TWI723298B - 不含鹼之磷硼矽酸鹽玻璃 - Google Patents
不含鹼之磷硼矽酸鹽玻璃 Download PDFInfo
- Publication number
- TWI723298B TWI723298B TW107140683A TW107140683A TWI723298B TW I723298 B TWI723298 B TW I723298B TW 107140683 A TW107140683 A TW 107140683A TW 107140683 A TW107140683 A TW 107140683A TW I723298 B TWI723298 B TW I723298B
- Authority
- TW
- Taiwan
- Prior art keywords
- glass
- mol
- less
- core
- melt
- Prior art date
Links
- 239000011521 glass Substances 0.000 title claims abstract description 182
- 239000005340 laminated glass Substances 0.000 claims abstract description 16
- 238000005253 cladding Methods 0.000 claims description 29
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 23
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 20
- 239000000156 glass melt Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 16
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 13
- 239000003607 modifier Substances 0.000 claims description 13
- 229910052783 alkali metal Inorganic materials 0.000 claims description 12
- 150000001340 alkali metals Chemical class 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000006025 fining agent Substances 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 239000008395 clarifying agent Substances 0.000 claims description 5
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- -1 B 2 O 3 Inorganic materials 0.000 claims description 3
- 239000010410 layer Substances 0.000 claims 5
- 239000011247 coating layer Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000006059 cover glass Substances 0.000 abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 229910018404 Al2 O3 Inorganic materials 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 7
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000003286 fusion draw glass process Methods 0.000 description 5
- 239000006060 molten glass Substances 0.000 description 4
- 239000005358 alkali aluminosilicate glass Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000007496 glass forming Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 229910001491 alkali aluminosilicate Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002419 bulk glass Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000003280 down draw process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical group [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 239000013558 reference substance Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000003283 slot draw process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000006058 strengthened glass Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/02—Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
- C03B17/064—Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
- B32B2457/208—Touch screens
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361821426P | 2013-05-09 | 2013-05-09 | |
| US61/821,426 | 2013-05-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201920033A TW201920033A (zh) | 2019-06-01 |
| TWI723298B true TWI723298B (zh) | 2021-04-01 |
Family
ID=50897940
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW107140683A TWI723298B (zh) | 2013-05-09 | 2014-05-09 | 不含鹼之磷硼矽酸鹽玻璃 |
| TW103116578A TWI646065B (zh) | 2013-05-09 | 2014-05-09 | 不含鹼之磷硼矽酸鹽玻璃 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103116578A TWI646065B (zh) | 2013-05-09 | 2014-05-09 | 不含鹼之磷硼矽酸鹽玻璃 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9527767B2 (OSRAM) |
| EP (1) | EP2994434B1 (OSRAM) |
| JP (1) | JP6784592B2 (OSRAM) |
| KR (1) | KR102243019B1 (OSRAM) |
| CN (1) | CN105358497B (OSRAM) |
| TW (2) | TWI723298B (OSRAM) |
| WO (1) | WO2014182753A1 (OSRAM) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9346699B2 (en) | 2008-10-06 | 2016-05-24 | Corning Incorporated | Method of making a glass laminate having controlled strength |
| EP3831785A1 (en) * | 2013-08-15 | 2021-06-09 | Corning Incorporated | Alkali-doped and alkali-free boroaluminosilicate glass |
| KR102255630B1 (ko) | 2013-08-15 | 2021-05-25 | 코닝 인코포레이티드 | 중간 내지 높은 cte 유리 및 이를 포함하는 유리 물품 |
| WO2015148618A1 (en) * | 2014-03-27 | 2015-10-01 | Corning Incorporated | Glass article |
| US10562272B2 (en) * | 2014-12-08 | 2020-02-18 | Corning Incorporated | Laminated glass article with low compaction and method for forming the same |
| TWI710537B (zh) * | 2015-04-03 | 2020-11-21 | 日商日本電氣硝子股份有限公司 | 玻璃 |
| US11472730B2 (en) * | 2015-06-02 | 2022-10-18 | Corning Incorporated | Laminated glass article with tinted layer |
| WO2017079540A1 (en) * | 2015-11-05 | 2017-05-11 | Corning Incorporated | Laminated glass article with determined modulus contrast and method for forming the same |
| TWI714698B (zh) | 2016-01-12 | 2021-01-01 | 日商日本電氣硝子股份有限公司 | 玻璃 |
| CN106630618A (zh) * | 2016-12-21 | 2017-05-10 | 蚌埠玻璃工业设计研究院 | 一种防辐射的低熔点高弹性玻璃基板 |
| NL2020896B1 (en) | 2018-05-08 | 2019-11-14 | Corning Inc | Water-containing glass-based articles with high indentation cracking threshold |
| US11236012B2 (en) | 2018-03-28 | 2022-02-01 | Corning Incorporated | Boron phosphate glass-ceramics with low dielectric loss |
| CN108467197A (zh) * | 2018-06-05 | 2018-08-31 | 中建材蚌埠玻璃工业设计研究院有限公司 | 一种适用于浮法成型的无碱玻璃配合料 |
| CN108483900A (zh) * | 2018-06-05 | 2018-09-04 | 中建材蚌埠玻璃工业设计研究院有限公司 | 一种适用于浮法成型的低磷无碱玻璃配合料 |
| CN109052936B (zh) * | 2018-09-04 | 2021-11-05 | 中国南玻集团股份有限公司 | 硅酸盐玻璃及其制备方法、玻璃基板和显示器 |
| EP3882222A4 (en) | 2018-11-14 | 2022-08-10 | Agc Inc. | Glass substrate for high frequency device, liquid crystal antenna and high frequency device |
| TW202026261A (zh) * | 2018-11-16 | 2020-07-16 | 美商康寧公司 | 可水蒸氣強化無鹼玻璃組成物 |
| TWI891613B (zh) | 2018-11-16 | 2025-08-01 | 美商康寧公司 | 用於透過蒸氣處理而強化之玻璃成分及方法 |
| CN113165949A (zh) * | 2018-12-10 | 2021-07-23 | 日本电气硝子株式会社 | 无碱玻璃 |
| KR20210154825A (ko) * | 2019-04-23 | 2021-12-21 | 코닝 인코포레이티드 | 확정 응력 프로파일을 갖는 유리 라미네이트 및 그 제조방법 |
| CN114127024B (zh) | 2019-05-16 | 2023-10-24 | 康宁股份有限公司 | 具有蒸汽处理雾度抗性的玻璃组合物及其方法 |
| US12122711B2 (en) | 2019-05-16 | 2024-10-22 | Corning Incorporated | Steam strengthenable glass compositions with low phosphorous content |
| WO2020231959A1 (en) | 2019-05-16 | 2020-11-19 | Corning Incorporated | Glasses with modified young's modulus profile |
| GB202012825D0 (en) | 2020-05-12 | 2020-09-30 | Corning Inc | Fusion formable and steam strengthenable glass compositions with platinum compatibility |
| TW202248010A (zh) | 2021-03-30 | 2022-12-16 | 美商康寧公司 | 具有多孔層之抗反射紅外線傳輸積層玻璃製品 |
| CN116854454B (zh) * | 2023-07-11 | 2024-01-26 | 上海大学 | 一种微波介质陶瓷组合物、微波介质陶瓷材料及其应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200531950A (en) * | 2003-12-30 | 2005-10-01 | Corning Inc | High strain point glasses |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4350532A (en) | 1980-09-08 | 1982-09-21 | Minnesota Mining And Manufacturing Company | Glass composition and articles |
| JPS6036349A (ja) | 1983-08-05 | 1985-02-25 | Ngk Spark Plug Co Ltd | ガラス組成物 |
| KR860008953A (ko) * | 1985-05-23 | 1986-12-19 | 알프레드 엘. 마이클센 | 함수소 글라스 미세포말 및 가스- 세라믹과 그 제조 방법 |
| SU1377250A1 (ru) | 1985-12-23 | 1988-02-28 | Предприятие П/Я В-2268 | Стекло |
| JPS6311543A (ja) * | 1986-06-30 | 1988-01-19 | Hoya Corp | 低膨張ガラス |
| JPH05508828A (ja) * | 1990-07-11 | 1993-12-09 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | 電子部品包装のためのボロンアルミニウムホスフェート及びボロンアルミニウムホスホシリケート |
| JPH06311543A (ja) | 1993-04-20 | 1994-11-04 | Oki Electric Ind Co Ltd | 出力バッファ型自己ルーティングスイッチ |
| JP2002003240A (ja) | 2000-06-19 | 2002-01-09 | Nippon Electric Glass Co Ltd | 液晶ディスプレイ用ガラス基板 |
| JP2002308643A (ja) * | 2001-02-01 | 2002-10-23 | Nippon Electric Glass Co Ltd | 無アルカリガラス及びディスプレイ用ガラス基板 |
| JP4453240B2 (ja) | 2002-05-16 | 2010-04-21 | 日本電気硝子株式会社 | 無アルカリガラス及びこれを用いたディスプレイ用ガラス基板 |
| DE10311802B4 (de) | 2003-03-12 | 2006-03-02 | Schott Ag | Boroaluminosilikatglas und dessen Verwendung |
| KR101043181B1 (ko) * | 2003-12-31 | 2011-06-20 | 코닝 인코포레이티드 | 알루미늄 실리코포스페이트 유리 |
| US7201965B2 (en) * | 2004-12-13 | 2007-04-10 | Corning Incorporated | Glass laminate substrate having enhanced impact and static loading resistance |
| DE102005034785B3 (de) * | 2005-07-21 | 2007-01-25 | Schott Ag | Glaszusammensetzung ausschließlich bestehend aus Oxiden,welche bei Reaktion mit Fluor schon bei niedrigen Temperaturen flüchtige Fluoride ausbilden, sowie deren Verwendung |
| US7635521B2 (en) * | 2006-02-10 | 2009-12-22 | Corning Incorporated | Glass compositions for protecting glass and methods of making and using thereof |
| DE102008056323B8 (de) * | 2007-11-21 | 2019-01-03 | Schott Ag | Verwendung von alkalifreien Aluminoborosilikatgläsern für Leuchtmittel mit außen- oder innenliegender Kontaktierung |
| JP5757451B2 (ja) * | 2009-03-18 | 2015-07-29 | 日本電気硝子株式会社 | 無アルカリガラス |
| US8486850B2 (en) | 2010-09-13 | 2013-07-16 | Schott Corporation | Aluminophosphate glass composition |
| US9346703B2 (en) | 2010-11-30 | 2016-05-24 | Corning Incorporated | Ion exchangable glass with deep compressive layer and high damage threshold |
| US8785336B2 (en) * | 2011-03-14 | 2014-07-22 | Nippon Electric Glass Co., Ltd. | Alkali-free glass |
| JP5935471B2 (ja) * | 2011-04-25 | 2016-06-15 | 日本電気硝子株式会社 | 液晶レンズ |
| TWI572480B (zh) * | 2011-07-25 | 2017-03-01 | 康寧公司 | 經層壓及離子交換之強化玻璃疊層 |
-
2014
- 2014-05-01 US US14/267,086 patent/US9527767B2/en active Active
- 2014-05-07 EP EP14729169.4A patent/EP2994434B1/en active Active
- 2014-05-07 CN CN201480037375.3A patent/CN105358497B/zh active Active
- 2014-05-07 WO PCT/US2014/037043 patent/WO2014182753A1/en not_active Ceased
- 2014-05-07 JP JP2016513032A patent/JP6784592B2/ja not_active Expired - Fee Related
- 2014-05-07 KR KR1020157033782A patent/KR102243019B1/ko not_active Expired - Fee Related
- 2014-05-09 TW TW107140683A patent/TWI723298B/zh active
- 2014-05-09 TW TW103116578A patent/TWI646065B/zh not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200531950A (en) * | 2003-12-30 | 2005-10-01 | Corning Inc | High strain point glasses |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI646065B (zh) | 2019-01-01 |
| WO2014182753A1 (en) | 2014-11-13 |
| KR102243019B1 (ko) | 2021-04-22 |
| JP2016517841A (ja) | 2016-06-20 |
| EP2994434A1 (en) | 2016-03-16 |
| TW201920033A (zh) | 2019-06-01 |
| EP2994434B1 (en) | 2021-07-21 |
| CN105358497B (zh) | 2021-04-20 |
| US9527767B2 (en) | 2016-12-27 |
| CN105358497A (zh) | 2016-02-24 |
| KR20160006715A (ko) | 2016-01-19 |
| US20140335331A1 (en) | 2014-11-13 |
| JP6784592B2 (ja) | 2020-11-11 |
| TW201444781A (zh) | 2014-12-01 |
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