓋2個開口部20H之方式，使熱塑性樹脂薄膜10與熱塑性樹脂成形品20熔接。熱塑性樹脂成形品(B)20之厚度為1.0mm，縱及橫之長度分別為4.0cm及15.0cm，各開口部20H之縱及橫之長度分別為1.0cm及12.5cm，各開口部20H之面積為12.5cm2(參考圖3)。而且，於熱塑性樹脂成形品(B)20之熔接面20S上，以包圍開口部20H周圍之方式，將熔接擋邊(C)24設於以虛線表示之位置。圖4中，放大顯示圖3所示之熔接面20S之區域I及II。
如此，以包圍開口部20H之實質全周之方式設置熔接擋邊(C)24進行超音波熔接，可將熱塑性樹脂薄膜(A)10對於熱塑性樹脂成形品(B)20強固地固定。又，於熔接面20S之區域I中，藉由設置熔接擋邊(C)24之中斷區域20D(參考圖4)，可使設置熔接擋邊之加工變容易。
Figure 105109227-A0202-12-0018-1
<模內薄膜成形>
針對覆蓋成形品開口部之薄膜撓曲狀態，為了對超音波熔接品與藉由模內薄膜之射出成形品進行比較，藉由模內薄膜成形射出成形品。預先於模具內設置與超音波熔接用成形品同尺寸(150mm×40mm)之聚碳酸酯樹脂薄膜，以未雕入超音波熔接用模具之熔接擋邊(C)之模具進行聚碳酸酯樹脂之射出成形。以下之成形條件亦即汽缸溫度320℃、模具溫度95℃之條件成形。以模內薄膜成形所得之結果示於比較例4。
Figure 105109227-A0202-12-0020-2
<超音波熔接方法>
超音波熔接係使用日本EMERSON公司製之Branson 2000×dt(20kHz 2200W)，使用配合成形品形狀之鈦合金製之熔接角(horn)。熔接試驗係於熱塑性樹脂薄膜(A)之鏡面側與熱塑性樹脂成形品(B)之形成熔接擋邊之面進行，將熱塑性樹脂成形品(B)固定於上部角側，熱塑性樹脂薄膜(A)固定於下部角承台進行熔接試驗。為了保護熱塑性樹脂薄膜(A)之墊子花樣，於薄膜接觸厚度0.03mm之聚乙烯製保護薄膜進行試驗。超音波熔接試驗中之參數設定係如下。亦即，以照射時間0.3秒(聚對苯二甲酸丁二酯樹脂時為0.45秒)，固定時間0.3秒，汽缸壓力200kPa，觸發力250N，及振幅100%之條件實施超音波溶接試驗。
上述實施例1~10中，熔接強度、薄膜外觀及形狀任一者均為良好以上，相對於此，比較例1~4中，至少一評價項目成為比實施例差之結果。由以上，確認藉由於熱塑性樹脂成形品之熔接面設置適當大小之熔接擋邊，將熱塑性樹脂薄膜與形成熱塑性樹脂成形品之樹脂之熱變形溫度調整為較小而藉由超音波熔接，可製造比模內成形所得者具有更高熔接強度及優異外觀之層合體。
10‧‧‧熱塑性樹脂薄膜
10S‧‧‧熔接面
10T‧‧‧熱塑性樹脂薄膜之厚度
20‧‧‧熱塑性樹脂成形體
20S‧‧‧熔接面
24‧‧‧熔接擋邊
24H‧‧‧熔接擋邊之高度

Claims (4)

  1. 一種熱塑性樹脂薄膜層合體，其係將厚度為0.1mm至0.4mm之熱塑性樹脂薄膜(A)與具有熔接擋邊(Margin)(C)之厚度0.5mm以上之熱塑性樹脂成形品(B)之前述熔接擋邊(C)進行超音波熔接而得的熱塑性樹脂層合體，該熔接擋邊(C)之高度為該熱塑性樹脂薄膜(A)之厚度的72~130%，前述熱塑性樹脂薄膜(A)與前述熱塑性樹脂成形品(B)之熱變形溫度之差為20℃以下，前述熱塑性樹脂成形品(B)具有至少一個3cm2以上的開口部，前述熱塑性樹脂薄膜(A)覆蓋前述開口部之至少一部分，前述熱塑性樹脂層合體具有內部空間，前述熔接擋邊(C)設置於前述熱塑性樹脂成形品(B)之前述開口部的周圍。
  2. 如申請專利範圍第1項之熱塑性樹脂薄膜層合體，其中前述熱塑性樹脂薄膜(A)與前述熱塑性樹脂成形品(B)以相同種類的樹脂材料所形成。
  3. 如申請專利範圍第1項之熱塑性樹脂薄膜層合體，其中前述熱塑性樹脂薄膜(A)的厚度為0.2mm~0.3mm。
  4. 一種成形品，其係含有如申請專利範圍第1~3項中任一項之熱塑性樹脂薄膜層合體。
TW105109227A 2015-03-25 2016-03-24 熱塑性樹脂薄膜層合體、及含有熱塑性樹脂薄膜層合體之成形品 TWI738642B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015062837 2015-03-25
JP2015-062837 2015-03-25

Publications (2)

Publication Number Publication Date
TW201702075A TW201702075A (zh) 2017-01-16
TWI738642B true TWI738642B (zh) 2021-09-11

Family

ID=56978752

Family Applications (1)

Application Number Title Priority Date Filing Date
TW105109227A TWI738642B (zh) 2015-03-25 2016-03-24 熱塑性樹脂薄膜層合體、及含有熱塑性樹脂薄膜層合體之成形品

Country Status (6)

Country Link
US (1) US20180071995A1 (zh)
JP (1) JP6718863B2 (zh)
KR (1) KR102427367B1 (zh)
CN (1) CN107405890B (zh)
TW (1) TWI738642B (zh)
WO (1) WO2016152974A1 (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210146081A1 (en) * 2017-02-22 2021-05-20 Weinmann Emergency Medical Technology GMBH + Co., KG Emergency resuscitation system with remote control
US11701736B2 (en) * 2021-09-30 2023-07-18 Wiegel Tool Works, Inc. Systems and methods for making a composite thickness metal part
KR102561388B1 (ko) * 2023-04-17 2023-08-01 김병진 골판지 인쇄용 조판지 제조방법 및 이에 의해 제조된 조판지

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4865217A (en) * 1987-08-31 1989-09-12 Sumitomo Bakelite Company, Limited Easily openable sealed container
US20140326391A1 (en) * 2011-11-08 2014-11-06 Dai Nippon Printing Co., Ltd. Method for producing cell culture vessel

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3997677A (en) * 1972-05-09 1976-12-14 Standard Packaging Corporation High temperature resistant hermetically sealed plastic tray packages
JPS52141880A (en) * 1976-05-19 1977-11-26 Ici Ltd Laminated structure and method for its production
US4322480A (en) * 1980-12-29 1982-03-30 Allied Chemical Corporation Polyamide-polyethylene laminates
JPS58160125A (ja) * 1982-03-17 1983-09-22 Hitachi Ltd 成形体とその製造方法
US4462849A (en) * 1982-04-23 1984-07-31 Cosden Technology, Inc. Method of oscillatory bonding
JPS6254757A (ja) 1985-05-23 1987-03-10 Toray Ind Inc ポリフエニレンスルフイド樹脂組成物
US4909434A (en) * 1988-05-20 1990-03-20 The Procter & Gamble Company Moisture impervious carton having one-piece pouring spout sealed to innermost and outermost surfaces
GB9110902D0 (en) * 1991-05-21 1991-07-10 Ici Plc Polymeric film
US5912084A (en) * 1994-08-10 1999-06-15 E. I. Du Pont De Nemours And Company Packaging seal layer
JP2000043915A (ja) 1998-07-29 2000-02-15 Toppan Printing Co Ltd 耐圧性蓋体
JP2000179103A (ja) * 1998-12-16 2000-06-27 Tsutsunaka Plast Ind Co Ltd 防水シート敷設用固定治具及び防水シートの敷設方法
JP3947321B2 (ja) * 1999-03-04 2007-07-18 パイオニア株式会社 発泡成形体およびその成形方法およびそれによるスピーカ振動板
JP2000326413A (ja) * 1999-05-20 2000-11-28 Meiwa Ind Co Ltd 超音波溶着方法
CN100334193C (zh) * 2003-11-17 2007-08-29 株式会社日立制作所 细胞培养容器、以及培养细胞
JP4558374B2 (ja) 2004-05-11 2010-10-06 上野製薬株式会社 液晶ポリエステル樹脂組成物の接合方法および液晶ポリエステル樹脂組成物接合体
JP2007253508A (ja) 2006-03-24 2007-10-04 Toppan Printing Co Ltd 超音波融着体
US20090045210A1 (en) * 2007-08-18 2009-02-19 Tilton Christopher R Pliable ground calcium carbonates storage articles and method of making same
JP2013129077A (ja) 2011-12-20 2013-07-04 Teijin Dupont Films Japan Ltd インモールド転写箔用積層ポリエステルフィルム
JP6083248B2 (ja) * 2013-02-08 2017-02-22 東レ株式会社 繊維強化熱可塑性樹脂一体化構造体の製造方法
JP6499581B2 (ja) * 2013-06-26 2019-04-10 三菱瓦斯化学株式会社 難燃性シートまたはフィルム、及びそれを用いた製品及びその製造方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4865217A (en) * 1987-08-31 1989-09-12 Sumitomo Bakelite Company, Limited Easily openable sealed container
US20140326391A1 (en) * 2011-11-08 2014-11-06 Dai Nippon Printing Co., Ltd. Method for producing cell culture vessel

Also Published As

Publication number Publication date
KR20170131477A (ko) 2017-11-29
JPWO2016152974A1 (ja) 2018-01-18
WO2016152974A1 (ja) 2016-09-29
CN107405890B (zh) 2020-09-29
CN107405890A (zh) 2017-11-28
JP6718863B2 (ja) 2020-07-08
KR102427367B1 (ko) 2022-07-29
US20180071995A1 (en) 2018-03-15
TW201702075A (zh) 2017-01-16

Similar Documents

Publication Publication Date Title
EP3112421B1 (en) Polyamide resin composition for molded article to be in contact with high-pressure hydrogen, and molded article obtained therefrom
TWI738642B (zh) 熱塑性樹脂薄膜層合體、及含有熱塑性樹脂薄膜層合體之成形品
JP6688574B2 (ja) ホットメルト接着性樹脂フィルムおよびその製造方法
US11111384B1 (en) Polyamide resin composition for blow-molded products exposed to high-pressure hydrogen, and blow-molded product
EP1238011A1 (en) Thermoplastic compositions having high dimensional stability
EP2594387A1 (en) Polymer article and method for producing polymer article
WO2008018473A1 (fr) Feuille conductrice
JP2009226615A (ja) 表面機能層を有する樹脂成形体の製造方法及びその成形体
JP6910041B2 (ja) 炭素繊維複合材料
JP6126457B2 (ja) チャック成型品
JP5935956B1 (ja) 高圧水素に触れる成形品用のポリアミド樹脂組成物およびそれを用いた成形品
JPH09248851A (ja) ポリアセタール樹脂の多層ブロー成形品及びその製造方法
US11261326B2 (en) Polyamide resin composition for extrusion molded products exposed to high-pressure hydrogen, and extrusion molded product
TW201141945A (en) Ignition resistant enclosure for electronic components
WO2014038508A1 (ja) 衝撃吸収部材
JP2021172017A (ja) 高圧水素に触れる中空成形品の製造方法
TW202344376A (zh) 樹脂片、容器、承載帶、以及電子元件封裝體
JP2021172018A (ja) 高圧水素に触れる中空成形品の製造方法
JP2024145412A (ja) 樹脂組成物、ペレット、成形品、樹脂組成物の製造方法、キット、レーザー溶着品、および、レーザー溶着品の製造方法
JPS62134242A (ja) ポリエステルシ−トの熱成形法
CN116547146A (zh) 树脂膜材料、具备树脂膜材料的层叠结构体、树脂组合物的制造方法、树脂膜材料的制造方法和层叠结构体的制造方法
JPS61207459A (ja) 耐衝撃性ポリエステル樹脂組成物