MX365072B - Procedimiento de preparacion de bifenilos sustituidos mediante activacion c-h. - Google Patents
Procedimiento de preparacion de bifenilos sustituidos mediante activacion c-h.Info
- Publication number
- MX365072B MX365072B MX2015001459A MX2015001459A MX365072B MX 365072 B MX365072 B MX 365072B MX 2015001459 A MX2015001459 A MX 2015001459A MX 2015001459 A MX2015001459 A MX 2015001459A MX 365072 B MX365072 B MX 365072B
- Authority
- MX
- Mexico
- Prior art keywords
- activation
- preparing substituted
- substituted biphenyls
- formula
- arenes
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
- C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
- C07C211/45—Monoamines
- C07C211/48—N-alkylated amines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/12—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
- C07C233/15—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Pyridine Compounds (AREA)
Abstract
La presente invención se refiere a un procedimiento novedososo de preparación de bifenilos sustituidos de formula (III) mediante la reacción de arenos de fórmula (I) con arenos de fórmula (II) en presencia de un catalizador de metal de transición y al menos un agente oxidante. R1 es NO2, un grupo amino o amida o una base de Schiff. (ver Fórmulas).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12179058 | 2012-08-02 | ||
PCT/EP2013/065925 WO2014019995A1 (de) | 2012-08-02 | 2013-07-29 | Verfahren zum herstellen von substituierten biphenylen durch c-h-aktivierung |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2015001459A MX2015001459A (es) | 2015-05-08 |
MX365072B true MX365072B (es) | 2019-05-22 |
Family
ID=48877252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2015001459A MX365072B (es) | 2012-08-02 | 2013-07-29 | Procedimiento de preparacion de bifenilos sustituidos mediante activacion c-h. |
Country Status (12)
Country | Link |
---|---|
US (1) | US9199915B2 (es) |
EP (1) | EP2880013B1 (es) |
JP (1) | JP6109938B2 (es) |
KR (1) | KR102125294B1 (es) |
CN (1) | CN104520267B (es) |
BR (1) | BR112015002355B1 (es) |
DK (1) | DK2880013T3 (es) |
ES (1) | ES2681026T3 (es) |
IN (1) | IN2015DN00665A (es) |
MX (1) | MX365072B (es) |
TW (1) | TWI589551B (es) |
WO (1) | WO2014019995A1 (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106232573B (zh) * | 2014-04-25 | 2020-04-21 | 拜耳作物科学股份公司 | 通过钌催化由苯胺制备联苯胺的方法 |
EP3009420A1 (de) | 2014-10-16 | 2016-04-20 | Bayer CropScience AG | Verfahren zum Herstellen von Biphenylaminen aus Aniliden durch Rutheniumkatalyse |
CN104557589A (zh) * | 2014-12-24 | 2015-04-29 | 天津大学 | N-(1,1’-二芳基)取代的酰胺类衍生物的制备方法 |
CN109678911B (zh) * | 2019-02-01 | 2021-11-02 | 中国科学院上海有机化学研究所 | 二茂铁化合物及其制备方法 |
CN113563147B (zh) * | 2021-07-29 | 2023-05-09 | 西湖大学 | 一种芳环苄位碳氢键选择性氘代的方法 |
CN113999130B (zh) * | 2021-11-26 | 2023-09-29 | 湖北工业大学 | 一种邻硝基酰基苯胺类化合物的制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2119697A1 (en) * | 2008-05-09 | 2009-11-18 | Bayer CropScience AG | Process for preparing substituted biphenylanilides |
DK2473476T3 (en) | 2009-08-31 | 2015-04-20 | Bayer Ip Gmbh | Tetraarylborat method for producing substituted biphenyls |
CN102005625A (zh) * | 2010-09-28 | 2011-04-06 | 苏州群瑞环保科技有限公司 | 一种废旧锂电池处理的工艺方法 |
-
2013
- 2013-07-29 JP JP2015524756A patent/JP6109938B2/ja not_active Expired - Fee Related
- 2013-07-29 US US14/418,968 patent/US9199915B2/en not_active Expired - Fee Related
- 2013-07-29 DK DK13742231.7T patent/DK2880013T3/en active
- 2013-07-29 IN IN665DEN2015 patent/IN2015DN00665A/en unknown
- 2013-07-29 MX MX2015001459A patent/MX365072B/es active IP Right Grant
- 2013-07-29 CN CN201380041158.7A patent/CN104520267B/zh not_active Expired - Fee Related
- 2013-07-29 BR BR112015002355A patent/BR112015002355B1/pt not_active IP Right Cessation
- 2013-07-29 WO PCT/EP2013/065925 patent/WO2014019995A1/de active Application Filing
- 2013-07-29 KR KR1020157002343A patent/KR102125294B1/ko active IP Right Grant
- 2013-07-29 EP EP13742231.7A patent/EP2880013B1/de not_active Not-in-force
- 2013-07-29 ES ES13742231.7T patent/ES2681026T3/es active Active
- 2013-08-01 TW TW102127561A patent/TWI589551B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
BR112015002355A2 (pt) | 2017-07-04 |
TW201434801A (zh) | 2014-09-16 |
EP2880013A1 (de) | 2015-06-10 |
CN104520267B (zh) | 2017-07-14 |
IN2015DN00665A (es) | 2015-06-26 |
DK2880013T3 (en) | 2018-08-06 |
BR112015002355B1 (pt) | 2020-04-14 |
CN104520267A (zh) | 2015-04-15 |
ES2681026T3 (es) | 2018-09-11 |
WO2014019995A1 (de) | 2014-02-06 |
EP2880013B1 (de) | 2018-05-09 |
TWI589551B (zh) | 2017-07-01 |
US20150203440A1 (en) | 2015-07-23 |
JP2015524814A (ja) | 2015-08-27 |
JP6109938B2 (ja) | 2017-04-05 |
US9199915B2 (en) | 2015-12-01 |
KR20150036246A (ko) | 2015-04-07 |
MX2015001459A (es) | 2015-05-08 |
KR102125294B1 (ko) | 2020-06-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX365072B (es) | Procedimiento de preparacion de bifenilos sustituidos mediante activacion c-h. | |
MY161413A (en) | Catalyst composition for selective catalytic reduction of exhaust gases | |
MX2012003377A (es) | N-(1,2,5-oxadiazol-3-il)benzamidas y su utilizacion como herbicidas. | |
UA109924C2 (uk) | Аміди аміноінданів, які мають високу фунгіцидну активність та їх фітосанітарна композиція | |
PH12015501960B1 (en) | Processes for the preparation of an apoptosis-inducing agent | |
IN2015DN02567A (es) | ||
MY187910A (en) | N-prop-2-ynyl carboxamide derivatives and their use as trpa1 antagonists | |
TN2012000281A1 (en) | Mglu2 agonists | |
WO2011144983A3 (en) | An improved process for the preparation of lacosamide | |
MX363730B (es) | Procedimiento para la preparacion de derivados de acido antranilico sustituidos. | |
MX2013005753A (es) | Nuevos derivados de biaril amida. | |
MX2019000753A (es) | Proceso para preparacion de dinitrilos del acido fenilmalonico. | |
CY1118451T1 (el) | Μεθοδος παρασκευης βορικοναζολης και αναλογων αυτης | |
SA518391413B1 (ar) | عملية تحضير وتبلر لليوزيمينول | |
MX2016005223A (es) | Tinturas dispersas, su preparacion y su uso. | |
NZ702073A (en) | Methanethione compounds having antiviral activity | |
MX2015011743A (es) | Un agente quelante de polioxazolina. | |
MX361998B (es) | Procedimiento de preparacion de derivados de acido 4-haloalquil-3-mercapto-2 sustituido-hidroxibenzoico. | |
MX2016005222A (es) | Tinturas acidas, proceso para su produccion y su uso. | |
MX2016005220A (es) | Tinturas acidas, proceso para su produccion y su uso. | |
CY1116826T1 (el) | Μεθοδος ενζυματικης συνθεσης toy (7s) 3,4-ιμεθοξυδικυκλο[4.2.0]οκτα- 1,3,5-τριενο-7-καρβοξυλικου οξεος και εφαρμογη στην συνθεση της ιβαμπραδινης και των αλατων αυτης | |
MX2015009377A (es) | Compuestos radiomarcados. | |
UA79867U (ru) | Применение N-(1-нафтил)амида 2-оксоиндолин-3-глиоксиловой кислоты в качестве средства з с анксиолитическим действием | |
MD20160072A2 (ro) | Procedeu nou de sinteză a 7-metoxi-naftalină-1-carbaldehidei şi aplicarea acesteia în sinteza agomelatinei | |
MX2016005221A (es) | Tinturas acidas, proceso para su produccion y su uso. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration |