MX365072B - Procedimiento de preparacion de bifenilos sustituidos mediante activacion c-h. - Google Patents

Procedimiento de preparacion de bifenilos sustituidos mediante activacion c-h.

Info

Publication number
MX365072B
MX365072B MX2015001459A MX2015001459A MX365072B MX 365072 B MX365072 B MX 365072B MX 2015001459 A MX2015001459 A MX 2015001459A MX 2015001459 A MX2015001459 A MX 2015001459A MX 365072 B MX365072 B MX 365072B
Authority
MX
Mexico
Prior art keywords
activation
preparing substituted
substituted biphenyls
formula
arenes
Prior art date
Application number
MX2015001459A
Other languages
English (en)
Other versions
MX2015001459A (es
Inventor
Lars Rodefeld
Frank Volz
Matthias Riedrich
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of MX2015001459A publication Critical patent/MX2015001459A/es
Publication of MX365072B publication Critical patent/MX365072B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2239—Bridging ligands, e.g. OAc in Cr2(OAc)4, Pt4(OAc)8 or dicarboxylate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45—Monoamines
    • C07C211/48—N-alkylated amines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/12—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
    • C07C233/15—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Pyridine Compounds (AREA)

Abstract

La presente invención se refiere a un procedimiento novedososo de preparación de bifenilos sustituidos de formula (III) mediante la reacción de arenos de fórmula (I) con arenos de fórmula (II) en presencia de un catalizador de metal de transición y al menos un agente oxidante. R1 es NO2, un grupo amino o amida o una base de Schiff. (ver Fórmulas).
MX2015001459A 2012-08-02 2013-07-29 Procedimiento de preparacion de bifenilos sustituidos mediante activacion c-h. MX365072B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12179058 2012-08-02
PCT/EP2013/065925 WO2014019995A1 (de) 2012-08-02 2013-07-29 Verfahren zum herstellen von substituierten biphenylen durch c-h-aktivierung

Publications (2)

Publication Number Publication Date
MX2015001459A MX2015001459A (es) 2015-05-08
MX365072B true MX365072B (es) 2019-05-22

Family

ID=48877252

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015001459A MX365072B (es) 2012-08-02 2013-07-29 Procedimiento de preparacion de bifenilos sustituidos mediante activacion c-h.

Country Status (12)

Country Link
US (1) US9199915B2 (es)
EP (1) EP2880013B1 (es)
JP (1) JP6109938B2 (es)
KR (1) KR102125294B1 (es)
CN (1) CN104520267B (es)
BR (1) BR112015002355B1 (es)
DK (1) DK2880013T3 (es)
ES (1) ES2681026T3 (es)
IN (1) IN2015DN00665A (es)
MX (1) MX365072B (es)
TW (1) TWI589551B (es)
WO (1) WO2014019995A1 (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160148589A (ko) 2014-04-25 2016-12-26 바이엘 크롭사이언스 악티엔게젤샤프트 루테늄 촉매반응에 의한 아닐리드로부터 비페닐아민의 제조방법
EP3009420A1 (de) 2014-10-16 2016-04-20 Bayer CropScience AG Verfahren zum Herstellen von Biphenylaminen aus Aniliden durch Rutheniumkatalyse
CN104557589A (zh) * 2014-12-24 2015-04-29 天津大学 N-(1，1’-二芳基)取代的酰胺类衍生物的制备方法
CN109678911B (zh) * 2019-02-01 2021-11-02 中国科学院上海有机化学研究所 二茂铁化合物及其制备方法
CN113563147B (zh) * 2021-07-29 2023-05-09 西湖大学 一种芳环苄位碳氢键选择性氘代的方法
CN113999130B (zh) * 2021-11-26 2023-09-29 湖北工业大学 一种邻硝基酰基苯胺类化合物的制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2119697A1 (en) * 2008-05-09 2009-11-18 Bayer CropScience AG Process for preparing substituted biphenylanilides
JP5795583B2 (ja) 2009-08-31 2015-10-14 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ 置換ビフェニル類を調製するためのテトラアリールボレートプロセス
CN102005625A (zh) * 2010-09-28 2011-04-06 苏州群瑞环保科技有限公司 一种废旧锂电池处理的工艺方法

Also Published As

Publication number Publication date
US20150203440A1 (en) 2015-07-23
MX2015001459A (es) 2015-05-08
JP6109938B2 (ja) 2017-04-05
EP2880013A1 (de) 2015-06-10
JP2015524814A (ja) 2015-08-27
TWI589551B (zh) 2017-07-01
DK2880013T3 (en) 2018-08-06
US9199915B2 (en) 2015-12-01
KR20150036246A (ko) 2015-04-07
ES2681026T3 (es) 2018-09-11
EP2880013B1 (de) 2018-05-09
KR102125294B1 (ko) 2020-06-23
TW201434801A (zh) 2014-09-16
CN104520267A (zh) 2015-04-15
BR112015002355B1 (pt) 2020-04-14
WO2014019995A1 (de) 2014-02-06
CN104520267B (zh) 2017-07-14
BR112015002355A2 (pt) 2017-07-04
IN2015DN00665A (es) 2015-06-26

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