TWI694127B - 一種黏結方法 - Google Patents

一種黏結方法 Download PDF

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TWI694127B
TWI694127B TW107100827A TW107100827A TWI694127B TW I694127 B TWI694127 B TW I694127B TW 107100827 A TW107100827 A TW 107100827A TW 107100827 A TW107100827 A TW 107100827A TW I694127 B TWI694127 B TW I694127B
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Taiwan
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bonded
carbon nanotube
super
carbon
serial
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TW107100827A
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TW201930506A (zh
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金翔
巫梓鵬
苗文韜
姜開利
范守善
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鴻海精密工業股份有限公司
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Abstract

本發明提供一種黏結方法,包括:提供一第一待黏結物,該第一待黏結物包括第一待黏結面;將奈米碳管結構鋪設在該第一待黏結面上,該奈米碳管結構包括至少一層超順排奈米碳管膜,該超順排奈米碳管膜包括複數個奈米碳管,該複數個奈米碳管基本朝同一方向延伸,且該複數個奈米碳管的延伸方向基本平行於超順排奈米碳管膜的表面;提供第二待黏結物,該第二待黏結物包括一第二待黏結面,將該第二待黏結面覆蓋並接觸所述奈米碳管結構;以及施加一壓力於所述第一待黏結物和一第二待黏結物。

Description

一種黏結方法
本發明涉及一種黏結方法,尤其是一種採用奈米碳管結構對物體進行黏結的方法。
先前技術中一般採用雙面膠或膠黏劑將物體之間進行黏結。然而,先前的黏結方法一般適用的溫度範圍很窄,當處於高溫環境或者低溫環境時,黏結劑會失去黏性。
有鑑於此,確有必要提供一種黏結方法,採用該黏結方法所黏結的物體在高溫和低溫下均可以保持良好的穩定性。
一種黏結方法,其包括以下步驟:提供一第一待黏結物,該第一待黏結物包括一第一待黏結面,該第一待黏結面的表面粗糙度小於等於1.0微米;將一奈米碳管結構鋪設在所述第一待黏結面上,該奈米碳管結構包括至少一層超順排奈米碳管膜,該超順排奈米碳管膜包括複數個奈米碳管,該複數個奈米碳管基本朝同一方向延伸,且該複數個奈米碳管的延伸方向基本平行於超順排奈米碳管膜的表面;提供一第二待黏結物,該第二待黏結物包括一第二待黏結面,將該第二待黏結面覆蓋並接觸所述奈米碳管結構,使所述奈米碳管結構位於所述第一待黏結物與第二待黏結物之間,該第二待黏結面的表面粗糙度小於等於1.0微米;以及施加一壓力於所述第一待黏結物和一第二待黏結物,進而黏結所述第一待黏結物和一第二待黏結物。
一種黏結方法,其包括以下步驟:提供一第一待黏結物,該第一待黏結物包括一第一待黏結面,該第一待黏結面為一光滑表面;將一奈米碳管 結構鋪設在所述第一待黏結面上,該奈米碳管結構由複數個奈米碳管組成,該複數個奈米碳管首尾相連且沿同一方向延伸,且延伸方向平行於奈米碳管結構的表面,所述複數個奈米碳管通過凡得瓦力相互連接;提供一第二待黏結物,該第二待黏結物包括一第二待黏結面,且該第二待黏結面為一光滑表面,將該第二待黏結面覆蓋並接觸所述奈米碳管結構,使所述奈米碳管結構位於所述第一待黏結物與第二待黏結物之間;以及施加一壓力於所述第一待黏結物和一第二待黏結物,進而黏結所述第一待黏結物和一第二待黏結物。
與先前技術相比較,由本發明提供的黏結方法具有以下優點,該奈米碳管結構僅通過凡得瓦力使第一待黏結物和第二待黏結物很好的黏結在一起,由於凡得瓦力受溫度影響較小,因此所述黏結方法的使用溫度範圍較大,例如在-196℃~1000℃的範圍內均可以使第一待黏結物和第二待黏結物之間很好的黏結。
10:第一待黏結物
100:第一待黏結面
20:奈米碳管結構
30:第二待黏結物
圖1為本發明實施例提供的黏結方法的流程圖。
圖2為本發明實施例提供的黏結方法的的過程的示意圖。
圖3為本發明實施例提供的超順排奈米碳管膜的掃描電子顯微鏡照片。
圖4為本發明實施例提供的黏結方法中奈米碳管結構包括多層超順排奈米碳管膜時的結構示意圖。
圖5為本發明實施例提供的奈米碳管結構包括8層超順排奈米碳管膜時的掃描電子顯微鏡照片。
圖6為本發明實施例提供的奈米碳管結構包括50層超順排奈米碳管膜時的掃描電子顯微鏡照片。
圖7為本發明實施例提供的奈米碳管結構的張力隨拉伸長度的變化曲線。
圖8為本發明實施例提供的矽片表面張力隨奈米碳管結構中超順排奈米碳管層數的變化曲線。
圖9為本發明實施例提供的矽片表面張力隨施加壓力的變化曲線。
下麵將結合附圖及具體實施例對本發明作進一步的詳細說明。
請參閱圖1和2,本發明第一實施例提供一種黏結方法,包括以下步驟:S1:提供一第一待黏結物10,該第一待黏結物10包括一第一待黏結面100,該第一待黏結面100為光滑平面;S2:將一奈米碳管結構20鋪設在所述第一待黏結面100,該奈米碳管結構20包括至少一層超順排奈米碳管膜,該超順排奈米碳管膜包括複數個奈米碳管,該複數個奈米碳管基本朝同一方向延伸,且該複數個奈米碳管的延伸方向基本平行於超順排奈米碳管膜的表面;S3:提供一第二待黏結物30,該第二待黏結物30包括一第二待黏結面300,且該第二待黏結面300為光滑表面,將該第二待黏結面300覆蓋並接觸所述奈米碳管結構20,使所述奈米碳管結構20位於所述第一待黏結物10與第二待黏結物30之間;以及S4:施加一壓力於所述第一待黏結物10和一第二待黏結物20,進而黏結所述第一待黏結物10和一第二待黏結物30。
步驟S1中,所述第一待黏結物10的材料和形狀不限。可以為規則的形狀也可以為不規則的形狀。所述規則的形狀包括正方體、長方體、圓錐或圓柱等。所述第一待黏結物10的材料可以為玻璃、石英片、矽片、PET片等等。所述第一待黏結面100可以為平面,也可以為彎曲表面。本發明中的所述奈米碳管結構20和第一待黏結表面100之間僅通過凡得瓦力黏結在一起,如果第一待黏結表面100的表面粗糙度太大或者不乾淨,均會降低奈米碳管結構20與第一待黏結表面100之間的凡得瓦力,進而影響奈米碳管結構20與第一待黏結表面100之間的黏結力。所述第一待黏結面100優選為乾淨的光滑平面。所述乾淨的光滑平面是指表面幾乎不含或者完全不含任何雜質、灰塵等且表面粗糙度較小。優選的,所述第一待黏結面100的表面粗糙度小於等於1.0微米。更優選的,所述第一待黏結面100的表面粗糙度小於等於0.1微米。當第一待黏結表面100為乾淨的光滑表面且表面粗糙度小於等於1.0微米時,奈米碳管結構20和第一待黏結表面100之間的凡得瓦力較大,進而提高第一待黏結物10和奈米碳管結構20之間的黏結力。本實施例中,所述第一待黏結物10為一邊長為7毫米的正方形矽片。
步驟S2中,請參閱圖3,所述超順排奈米碳管膜中的複數個奈米碳管基本朝同一方向延伸是指超順排奈米碳管膜中大多數奈米碳管的延伸方向朝同一方向,僅存在少數隨機排列的奈米碳管,這些奈米碳管不會對超順排奈米碳管膜中大多數奈米碳管的整體延伸方向構成明顯影響,該少數隨機排列的奈米碳管可以忽略。所述超順排奈米碳管膜中的複數個奈米碳管是通過凡得瓦力首尾相連。進一步地,所述超順排奈米碳管膜中每一奈米碳管與在延伸方向上相鄰的奈米碳管通過凡得瓦力首尾相連。所述超順排奈米碳管膜中的複數個奈米碳管為純奈米碳管,純奈米碳管是指奈米碳管未經過任何物理、化學等修飾,奈米碳管的表面純淨(純淨度達到99.9%以上),基本不含有雜質,如無定型碳或殘留的催化劑金屬顆粒等。因此,所述奈米碳管結構中不含有有機溶劑,對環境基本上沒有污染。
所述超順排奈米碳管膜為一自支撐結構,所謂自支撐是指超順排奈米碳管膜無需其它基體支撐,可自支撐保持一膜的形態。因此,所述超順排奈米碳管膜可直接鋪設於所述第一待黏結表面100上,並與該第一待黏結表面100貼合設置。
請參閱圖4~6,當所述奈米碳管結構20包括至少兩層超順排奈米碳管膜時,該至少兩層超順排奈米碳管膜重疊且平行設置。相鄰兩個超順排奈米碳管膜之間通過凡得瓦力緊密連接。該至少兩層超順排奈米碳管膜中每層超順排奈米碳管膜中奈米碳管的延伸方向與其它層超順排奈米碳管膜中奈米碳管的延伸方向基本相同。
當所述奈米碳管結構20包括一層所述超順排奈米碳管膜時,將所述奈米碳管結構20鋪設在所述第一待黏結表面100包括:步驟S21,提供一超順排奈米碳管陣列;以及步驟S22,採用一拉伸工具從所述超順排奈米碳管陣列中拉取所述超順排奈米碳管膜,將該超順排奈米碳管膜直接鋪設在所述第一待黏結表面100上。步驟S22具體包括以下步驟:步驟S221,從所述超順排奈米碳管陣列中選定一定寬度的複數個奈米碳管片斷;以及步驟S222,以一定速度沿基本垂直於所述超順排奈米碳管陣列生長方向拉伸該複數個奈米碳管片斷,以形成一連續的超順排奈米碳管膜,將該超順排奈米碳管膜直接鋪設在所述第一待黏結表面100。
當所述奈米碳管結構20包括至少兩層超順排奈米碳管膜時,將所述奈米碳管結構20直接鋪設在所述第一待黏結表面100的方法進一步包括一在步驟S222中的超順排奈米碳管膜的表面直接重疊且平行鋪設至少一層所述超順排奈米碳管膜的步驟。
可以理解,也可以預先形成所述奈米碳管結構20後再將該奈米碳管結構20鋪設於所述第一待黏結表面100。其具體可包括以下步驟:提供一支撐結構;將一層所述超順排奈米碳管膜或至少兩層超順排奈米碳管膜重疊且平行設置於該支撐結構的表面形成一奈米碳管結構20;將該奈米碳管結構20從該支撐結構上取下,鋪設於所述第一待黏結表面100。可以理解,所述支撐結構可以為一基底,也可以為一框架結構。當支撐結構為一框架結構時,奈米碳管結構20可部分懸空,此時可直接將懸空的奈米碳管結構20直接鋪設於第一待黏結表面100上,再將該框架結構的支撐結構去除。
步驟S21中的所述超順排奈米碳管陣列中的奈米碳管純淨且奈米碳管長度較長,一般大於300微米。所述超順排奈米碳管陣列的製備方法不限,可以為化學氣相沉積法、電弧放電製備方法或氣溶膠製備方法等。本實施例中,所述超順排奈米碳管陣列的製備方法採用化學氣相沉積法,其具體步驟包括:(a)提供一基底,該基底可選用P型矽基底、N型矽基底或形成有氧化層的矽基底等;(b)在基底表面均勻形成一催化劑層,該催化劑層材料可選用鐵(Fe)、鈷(Co)、鎳(Ni)或其任意組合的合金之一;(c)將上述形成有催化劑層的基底在700~900℃的空氣中退火約30分鐘~90分鐘;(d)將處理過的基底置於反應爐中,在保護氣體環境下加熱到500~740℃,然後通入碳源氣體反應約5~30分鐘,生長得到超順排奈米碳管陣列,其高度為200~400微米。本實施例中碳源氣可選用乙炔等化學性質較活潑的碳氫化合物,保護氣體可選用氮氣、氨氣或惰性氣體。所述超順排奈米碳管陣列的製備方法可以參見中國專利CN1483668A。採用上述方法生長出的超順排奈米碳管陣列中,奈米碳管表面純淨,不含雜質或者幾乎不含雜質,因此,奈米碳管表面具有較強的凡得瓦力。
可選擇地,步驟S2進一步包括一步驟S23,步驟S23包括:對所述超順排奈米碳管膜進行拉伸。即在步驟S22得到所述超順排奈米碳管膜之後,採用一拉伸工具沿所述超順排奈米碳管膜中奈米碳管的延伸方向繼續將該超順排奈米碳管膜拉伸一定的長度。優選的,該拉伸的長度為1~3毫米。更優選的, 該拉伸的長度為3毫米。該拉伸的步驟可以使超順排奈米碳管膜中隨機排列的一些奈米碳管的延伸方向與大多數奈米碳管的延伸方向一致,使超順排奈米碳管膜的表面更光滑。請參閱圖7,分別採用沒有拉伸的10層超順排奈米碳管膜形成的奈米碳管結構,拉伸1毫米的10層超順排奈米碳管膜形成的奈米碳管結構、拉伸2毫米的10層超順排奈米碳管膜形成的奈米碳管結構、拉伸3毫米的10層超順排奈米碳管膜形成的奈米碳管結構,以及拉伸4毫米的10層超順排奈米碳管膜形成的奈米碳管結構黏結兩個邊長為7毫米的正方形矽片,拉伸之前奈米碳管結構的長度均為174mm,從圖中可以看出,當拉伸的距離小於3毫米時,即當拉伸的長度與超順排奈米碳管膜原始長度的百分比小於0.57時,兩個矽片之間的黏結力隨著拉伸長度的增加而增大,而當拉伸距離大於3毫米時,即當拉伸的長度與超順排奈米碳管膜原始長度的百分比大於0.57時兩個矽片之間的黏結力隨著拉伸長度的增加而減小。
所述奈米碳管結構20中超順排奈米碳管膜的層數不限,可以根據實際需要進行選擇。優選的,所述奈米碳管結構20中超順排奈米碳管膜的層數為5~30層。更優選的,所述超順排奈米碳管膜的層數為10~15層。請參閱圖8,分別採用由1層、2層、4層、6層、8層、10層、12層、15層、30層超順排奈米碳管膜10組成的奈米碳管結構作為雙面膠黏結兩個邊長為7毫米的正方形矽片,從圖中可以看出,當兩個矽片之間沒有奈米碳管結構20時,兩個矽片完全沒有黏結力;隨著奈米碳管結構20中超順排奈米碳管膜的層數增加,兩個矽片之間的黏結力增加,當奈米碳管結構20中超順排奈米碳管膜層數大於15層之後,黏結力隨超順排奈米碳管膜的層數增加的速率減慢。本實施例中,所述奈米碳管結構20包括10層超順排奈米碳管膜重疊且平行設置。
步驟S3中,可以理解,在同一實施例中,第二待黏結物30的形狀可以與第一待黏結物10的形狀相同,也可以不同;第二待黏結物30的材料可以與第一待黏結物10的材料相同,也可以不同。所述第二待黏結面300可以為平面,也可以為彎曲表面。所述奈米碳管結構20和第二待黏結表面300之間僅通過凡得瓦力黏結在一起,如果第二待黏結表面300的表面粗糙度太大或者不乾淨,均會降低奈米碳管結構20與第二待黏結表面300之間的凡得瓦力,進而影響奈米碳管結構20與第二待黏結表面300之間的黏結力。所述第二待黏結面300優選為乾淨的光滑平面。所述乾淨的光滑平面是指表面幾乎不含或者完全不含任何雜 質、灰塵等且表面粗糙度較小。優選的,所述第二待黏結面300的表面粗糙度小於等於1.0微米。更優選的,所述第二待黏結面300的表面粗糙度小於等於0.1微米。當第二待黏結表面300為乾淨的光滑表面且表面粗糙度小於等於1.0微米時,奈米碳管結構20和第一待黏結表面100之間的凡得瓦力較大,進而提高第二待黏結物30和奈米碳管結構20之間的黏結力。本實施例中,所述第二待黏結物30所包括的形狀和材料與第一待黏結物10所包括的形狀和材料相同。
步驟S4中,所述壓力的大小根據所述第一待黏結物10和第二待黏結物30的體積,第一待黏結面100和第二待黏結面300的面積等實際需要設定。優選的,所述壓力的大小為10~20N。
請參閱圖9,採用由10層超順排奈米碳管膜組成的奈米碳管結構作為雙面膠黏結兩個邊長為7毫米的正方形矽片,施加不同的壓力於兩個邊長為7毫米的正方形矽片,由圖中可以看出,隨著施加壓力的增加,兩個矽片的黏結力增大。
本發明本發明第二實施例提供一種黏結方法,本實施例中的黏結方法與第一實施例中的黏結方法基本上相同,其不同僅在於,本實施例中步驟S2中的奈米碳管結構由至少一層超順排奈米碳管膜組成,且該超順排奈米碳管膜由複數個基本朝同一方向延伸的奈米碳管組成。
本發明第三實施例提供一黏結方法,本實施例中的黏結方法與第一實施例中的黏結方法基本上相同,其不同僅在於,本實施例中步驟S2中的奈米碳管結構由複數個奈米碳管組成,該複數個奈米碳管首尾相連且沿同一方向延伸,且延伸方向平行於奈米碳管結構的表面,所述複數個奈米碳管通過凡得瓦力相互連接。
本實施例中的複數個奈米碳管為純奈米碳管,純奈米碳管是指奈米碳管未經過任何物理、化學等修飾,奈米碳管的表面純淨(純淨度達到99.9%以上),基本不含有雜質,如無定型碳或殘留的催化劑金屬顆粒等。
本發明提供的黏結方法具有很多優點:第一,所述奈米碳管結構僅通過凡得瓦力將第一待黏結物和第二待黏結物黏結在一起。溫度對凡得瓦力的影響很小,因此,所述奈米碳管結構在高溫和低溫下仍然具有很好的黏性,進而使所述該黏結方法的應用溫度範圍較廣。而且,由於所述超順排奈米碳管膜中的奈米碳管的表面純淨,基本不含有無定型碳或殘留的催化劑金屬顆粒 等,所以該超順排奈米碳管膜具有很高的熱穩定性,即使在很高的溫度下也不易氧化。優選的,所述黏結方法的應用溫度範圍為-196℃~1000℃。第二,由於奈米碳管結構中超順排奈米碳管膜中的奈米碳管非常純淨,且由於奈米碳管本身的比表面積非常大,所以該超順排奈米碳管膜本身具有較強的黏性,由其形成的奈米碳管結構也具有很強的黏性,因此該黏結方法可以很好的黏結和固定物體。第三,該黏結方法中,由於所述奈米碳管結構僅通過凡得瓦力將第一黏結物和第二黏結物黏結在一起,當黏結在一起的第一黏結物和第二黏結物之間需要分開時,只需要施加一定的力即可,該奈米碳管結構可以從第一待黏結表面和待第二黏結表面去除乾淨,不會對第一待黏結表面和第二待黏結表面造成傷害;而且本發明的黏結方法,如果黏結的位置不是很準確可以隨時進行調整。第四,所述奈米碳管結構僅通過凡得瓦力將第一待黏結物和第二待黏結物黏結在一起,且所述奈米碳管結構中的奈米碳管非常純淨,該黏結方法過程中沒有使用有機溶劑,對環境基本無污染。
綜上所述,本發明確已符合發明專利之要件,遂依法提出專利申請。惟,以上所述者僅為本發明之較佳實施例,自不能以此限制本案之申請專利範圍。舉凡習知本案技藝之人士援依本發明之精神所作之等效修飾或變化,皆應涵蓋於以下申請專利範圍內。

Claims (11)

  1. 一種黏結方法,其包括以下步驟:提供一第一待黏結物,該第一待黏結物包括一第一待黏結面,該第一待黏結面的表面粗糙度小於等於1.0微米;將一奈米碳管結構鋪設在所述第一待黏結面上,該奈米碳管結構包括至少一層超順排奈米碳管膜,該超順排奈米碳管膜包括複數個奈米碳管,該複數個奈米碳管基本朝同一方向延伸,且該複數個奈米碳管的延伸方向基本平行於超順排奈米碳管膜的表面以及第一待粘結物的表面;提供一第二待黏結物,該第二待黏結物包括一第二待黏結面,將該第二待黏結面覆蓋並接觸所述奈米碳管結構,使所述奈米碳管結構位於所述第一待黏結物與第二待黏結物之間,該第二待黏結面的表面粗糙度小於等於1.0微米;以及施加一壓力於所述第一待黏結物和一第二待黏結物,進而黏結所述第一待黏結物和一第二待黏結物。
  2. 如請求項1所述的黏結方法,其中,將所述奈米碳管結構鋪設在所述第一待黏結表面上包括:提供一超順排奈米碳管陣列;以及採用一拉伸工具從該超順排奈米碳管陣列中拉取所述超順排奈米碳管膜,並將所述超順排奈米碳管膜直接鋪設在所述第一待黏結表面上。
  3. 如請求項2所述的黏結方法,其中,所述採用拉伸工具從該超順排奈米碳管陣列中拉取所述超順排奈米碳管膜包括:從所述超順排奈米碳管陣列中選定一定寬度的複數個奈米碳管片斷;以及以一定速度沿基本垂直於所述超順排奈米碳管陣列生長方向拉伸該複數個奈米碳管片斷,以形成一連續的超順排奈米碳管膜。
  4. 如請求項3所述的黏結方法,其中,所述採用拉伸工具從該超順排奈米碳管陣列中拉取所述超順排奈米碳管膜進一步包括對所述超順排奈米碳管膜進行拉伸的步驟,具體的,在得到所述超順排奈米碳管膜之後,採用一拉伸工具沿超順排奈米碳管膜中奈米碳管的延伸方向繼續將該超順排奈米碳管膜拉伸一定的長度。
  5. 如請求項2所述的黏結方法,其中,當所述奈米碳管結構包括至少兩層超順排奈米碳管膜時,將所述奈米碳管結構直接鋪設在所述第一待黏結表面上的方法進一步包括一在超順排奈米碳管膜的表面直接重疊且平行鋪設至少一層所述超順排奈米碳管膜的步驟。
  6. 如請求項1所述的黏結方法,其中,將一奈米碳管結構鋪設在所述第一待黏結面上包括:提供一支撐結構;將一層所述超順排奈米碳管膜或至少兩層超順排奈米碳管膜重疊且平行設置於該支撐結構的表面形成一奈米碳管結構;將該奈米碳管結構從該支撐結構上取下,鋪設於所述第一待黏結表面上。
  7. 如請求項1所述的黏結方法,其中,應用溫度範圍為-196℃~1000℃。
  8. 如請求項1所述的黏結方法,其中,所述奈米碳管結構僅通過凡得瓦力與所述第一待黏結面和第二待黏結面黏結。
  9. 如請求項1所述的黏結方法,其中,所述奈米碳管結構包括10~15層超順排奈米碳管膜重疊且平行設置。
  10. 如請求項1所述的黏結方法,其中,所述超順排奈米碳管膜中的複數個奈米碳管為純奈米碳管。
  11. 一種黏結方法,其包括以下步驟:提供一第一待黏結物,該第一待黏結物包括一第一待黏結面,該第一待黏結面為一光滑表面,該第一待黏結面的表面粗糙度小於等於1.0微米;將一奈米碳管結構鋪設在所述第一待黏結面上,該奈米碳管結構由複數個奈米碳管組成,該複數個奈米碳管首尾相連且沿同一方向延伸,且延伸方向平行於奈米碳管結構的表面,所述複數個奈米碳管通過凡得瓦力相互連接,將所述奈米碳管結構鋪設在所述第一待黏結面上包括:提供一支撐結構;將一層超順排奈米碳管膜或至少兩層超順排奈米碳管膜重疊且平行設置於該支撐結構的表面形成所述奈米碳管結構;將該奈米碳管結構從該支撐結構上取下,鋪設於所述第一待黏結表面上;提供一第二待黏結物,該第二待黏結物包括一第二待黏結面,且該第二待黏結面為一光滑表面,該第二待黏結面的表面粗糙度小於等於1.0微米,將該第二待黏結面覆蓋並接觸所述奈米碳管結構,使所述奈米碳管結構位於所述第一待黏結物與第二待黏結物之間;以及 施加一壓力於所述第一待黏結物和一第二待黏結物,進而黏結所述第一待黏結物和一第二待黏結物。
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1483668A (zh) * 2002-09-17 2004-03-24 清华大学 一种碳纳米管阵列生长方法
CN101280161A (zh) * 2007-04-06 2008-10-08 清华大学 导电胶带及其制造方法
CN102741465A (zh) * 2010-02-02 2012-10-17 应用纳米结构方案公司 包含平行排列的碳纳米管的碳纳米管并入的纤维材料、其制造方法及从其衍生的复合材料

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4273193B2 (ja) 2002-06-24 2009-06-03 フジコピアン株式会社 両面密着シート
US8202505B2 (en) * 2006-01-06 2012-06-19 National Institute Of Advanced Industrial Science And Technology Aligned carbon nanotube bulk aggregate, process for producing the same and uses thereof
CN101517700B (zh) * 2006-09-20 2014-04-16 伊利诺伊大学评议会 用于制造可转移半导体结构、器件和器件构件的松脱策略
CN101239712B (zh) * 2007-02-09 2010-05-26 清华大学 碳纳米管薄膜结构及其制备方法
US8974904B2 (en) * 2007-07-05 2015-03-10 University Of Dayton Aligned carbon nanotubes for dry adhesives and methods for producing same
CN101353164B (zh) * 2007-07-25 2011-03-30 鸿富锦精密工业(深圳)有限公司 一种高密度碳纳米管阵列的制备方法
CN101458975B (zh) * 2007-12-12 2012-05-16 清华大学 电子元件
CN101920955B (zh) * 2009-06-09 2012-09-19 清华大学 碳纳米管膜保护结构及其制备方法
CN102039708B (zh) 2009-10-22 2013-12-11 清华大学 一种粘合两基体的方法
CN102087555B (zh) * 2009-12-03 2013-01-30 北京富纳特创新科技有限公司 触摸屏
CN101887829B (zh) * 2010-04-14 2013-03-13 北京富纳特创新科技有限公司 透射电镜微栅的制备方法
CN102101371B (zh) * 2010-10-29 2014-04-23 清华大学 粘合物件的方法
CN202730058U (zh) * 2012-04-05 2013-02-13 成都市华森电子信息产业有限责任公司 一种粘贴物
CN103841503B (zh) * 2012-11-20 2017-12-01 清华大学 发声芯片
CN103964410B (zh) * 2013-01-30 2016-01-13 北京富纳特创新科技有限公司 碳纳米管膜贴膜方法
US10350852B2 (en) * 2014-11-13 2019-07-16 GM Global Technology Operations LLC Systems for bonding surfaces using a releasable adhesive
CN106299430B (zh) * 2015-05-28 2018-10-02 清华大学 燃料电池的使用方法
JPWO2017082387A1 (ja) * 2015-11-12 2018-08-02 富士フイルム株式会社 液晶配向膜の製造方法、および三次元液晶セルの製造方法、ならびに三次元液晶セル
CN205468662U (zh) * 2015-11-24 2016-08-17 清华大学 触控式汽车座椅及车载娱乐系统
CN107337196B (zh) * 2016-04-28 2019-09-03 清华大学 一种碳纳米管膜的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1483668A (zh) * 2002-09-17 2004-03-24 清华大学 一种碳纳米管阵列生长方法
CN101280161A (zh) * 2007-04-06 2008-10-08 清华大学 导电胶带及其制造方法
CN102741465A (zh) * 2010-02-02 2012-10-17 应用纳米结构方案公司 包含平行排列的碳纳米管的碳纳米管并入的纤维材料、其制造方法及从其衍生的复合材料

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Chen, "Influence of packing density and surface roughness of vertically-aligned carbon nanotubes on adhesive properties of gecko-inspired mimetics.", ACS applied materials & interfaces, Vol. 7, No.6, 22 January 2015, page 3626-3632. *

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