TWI582290B - 使用經醛官能化聚合物以提高抄紙機性能且增進上膠之方法 - Google Patents
使用經醛官能化聚合物以提高抄紙機性能且增進上膠之方法 Download PDFInfo
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- TWI582290B TWI582290B TW100136901A TW100136901A TWI582290B TW I582290 B TWI582290 B TW I582290B TW 100136901 A TW100136901 A TW 100136901A TW 100136901 A TW100136901 A TW 100136901A TW I582290 B TWI582290 B TW I582290B
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- DZGUJOWBVDZNNF-UHFFFAOYSA-N azanium;2-methylprop-2-enoate Chemical compound [NH4+].CC(=C)C([O-])=O DZGUJOWBVDZNNF-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
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- WQHCGPGATAYRLN-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl prop-2-enoate Chemical compound ClC.CN(C)CCOC(=O)C=C WQHCGPGATAYRLN-UHFFFAOYSA-N 0.000 description 1
- QTVYEVBMJKSGLP-UHFFFAOYSA-N chloromethane;ethyl 2-methylprop-2-enoate;n-methylmethanamine Chemical compound ClC.CNC.CCOC(=O)C(C)=C QTVYEVBMJKSGLP-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000011436 cob Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000412 dendrimer Substances 0.000 description 1
- 229920000736 dendritic polymer Polymers 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- IOMDIVZAGXCCAC-UHFFFAOYSA-M diethyl-bis(prop-2-enyl)azanium;chloride Chemical group [Cl-].C=CC[N+](CC)(CC)CC=C IOMDIVZAGXCCAC-UHFFFAOYSA-M 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- LZPKOWNQYHIGGH-UHFFFAOYSA-N dimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;hydrogen sulfate Chemical group OS(O)(=O)=O.CN(C)CCCNC(=O)C(C)=C LZPKOWNQYHIGGH-UHFFFAOYSA-N 0.000 description 1
- ZMYRMZSAJVTETR-UHFFFAOYSA-N dimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical group Cl.CN(C)CCCNC(=O)C=C ZMYRMZSAJVTETR-UHFFFAOYSA-N 0.000 description 1
- OWMBTIRJFMGPAC-UHFFFAOYSA-N dimethylamino 2-methylprop-2-enoate Chemical group CN(C)OC(=O)C(C)=C OWMBTIRJFMGPAC-UHFFFAOYSA-N 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- OVHHHVAVHBHXAK-UHFFFAOYSA-N n,n-diethylprop-2-enamide Chemical compound CCN(CC)C(=O)C=C OVHHHVAVHBHXAK-UHFFFAOYSA-N 0.000 description 1
- YWWNNLPSZSEZNZ-UHFFFAOYSA-N n,n-dimethyldecan-1-amine Chemical compound CCCCCCCCCCN(C)C YWWNNLPSZSEZNZ-UHFFFAOYSA-N 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004344 phenylpropyl group Chemical group 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001523 phosphate polymer Polymers 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000962 poly(amidoamine) Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- NSETWVJZUWGCKE-UHFFFAOYSA-N propylphosphonic acid Chemical compound CCCP(O)(O)=O NSETWVJZUWGCKE-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000007652 sheet-forming process Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C3/00—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
- B05C3/02—Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/47—Condensation polymers of aldehydes or ketones
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08L57/06—Homopolymers or copolymers containing elements other than carbon and hydrogen
- C08L57/10—Homopolymers or copolymers containing elements other than carbon and hydrogen containing oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08L57/06—Homopolymers or copolymers containing elements other than carbon and hydrogen
- C08L57/12—Homopolymers or copolymers containing elements other than carbon and hydrogen containing nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (1)
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|---|---|---|---|
| US12/938,017 US8709207B2 (en) | 2010-11-02 | 2010-11-02 | Method of using aldehyde-functionalized polymers to increase papermachine performance and enhance sizing |
Publications (2)
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| TW201226659A TW201226659A (en) | 2012-07-01 |
| TWI582290B true TWI582290B (zh) | 2017-05-11 |
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Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US8088250B2 (en) | 2008-11-26 | 2012-01-03 | Nalco Company | Method of increasing filler content in papermaking |
| US9752283B2 (en) | 2007-09-12 | 2017-09-05 | Ecolab Usa Inc. | Anionic preflocculation of fillers used in papermaking |
| US8852400B2 (en) * | 2010-11-02 | 2014-10-07 | Ecolab Usa Inc. | Emulsification of alkenyl succinic anhydride with an amine-containing homopolymer or copolymer |
| US8636875B2 (en) * | 2011-01-20 | 2014-01-28 | Hercules Incorporated | Enhanced dry strength and drainage performance by combining glyoxalated acrylamide-containing polymers with cationic aqueous dispersion polymers |
| CN103132383B (zh) * | 2011-11-25 | 2017-04-12 | 纳尔科公司 | 在造纸中用于改善纸强度助剂性能的浆料预处理 |
| US8747616B2 (en) | 2012-09-12 | 2014-06-10 | Ecolab Usa Inc | Method for the emulsification of ASA with polyamidoamine epihalohydrin (PAE) |
| CN105026648B (zh) * | 2013-03-01 | 2017-12-08 | 巴斯夫欧洲公司 | 施胶剂水乳液 |
| ES2987934T3 (es) | 2013-03-13 | 2024-11-18 | Nalco Co | Método de uso de polímeros funcionalizados con aldehído para aumentar el rendimiento de la máquina para fabricar papel y mejorar el encolado |
| US9562326B2 (en) * | 2013-03-14 | 2017-02-07 | Kemira Oyj | Compositions and methods of making paper products |
| CN104746388B (zh) * | 2013-12-25 | 2018-05-08 | 艺康美国股份有限公司 | 一种提高高分子乳化剂乳化的asa 乳液的施胶效果的方法 |
| US9567708B2 (en) | 2014-01-16 | 2017-02-14 | Ecolab Usa Inc. | Wet end chemicals for dry end strength in paper |
| US9920482B2 (en) | 2014-10-06 | 2018-03-20 | Ecolab Usa Inc. | Method of increasing paper strength |
| US9702086B2 (en) | 2014-10-06 | 2017-07-11 | Ecolab Usa Inc. | Method of increasing paper strength using an amine containing polymer composition |
| US9689115B2 (en) * | 2014-12-26 | 2017-06-27 | Westrock Mwv, Llc | Sizing of paperboard |
| CN106317421B (zh) * | 2015-06-19 | 2019-09-10 | 上海东升新材料有限公司 | 一种高性能阳离子松香胶及其制备方法 |
| CN107849821B (zh) | 2015-08-06 | 2021-12-14 | 艺康美国股份有限公司 | 用于纸张强度和脱水的醛官能化聚合物 |
| CN106917324B (zh) | 2015-12-25 | 2019-11-08 | 艺康美国股份有限公司 | 一种造纸施胶方法及其制备的纸张 |
| KR102063409B1 (ko) * | 2015-12-25 | 2020-01-07 | 세이코 피엠씨 가부시키가이샤 | 폴리아크릴아미드계 제지용 첨가제 및 그의 제조 방법, 및 종이의 제조 방법 |
| US10006171B2 (en) * | 2016-04-25 | 2018-06-26 | Ecolab Usa Inc. | Methods and compositions for enhancing sizing in papermaking process |
| US10648133B2 (en) | 2016-05-13 | 2020-05-12 | Ecolab Usa Inc. | Tissue dust reduction |
| WO2021102266A1 (en) | 2019-11-22 | 2021-05-27 | Ecolab Usa Inc. | Di alkenyl succinic amide acids and processes for making and using same |
| CN118480984A (zh) * | 2023-07-25 | 2024-08-13 | 上海君周化工科技有限公司 | 一种烯基琥珀酸酐乳化施胶剂及其制备方法与应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0151994A2 (en) * | 1984-01-27 | 1985-08-21 | Nalco Chemical Company | Method of preparing an improved sizing agent and novel paper sizing method |
| US6238521B1 (en) * | 1996-05-01 | 2001-05-29 | Nalco Chemical Company | Use of diallyldimethylammonium chloride acrylamide dispersion copolymer in a papermaking process |
| US20060142535A1 (en) * | 2004-12-21 | 2006-06-29 | Shane Cyr | Reactive cationic resins for use as dry and wet strength agents in sulfite ion-containing papermaking systems |
| US7641766B2 (en) * | 2004-01-26 | 2010-01-05 | Nalco Company | Method of using aldehyde-functionalized polymers to enhance paper machine dewatering |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982749A (en) | 1957-07-15 | 1961-05-02 | Dow Chemical Co | Inverse suspension polymerization of water soluble unsaturated monomers |
| US3284393A (en) | 1959-11-04 | 1966-11-08 | Dow Chemical Co | Water-in-oil emulsion polymerization process for polymerizing watersoluble monomers |
| US3556932A (en) * | 1965-07-12 | 1971-01-19 | American Cyanamid Co | Water-soluble,ionic,glyoxylated,vinylamide,wet-strength resin and paper made therewith |
| US3734873A (en) | 1970-12-15 | 1973-05-22 | Nalco Chemical Co | Rapid dissolving water-soluble polymers |
| US4240935A (en) * | 1978-12-22 | 1980-12-23 | Hercules Incorporated | Ketene dimer paper sizing compositions |
| JPS60246893A (ja) * | 1984-01-27 | 1985-12-06 | ナルコ ケミカル カンパニ− | サイズ剤の調製方法 |
| US4657946A (en) | 1984-06-25 | 1987-04-14 | Nalco Chemical Company | Paper sizing method and emulsion |
| US4605702A (en) | 1984-06-27 | 1986-08-12 | American Cyanamid Company | Temporary wet strength resin |
| CA1267483A (en) | 1984-11-19 | 1990-04-03 | Hisao Takeda | Process for the production of a water-soluble polymer dispersion |
| US4603176A (en) | 1985-06-25 | 1986-07-29 | The Procter & Gamble Company | Temporary wet strength resins |
| US4919821A (en) | 1986-03-21 | 1990-04-24 | Nalco Chemical Company | Modified maleic anhydride polymers and the like for use as scale inhibitors |
| JPH0651755B2 (ja) | 1988-10-14 | 1994-07-06 | ハイモ株式会社 | 水溶性カチオンポリマー分散液の製造方法 |
| US5147908A (en) | 1990-09-24 | 1992-09-15 | Sequa Chemicals Inc. | Cationic polyvinyl alcohol binder additive |
| SE9103140L (sv) * | 1991-10-28 | 1993-04-29 | Eka Nobel Ab | Hydrofoberat papper |
| US5571380A (en) | 1992-01-08 | 1996-11-05 | Nalco Chemical Company | Papermaking process with improved retention and maintained formation |
| ES2126018T3 (es) | 1993-06-04 | 1999-03-16 | Nalco Chemical Co | Procedimiento de polimerizacion de dispersiones. |
| US5597858A (en) | 1993-06-10 | 1997-01-28 | Nalco Chemical Company | Hydrophobically associating dispersants used in forming polymer dispersions |
| AU8024794A (en) | 1993-12-09 | 1995-06-15 | Nalco Chemical Company | An improved process for the preparation of water soluble polymer dispersion |
| US6133368A (en) | 1993-12-09 | 2000-10-17 | Nalco Chemical Company | Seed process for salt dispersion polymer |
| US6610209B1 (en) | 1994-12-27 | 2003-08-26 | Ondeo Nalco Company | Use of polymers containing vinylamine/vinylformamide for the treatment of food processing wastewater |
| US5654198A (en) * | 1995-06-05 | 1997-08-05 | National Starch And Chemical Investment Holding Corporation | Detectable water-treatment polymers and methods for monitoring the concentration thereof |
| US5674362A (en) * | 1996-02-16 | 1997-10-07 | Callaway Corp. | Method for imparting strength to paper |
| US5837776A (en) | 1996-03-20 | 1998-11-17 | Nalco Chemical Company | Process for producing water soluble anionic dispersion polymers |
| US5605970A (en) | 1996-03-20 | 1997-02-25 | Nalco Chemical Company | Synthesis of high molecular weight anionic dispersion polymers |
| US6013708A (en) | 1996-10-03 | 2000-01-11 | Cytec Technology Corp. | Cationic water-soluble polymer precipitation in salt solutions |
| DE19654390A1 (de) | 1996-12-27 | 1998-07-02 | Basf Ag | Verfahren zur Herstellung von Papier |
| US6426383B1 (en) | 1997-05-28 | 2002-07-30 | Nalco Chemical Company | Preparation of water soluble polymer dispersions from vinylamide monomers |
| US5985992A (en) | 1997-12-10 | 1999-11-16 | Cytec Technology Corp. | Anionic polymer products and processes |
| AU3217399A (en) | 1998-03-31 | 1999-10-18 | Callaway Corporation | Improving retention and drainage in alkaline fine paper |
| US6491790B1 (en) | 1998-09-10 | 2002-12-10 | Bayer Corporation | Methods for reducing amine odor in paper |
| CO5180563A1 (es) | 1999-01-25 | 2002-07-30 | Kimberly Clark Co | Polimeros de vinilo modificados que contienen medios de hidrocarbono anfifilico de y el metodo para su fabricacion |
| US6315866B1 (en) * | 2000-02-29 | 2001-11-13 | Nalco Chemical Company | Method of increasing the dry strength of paper products using cationic dispersion polymers |
| EP1314822A1 (en) * | 2001-11-19 | 2003-05-28 | Akzo Nobel N.V. | Process for sizing paper and sizing composition |
| US7119148B2 (en) | 2004-02-25 | 2006-10-10 | Georgia-Pacific Resins, Inc. | Glyoxylated polyacrylamide composition strengthening agent |
| US7488403B2 (en) | 2004-08-17 | 2009-02-10 | Cornel Hagiopol | Blends of glyoxalated polyacrylamides and paper strengthening agents |
| US7034087B2 (en) | 2004-08-17 | 2006-04-25 | Georgia-Pacific Resins, Inc. | Aldehyde scavengers for preparing temporary wet strength resins with longer shelf life |
| US7897013B2 (en) | 2004-08-17 | 2011-03-01 | Georgia-Pacific Chemicals Llc | Blends of glyoxalated polyacrylamides and paper strengthening agents |
| US7455751B2 (en) | 2005-04-15 | 2008-11-25 | Nalco Company | Use of alkenyl succinic anhydride compounds derived from symmetrical olefins in internal sizing for paper production |
| US7550060B2 (en) | 2006-01-25 | 2009-06-23 | Nalco Company | Method and arrangement for feeding chemicals into a process stream |
| US7938934B2 (en) | 2006-01-25 | 2011-05-10 | Nalco Company | ASA emulsification with ultrasound |
| CN100507148C (zh) * | 2006-06-23 | 2009-07-01 | 华章电气（桐乡）有限公司 | 一种多层喷雾纸张表面施胶方法 |
| US7875676B2 (en) | 2006-09-07 | 2011-01-25 | Ciba Specialty Chemicals Corporation | Glyoxalation of vinylamide polymer |
| CN101688370A (zh) * | 2007-05-09 | 2010-03-31 | 巴科曼实验室国际公司 | 用于纸或纸板的烯基琥珀酸酐施胶乳液 |
| WO2008157321A2 (en) | 2007-06-15 | 2008-12-24 | Buckman Laboratories International, Inc. | High solids glyoxalated polyacrylamide |
| US8288502B2 (en) | 2009-12-18 | 2012-10-16 | Nalco Company | Aldehyde-functionalized polymers with enhanced stability |
-
2010
- 2010-11-02 US US12/938,017 patent/US8709207B2/en active Active
-
2011
- 2011-10-12 TW TW100136901A patent/TWI582290B/zh active
- 2011-11-01 CA CA2816565A patent/CA2816565C/en active Active
- 2011-11-01 CN CN201180023819.4A patent/CN102892832B/zh active Active
- 2011-11-01 MX MX2013004955A patent/MX351556B/es active IP Right Grant
- 2011-11-01 BR BR112013010635-2A patent/BR112013010635B1/pt active IP Right Grant
- 2011-11-01 KR KR1020137011361A patent/KR101789526B1/ko active Active
- 2011-11-01 EP EP11838677.0A patent/EP2635634B1/en not_active Revoked
- 2011-11-01 MY MYPI2013001543A patent/MY163925A/en unknown
- 2011-11-01 RU RU2013119833/05A patent/RU2595681C2/ru active
- 2011-11-01 AU AU2011323531A patent/AU2011323531B2/en active Active
- 2011-11-01 ES ES11838677.0T patent/ES2627435T3/es active Active
- 2011-11-01 JP JP2013537764A patent/JP5925794B2/ja active Active
- 2011-11-01 WO PCT/US2011/058783 patent/WO2012061384A2/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0151994A2 (en) * | 1984-01-27 | 1985-08-21 | Nalco Chemical Company | Method of preparing an improved sizing agent and novel paper sizing method |
| US6238521B1 (en) * | 1996-05-01 | 2001-05-29 | Nalco Chemical Company | Use of diallyldimethylammonium chloride acrylamide dispersion copolymer in a papermaking process |
| US7641766B2 (en) * | 2004-01-26 | 2010-01-05 | Nalco Company | Method of using aldehyde-functionalized polymers to enhance paper machine dewatering |
| US20060142535A1 (en) * | 2004-12-21 | 2006-06-29 | Shane Cyr | Reactive cationic resins for use as dry and wet strength agents in sulfite ion-containing papermaking systems |
Also Published As
| Publication number | Publication date |
|---|---|
| US8709207B2 (en) | 2014-04-29 |
| EP2635634B1 (en) | 2017-03-22 |
| TW201226659A (en) | 2012-07-01 |
| WO2012061384A2 (en) | 2012-05-10 |
| CA2816565A1 (en) | 2012-05-10 |
| RU2013119833A (ru) | 2014-12-10 |
| KR20140027054A (ko) | 2014-03-06 |
| CA2816565C (en) | 2020-08-04 |
| AU2011323531B2 (en) | 2017-02-02 |
| AU2011323531A1 (en) | 2013-05-23 |
| MY163925A (en) | 2017-11-15 |
| JP5925794B2 (ja) | 2016-05-25 |
| MX351556B (es) | 2017-10-19 |
| EP2635634A4 (en) | 2015-10-21 |
| WO2012061384A3 (en) | 2012-07-19 |
| MX2013004955A (es) | 2013-06-28 |
| US20120103547A1 (en) | 2012-05-03 |
| BR112013010635B1 (pt) | 2020-12-08 |
| JP2013543067A (ja) | 2013-11-28 |
| KR101789526B1 (ko) | 2017-10-25 |
| ES2627435T3 (es) | 2017-07-28 |
| EP2635634A2 (en) | 2013-09-11 |
| AU2011323531A9 (en) | 2017-02-09 |
| CN102892832A (zh) | 2013-01-23 |
| RU2595681C2 (ru) | 2016-08-27 |
| BR112013010635A2 (pt) | 2016-08-09 |
| CN102892832B (zh) | 2016-01-20 |
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