TWI589551B - 經由ｃ－ｈ活化作用製備經取代的聯苯類之方法 - Google Patents

經由ｃ－ｈ活化作用製備經取代的聯苯類之方法 Download PDF

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TWI589551B
TWI589551B TW102127561A TW102127561A TWI589551B TW I589551 B TWI589551 B TW I589551B TW 102127561 A TW102127561 A TW 102127561A TW 102127561 A TW102127561 A TW 102127561A TW I589551 B TWI589551 B TW I589551B
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TW
Taiwan
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formula
group
aromatic hydrocarbon
alkyl
iii
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TW102127561A
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Chinese (zh)
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TW201434801A (zh
Inventor
馬修斯 瑞德里奇
拉斯 羅德菲爾德
法蘭克 渥茲
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拜耳作物科學股份有限公司
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45—Monoamines
    • C07C211/48—N-alkylated amines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/12—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
    • C07C233/15—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)
TW102127561A 2012-08-02 2013-08-01 經由ｃ－ｈ活化作用製備經取代的聯苯類之方法 TWI589551B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12179058 2012-08-02

Publications (2)

Publication Number Publication Date
TW201434801A TW201434801A (zh) 2014-09-16
TWI589551B true TWI589551B (zh) 2017-07-01

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Country Link
US (1) US9199915B2 (ar)
EP (1) EP2880013B1 (ar)
JP (1) JP6109938B2 (ar)
KR (1) KR102125294B1 (ar)
CN (1) CN104520267B (ar)
BR (1) BR112015002355B1 (ar)
DK (1) DK2880013T3 (ar)
ES (1) ES2681026T3 (ar)
IN (1) IN2015DN00665A (ar)
MX (1) MX365072B (ar)
TW (1) TWI589551B (ar)
WO (1) WO2014019995A1 (ar)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3009420A1 (de) 2014-10-16 2016-04-20 Bayer CropScience AG Verfahren zum Herstellen von Biphenylaminen aus Aniliden durch Rutheniumkatalyse
WO2015162144A1 (de) * 2014-04-25 2015-10-29 Bayer Cropscience Ag Verfahren zum herstellen von biphenylaminen aus aniliden durch rutheniumkatalyse
CN104557589A (zh) * 2014-12-24 2015-04-29 天津大学 N-(1，1’-二芳基)取代的酰胺类衍生物的制备方法
CN109678911B (zh) * 2019-02-01 2021-11-02 中国科学院上海有机化学研究所 二茂铁化合物及其制备方法
CN113563147B (zh) * 2021-07-29 2023-05-09 西湖大学 一种芳环苄位碳氢键选择性氘代的方法
CN113999130B (zh) * 2021-11-26 2023-09-29 湖北工业大学 一种邻硝基酰基苯胺类化合物的制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2119697A1 (en) * 2008-05-09 2009-11-18 Bayer CropScience AG Process for preparing substituted biphenylanilides
WO2011023324A1 (de) 2009-08-31 2011-03-03 Bayer Cropscience Ag Tetraarylborat verfahren zur herstellung von substituierten biphenylen
CN102005625A (zh) * 2010-09-28 2011-04-06 苏州群瑞环保科技有限公司 一种废旧锂电池处理的工艺方法

Also Published As

Publication number Publication date
KR20150036246A (ko) 2015-04-07
MX2015001459A (es) 2015-05-08
IN2015DN00665A (ar) 2015-06-26
US20150203440A1 (en) 2015-07-23
JP6109938B2 (ja) 2017-04-05
DK2880013T3 (en) 2018-08-06
BR112015002355B1 (pt) 2020-04-14
CN104520267B (zh) 2017-07-14
EP2880013A1 (de) 2015-06-10
BR112015002355A2 (pt) 2017-07-04
CN104520267A (zh) 2015-04-15
ES2681026T3 (es) 2018-09-11
MX365072B (es) 2019-05-22
US9199915B2 (en) 2015-12-01
TW201434801A (zh) 2014-09-16
JP2015524814A (ja) 2015-08-27
WO2014019995A1 (de) 2014-02-06
EP2880013B1 (de) 2018-05-09
KR102125294B1 (ko) 2020-06-23

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